1755 results about "High conductivity" patented technology

The invention relates to a method for preparing a lithium iron phosphate / carbon composite material of a lithium ion battery, which belongs to the technical field of lithium ion batteries. The method for preparing the lithium iron phosphate / carbon composite material of the lithium ion battery comprises the following steps of: 1) preparing a suspending graphene-dispersed aqueous solution system, namely, crushing graphite to 1 to 5 microns, adding the crushed graphite into distilled water or purified water, adding 0.1 to 5 percent of surfactant, heating with stirring the mixed solution to 180 to 250 DEG C in a sealing way, performing stirring for 2 to 6 hours and reducing the temperature; 2) crushing lithium iron phosphate to the particle size of 1 to 5 microns, adding the crushed lithium iron phosphate into the distilled water or the purified water, adding with stirring 0.01 to 1 percent of coupling agent, performing uniform stirring, adding the graphene-dispersed aqueous solution, and performing stirring and filtration; and 3) vacuum-drying solid powder obtained by the filtration, and calcinating the dried solid powder for 2 to 12 hours to obtain the graphene-coated lithium iron phosphate cathode material. The method has the advantages of simple process, high material performance, high conductivity, high bulk density, high compacted density and the like.

The invention discloses a high-conductivity palladium alloy for a chip test probe and a preparation method of the high-conductivity palladium alloy, and the palladium alloy comprises the following components in percentage by mass: 50-58% of Pd, 35-40% of Cu, 5-10% of Ag, 0.05-1.0% of Cr and 0.1-1.5% of auxiliary elements, the auxiliary element is selected from at least one of Al, Zn, In and Si; the resistivity of the palladium alloy is 8.0 mu omega.cm or below, the Vickers hardness is 450 HV or above, the 90-degree bending frequency is 8 or above, the tensile strength is 1500 MPa or above, and the ductility is 6% or above, the palladium alloy is subjected to pre-smelting and secondary smelting, and at least part of Cu and at least part of Cr in raw materials are mixed and pre-smelted to obtain a copper-chromium intermediate alloy; and the copper-chromium intermediate alloy and the remaining raw materials are mixed and then subjected to secondary smelting. The palladium alloy can meet the urgent requirements of probes in various forms on low resistance, high plasticity and toughness, fatigue resistance, mechanical strength and the like at the same time.

The application relates to the technical field of material preparation, and discloses multi-element carbon-coated lithium manganate, a preparation method thereof and a secondary battery. The multi-element carbon-coated lithium manganate comprises a lithium manganate core and a carbon nanotube layer and a hard carbon layer which are sequentially coated on the lithium manganate core. The chemical formula of the lithium manganate core is LiAl a X b Mn 2‑a‑b O4, wherein 0.01<=a<=0.10, 0.01<=b<=0.05, and X comprises at least one of Co, Cr, Ti, V and B. The preparation method of the multi-element carbon-coated lithium manganate comprises the following steps: (I) preparing doped lithium manganate, (II) preparing carbon nanotubes and (III) multi-element carbon coating. The multi-element carbon-coated lithium manganate has high conductivity, rate performance, cycle performance and safety performance, and can be used as an alternative positive electrode material with high cycle and excellent fast-charging performance.

The invention belongs to the technical field of halide solid-state electrolyte, and relates to a high-conductivity and high-lithium-stability modified halide solid-state electrolyte material constructed by solid source plasma, and a preparation method and application of the high-conductivity and high-lithium-stability modified halide solid-state electrolyte material. According to the preparation method, a halide solid electrolyte is taken as a matrix, halogenated ammonium salt is taken as a solid source, and the halide solid electrolyte is subjected to synergistic doping modification of elements such as nitrogen, fluorine / chlorine / bromine and the like by utilizing a plasma technology, so that the modified halide solid electrolyte material is obtained. The modified halide solid electrolyte material shows excellent conductivity and lithium-lithium symmetrical battery performance, and has a wide market application prospect. Meanwhile, the preparation method provided by the invention is simple, rapid, efficient and convenient, is easy to control, and contributes to promoting the development and application of the high-performance halide solid electrolyte material.

