The invention discloses a preparation method of a single-component water-oil
mixed type environment-friendly composite
adhesive. The preparation method comprises the following steps: S1, a synergistic pretreatment stage; s2, a gradient
polymerization stage; s3, an ultrasonic compounding stage; and S4, a low-temperature curing stage. Through the synergistic effect of the
nanocellulose and the
montmorillonite, modification of the green
coupling agent and the
graphene quantum dot-
chitosan composite modified material, the problem that a traditional filler is prone to agglomeration is solved, the filler is evenly dispersed in the
adhesive, the
mechanical property of the
adhesive is greatly improved, the gradient
polymerization process has the advantages that the temperature is accurately controlled, and the
mechanical property of the adhesive is greatly improved. According to the present invention, the
monomer conversion rate is increased to more than 98%, the molecular
weight distribution of the product is uniform, the stability of the
bonding strength is ensured, the
bonding strength can achieve 4.2 MPa, the strength
retention rate can still achieve 92% in the temperature cycle test of-20-60 DEG C, the application reliability in different environments is ensured, and the high requirements on the adhesive performance in the fields of building, packaging and the like are met.