3247 results about "Methacrylate" patented technology

The invention relates to the technical field of polyurethane films, in particular to a long-acting, stable, flexible, impact-resistant and resistance-reducing protective film and a preparation process thereof. According to the invention, the raw materials such as polyethylene glycol, a modified fluorosilicone monomer, isophorone diisocyanate, hydroxyethyl acrylate, an acrylic antifouling monomer, dodecafluoroheptyl methacrylate and the like are added to prepare the anti-drag coating. Mixing a polyurethane thermoplastic elastomer, aminopropyl polydimethylsiloxane, an antioxidant and an ultraviolet light absorber, and carrying out melt extrusion and blow molding to form a film, so as to obtain a flexible impact-resistant base film; and uniformly coating the surface of the flexible anti-impact base film with the anti-drag coating, and carrying out ultraviolet curing to obtain a finished product. The finished product prepared by the invention has good impact resistance, and can effectively reduce frictional resistance, so that the finished product has wide application prospects in the technical field of polyurethane films.

The invention discloses a lithium battery polymer solid electrolyte membrane capable of rapidly polymerizing at room temperature as well as a preparation method and application thereof, and belongs to the field of polymer electrolyte. The preparation method of the lithium battery polymer solid electrolyte membrane provided by the invention comprises the following steps: uniformly mixing polyethylene glycol methyl ether methacrylate and acrylonitrile according to a preset proportion to obtain a blended solution; sequentially adding lithium bis (trifluoromethanesulfonimide), divinylbenzene and benzoin diethyl ether into the blended solution, and uniformly mixing to obtain a precursor solution; and coating the precursor solution, and carrying out ultraviolet curing to obtain the lithium battery polymer solid electrolyte membrane. According to the lithium battery polymer solid electrolyte membrane provided by the invention, the voltage withstanding characteristic and the high ion conduction performance of the polymer electrolyte can be simultaneously improved, and the lithium battery polymer solid electrolyte membrane has a great gain on battery circulation and stability.

Disclosed in the present invention are a fluorosilicone-modified low-surface-energy antifouling coating and a preparation method therefor. The coating comprises the following components in parts by weight: 11-15 parts of butyl acrylate, 3-4 parts of dodecafluoroheptyl methacrylate, 3-4 parts of vinyl-terminated polydimethylsiloxane, 3-4 parts of 2-hydroxy-4-acryloyloxybenzophenone, 30-38 parts of methyl isobutyl ketone, 0.15-0.25 parts of azobisisobutyronitrile, 0.1-0.2 parts of sodium hydroxide, 2-3 parts of modified titanium dioxide nanoparticles, and 0.5-1.5 parts of 3-aminopropyltriethoxysilane. In the present invention, vinylpentamethyldisiloxane reacts with decamethylcyclopentasiloxane to prepare vinyl-terminated polydimethylsiloxane; a titanium dioxide precursor is mixed with polydopamine nanoparticles for modification to prepare modified titanium dioxide nanoparticles; and then the components above are mixed to prepare the fluorosilicone-modified low-surface-energy antifouling coating. The coating has low surface energy and good adhesion and ultraviolet resistance.

The invention provides high-stability ceramic ink and a preparation method thereof. The high-stability ceramic ink is prepared from the following components in parts by mass: 30 parts of inorganic pigment, 2 to 8 parts of sulfonic block polymer, 1 to 3 parts of polyvinyl alcohol grafted glycidyl methacrylate and 50 to 70 parts of organic solvent, wherein the polyving akohol grafted glycidyl methacrylate contains a plurality of epoxy groups. According to the high-stability ceramic ink, by constructing a composite system containing a sulfonic block polymer dispersing agent and polyvinyl alcohol grafted glycidyl methacrylate, stable dispersion of an inorganic pigment, construction of a thermal anchoring structure of an ink-jet pattern area and optimization of glaze layer fusion compatibility are realized; the high-stability ceramic ink effectively solves the problems of fuzzy pattern boundary and glaze-ink separation in the high-temperature sintering process of the existing ceramic ink, so that the high-stability ceramic ink has good storage stability and glaze-ink separation resistance.

