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2056results about How to "Improve antifouling performance" patented technology

Curable composition, coating composition, paint, antifouling paint, cured product thereof and method of rendering base material antifouling

InactiveUS20020197490A1Shorten the running cycleExcellent in uniformity of coating film surfaceAntifouling/underwater paintsLayered productsHydrophobic silicaHardness
A curable composition comprising (A) an organopolysiloxane having functional groups capable of condensation reaction at both molecular terminals thereof and (B-1) a hydrophobic silica and a hydrophilic silica. A curable composition comprising (A) an organopolysiloxane having functional groups capable of condensation reaction at both molecular terminals thereof and (B-2) a hydrophobic silica, wherein the hydrophobic silica (B-2) is thermally treated together with the organopolysiloxane (A). The organopolysiloxane (A) is preferably represented by the formula: W3-a(R1a)Si(R2)O-(Si(R2)O)n-Si(R1a)W3-a [alpha] (wherein W represents a hydroxyl group or a hydrolyzable group; each of R1 and R independently represents an unsubstituted or substituted monovalent hydrocarbon group having 1 to 12 carbon atoms, provided that the hydrocarbon groups R1 as well as the hydrocarbon groups R may be identical with or different from each other; n is an integer of 5 or greater; and a is 0, 1 or 2). When, in the formula [alpha], W represents a hydroxyl group and a is 2, the curable composition preferably comprises, in addition to the components (A) and either (B-1) or (B-2), (C) an organosilane represented by the formula: R1bSiX4-b [I] (wherein R1 represents an unsubstituted or substituted monovalent hydrocarbon group having 1 to 8 carbon atoms; X represents a hydrolyzable group; and b is 0 or 1), or a partial hydrolyzate of the organosilane. Thus, a curable composition, especially a curable paint composition and an antifouling paint composition, and an antifouling coating film of the following characteristics can be provided. The curable composition, in particular when used as a coating material or a paint, is excellent in sprayability and enables forming a thick coating film by one-time application. The curable composition enables shortening the operating period for coating, and a coating film of uniform thickness can be obtained by the application thereof. The obtained coating film is excellent in film strength and film hardness and, when used for antifouling purposes, exerts excellent antifouling capability for a prolonged period of time. Further, the curable composition ensures excellent storage stability before application thereof.
Owner:CHUGOKU MARINE PAINTS +1

Surface-finishing agent and finished material and method of surface finishing

InactiveUS20060266258A1Developing surfaceHigh water slipping propertyOther chemical processesFibre treatmentSoil propertiesSlurry
The present invention provides a surface-treating agent to form fine roughness on the surface of a material and more specifically a surface treating-agent which forms fine roughness on the surface of a material and is easy to process, thereby being useful for materials for highly water-repellent glass, lenses and fabric, materials with an excellent anti-soiling property, panels having an excellent light scattering property, illumination of optical fiber and the like, materials and coatings to prevent accumulation and adhesion of snow or icicle formation on antennas, wires and steel towers, and roughness formation on the surface of semiconductor substrates; the treated materials; and a method of surface treatment to develop the roughness. The surface-treating agent of the present invention has an average primary particle diameter in the range of 1-50 nm, contains fine particles in the range of 5-60% by mass of the total amount of the surface-treating agent in a slurry of nanoparticles which are treated for water repellency and mechanically dispersed in a solvent containing a volatile solvent, and forms a roughness structure with upward protrusions having a spatial periodicity of 0.1-50 μm on the surface of a material by volatilizing the solvent or dipping repeatedly in water upon treating the surface of the material.
Owner:KEIO UNIV

Antifouling coating composition, coating film therefrom, base material covered with the coating film and antifouling method

