4012 results about "Perovskite" patented technology

The invention discloses a green preparation process of a microwave-assisted synthesized perovskite semiconductor material, which aims at solving the problems of long reaction period, large reagent dosage, heavy pollution and the like of the traditional perovskite preparation process, adopts a novel organic-inorganic hybrid precursor and green solvent system, and accelerates the reaction by microwave radiation. The rapid and environment-friendly synthesis of the material is realized by accurately regulating and controlling microwave parameters and combining multiple processes such as intermittent and collaborative ultrasonic processes. Novel compounds such as nitrogen-containing heterocyclic borate and organic phosphonate are introduced to optimize the performance of the material. The process significantly shortens the preparation period, reduces reagent consumption, improves photoelectric properties, and enhances material stability.

The invention discloses an on-line detection method and system for etching quality of a laser perovskite cell, and the method comprises the steps: employing a double-camera alternate working mode, installing high-resolution CCD camera assemblies at two sides of a laser processing head in an X direction, eliminating the shielding of a motion direction, carrying out the scribing quality analysis through combining the submicron optical imaging of the CCD camera assemblies with an image processing algorithm, and carrying out the detection of the etching quality of the laser perovskite cell. According to the method, local adaptive threshold segmentation is put forward, an Otsu method is used for adaptively calculating a binarization threshold, a morphological opening operation is used for removing irrelevant information, an edge searching logic algorithm is used for searching two edges of a scribed line, finally, the two edges and a center line are fitted, and scribed line quality analysis is carried out through the three lines. And real-time power adjustment, position calibration and defect position marking are carried out by detecting the scribing quality, the calculation speed of the high-resolution optical detection system is high, detection can be carried out while machining is carried out, and machining-detection-correction closed-loop control is achieved.

The invention relates to the technical field of solar cells, and provides a laminated cell and a manufacturing method thereof, which are at least beneficial to improving the efficiency of the laminated cell. The laminated cell comprises a crystalline silicon bottom cell, a middle layer and a perovskite top cell which are sequentially laminated in a preset direction, the middle layer comprises a conductive composite layer, the conductive composite layer is located on the surface, facing the perovskite top cell, of the crystalline silicon bottom cell, and materials of the conductive composite layer comprise a conductive polymer and a metal dopant; the metal grid layer is embedded into one side, far away from the crystalline silicon bottom battery, of the conductive composite layer, and the conductive composite layer exposes the surface, far away from the conductive composite layer, of the metal grid layer; the barrier layer is located on the side, away from the composite layer, of the metal grid layer and covers the surfaces of the metal grid layer and the conductive composite layer.

The invention relates to the technical field of solar cell module packaging, in particular to a packaging structure for a perovskite-back contact crystalline silicon laminated solar cell and a preparation method of the packaging structure. The packaging structure comprises a front light conversion glass layer, a perovskite top cell layer, an infrared light-transmitting adhesive film layer, a back contact crystal silicon bottom cell layer, an adhesive film layer and a packaging bottom plate which are arranged in sequence, and butyl rubber surrounding the perovskite top cell layer, the infrared light-transmitting adhesive film layer, the back contact crystal silicon bottom cell layer and the adhesive film layer is arranged between the front light conversion glass layer and the packaging bottom plate, and the near infrared transmittance of 780 nm to 1100 nm in the infrared transparent adhesive film layer is 93% to 100%. According to the packaging structure based on the front light conversion glass layer and the infrared light-transmitting adhesive film layer, regulation and control of short-wave ultraviolet and near-infrared spectrums are considered, and the photoelectric property and reliability of the perovskite-crystalline silicon four-terminal laminated device are remarkably improved.

The embodiment of the invention discloses an etching method, an etching device and a solar cell module. The etching method comprises the following steps: controlling a light spot overlapping rate to be smaller than a preset overlapping rate; generating laser with preset performance parameters; shaping the laser into rectangular flat-topped light; and focusing the rectangular flat-topped light into a light spot with a preset size, and etching the perovskite functional layer in the to-be-etched cell according to the light spot overlapping rate. According to the technical scheme provided by the embodiment of the invention, the etching method is set, the perovskite functional layer is etched by adopting point contact, the laser beam adopts rectangular flat-topped light, each pulse independently acts on the film layer, single-pulse etching is performed on the perovskite functional layer in the to-be-etched cell, heat accumulation in an optical pulse overlapping region is avoided, and electrode deposition is more facilitated.