The invention provides gel with a three-dimensional network structure, a preparation method of the gel and a lithium battery, and belongs to the technical field of lithium batteries. The gel provided by the invention comprises the following raw materials: polyethylene glycol dimethacrylate (PEGDMA) and / or a derivative thereof, a fluorine-containing carbonate compound, a cross-linking agent, a lithium salt, a flame retardant and an organic solvent. The PEGDMA and / or the derivative thereof and the fluorine-containing carbonic ester compound generate a three-dimensional network structure under the action of the cross-linking agent, the fluorine-containing carbonic ester compound can improve the interface stability between the gel and the electrode material, reduce the interface side reaction and improve the thermal stability of the gel, and the performance of the electrode material is improved. Meanwhile, the three-dimensional network structure has relatively high porosity and liquid absorption capacity, so that an ion transmission channel is improved, and the ionic conductivity of the gel is further improved. The room-temperature ionic conductivity of the gel with the three-dimensional network structure is larger than or equal to 3 mS / cm, and the thermal decomposition initial temperature is larger than or equal to 250 DEG C.

The invention discloses a carbon fiber reinforced polyamide composition as well as a preparation method and application thereof. The carbon fiber reinforced polyamide composition comprises the following components in parts by weight: 25-60 parts of polyamide resin; 30 to 65 parts of carbon fiber; 2-8 parts of a toughening agent; 0.5 to 6 parts of compatilizer; wherein the compatilizer is ethylene-acrylic ester grafted methacrylic ester glycidyl ester. Ethylene-acrylate grafted glycidyl methacrylate is added into the carbon fiber reinforced polyamide composition to serve as a compatilizer, ethylene-acrylate and carbon fibers have good compatibility, and GMA and polyamide resin end group reaction have good compatibility. And the toughening agent is cooperated, so that the prepared material has relatively good mechanical properties and good appearance.

The invention relates to a preparation technology of a gel polymer lithium ion battery cell electrolyte, and belongs to the field of battery preparation technologies, the preparation technology comprises the following steps: mixing methacrylate monomers and silane monomers according to a mass ratio of 3: 1-5: 1, adding 1-3% of an initiator, and carrying out prepolymerization at 60-80 DEG C for 1-3 h to prepare a prepolymer solution; mixing with a non-aqueous solvent containing lithium hexafluorophosphate according to a mass ratio of (1: 4)-(1: 6) to form a precursor mixed solution, and controlling the injection rate to be 1.5-2.5 g / Ah to a gap between a battery cell pole piece and a diaphragm; after standing for 2-4 hours at the vacuum degree of less than or equal to-0.08 MPa, curing for 3-6 hours at the temperature of 60-70 DEG C to form a gel polymer electrolyte; the wettability is improved through pole piece surface hydrophilic treatment, 1-5% of vinylene carbonate is added to optimize an SEI film, the prepolymerization temperature fluctuation is controlled to be smaller than or equal to + / -2 DEG C through microwave-assisted heating, the pressure of 0.2-0.5 MPa is applied after injection to promote uniform permeation, a polyvinylidene fluoride coating of 5-10 microns is coated after curing to enhance protection, and the interface performance is ensured through an alternating-current impedance test.

The invention discloses a double-crosslinking network hydrogel film for treating oral ulcer, a preparation method and application, and relates to the technical field of biomedical materials. According to the hydrogel film, a dual-network synergistic enhancement structure is constructed through covalent / non-covalent bi-crosslinking, the adhesion to oral mucosa is remarkably enhanced by adopting dopamine (DA) modified hyaluronic acid (HA), and the mechanical property is greatly improved by utilizing a bi-crosslinking network system of disulfide bond / double bond crosslinking (chitosan and CS) and hydrogen bond / catechol self-crosslinking (hyaluronic acid and HA); the antioxidant and anti-inflammatory characteristics of lipoic acid (LA) and the natural antibacterial property of chitosan (CS) are combined to play a synergistic effect, so that the antibacterial and anti-inflammatory effects are remarkably improved. Meanwhile, multifunctional modified materials such as metacrylic acid ester are introduced, so that the functionality and the application range of the hydrogel film are expanded. The preparation technology is optimized, it is ensured that the material is safe and effective, large-scale production is easy, and an efficient and reliable novel material is provided for oral ulcer treatment.