An antifouling coating composition comprising (A) a silyl ester copolymer containing constituent units derived from a polymerizable unsaturated carboxylic acid silyl ester; (B) a carboxylic acid; (C) a bivalent or trivalent metal compound; and (D) a dehydrating agent. It is preferred that the component (C) be contained in an amount of 1.2 equivalents or more, in terms of the number of equivalents of metal as a constituent of the component (C), per equivalent of carboxyl group of the carboxylic acid (B); that the component (C) be a bivalent metal compound; and that the component (C) be a compound of at least one metal selected from the group consisting of zinc, copper, magnesium, calcium and barium. From the antifouling coating composition, there can be obtained an antifouling coating film which exhibits less cracking tendency, excellent adherence so as to ensure less peeling tendency and desirably controlled hydrolysis rate so as to be excellent in antifouling performance, in particular, antifouling properties in highly fouling environment and long-term antifouling properties. With respect to the provided antifouling coating composition, its storage stability is high, its concentration can be increased, the amount of solvent used therefor can be reduced, and its applicability is high.
Owner:CHUGOKU MARINE PAINTS

Quaternary ammonium salt modified organosilicon polyurethane ocean antifouling paint and preparation method and application thereof

The invention discloses a quaternary ammonium salt modified organosilicon polyurethane ocean antifouling paint, the structure is shown as the formula (1); in the formula, an organosilicon soft segment containing quaternary ammonium salt side chain is an isocyanate hard segment; the quaternary ammonium salt modified organosilicon polyurethane ocean antifouling paint is prepared by the following steps: preparing 2,4,6-tri(3- chlorine propyl group)-2,4,6- trimethyl-ring trisiloxane; preparing 1,3-bi(3-(1-methoxy group-2-hydroxy propyl group) propyl group)-tetramethyl disiloxane; preparing 1,3-bi(3-(1-methoxy group-2-hydroxy propyl group) propyl group)-tetramethyl disiloxane; preparing dihydroxy ended chloropropylated polysiloxane; preparing polysiloxane compound containing the quaternary ammonium salt and hydroxyl; mixing the compound with the isocyanate, and adding gamma-aminopropyl triethoxy silane for chain extension to obtain a prepolymer, and the prepolymer being crosslinked and condensed in air. In the invention, the double effect of low surface energy and poison killing are achieved, so as to suppress the adsorption of marine organisms and kill bacteria adsorbed on the surface of a ship body through the quaternary ammonium salt.
Owner:ZHEJIANG UNIV

Tei Coat for Organopolysiloxane Antifouling Coat, Composite Coats, and Ships and Underwater Structures Covered with the Composite Coats

Disclosed is a tie coat which is formed on a surface of a base or an undercoating film prior to formation of an organopolysiloxane-based antifouling coating film and is formed from a moisture-curing organopolysiloxane-based composition comprising (b1) organopolysiloxane having condensing functional groups at both ends of a molecule and/or (b2) a curing composition formed by subjecting the component (b1) and an extender pigment selected from the group consisting of silica, calcium carbonate, talc, mica, clay, kaolin and barium sulfate to contact treatment with heating or without heating. Also disclosed is a composite coating film wherein on a surface of the above tie coat is formed a finish coat formed from a three-pack type organopolysiloxane-based curing composition comprising (c1) a main agent comprising the component (b1), (c2) a curing agent component comprising tetraalkoxysilicate or its condensate and (c3) a curing accelerator component comprising a metallic compound. Further disclosed is a composite coating film wherein an epoxy-based sealer coat, the tie coat and the finish coat are formed in this order on a surface of an old antifouling coating film (G). There is provided by the invention a tie coat capable of forming a composite coating film having excellent interlaminar bond property. The composite coating film is favorably formed on a surface of a base, an undercoating film, an old antifouling coating film or the like, has excellent interlaminar bond strength and antifouling property and is preferably used for coating outer surfaces of ships, submerged parts of marine structures, water supply/drainage channels of atomic power plant, etc.
Owner:CHUGOKU MARINE PAINTS

FFC glaze with high stain resistance, FFC sanitary ceramic and preparation method of FFC sanitary ceramic