The invention discloses an A-site high-entropy solid oxide fuel cell cathode material as well as a preparation method and application thereof, and provides an A-site high-entropy solid oxide fuel cell cathode material Pr < 0.2 > M < 0.2 > La < 0.2 > Ba < 0.2 > Sr < 0.2 > Co < 0.8 > Fe < 0.2 > O < 3-delta > with a perovskite phase. The preparation method comprises the following steps: S1, weighing multi-element metal nitrates, and mixing to obtain a first mixed solution; s2, dissolving ethylenediamine tetraacetic acid in ammonia water to obtain a second mixed solution; mixing the first mixed solution, the second mixed solution and citric acid to form a mixed precursor solution; s3, carrying out second heating treatment on the mixed precursor solution, and adjusting the pH value to form a gel precursor; and S4, carrying out pre-sintering treatment, third heat treatment and calcination treatment on the gel precursor to obtain a high-grade powder precursor, and carrying out ball milling and sieving treatment to obtain the A-site high-entropy solid oxide fuel cell cathode material. The cathode material is high in stability and good in chemical compatibility with a barrier layer GDC, provides high-quality mass transfer channels and active sites for O2 / O- / O2-, and has good electrochemical performance at medium and low temperatures.

The utility model discloses a perovskite cell assembly and a solar cell. The perovskite battery assembly comprises at least two perovskite batteries which are electrically connected. The perovskite battery assembly comprises a substrate, a bottom electrode layer, a perovskite functional layer, a top electrode layer and an isolation part, the bottom electrode layer is located on the surface of the substrate, and the bottom electrode layer is provided with a through first scribing groove; the perovskite functional layer is located on one side, far away from the substrate, of the bottom electrode layer, and the perovskite functional layer is provided with a second scribing groove; the top electrode layer is located on the side, away from the bottom electrode layer, of the perovskite functional layer, the top electrode layer is provided with a third scribed line groove, and the third scribed line groove penetrates through the top electrode layer and the perovskite functional layer; and the isolation part is filled in the third scribing groove. According to the technical scheme of the embodiment of the utility model, the risk of internal short circuit of the perovskite cell can be reduced, and the production yield of the perovskite cell assembly is improved.

The invention provides a perovskite thin film and a preparation method thereof, and belongs to the technical field of perovskite thin films, and the preparation method comprises the following steps: S1, preparing modified octa (aminophenyl trioxosilane); s2, preparing a precursor solution; and S3, spin-coating the pretreated substrate with the precursor solution, dropwise adding ethyl acetate at the same time, performing illumination treatment under ultraviolet light, and then immediately performing micro-vibration and curing annealing on the substrate to obtain the perovskite thin film. According to the perovskite thin film obtained by the invention, the purposes of synchronously increasing the open-circuit voltage and the filling factor of a solar cell, improving the photoelectric conversion efficiency and enhancing the long-term stability can be achieved.

The invention discloses an anti-interference resistance detection circuit board and system based on four-wire system measurement, and relates to the technical field of industrial automatic detection. Aiming at the problems of low measurement precision, weak interference resistance and limited channel expansion of a traditional two-wire system, a current loop and a voltage sampling loop which are independently and electrically isolated are adopted, and a lead resistance error is eliminated through Kelvin connection; an EMI filter, a photoelectric coupler and a double-layer shielding cable are integrated, so that the influence of electromagnetic interference and a ground loop is inhibited; a single circuit board supports the parallel connection of at least two measuring units, realizes the cascade connection of multiple boards by combining an EtherCAT bus, and supports 384 channels at most. The measuring error is smaller than or equal to + / -0.1%, the single-channel detection time is smaller than or equal to 10 ms, the requirements of high-density and high-beat scenes such as perovskite photovoltaic glass are met, the method is suitable for 100-100 Momega wide-range resistance measurement, the signal transmission error rate in the industrial strong electromagnetic environment is extremely low, and the detection precision and the system reliability are remarkably improved.