The invention relates to the technical field of tumor biomedical engineering and organ chips, in particular to a vascularized gastric cancer organ chip and a preparation method thereof.The chip is composed of an integrated micro-fluidic main body, an annular micro-column array and an optical sealing film, and a central culture cavity is divided into a tumor area and a blood vessel area by micro-columns; the preparation method comprises the following steps: injecting a fibrous protein solution containing human umbilical vein endothelial cells and cancer-related fibroblasts into a vascular region, and adding thrombin for in-situ gelation to form a pre-vascularized network; the method comprises the following steps: mixing a patient-derived gastric cancer organ with a methacrylic acid esterified gelatin pre-polymerized solution, injecting the mixture into a tumor area, and carrying out photo-crosslinking immobilization; culturing for 7-14 days under the dynamic perfusion condition of a mixed culture medium to obtain a three-dimensional gastric cancer organ model containing a capillary network; the method is expected to be used for rapid, low-cost and high-throughput screening of chemotherapy or anti-angiogenesis drugs and accurate prediction of individual curative effects of patients.

The invention relates to an automobile paint surface protective film agent and a preparation method thereof, and belongs to the technical field of automobile beauty. The automobile paint surface protective film agent is prepared from the following raw materials: amino functional polysiloxane, fluorine modified acrylic resin, epoxy modified organic silicon emulsion, functional filler, a surfactant, hydrophobic modified silicone oil, a brightening agent, a penetrating agent, a cosolvent and deionized water, and the raw materials are blended to prepare the automobile paint surface protective film agent. The functional filler is prepared by firstly carrying out surface modification on a polymer and then carrying out click chemistry on dodecanethiol on hydroxylated nano silicon dioxide, and the polymer is prepared by carrying out nucleophilic addition on poly (ethylene glycol) methacrylate Mn360, poly (ethylene glycol) methacrylate Mn500 and isophorone diisocyanate. The automobile paint surface protective film agent is high in film forming speed, a formed film layer has the characteristic of multiple effects, and meanwhile, the wear resistance is also very good.

The application provides a kind of fast curing acrylic glue and application, the fast curing acrylic glue is prepared from the following components according to weight parts: butyl nitrile rubber of terminal methacrylate is 13-17 parts;Polyurethane acrylate is 5-8 parts;Monofunctional acrylate monomer is 14-20 parts;Two functionality acrylate monomer is 7-13 parts;Three functionality acrylate monomer is 1-3 parts;Peroxide is 0.5-1.5 parts;Polymerization inhibitor is 0.01-0.04 parts;Coupling agent is 0.5-0.7 parts.The acrylic glue provided by the application has the advantages of fast curing, low volume resistivity after adding silver powder curing, good bonding strength, moderate elastic modulus, and can be used for photovoltaic tile conductive silver glue.

The instant disclosure is drawn to a cosmetic or personal care compositions in the form of oil-in-water dispersions, wherein the dispersion comprises oil droplets having a size from about 10 nm to about 1 μm. The compositions also include: (a) a hydrophobic polymer formed from a reaction product of a natural or food-derived oil and a methacrylate or acrylate polymer; (b) one or more solvents capable of solubilizing the hydrophobic polymer; (c) one or more biosurfactants, and optionally, one or more co-surfactants; and (d) water. Methods for making and using the compositions and methods for boosting foam are also disclosed.

