The invention discloses a
near ultraviolet excited cyan fluorescent material as well as a preparation method and application thereof, and belongs to the technical field of luminescent materials. The general
chemical formula of the fluorescent material is CaLu2-xScZrAl3O12: xCe < 3 + >, x is the
doping molar concentration of Ce < 3 + >, and x is larger than or equal to 0.005 and smaller than or equal to 0.12. The material is prepared by adopting a high-temperature
solid-
phase method, the process is simple, and the cost is low. The material has a wide excitation band in a
near ultraviolet to
blue light region of 320-475 nm, the
peak value is 420 nm, and the wide excitation band is highly matched with the
emission spectrum of a commercial
near ultraviolet LED
chip; under the excitation of 420 nm light, strong
broadband cyan light with the central
wavelength of 500 nm and the
full width at half maximum of about 100 nm is emitted. When x is equal to 0.01, the
luminous intensity is the maximum, and the CIE color coordinate is (0.195, 0.358), which is close to ideal cyan. The material has excellent
thermal stability, the
luminous intensity at 225 DEG C can still be kept at 50% at
room temperature, and the
thermal quenching activation energy is high. The fluorescent
powder is suitable for being combined with red and green fluorescent
powder and a near
ultraviolet chip to construct a full-spectrum
white light emitting
diode with a
high color rendering index, and has a wide application prospect in the field of high-end illumination and display.