The invention discloses a Prussian blue type composite positive electrode material and a preparation method and application thereof, and the Prussian blue type composite positive electrode material provided by the invention is composite powder containing a Prussian blue type positive electrode material, a conductive agent, a binder and a functional additive, the mass ratio of the Prussian blue positive electrode material to the conductive agent to the binder to the functional additive is (90-99): (1-5): (0-5): (0-0.5). According to the Prussian blue composite positive electrode material provided by the invention, the components are uniformly distributed, the Prussian blue composite positive electrode material has the characteristics of high compaction, easy dispersion, relapse resistance, high conductivity and the like, and the Prussian blue composite positive electrode material can be directly used for wet homogenization and can also be directly used for dry electrode manufacturing.

The invention relates to the technical field of aluminum alloy wire processing, and particularly discloses a high-modulus high-conductivity heat-resistant aluminum alloy material, an aluminum wire, a preparation method and a power transmission cable. According to the high-modulus, high-conductivity and heat-resistant aluminum alloy material provided by the invention, the nanoscale TiB2 particles and the micron-sized SiC particles are compounded in the aluminum alloy powder, a dual-reinforcement system is constructed, and the mechanical property and the electrical property of an aluminum conductor are synergistically improved. The invention further provides a preparation method of the high-modulus and high-conductivity heat-resistant aluminum conductor. According to the process, a multi-stage coupling plastic processing technology of hot extrusion, continuous rolling, drawing and surface treatment is adopted. The grain structure is refined through the dynamic recrystallization effect in the series of machining processes, oxidation film defects on the surface and in the structure are damaged through plastic deformation, the rigidity and the conductivity of the aluminum wire are further optimized, and the technical bottleneck that high modulus, high conductivity and heat resistance of traditional aluminum alloy are difficult to consider at the same time is effectively solved.

The invention belongs to the field of metallurgical wire processing, and relates to an aluminum alloy material, in particular to an ultrahigh-strength high-conductivity slender grain aluminum alloy material and a preparation method thereof. The aluminum alloy material is prepared from the following elements in percentage by mass: 0.56 percent to 0.75 percent of Si, 0.2 percent to 0.5 percent of Fe, 0.005 percent to 0.15 percent of Cu, 0.45 percent to 0.85 percent of Mg, 0.1 percent to 0.25 percent of RE, 0.005 percent to 0.03 percent of B, 0.001 percent to 0.02 percent of Ti and the balance of aluminum, the preparation method comprises the processes of smelting, alloying treatment, refining, continuous casting, continuous rolling, quenching, drawing, tempering recrystallization and aging treatment in sequence. By setting the aluminum alloy material formula and improving the preparation method, the distribution of grain boundaries is optimized, and the strength and the conductivity of the aluminum alloy conductor are synchronously improved.

The invention relates to the technical field of preparation of aluminum alloy conductor materials, and particularly discloses a preparation method of an Al-Mg-Si-RE-based aluminum alloy conductor for a 10-35kV middle and low voltage cable, which comprises the following steps: adding a microalloyed intermediate alloy into an aluminum melt by adopting an addition method, stirring, smelting, refining, and casting to form, thereby obtaining the Al-Mg-Si-RE-based aluminum alloy conductor for the 10-35kV middle and low voltage cable. And performing annealing, rolling, wire drawing and aging heat treatment to obtain a final product. Wherein in the smelting stage, raw materials are completely melted at 700-750 DEG C; hexachloroethane is used as a refining agent for refining; annealing at 330-350 DEG C and preserving heat for 4-8 hours; and aging at 300 DEG C for 10 hours after deformation. In the preparation of a wire of a 10-35kV medium and low voltage power cable, the aluminum alloy wire has high conductivity of 62.1-62.5% IACS (International Annealed Copper Standard) and tensile strength of 101-117MPa by simplifying the process steps and optimizing the element ratio on the premise of ensuring the controllable raw material cost, and the mechanical property and electrical property requirements of the medium and low voltage wire are balanced.

The present disclosure provides a low-temperature conductive paste and a raw material composition thereof, and a heterojunction cell electrode and a manufacturing method therefor. The raw material composition comprises the following components in percentage by mass: 2%-10% of a composite resin, 2%-4% of an organic solvent, 0.2%-1% of an auxiliary agent, and 85%-94% of conductive metal powder. The resin comprises a component A and a component B. The component A comprises a polyol and a blocked isocyanate. The component B comprises a curing agent and a resin. The present disclosure further provides a low-temperature conductive paste prepared from the raw material composition, a heterojunction cell electrode manufactured from the low-temperature conductive paste, a manufacturing method for the electrode, and a heterojunction cell manufactured from the electrode. The low-temperature conductive paste and the heterojunction cell electrode provided by the present disclosure have high conductivity and weather resistance.