The invention relates to the technical field of soil remediation, in particular to a biochar-humic acid-calcium alginic acid composite saline-alkali soil modifier and a preparation and application method thereof. The modifier adopts a multi-layer structure design: biochar is pre-adsorbed by calcium chloride, compounded with sodium humate, and then crosslinked with sodium alginate to form a gel to form a composite inner core; secondly, sulfobetaine methacrylate and vinyl phosphonic acid are introduced into a sodium alginate molecular chain through graft polymerization, and modified sodium alginate is obtained to serve as an outer layer coating material; and finally, dipping the composite inner core into the outer layer solution, and carrying out graded recalcification by calcium chloride and short-time treatment by sodium sulfate to obtain a final product. Through the synergistic effect of calcium ion slow release of the inner core and zwitterionic characteristics of the outer layer, efficient replacement and long-term stable regulation and control of soil sodium ions are achieved, the pH value, the conductivity and the alkalization degree of soil are remarkably reduced, the water holding capacity is effectively improved, and the soil conditioner is suitable for sustainable improvement of moderate and severe saline-alkali soil.

The invention discloses high-performance anti-wear engine lubricating oil as well as a preparation method and application thereof. The high-performance anti-wear engine lubricating oil is prepared from the following raw materials: self-developed lubricating oil base oil, poly-alpha-olefin, zinc dialkyl dithiophosphate, calcium sulfonate, polyisobutylene succinimide, an antioxidant, polymethacrylate, an organic molybdenum complex, a de-foaming agent and a pour point depressant. The preparation method comprises the following steps: 1) synthesizing 9, 10-bis (2-tert-butyl-4-methylphenoxy) trimethylolethane stearate as base oil of the lubricating oil; and 2) mixing the base oil with other assistants to obtain the high-performance anti-wear engine lubricating oil. According to the preparation method, novel-like synthetic ester oil is firstly prepared, a phenol group and a large steric hindrance substituent group are introduced into a polymer, the anti-oxidation function is directly built in base oil molecules, meanwhile, super-strong heat resistance is achieved, and finally the high-performance anti-wear engine lubricating oil is obtained and can be applied to high-end application scenes such as aero-engines or gas turbines.

The invention discloses a preparation method of an optical OCA (Optical Clear Adhesive) and application of the optical OCA in a mobile phone folding screen, and relates to the technical field of optical cement, the optical OCA is prepared from the following raw materials in parts by weight: 50 parts of acrylate prepolymers, 2-4 parts of 3-allyl-2-mercapto-3H-quinazoline-4-ketone, 1-3 parts of diallyl disulfide, 1-3 parts of 3-[N, N-dimethyl formamide], 1-3 parts of 2, 3, 5-trimethyl-1, 3-pentanediol monoisobutyronitrile, 1-3 parts of 2, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3 The preparation method comprises the following steps: adding 3-5 parts of N, N-dimethyl-[2-(2-methylpropane-2-enoyloxy) ethyl] ammonium] propane-1-sulfonic acid inner salt, 1-3 parts of allyl succinimido carbonate, 2-4 parts of dicyclopentene methacrylate, 1-3 parts of 1, 3, 5-triacryloyl hexahydro-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5-trimethyl-1, 3, 5- The invention relates to a graphene quantum dot photoinitiator which is prepared from the following components in parts by weight: 1-3 parts of 1, 3, 5-triazine, 0.8-1.2 parts of a photoinitiator, 1-3 parts of an aziridine cross-linking agent, 1-3 parts of graphene quantum dots, 0.8-1.2 parts of a coupling agent and 40-50 parts of a diluent. The optical OCA adhesive is high in light transmittance and bonding strength, good in weather resistance and excellent in folding resistance.

The invention relates to an optical monomer and a preparation method and application thereof, the structural general formula of the optical monomer is as follows: R1, R2 and R3 are respectively selected from one of hydrogen and C1-C4 alkyl, A1 is selected from one of hydrogen and C1-C4 alkyl, and A2 is C1-C4 alkyl; r4 is selected from one of H, phenyl and C1-C4 alkyl, and A2 is C1-C4 alkyl; and R5 is hydrogen or methyl. The optical monomer provided by the invention contains a (methyl) acrylate group, and has the properties of high refractive index and low volume shrinkage; and a plurality of aromatic rings with high molar refractive index and low molar volume are contained, so that the whole molecule of the whole monomer is extremely high in refractive index. The monomer structure provided by the invention has a plurality of branched chains, the overall molecular weight is small, and the molecules are not easy to agglomerate.