ActiveCN111253071AExtended firing temperature rangeReduce glaze porosityPotassium feldsparSodium carboxymethylcellulose
The invention discloses an FFC glaze with high stain resistance, an FFC sanitary ceramic and a preparation method of the FFC sanitary ceramic. The FFC glaze with high stain resistance comprises the following raw materials in parts by weight: 22-29 parts of quartz, 24-28 parts of potassium feldspar, 6-10 parts of wollastonite, 7-8 parts of zirconium silicate, 5-10 parts of kaolin, 0-5 parts of calcite, 5-7 parts of zinc oxide, 5-7 parts of aluminum oxide, 2-3 parts of frit, 4-8 parts of dolomite, 5-8 parts of calcined talc, 1-4 parts of barium carbonate and 0.2-0.5 part of sodium carboxymethylcellulose. According to the FFC glaze with high stain resistance, multi-alkali effect is utilized, barium carbonate is introduced, the use amount of calcined talc is increased, and the use amount of albite is reduced, so venting of a green body is more smooth, the porosity of a glaze surface is reduced, and microcracks of the glaze surface are reduced. Besides, the FFC glaze with high stain resistance also utilizes the principle of like dissolves like to increase the consumption of aluminum oxide and quartz, improve the bonding property of the blank and a glaze, and further reduce the microcracks on the glaze surface of the sanitary ceramic correspondingly.
Owner:江门市东鹏智能家居有限公司

Preparation method of highly-hydrophobic fluorocarbon coating for photovoltaic component back plate

The invention provides a preparation method of a highly-hydrophobic fluorocarbon coating for a photovoltaic component back plate. The preparation method is suitable for outdoor coatings and in particular suitable for coated type photovoltaic back plates. The fluorocarbon coating consists of a component A and a component B in a mass ratio of (1-5):1, wherein the component A comprises fluorocarbon resin, hydrophobic modified nano-particles, a tin type catalyst and an anhydrous diluent A; and the component B comprises an isocyanate curing agent and an anhydrous diluent B. The nano-particles can be uniformly dispersed in main body resin after being subjected to coupling agent hydrophobic modification, is good in compatibility, and can form a micro-nano rough grain structure after being coated on a substrate; and by combining low surface energy of the fluorocarbon resin, the surface of the fluorocarbon coating has high hydrophobicity of a 'lotus leaf effect', has a good antifouling effect, and can greatly reduce influence of water drops on components. Meanwhile, the prepared fluorocarbon coating is excellent in weathering resistance, chemical resistance and salt spray resistance, so that the fluorocarbon coating is suitable for coated type photovoltaic component back plates and is good in performance.
Owner:HANGZHOU FIRST APPLIED MATERIAL CO LTD

Organosilicon type marine antifouling paint binder and preparation method and application thereof

The invention discloses organosilicon type marine antifouling paint binder. The structure of the paint binder is shown in the formula (1), wherein the paint binder is an organosilicon-polyurethane compound with bactericide side chain and R represents CH2CH3. The preparation method comprises the following preparation steps: 1) using chloropropylmethyldimethoxysilane and dimethyldimethoxysilicane to react and obtain chloropropyl-containing polysiloxane; 2) using chloropropyl-containing polysiloxane, tertiary amine and hydroxyl-containing tertiary amine to perform reflux reaction and generate polysiloxane with quaternary ammonium salt and hydroxyl; and 3) mixing isocyanate, butyltin dilaurate and polysiloxane with quaternary ammonium salt and hydroxyl with solvent, adding gamma-aminopropyltriethoxysilane to extend the chain and obtain prepolymer with the crosslinked group -Si(OCH2CH3), and using the prepolymer to perform crosslinking and condensation in the air and obtain the finished product. The organosilicon type binder has low surface energy performance and very good hydrophobicity; and the molecular chain has environmentally-friendly bactericide, thus the binder has very good bactericidal effect and marine antifouling effect.
Owner:ZHEJIANG UNIV
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