The invention discloses a carbon nano tube reinforced tungsten carbide titanium metal ceramic material as well as a preparation method and application thereof, and belongs to the field of metal ceramic materials. According to the invention, a spark plasma coupling high-frequency induction sintering method is adopted, CNTs are uniformly dispersed in a material matrix through a method of dispersing CNTs through dry ball milling again, and the uniformly dispersed CNTs improve the discharge environment, reduce the sintering current and reduce the energy consumption under the spark plasma coupling high-frequency induction effect in the sintering process. The high-compactness, high-strength and high-wear-resistance (W, Ti) C-based metal ceramic material is prepared at the sintering temperature of 1350 DEG C by utilizing the ultrahigh conductive complementary effect of the (W, Ti) C metal ceramic material and the CNTs.

The application belongs to the technical field of aluminum alloy, and particularly relates to a high-strength and high-conductivity aluminum alloy wire rod and a preparation method and application thereof. The high-strength and high-conductivity aluminum alloy wire rod is improved by simultaneously adding Be, Ni and Ca. Meanwhile, the solid solution heat treatment and aging heat treatment in the preparation method of the aluminum alloy wire rod are optimized, three-stage solid solution heat treatment with temperature increment and three-stage aging heat treatment with temperature increment are adopted, and the temperature of the three-stage solid solution heat treatment and the three-stage aging heat treatment with temperature increment is improved, so that the aluminum alloy wire rod with high strength and conductivity is provided, and the technical problem that there is lack of Al-Mg-Si alloy material with high conductivity and high strength in the prior art is solved.

The invention relates to the technical field of steel-cored aluminum stranded wires, and provides an overhead high-conductivity steel-cored aluminum stranded wire which comprises a galvanized steel core and aluminum wires stranded on the surface of the galvanized steel core, the galvanized steel core is formed by stranding 19 steel wires, and the aluminum wires are divided into two layers and stranded on the outer side of the galvanized steel core; the preparation method of the galvanized steel core comprises the following steps that after being galvanized, a steel wire is added into a passivation solution to be passivated, and the galvanized steel core is obtained after drying and twisting; the passivation solution is prepared from the following raw material components: waterborne acrylic resin, nickel nitrate, sodium carboxymethyl cellulose, sodium dodecyl sulfate, functionalized single-walled carbon nanotubes and water; the functionalized single-walled carbon nanotube is prepared from the following raw materials: a single-walled carbon nanotube and 5-carboxyl-2, 3-diaminopyridine. According to the technical scheme, the problem that the corrosion resistance of the manufactured overhead steel-cored aluminum stranded wire is poor due to the fact that the corrosion resistance of a galvanized steel core is poor in the prior art is solved.

The invention relates to the technical field of semi-gold-nickel plating and processing, in particular to a floating connector terminal continuous semi-gold-nickel plating process which comprises the following preparation steps: S1, a floating connector terminal to be electroplated is put into degreasing fluid for degreasing treatment, and then the degreased terminal is put into activating fluid for activating treatment; s2, nickel electroplating is conducted on the activated floating connector terminal through a nickel plating solution, a nickel cake serves as an anode, the pH value of the nickel plating solution is controlled to be 3.5-5.5 through weak acid in the electroplating process, the electroplating current is controlled to be 0.4-0.8 A / dm < 2 >, the temperature is controlled to be 50-60 DEG C, cleaning is conducted, and the nickel-plated floating connector terminal is obtained; and S3, the nickel-plated floating connector terminal is put into the gold plating solution to be electroplated, the electroplating temperature is 40-50 DEG C, the current density is 0.1-2 A / dm, a finished product is obtained, and the floating connector terminal can still keep high conductivity, low contact resistance, high abrasion resistance and high corrosion resistance under the complex environments of high temperature, vibration, salt mist and the like through the technology.