The invention discloses a low-seepage recyclable acrylate infiltration sealant and a preparation method thereof, and belongs to the field of metal die casting infiltration sealing. The impregnation sealant is prepared from 45 to 70 parts of monofunctional (methyl) acrylate, 10 to 35 parts of bifunctional (methyl) acrylate, 0.5 to 1 part of an initiator, 0.1 to 0.5 part of a polymerization inhibitor, 0.1 to 0.5 part of a stabilizer and 2 to 7 parts of an acrylate graft modified surfactant, the impregnating sealant is prepared by reacting 50-100 parts of a nonionic surfactant, 25-75 parts of an acrylate monomer, 0.5-1 part of deionized water and 0.05-0.1 part of Lewis acid at 75-96 DEG C for 3-6 hours. The impregnating sealant prepared by the invention is used for impregnating and sealing various metal die castings; excessive impregnant on the surface of the die casting is easy to clean and recycle by water; and the surface of the heated and cured die casting is clean and free of exudate oil stains.

The invention relates to the technical field of polymethacrylimide foam, in particular to polymethacrylimide wave-absorbing foam and a preparation method thereof. The high-temperature-resistant acrylic resin is prepared from the following raw materials in parts by weight: 55 to 60 parts of methacrylic acid, 45 to 55 parts of methacrylonitrile, 5 to 8 parts of 1-amino octadecane, 0.3 to 0.6 part of N-acrylamide, 0.4 to 0.7 part of N-hydroxysuccinimide ester, 0.5 to 1.2 parts of carbodiimide, 4 to 7 parts of tridecyl methacrylate, 2 to 8 parts of functional filler, 0.35 to 0.40 part of initiator, 0.6 to 0.8 part of foaming agent, 12 to 15 parts of cross-linking agent and 8 to 12 parts of absorbent. 21-35 parts of modified cellulose, 12-25 parts of a biomass-based additive, and 5-18 parts of a dispersant. The prepared polymethacrylimide wave-absorbing foam is relatively good in mechanical property, and shows excellent chemical stability under the conditions of room temperature and extremely low temperature.

The invention belongs to the technical field of lithium ion battery additive materials, and particularly relates to a high-compaction dispersion material and a preparation method thereof, and a high-compaction flexible positive pole piece, the high-compaction dispersion material comprises the following components by mass: 30-40 parts of a component A, 5-10 parts of a component B, 5-10 parts of a component C, and 40-60 parts of a solvent; wherein the component A comprises an unsaturated cyclic monomer, unsaturated polyether and a solution polymerization copolymer of an amine-containing monomer and a (methyl) acrylate monomer; the component B comprises a long-chain amine substance; the component C comprises organic ester; the high-compaction dispersion material, the preparation method thereof and the high-compaction flexible positive pole piece have the advantages of being excellent in dispersion performance, outstanding in softening effect, remarkable in pole piece compaction density improvement and the like, can have the two functions of dispersion and compaction improvement, reduces the production cost, improves the pole piece yield and has a good application prospect.

The invention belongs to the technical field of oil well paraffin removal and prevention, and relates to a paraffin removal and prevention agent for a shale oil shaft and a preparation method thereof. The paraffin remover and inhibitor for the shale oil wellbore comprises the following raw materials in percentage by mass: 40-55% of an oily solvent, 1-3% of a cosolvent, 1-2% of imidazole bis (trifluoromethanesulfonyl) imide salt, 10-20% of a wax crystal modifier, 3-5% of an emulsifier, 1-2% of an alkaline regulator and 25-35% of water, wherein the sum of the mass percentages of the raw materials is 100%. The wax crystal modifier is prepared by copolymerizing (methyl) acrylic acid C12-C16 ester, (methyl) acrylic acid C1-C3 ester and (methyl) acryloyl chloride and then reacting with C20-C30 alkyl alcohol. The wax crystal modifier provided by the invention has long-medium-short branched chains, and interacts with the imidazole bis (trifluoromethanesulfonimide) salt capable of improving the paraffin removal effect and low-temperature fluidity, so that the efficient paraffin removal and inhibition effect is realized, and the better paraffin removal and inhibition effect can still be kept at low temperature.