The invention is suitable for the technical field of inorganic luminescent materials, and provides a fluorescent powder material based on a double-perovskite structure and a preparation method and application thereof. The general chemical formula of the fluorescent powder is Ca2AlNbO6: xEu < 3 + >, wherein x is a molar fraction of 0.06 to 0.30; the excitation spectrum coverage range of the fluorescent powder under the condition of monitoring the emission wavelength of 615 nm is 260-500 nm, and the emission main peak is located at 615 nm; when x is equal to 0.18, the quantum efficiency under the excitation of 396nm ultraviolet light is greater than or equal to 91%, and the red light emission ratio is greater than or equal to 85%. According to the invention, Ca2AlNbO6 double perovskite is taken as a substrate, and a red fluorescent powder material with wide-spectrum excitation and high quantum efficiency is designed through Eu < 3 + > high-concentration doping and local symmetry regulation and control design engineering, so that the characteristics of high quantum efficiency, efficient red light emission, wide-spectrum excitation and excellent concentration quenching resistance are realized.

The invention discloses a method for preparing a fluorescent material based on a waste NCM ternary lithium battery and application of the fluorescent material, and the preparation method of the fluorescent material comprises the following steps: disassembling the waste NCM ternary lithium battery to obtain a nickel cobalt lithium manganate waste material and preparing the nickel cobalt lithium manganate waste material into powder; impurities and part of ions in the nickel cobalt lithium manganate waste powder are removed, and manganese-containing powder is prepared; and mixing manganese-containing powder, a first perovskite fluorescent raw material, a ligand, a protective material and a solvent, heating and stirring under a vacuum condition, heating under a nitrogen atmosphere, adding a second perovskite fluorescent raw material solution into the system for reaction, and cooling after the reaction is finished to obtain the manganese-doped perovskite fluorescent material. According to the method, the efficient recycling of the waste NCM ternary lithium battery is realized, the preparation cost of the fluorescent material is reduced, the resource recycling rate is improved, the environmental pollution is reduced, and the manganese-doped perovskite fluorescent material is simple to operate when chloride ions are detected after being loaded on the carrier and can be used for field detection.

The application relates to a linear NTC thermistor material LaMnO3-Al2O3 and a preparation method thereof, and belongs to the technical field of NTC thermistor materials. The linear NTC thermistor material LaMnO3-Al2O3 is composed of a Mn-based perovskite LaMnO3 and Al2O3, and the mole fraction of the Al2O3 accounts for 10-30% of the total mole fraction of the system. The material is prepared by ball milling, drying, sieving, pressing and sintering of the Mn-based perovskite LaMnO3 and the Al2O3. The NTC thermistor material LaMnO3-Al2O3 has a linear resistance-temperature characteristic in the range of 30 DEG C-65 DEG C, and the linearity reaches more than 99.6%. The linear NTC thermistor material can make the working circuit more simple and the whole system operation more simple and reliable.

The invention provides a method for improving the illumination stability of perovskite through post-treatment. The method comprises the following steps: S1, preparing a perovskite illuminant; s2, grinding and diffusing; and S3, inducing exposure and passivation of photoinduced defects. According to the invention, the light stability of the perovskite illuminant synthesized in a temperature solid state can be improved, so that the perovskite illuminant is applicable to wider application fields.

The invention discloses a high-entropy relaxation type lead-free perovskite ceramic and a preparation method thereof. The high-entropy relaxation type lead-free perovskite ceramic is a solid solution of Na < 0.2 > Bi < 0.2 > Ba < 0.2 > Sr < 0.2 > Ca < 0.2 >) TiO3 and (K < 0.5 > Na < 0.5 >) NbO3; the content of the (K0. 5Na0. 5) NbO3 accounts for 5 to 15 mol percent of the high-entropy relaxation type lead-free perovskite ceramic. By introducing (K0. 5Na0. 5) NbO3, energy band regulation and relaxation behavior adjustment are effectively realized, the breakdown electric field intensity is remarkably improved, the energy storage performance is improved, good stability is kept under the conditions of temperature, frequency and a circulating electric field, and the actual requirements of a pulse power capacitor on a high-performance and long-life energy storage dielectric material are met.