The invention relates to the field of positive electrode materials, in particular to a graphene reinforced lithium iron phosphate material and a preparation method and application thereof. According to the positive electrode material, europium ions are doped into lithium iron phosphate, the europium ions are large in radius, a larger migration channel is provided for lithium ions, meanwhile, the binding energy of the lithium ions can be reduced, the surface of the europium-doped lithium iron phosphate is coated with carbonized hydroxyethyl methyl cellulose grafted graphene, the hydroxyethyl methyl cellulose reduces the agglomeration phenomenon of the graphene, and the conductivity of the lithium iron phosphate is improved. After carbonization, a 3D conductive carbon network is jointly formed with graphene, so that the electronic conductivity is enhanced; the positive electrode material has the advantages of long cycle life, high charge-discharge efficiency, high conductivity and high cycle stability, provides a good energy storage basis for batteries, and is suitable for the fields of power batteries and energy storage.

The invention discloses a novel induction-type magneto-thermo-acoustic detection method for the conductivity of a supercapacitor, and relates to the technical field of nondestructive material detection.The method comprises the steps that a steady-state static magnetic field and a pulse alternating magnetic field are introduced to form a composite excitation field, and a magneto-acoustic effect and a thermo-acoustic effect are simultaneously and cooperatively excited in a solid-state electrode material; the magnetoacoustic-thermoacoustic coupling effect is formed, eddy current induced by a pulse alternating magnetic field in the material not only generates joule heat, but also generates a direct carrier of Lorentz force under the action of a steady-state static magnetic field, the two physical effects are derived from the same electromagnetic excitation process, but the mechanisms for generating acoustic signals are complementary to each other, so that the effect of the magnetoacoustic-thermoacoustic coupling is achieved. The two effects are coupled as a unified sound source item, a sound pressure wave equation is established, the equation describes a sound field excitation process under the combined action of a force source and a heat source, the coupling mechanism remarkably enhances the strength and information abundance of ultrasonic signals, and the inherent defect that a single thermoacoustic detection method is insensitive to a high-conductivity material is overcome.

The invention discloses a preparation method and application of a zinc-bromine flow battery positive electrode material, and belongs to the field of zinc-bromine flow batteries. The preparation method comprises the following steps: firstly, cleaning and activating a carbon-based three-dimensional conductive network substrate by adopting plasmas, performing oxygen / argon plasma etching, and performing chemical vapor deposition on carbon to prepare three-dimensional porous carbon; then growing a metal oxide nanocrystalline array on the three-dimensional porous carbon by a hydrothermal method, and carrying out ammonia gas calcination to convert the metal oxide nanocrystalline array into a metal nitride nanocrystalline array; then preparing an electro-deposition solution containing tin bismuth salt and an aniline-bromine source polymerization solution, and constructing Sn-Bi bimetallic nanoparticles and a polyaniline-bromine complex layer on the metal nitride nanocrystalline array / three-dimensional porous carbon precursor through electro-deposition and electro-polymerization in sequence to finally prepare the high-performance zinc-bromine battery positive electrode material. The positive electrode material has high conductivity, excellent Br2 / Br <-> catalytic activity and structural stability, and the coulombic efficiency, the voltage efficiency and the energy efficiency of the battery are remarkably improved.

The invention discloses an instrument capable of being separated through light control and a preparation method and application of the instrument, and belongs to the technical field of biomedical engineering and flexible electronics. The instrument capable of being separated through light control comprises a flexible substrate layer, an electrode layer and a gel integration layer, the preparation method comprises the following steps: (1) forming an electrode pattern on a silicon wafer through photoetching, and carrying out oxygen plasma treatment to prepare a hydrophilic surface; (2) spin-coating a water-soluble polymer solution to form a sacrificial layer; (3) spin-coating silicone rubber pre-polymerized liquid and curing to form a flexible substrate layer; (4) dissolving the sacrificial layer with water to realize demolding, and embedding a patterned conductive material into the surface to form an electrode layer; and (5) coating the photo-responsive adhesive hydrogel pre-polymerization liquid, and performing cross-linking curing to form a gel integration layer, thereby obtaining the photo-responsive adhesive hydrogel. Through integrated structural design and functional material integration, the brain-computer interface ECoG electrode with high flexibility, high adhesion, high conductivity and controllable debonding capacity and the like is provided, and a technical basis and an application platform are provided for a next-generation intelligent implantable brain-computer system.