The invention discloses a (methyl) acrylate monomer, a holographic recording medium, a preparation method and a related device.The structural formula of the (methyl) acrylate monomer is as shown in G1-G19. The preparation method is easy to operate and high in synthesis yield, and further, the holographic recording medium can be applied to holographic recording. According to the photopolymer holographic recording medium, the (methyl) acrylate monomer with the structure is introduced into the photopolymer holographic recording medium, so that the holographic recording medium with high sensitivity, high diffraction efficiency and no yellowing is obtained, and the invention further provides a preparation method of the holographic recording medium. The invention also provides a volume holographic grating, a holographic optical element and an optical device comprising the holographic recording medium.

The invention discloses a (methyl) acrylate monomer, a holographic recording medium, a preparation method and a related device.The structural formula of the (methyl) acrylate monomer is as shown in G1-G5. The preparation method is easy to operate and high in synthesis yield, and further, the holographic recording medium can be applied to holographic recording. The (methyl) acrylate monomer with the structure is introduced into the photopolymer type holographic recording medium, reverse migration of a short polymer chain can be effectively inhibited, and therefore the holographic recording medium with high sensitivity and high diffraction efficiency is obtained, and the invention further provides a preparation method of the holographic recording medium. The invention also provides a volume holographic grating, a holographic optical element and an optical device comprising the holographic recording medium.

The invention provides a methacrylate-terminated polyurethane prepolymer, a preparation method and two-component dual-curing photosensitive resin, and relates to the technical field of 3D printing new materials. The structure of the methacrylate-terminated polyurethane prepolymer is shown as a formula IV, and the invention also provides a two-component dual-curing photosensitive resin which comprises the methacrylate-terminated polyurethane prepolymer shown as the formula IV, the bi-component dual-curing photosensitive resin is prepared by the following steps: firstly, fully mixing a methacrylate-terminated polyurethane prepolymer as shown in a formula IV, a reactive diluent and a photoinitiator as a component A and diamine as a component B at room temperature to form the bi-component dual-curing photosensitive resin. According to the invention, the methacrylate-terminated polyurethane prepolymer generates a mismatched supramolecular effect through the molecular structure design of'rigid main chain-flexible side chain ', so that the strength and toughness of the material are synergistically improved, and a 3D printed product shows ultrahigh mechanical properties.

This anticorrosive coating composition comprises a main agent (I) and a curing agent (II), wherein: the main agent (I) contains an epoxy resin (a); the epoxy resin (a) contains at least one of a bisphenol A epoxy resin (a-11) and a novolac epoxy resin (a-12) each having a weight average molecular weight of 6,000-12,000; the curing agent (II) contains a polyamine (b) and an alkylphenol (c); the polyamine (b) contains an alicyclic polyamine (b-1) having a cyclic aliphatic hydrocarbon group to which an amino group is bonded and contains a non-alicyclic polyamine (b-2) having no cyclic aliphatic hydrocarbon group to which an amino group is bonded; at least one of the main agent (I) and the curing agent (II) includes a vinyl-based defoaming agent (d) that has a constituent unit derived from at least one monomer selected from the group consisting of alkyl (meth)acrylates, alkyl vinyl ethers, and olefins and that has a number average molecular weight of 30,000-100,000 or 300,000-2,000,000; the content of the alicyclic polyamine (b-1) is 30%-80% by mass of the solid content of the curing agent (II); the content of the non-alicyclic polyamine (b-2) is 2%-45% by mass of the solid content of the curing agent (II); the content of the alkylphenol (c) is 5%-60% by mass of the solid content of the curing agent (II); and the content of the vinyl-based defoaming agent (d) is 0.005-3 parts by mass with respect to 100 parts by mass of the anticorrosive coating composition.