The invention belongs to the technical field of solar cells, and relates to a perovskite laminated cell and a preparation method thereof, the perovskite laminated cell can reduce light parasitic absorption, the perovskite laminated cell comprises a bottom crystalline silicon cell, the bottom crystalline silicon cell comprises a substrate, the substrate comprises a first surface and a second surface which are opposite to each other, a first tunneling oxide layer and a first composite passivation layer are sequentially arranged on the first surface in the direction perpendicular to and away from the first surface, and the first composite passivation layer comprises first doped crystalline silicon conductive regions and first wide-band gap conductive regions which are alternately arranged in the direction parallel to the first surface; the top perovskite cell is arranged on the first composite passivation layer and is electrically connected with the bottom crystalline silicon cell, and the top perovskite cell comprises a hole transport layer, a perovskite active absorption layer, an electron transport layer, an interface buffer layer, a transparent conductive layer and an anti-reflection layer which are sequentially far away from the first composite passivation layer; and a first electrode in electrical contact with the transparent conductive layer.

The invention provides a preparation method of a laminated cell, the laminated cell and a photovoltaic module, and can be widely applied to the photovoltaic technical field, the preparation method of the laminated cell comprises the following steps: providing a bottom cell, and forming a composite layer on the bottom cell; a first transmission layer is formed on the composite layer, and a skeleton layer is formed on the first transmission layer through double-source evaporation; wherein a first evaporation source of the double-source evaporation comprises inorganic cesium salt, and a second evaporation source of the double-source evaporation comprises inorganic lead salt and inorganic rubidium salt; coating organic salt on the framework layer to form a perovskite layer; forming a second transmission layer and an electrode on the perovskite layer to obtain a laminated cell; wherein carriers of the first transmission layer and the second transmission layer are different. The framework layer is formed through double-source evaporation, the proportion is better controlled, through rubidium and lead, a positive effect can be generated on crystallization, stress release and the like of perovskite in the crystallization process, part of rubidium salt can be combined with PbI2 decomposed on the surface, ion migration is reduced, and the device stability is improved.

The utility model discloses an integrated assembly machine for a perovskite component before lamination. The integrated assembly machine comprises a component conveying line, and an adhesive tape pasting station, a bus bar pasting station, a drainage tape pasting station and a butyl rubber pasting station which are sequentially arranged along the conveying direction of the component conveying line, the adhesive tape pasting station, the bus bar pasting station, the drainage belt pasting station and the butyl rubber pasting station are each provided with a jacking mechanism for jacking a photovoltaic module and a correcting mechanism for correcting the photovoltaic module, and the adhesive tape pasting station is provided with an adhesive tape pasting device above the module conveying line. A bus bar pasting device is arranged at the position, above the assembly conveying line, of the bus bar pasting station, a drainage belt pasting device is arranged at the position, above the assembly conveying line, of the drainage belt pasting station, and a butyl rubber pasting device is arranged at the position, above the assembly conveying line, of the butyl rubber pasting station. According to the utility model, the overall length of the assembly machine is shortened, and the production efficiency is also improved.

The invention relates to a black-phase all-inorganic perovskite flexible thick film stable at room temperature and a preparation method and application thereof, and the preparation method comprises the following steps: uniformly mixing PbI2, CsI and an organic ammonium salt in an organic solvent to obtain a perovskite precursor solution; filling a polymer filter membrane with the perovskite precursor solution through a vacuum filtration method to obtain a wet flexible thick membrane; the polymer filter membrane is cleaned, and the thickness is 50 microns or above; and carrying out gradient annealing on the wet flexible thick film to obtain the black-phase all-inorganic perovskite flexible thick film which is stable at room temperature. According to the invention, low-dimensional perovskite induced lattice distortion is formed by adding A-site cations, and the flexible thick film which is thermodynamically stable and uniform at room temperature is obtained based on a solvent suction filtration method by regulating and controlling the addition amount of organic ammonium salt and gradient annealing and regulating and controlling the proportion of residual organic ammonium salt of lattices, and is applied to an X-ray detector. High [mu] [tau] product and high sensitivity are realized, and good flexible detection performance is shown.