The invention discloses a preparation method of a high-conductivity and low-thermal-conductivity carbon-carbon composite material electrode, and relates to the technical field of electrode preparation, the preparation method comprises the following steps: mixing nano carbon spheres, an organic binder and a solvent to obtain a mixed slurry, respectively coating the mixed slurry on a PAN-based carbon fiber web and pitch-based carbon fiber non-woven cloth, and drying to obtain the high-conductivity and low-thermal-conductivity carbon-carbon composite material electrode. Then preparing a preform by alternately laying and needling the PAN-based carbon fiber web coated with the mixed slurry and pitch-based carbon fiber non-woven cloth, pretreating the preform by adopting a chemical vapor deposition technology to obtain an intermediate I, and treating the intermediate I in a pressure impregnation tank and a carbonization and graphitization furnace to obtain an intermediate II; and carrying out pressure impregnation-carbonization treatment on the intermediate II to obtain the carbon / carbon composite material. According to the preparation method of the high-conductivity and low-heat-conductivity carbon-carbon composite material electrode, the material has high conductivity and low heat conductivity, a carrier is provided for precise heat management under specific conditions in a high-temperature furnace, and the energy consumption of equipment is reduced.

The invention discloses a jack connecting terminal, which comprises an inner conductor provided with a jack for connecting a plug, and the inner conductor comprises a first connecting section which is a plurality of connecting sheets uniformly distributed along the axis of the jack; and a second connection section; the outer conductor wraps the first connecting section and the second connecting section, a first opening is formed in the position, corresponding to the connecting sheet, of the outer conductor at the first connecting section, and an abutting sheet used for abutting against the connecting sheet is connected to the first opening; the shell is connected to the outer conductor, and the shell and the outer conductor are arranged in a clamped mode; an adjusting mechanism is arranged on the shell and used for driving the abutting piece to move between the first position and the second position. When the abutting piece moves from the first position to the second position, the abutting piece is used for driving one end of the connecting piece to deviate towards the axis direction of the jack. The problems that in the prior art, high conductivity and high mechanical strength cannot be met, and good heat dissipation capacity is not achieved can be effectively solved.

The invention belongs to the field of functional material preparation, and relates to an MOFs crystal film and a preparation method and application thereof. According to the MOFs crystal film, a porous polymer supporting film is used as a carrier, a high-crystallinity, compact and continuous rigid MOFs crystal layer grows on the surface of the porous polymer supporting film in situ, and a solid / quasi-solid electrolyte system is formed by matching polymer electrolyte or electrolyte. The MOFs ordered pore channel ion screening effect and metal ion sites are used for limiting anions, so that the ion transference number is increased; a physical-chemical synergistic dendritic crystal inhibiting mechanism is realized by utilizing high mechanical strength and a high crystal structure; the low-tortuosity compact ordered MOFs crystal film is used for improving the conductivity, the MOFs electrolyte with wide temperature range stability and high voltage resistance is obtained, and a support is provided for realizing a secondary battery with high energy density and high safety.

The invention belongs to the technical field of electromagnetic wire materials and manufacturing, and particularly relates to a copper-aluminum composite special-shaped enameled wire and a preparation method thereof.The enameled wire comprises a copper-clad aluminum composite conductor and an insulating paint layer coated on the outer surface of the copper-clad aluminum composite conductor; the composite conductor is composed of a copper layer and an aluminum core, and the volume ratio of the copper layer to the aluminum core is 60%: 40%-70%: 30%. The thickness of the composite conductor is 0.5-2.0 mm, the width of the composite conductor is 2.0-10.0 mm, and the width-to-thickness ratio of the composite conductor is 2-8; the eccentricity of the copper layer is less than or equal to 2.5. The enameled wire has high conductivity, light weight and high reliability, and is especially suitable for high-frequency power electronic devices such as new energy automobile motors, high-frequency transformers and photovoltaic inverters, and application scenarios with high requirements for space utilization rate, heat dissipation performance and long-term stability such as spaceflight and deep sea equipment in extreme environments.