The invention discloses a bacteriostatic silicone rubber material and a preparation method thereof. The material is prepared by taking methyl vinyl silicone rubber as a matrix and adding components including polysiloxane containing quaternary ammonium salt groups, nano zinc oxide / cerium oxide composite particles, polyethylene glycol monomethyl ether methacrylate and the like through an artificial intelligence optimization process. The preparation method comprises the following steps: preparing polysiloxane containing quaternary ammonium salt and trifluoropropyl through AI optimization; preparing nano zinc oxide / cerium oxide composite particles through AI control; mixing to prepare the antibacterial silicone rubber composition; carrying out AI optimization step-by-step curing molding; aI optimization ultraviolet grafting and plasma treatment are carried out for surface functionalization. The obtained material has excellent antibacterial durability, surface hydrophilicity, mechanical performance, anti-aging performance and biological safety, is high in batch consistency, and is suitable for long-term implanted medical instruments such as medical catheters and artificial blood vessels.

The invention relates to the technical field of photovoltaics, in particular to an anti-migration ultraviolet cut-off photovoltaic adhesive film and application thereof. The anti-migration ultraviolet cut-off photovoltaic adhesive film comprises matrix resin and an ultraviolet cut-off agent, the ultraviolet cut-off agent is a benzotriazole compound with a reactive double bond, and the reactive double bond is selected from one of an olefinic bond, an acrylate bond, a methacrylate bond or a vinyl ester bond; and the absorption wave band of the ultraviolet cut-off agent is 280 to 380 nm. Therefore, the anti-migration ultraviolet cut-off photovoltaic adhesive film has a good cut-off effect and an anti-migration effect and is not prone to yellowing, and a battery assembly adopting the photovoltaic adhesive film has a longer service life.

A resin composition for optical fiber coating contains a photopolymerizable compound and a photopolymerization initiator, in which the photopolymerizable compound contains epoxy di(meth)acrylate having a bisphenol skeleton and alkylene oxide-modified tri(meth)acrylate, and a content of the alkylene oxide-modified tri(meth)acrylate is 0.5% by mass or more and less than 40% by mass based on the total amount of the photopolymerizable compound.

The invention relates to an optical monomer and a preparation method and application thereof, the structural general formula of the optical monomer is shown as G1, G2, G3 and G4, R1 and R2 are respectively selected from one of H, C1-C10 alkyl and halogen, A1 is C1-C10 alkyl, R3 is hydrogen or methyl, and n is a positive integer selected from 1-10. The optical monomer provided by the invention has a (methyl) acrylate group with high refractive index and low volume shrinkage property, contains a plurality of aromatic rings with high molar refractive index and low molar volume, and also has sulfur atoms with relatively high molar refractive index, so that the whole molecule of the whole monomer has extremely high refractive index. The whole monomer structure in the invention has at least two functionalities, and can realize fast reaction; the monomer structure also contains more branched chains and carbon chains, and molecules are not easy to agglomerate and have a certain migration rate.

The invention discloses high-adhesiveness water-based printing ink and a preparation method thereof, and belongs to the technical field of printing, and the high-adhesiveness water-based printing ink comprises the following components: water-based acrylic resin, SiO2 (at) TiO2 (at) EPS composite filler, pigment, a dynamic covalent cross-linking agent, nano cellulose, a wetting dispersant, a defoaming agent and deionized water. The preparation method comprises the following steps: firstly, preparing an EPS terpolymer containing a multi-functional group, and then modifying a SiO2 / TiO2 preassembly to prepare a composite filler; meanwhile, a dynamic covalent cross-linking agent generated by the reaction of furan methacrylate and maleimide propyl triethoxy silane is prepared; and finally, mixing the components step by step to obtain the ink. The multi-stage structure of the composite filler enhances the interface effect and covering power, the dynamic covalent cross-linking agent forms a reversible network to improve the stability and the self-repairing property, and the nano cellulose and other components have the synergistic effect, so that the ink has good adhesiveness and stability.

A thiol masterbatch composition for preparing a UV curable composition is provided, the thiol masterbatch composition comprising at least 70% by weight of a thiol compound, and at least one stabilizer. A kit for providing an ultraviolet curable composition includes: a first portion including a thiol masterbatch composition therein; and a second portion separate from the first portion and including a (meth) acrylate composition therein. A method of making a UV curable composition includes combining a thiol masterbatch composition and a (meth) acrylate composition.