The invention belongs to the technical field of
organic electroluminescence preparation, and particularly relates to a tetradentate cyclometalated
platinum (II) complex guest phosphorescent material with a
biphenyl structure, an electronic device, a device and application of the tetradentate cyclometalated
platinum (II) complex guest phosphorescent material. According to the invention,
alkyl or
aryl is introduced to 3 ', 4 'and 5' positions of 1, 1 '
biphenyl to increase steric hindrance, so that
red shift or
luminescence quenching caused by
molecular aggregation can be avoided; the stability of the material can be improved by deuteration on the periphery of the cyclometalated ligand, so that the phosphorescent material disclosed by the invention has good
chemical stability and
thermal stability and is easy to prepare an
evaporation type
OLED (Organic
Light Emitting Diode) device. The current efficiency and the service life of an organic light-emitting device manufactured by taking the complex as a light-emitting layer material are obviously improved, and the organic light-emitting device has a great application prospect in the fields of
OLED display and illumination.