The invention discloses a preparation method of a high-specific-power manganese dioxide-carbon fluoride battery positive pole piece. The preparation method comprises the following steps: (1) carrying out high-temperature heat treatment on electrolytic manganese dioxide to finish crystal transformation of the electrolytic manganese dioxide; (2) carrying out ball milling on the manganese dioxide, the carbon fluoride and the conductive agent which are subjected to heat treatment to obtain a composite substance of the manganese dioxide, the carbon fluoride and the conductive agent; (3) stirring and mixing the composite substance with a binder, a surfactant and deionized water to form manganese dioxide-carbon fluoride battery positive electrode slurry; and (4) coating the prepared positive electrode slurry on an aluminum mesh with a certain surface density in an extrusion or roller coating manner, and carrying out drying and rolling processes to obtain the high-loading-amount manganese dioxide-carbon fluoride battery positive electrode plate with a certain compaction density and surface density. The prepared positive pole piece has relatively high conductivity and energy density, and the high-magnification application scene of the lithium manganese dioxide-carbon fluoride battery is further widened.

The application relates to the technical field of solid-state batteries, in particular to a halide oxyde and a preparation method and application thereof. The application takes a molten salt Li a M b X c as raw material, reacts with an oxide A d O f in a molten state, removes steam impurities by means of high-temperature vacuum extraction, and obtains the halide oxyde solid-state electrolyte after cooling; the molten salt raw material is melted into an ionic melt at high temperature, oxygen elements are introduced to replace part of halogens, the hardness of the target electrolyte is reduced after cooling, the deformation ability at room temperature is improved, the obtained electrolyte has high conductivity, a wide oxidation electrochemical window, and the like. The prepared halide oxyde solid-state electrolyte is used for preparing a positive electrode, and the adhesion, actual micro contact area and ion migration rate between the electrolyte and positive electrode material particles are improved through melt infiltration, the positive electrode interface problem is effectively relieved, and the electrochemical performance of the full solid-state battery is improved.

The invention relates to the technical field of conductive agents, and particularly discloses graphene carbon nanotube composite conductive paste for a high-voltage electrode and a preparation method of the graphene carbon nanotube composite conductive paste. The graphene carbon nanotube composite conductive paste for the high-voltage electrode is prepared from the following raw materials in parts by weight: 2 to 6 parts of carboxylated single-walled carbon nanotube powder, 1 to 3 parts of fluorinated modified graphene powder, 0.6 to 1.2 parts of superfine carbon black, 2 to 4 parts of an ionic liquid dispersing agent, 0.2 to 0.4 part of a rheology modifier and 80 to 100 parts of N-methyl pyrrolidone. According to the graphene carbon nanotube composite conductive paste for the high-voltage electrode, the breakdown field strength can be remarkably improved, partial discharge is inhibited, and high conductivity is kept while the high-voltage service life is prolonged.

The present application relates to the technical field of negative electrode materials. Provided are a negative electrode material and a battery. The negative electrode material comprises an inner core and a coating layer located on at least part of the surface of the inner core. The inner core comprises a carbon matrix, and an active substance and boron element distributed in the carbon matrix. The active substance comprises a silicon material and a metal material, and at least part of the silicon material being connected to the metal material. The negative electrode material of the present application has low expansion, ultra-high conductivity, and high initial coulombic efficiency.

The invention provides a lithium iron phosphate positive electrode material, a preparation method thereof and a lithium ion battery. The lithium iron phosphate positive electrode material is secondary particles formed by stacking primary particles, the primary particles comprise first lithium iron phosphate particles and second lithium iron phosphate particles, the D50 of the second lithium iron phosphate particles is larger than that of the first lithium iron phosphate particles, and the difference value between the D50 of the second lithium iron phosphate particles and the D50 of the first lithium iron phosphate particles is larger than or equal to 1000 nm; each first lithium iron phosphate particle sequentially comprises a first inner core, a first coating layer and a second coating layer from inside to outside; the first inner core has a chemical formula Lix1FeMm1Pz1O4 (I) as shown in a general formula (I), and M is a first metal element; each second lithium iron phosphate particle comprises a second inner core and a third coating layer arranged on the surface of the second inner core; the second inner core has a chemical formula Lix2FeM'm2Pz2O4 (II) as shown in a general formula (II), M'is a second metal element, and the lithium iron phosphate positive electrode material has high conductivity and high compaction density.

