The invention discloses a preparation method and application of a
vanillin-based chain
extender and a waterborne
polyurethane film-forming agent, and belongs to the technical field of waterborne
polyurethane preparation.The preparation method comprises the steps that firstly,
vanillin and 4, 4-diaminodiphenylmethane are subjected to a
Schiff base reaction to synthesize the
vanillin-based chain
extender, then the vanillin-based chain
extender reacts with
isocyanic acid and polyhydric alcohols to generate a
prepolymer, and then the
prepolymer is subjected to a reaction with the waterborne
polyurethane film-forming agent to obtain the vanillin-based chain extender. Then synthesizing a waterborne polyurethane
emulsion through an emulsification reaction, adding an amine chain extender after emulsification, and carrying out a post-chain extension reaction, so as to obtain the waterborne polyurethane film-forming agent. The waterborne polyurethane film-forming agent prepared by the invention can be used for preparing a
glass fiber wire-drawing impregnating compound, a fabric
sizing agent or a
coating and the like, the film-forming agent is environment-friendly, the production process is green and
pollution-free, an
organic solvent does not need to be added in the reaction process, and zero VOC (Volatile Organic Compounds) emission can be realized; meanwhile, the special structure of the vanillin-based chain extender also endows the waterborne polyurethane film-forming agent with higher rigidity.