The invention relates to a preparation method of a local ITO interconnected perovskite-TOPCon laminated cell, which comprises the following steps: taking an n-type monocrystalline silicon wafer as a substrate, cleaning and texturing, diffusing boron on the back to form a P + emitter, oxidizing at high temperature, and treating the surface through acid etching and alkali polishing; sequentially preparing a tunneling oxide layer and a phosphorus-doped polycrystalline silicon layer on the front surface, annealing and crystallizing, depositing an aluminum oxide film and a multi-layer silicon nitride film on the back surface after cleaning, and depositing a single-layer silicon nitride film on the front surface; preparing a back metal electrode, etching according to a designed pattern to remove a local silicon nitride film on the front surface, sequentially preparing an ITO interconnection layer, a hole transport layer, a perovskite layer, a passivation layer, an electron transport layer and an ITO transparent conductive layer on the front surface, and finally preparing a front metal electrode and solidifying to form a contact electrode. According to the invention, the problems of back corrosion risk, effective area loss and tedious process in the existing method are solved, full-size manufacturing is realized, the cell performance is improved, and industrialization is easier.

The invention relates to (i) a photovoltaic cell, comprising: an absorber layer comprising a perovskite material; and an ultrathin hole-transport layer; (ii) a photovoltaic cell comprising an absorber layer comprising perovskite material, a 5 hole transport layer and a protective layer located between the absorber layer and the hole transport layer, the protective layer having a valence band with an energy level that is between the energy levels of the valence bands of the absorber layer and the hole transport layer; and (iii) a photovoltaic cell comprising a barrier layer located between inner cell layers and an electrode and configured to suppress 0 diffusion of metal from the electrode into the inner layers. Also disclosed are methods of fabricating said photovoltaic cells and methods of fabricating a doped precursor for use in fabricating a photovoltaic cell.

A solar cell includes a first photoelectric conversion part, a second photoelectric conversion part, a side insulating layer, a first electrode, and a second electrode. The first photoelectric conversion part includes a photoelectric conversion layer composed of a perovskite compound, a first transport layer on one side of the photoelectric conversion layer, and a second transport layer on the other side of the photoelectric conversion layer. The second photoelectric conversion part is arranged below the second transport layer and has a different material or structure from the first photoelectric conversion part. The side insulating layer is formed as a side surface surrounding the first photoelectric conversion part. The first electrode is electrically connected to the first photoelectric conversion part on one surface of the first photoelectric conversion part serving as a light-receiving surface. The second electrode is electrically connected to a bottom of the second photoelectric conversion part.

The invention provides a high-dielectric low-loss X7P type dielectric ceramic material and a preparation method and application thereof, and relates to the technical field of functional ceramic materials, the dielectric ceramic material is composed of a perovskite type compound as a main component and an auxiliary component; wherein the perovskite type compound contains a Ba element and a Ti element, and the auxiliary components comprise a first auxiliary component containing an Mg element, a second auxiliary component containing SiO2, a third auxiliary component containing an Mn element and a fourth auxiliary component containing a rare earth element R. According to the invention, barium titanate is doped and modified, so that the excellent performance of combining different compounds is realized, the dielectric constant and temperature stability of the dielectric ceramic material are improved, and the dielectric loss is reduced.

The invention relates to the field of quantum dot materials, in particular to a bismuth-based lead-free perovskite quantum dot material and a preparation method and application thereof. The invention discloses a preparation method of a bismuth-based lead-free perovskite quantum dot material, which is characterized by comprising the following steps of: 1, weighing bismuth salt and salt containing halide ions, adding the bismuth salt and the salt containing halide ions into a good solvent, then adding ionic liquid, and uniformly stirring to obtain a precursor solution; 2, heating the precursor solution, rapidly injecting the precursor solution into an anti-solvent, and violently stirring for 5-15 minutes; and then cooling, precipitating, centrifuging, washing and dispersing in methylbenzene to obtain a quantum dot solution. The bismuth-based lead-free perovskite quantum dot material prepared by the invention has high quantum yield, good stability and excellent photoelectric properties, and can meet the application requirements of various photoelectric devices.

The invention relates to the technical field of perovskite thin film detection, in particular to a perovskite blade coating thin film defect detection device and method based on real-time visual monitoring, and the device comprises a support, an image acquisition unit, an illumination unit and a self-adaptive adjustment system which are arranged in a glove box and located at a coating machine, a flash evaporation box and a heating stage respectively; the camera and the lens are installed on the adjusting frame, and the first driving piece achieves height adjustment. The light source is installed on the supporting frame and controlled by the second driving piece to ascend and descend. The image analysis unit evaluates the definition, contrast and illumination uniformity of the acquired image, and the control unit automatically adjusts the height and angle of the light source and the position of the camera according to the result so as to keep the image quality stable; according to the scheme, real-time monitoring is carried out in the working procedures of coating, flash evaporation, heat treatment and the like, the comprehensiveness, real-time performance and accuracy of thin film detection are effectively improved, influences caused by environmental fluctuation are avoided, and the accuracy and consistency of defect recognition are guaranteed.

