The invention relates to a 
graphene composite material and a preparation method thereof. The 
graphene composite material provided by the invention is characterized in that a 
graphene material plate fixed on a metallic matrix serves as a carrier, and the elementary substance and / or a compound are compounded on the graphene surface. Meanwhile, the invention also discloses a method for preparing the graphene 
composite material. The graphene composite material prepared by the invention is opened between graphene sheets and is compounded with a 
chemical substance under the condition that a space body structure is formed, and the obtained material has 
high conductivity, high specific surface area and excellent performance of low electrical resistivity between the sheets, and can be widely applied to the fields of 
energy storage materials such as 
lithium ion batteries, super-capacitors, super lead carbon batteries, super 
nickel-carbon electrodes, 
solar energy and 
fuel cells, the field of heat dissipation materials, the field of environment-friendly adsorbing materials, the field of sea 
water desalination materials, the field of 
photoelectric sensor materials, the biological relevance field, the field of catalyst materials and the fields of 
conductive ink and 
coating materials.