The invention provides a preparation method of high-
conductivity composite
graphene,
conductive ink and application thereof, and the preparation method comprises the following steps: dispersing
graphene into a
solvent to obtain a
graphene dispersion liquid; adding a
silane coupling agent with an amino group into the graphene dispersion liquid, and reacting to obtain aminated graphene; and adding a first dispersing agent into the aminated graphene, adding silver
powder after uniform dispersion, and
grinding to form an Ag-N coordinate bond between the silver
powder and the aminated graphene, thereby obtaining the high-
conductivity composite graphene. In the preparation method of the high-
conductivity composite graphene provided by the invention, a
silane coupling agent with an amino group is added into a graphene dispersion liquid,
amination modification is completed through a
condensation reaction with a hydroxyl group on the surface of the graphene, silver
powder and the amino group of the graphene form an Ag-N coordinate bond, so that
silver particles are completely coated with the graphene, a continuous C-Ag-C conductive network is constructed, and the high-conductivity composite graphene is obtained. According to the network, path breakpoints are reduced, interface
contact resistance is reduced, charge transmission efficiency is improved, conductivity reduction after graphene compounding is effectively inhibited, and
high conductivity and
high heat resistance are achieved.