An energy harvesting device is provided. The device includes a patterned graphene sheet arranged on a substrate, wherein the graphene sheet contains channels; a perovskite composition arranged on the graphene sheet, wherein the perovskite composition conforms to the channels of the graphene sheet; and a luminescent material composition or a 2D material composition arranged on the perovskite composition. The device is configured to convert electromagnetic radiation and / or thermal energy to an electrical signal.

The invention provides a packaging adhesive film for a perovskite assembly and a photovoltaic assembly and application thereof. The adhesive film comprises organic ammonium salt and a packaging adhesive film base material, wherein the organic ammonium salt is selected from one or more of diammonium halogen ammonium salt, phenyl halogen ammonium salt and thiophene halogen ammonium salt. According to the invention, the organic ammonium salt is used as the passivation material and is combined with the adhesive film matrix material to prepare the packaging adhesive film, so that the process step of post-passivation of the perovskite assembly and corresponding expensive vacuum equipment can be omitted, and the packaging cost is greatly reduced while the service life of the perovskite assembly is prolonged.

The invention discloses a preparation method of a perovskite thin film and a perovskite cell, and relates to the technical field of solar cells. The preparation method of the perovskite thin film comprises the following steps: forming a mixed layer containing PbI2 on a substrate as a metal halide framework layer; coating the metal halide framework layer with an organic ammonium salt solution containing a crystallization regulating agent to obtain a first device; wherein the crystallization regulating agent contains a guanidine group; and carrying out annealing treatment on the first device to obtain the perovskite thin film. According to the perovskite thin film, the problems that perovskite prepared in the prior art is small in grain size and uneven in interface can be solved, and the performance of the perovskite thin film is improved.

The invention belongs to the technical field of catalytic materials and hydrocarbon reforming, and particularly relates to a high-entropy catalyst as well as a preparation method and application thereof. The preparation method comprises the following steps: mixing a metal salt solution containing lanthanum, chromium, copper, zinc, manganese, nickel, iron and cobalt ions with a chelating agent and a dispersing agent for reaction, carrying out ultrasonic cavitation treatment to obtain sol, adjusting the pH value, gelatinizing under an oil bath heating condition to obtain a colloidal precursor, drying, and calcining in an air atmosphere to obtain a perovskite type high-entropy oxide precursor; and then treating in a reducing atmosphere to obtain the FeZnCuNiCo perovskite type high-entropy alloy catalyst which contains metal components of La, Cr, Ni, Mn, Fe, Zn, Cu and Co and takes a multi-metal alloy active center of Fe-Zn-Cu-Ni-Co as a main component. The high-entropy catalyst can meet the harsh requirements of high temperature, strong carbon deposition driving force and long-period operation in a propane dry reforming reaction, and is suitable for industrial application scenarios of continuous production of high-temperature synthesis gas.

The invention relates to a sodium electrode layered oxide and a preparation method and application thereof. The sodium electrode layered oxide comprises a positive electrode material and a coating layer on the particle surface of the positive electrode material, the coating layer comprises perovskite and sodium metaaluminate. The sodium electrode layered oxide provided by the invention has a uniform composite coating layer comprising perovskite and sodium metaaluminate, and by combining interface gradient doping, the cycling stability of a positive electrode material under high voltage can be remarkably improved.

The present invention generally relates to a field of material science and chemistry. Specifically, the present invention relates to synthesis and characterization of lead-free hybrid organic-inorganic Perovskite compounds for metal ion sensing applications. More particularly, the present invention relates to lead-free low dimensional manganese (Mn)- and copper (Cu)- based hybrid organic-inorganic perovskites (HOIPs) for visual fluorometric Pb2+ ion detection. Further, the present invention relates to synthesis of lead-free low dimensional manganese (Mn)- and copper (Cu)-based hybrid organic-inorganic perovskites (HOIPs) via mechanochemical synthesis methodology.