The invention relates to a process for preparing a phosphor copper rod by using a phosphonate-amide composite purifying agent as a quenching aid, and belongs to the technical field of non-ferrous metallurgy. Phosphorus pentoxide and sodium carbonate are mixed and decocted into fused salt, the fused salt is cooled and ground and then added into a corundum crucible together with scrap copper to be rapidly heated, compressed air is blown in, and slagging-off is conducted after heat preservation and standing; blowing mixed gas into the melt for reduction refining; adding calcium boride into the melt for refining; the refined copper liquid is subjected to continuous casting and continuous rolling; rapidly immersing the phosphorus copper rod subjected to continuous casting and rolling into a quenching aid solution, and carrying out quenching treatment; and the quenched phosphor copper rod is blow-dried and dried, and the high-conductivity phosphor copper rod is obtained. The high-purity phosphorus copper rod prepared by the method is excellent in key indexes of copper content, phosphorus content and conductivity, and meets the expected requirements of high purity and high conductivity.

The invention discloses low-silver-content composite conductive silver paste based on a three-dimensional conductive network and a preparation method, and relates to the technical field of composite conductive silver paste preparation, and the low-silver-content composite conductive silver paste comprises a low-silver-content conductive phase, an interface bonding layer, a support body and an organic carrier; and the conductive phase with low silver content comprises the following components: 25 wt%-30 wt% of silver-plated hollow glass beads and 12 wt%-18 wt% of a three-dimensional conductive network. According to the invention, through accurate proportioning of the conductive phase with low silver content, the use amount of silver is greatly reduced. The silver-plated hollow glass bead takes light glass as a core and an ultrathin silver layer as a conductive shell, so that the silver consumption is reduced by more than 60wt%; the three-dimensional conductive network adopts a synergistic structure of silver nanowire fragments and graphene composite fragments, and the high conductivity of graphene is utilized to replace part of silver materials, so that the dependency degree of silver is further reduced. The silver content of the silver paste is greatly reduced, the cost of raw materials is greatly reduced, and the economical efficiency of the silver paste in large-scale application scenes such as photovoltaic and electronic packaging is remarkably improved.

The invention discloses a preparation method of low-temperature solderable conductive copper paste, and belongs to the technical field of electronic materials. The conductive copper paste is prepared from the following raw materials: silver-coated copper powder, an organic carrier, an antioxidant, a curing agent, an auxiliary agent, a thixotropic agent, a solvent and an adhesion enhancer. The design of the composite copper powder coated with the silver layer on the surface is matched with the graded particle size, and an organic carrier is combined, so that high conductivity and strong oxidation resistance under low-temperature curing are realized. The preparation method comprises the following steps: treating the copper powder by adopting a dipping-drying process, and coating the surface of the copper powder with the adhesion enhancer and the antioxidant by adopting a chemical method; uniformly mixing the organic carrier, the curing agent, the solvent and the auxiliary agent; and finally, copper powder and a thixotropic agent are added into the mixed organic carrier, and the low-temperature solderable conductive copper paste is prepared through high-speed dispersion and grinding of a three-roller machine. The product can be rapidly cured at 100-180 DEG C, the sheet resistance is smaller than or equal to 20 m omega / square, the welding strength reaches 15 MPa or above, cost is low, production is easy, and wide industrial application value is achieved.

The invention discloses a prefabricated branch fireproof cable with a copper metal shell and a preparation method of the prefabricated branch fireproof cable. The prefabricated branch fireproof cable comprises a copper metal main shell, the bottom of the copper metal main shell is communicated with a copper metal sub-shell, a main cable is installed in the copper metal main shell, and a branch cable is installed in the copper metal sub-shell; the main cable and the branch cable both adopt copper core conductors, and copper has high conductivity, so that resistance in a current transmission process can be reduced, electric energy loss can be reduced, electric energy transmission efficiency can be improved, and stable and efficient transmission of electric power to each electric device can be ensured; the nanoscale magnesium oxide insulation powder filled in the copper metal main shell and the copper metal branch shell has excellent insulation performance, can effectively isolate electrical connection between the main cable and the branch cable and the external environment and between the main cable and the branch cable and other conductors, prevents electric leakage and short circuit accidents, and improves the electrical safety of a cable system.