552 results about "Hydrogen bonded network" patented technology

The invention discloses a self-repairing polymer electrolyte, a preparation method and application thereof, and a polymer lithium battery, the self-repairing polymer electrolyte comprises the following preparation raw materials by mass: 50-100 parts of polysiloxane diacrylate, 1-10 parts of disulfide diacrylate, 10-40 parts of a cross-linking agent, 60-120 parts of a plasticizer, 60-120 parts of a lithium salt, and 1-10 parts of a photoinitiator. According to the self-repairing polymer electrolyte disclosed by the invention, a thiol-ene click reaction can be carried out between carbon-carbon double bonds in polysiloxane diacrylate and disulfide diacrylate and sulfydryl of the cross-linking agent, so that a dynamic disulfide bond and hydrogen bond network structure is endowed to the self-repairing polymer electrolyte; and the dynamic disulfide bond and the hydrogen bond can enable the electrolyte membrane to realize self-healing at room temperature without external stimulation.

The invention relates to editing oligonucleotides (EONs) that carry stereospecific phosphorothioate internucleotide linkage modifications at specified positions and that do not carry such modifications on positions that would lower RNA editing efficiency. The selection of positions that should or should not carry a phosphorothioate Rp and / or Sp configuration modification is based on computational modelling that revealed incompatibilities of the stereospecific linkages with the intermolecular oxygen-mediated hydrogen bond network.

The invention provides a preparation method of a self-repairing waterborne polyurethane coating based on a synergistic effect of a dynamic disulfide bond and a pH response microcapsule. The preparation method comprises the following steps: step 1, preparing a dynamic disulfide bond-containing waterborne polyurethane (D-WPU) emulsion; step 2, preparing a pH response microcapsule; step 3, preparing a self-repairing waterborne polyurethane coating; a dynamic disulfide bond of the self-repairing waterborne polyurethane coating rapidly repairs macrocracks at 50-60 DEG C through mercaptan catalysis, and pH < lt > is caused by local corrosion of a pH response microcapsule; when the pH value is 4.0, cysteine is released, sulfydryl accelerates recombination of dynamic bonds, and amino enhances cohesive force of the coating and neutralizes H < + >. And in combination with a hydrogen bond network of the nanocellulose, the coating has low-temperature repair (the mechanical strength recovery rate is greater than or equal to 90%), high toughness (the water absorption rate is less than or equal to 2.1%) and long-acting corrosion resistance (the salt spray resistance life is greater than or equal to 600 hours), and is suitable for severe environments such as ocean engineering and new energy equipment.

The invention discloses a compound containing a urea structure as well as a preparation method and application of the compound in a color developing agent, and relates to the technical field of color developing agents. The compound containing the urea structure is a # imgabs0 # structure as shown in a formula 1. The compound containing the urea structure is synthesized through multiple steps of Suzuki reaction, bromination reaction and substitution reaction. The compound is used as an electron donor to be applied to a thermosensitive color development system and forms a color development composition with a phenolic compound and an acidic material, and the activation temperature is as low as 60-120 DEG C. The ureido structure stabilizes a reaction intermediate through a hydrogen bond network, enhances the electron transfer efficiency, and significantly improves the color developing sensitivity; the aryl / heteroaryl substituent optimizes the color contrast through the conjugation effect, and meanwhile, the synergistic effect of the hot-melt filler ensures the stability of the system. Compared with a traditional color developing agent, the color developing agent has the advantages of low-temperature activation, high color developing intensity and excellent weather resistance, is suitable for the fields of thermal printing, anti-counterfeiting materials and the like, and overcomes the defects of high reaction temperature and insufficient stability in the prior art.

The invention provides a preparation method of a high-adhesion transparent self-healing super-smooth coating. Polydimethylsiloxane is taken as a matrix, a three-arm type dynamic hydrogen bond network structure is constructed, and 2-ureido-4-pyrimidone (UPy unit) is taken as a crosslinking node to be connected with a siloxane main chain, so that the crosslinking density and the interface binding energy are remarkably improved. According to the invention, a UPy unit is innovatively introduced into a main chain or a side chain to construct two topological structures of (SUP) 2TD or (MUP) 2TD. Compared with (MUP) 2TD, the (SUP) 2TD shows excellent tensile property and self-healing property in both air and underwater environments. The enhancement of this performance is attributed to the improvement of chain displacement capability in (SUP) 2TD. Through interface dynamics, a UPy unit is guided to an interface and interacts with an interface group, and a very strong adhesion effect is obtained. In addition, the coating shows excellent self-healing performance.

The invention belongs to the field of flexible electronic devices, and discloses a preparation method of a high-performance strain sensor based on a nano-silver nano-cellulose seepage network. According to the hydrogel, polyvinyl alcohol is used as a matrix, a seepage network formed by polydopamine anchored nano-silver / nano-cellulose PCNF is used as a conductive phase, glycerin is used as an anti-freezing humectant, and through the synergistic effect of a three-dimensional seepage conductive network and a dynamic hydrogen bond network, the defects that traditional hydrogel is poor in sensing stability, poor in environmental stability and low in mechanical strength are overcome. The preparation process is simple, the conductive hydrogel is high in tensile strength, high in sensitivity and good in cycling stability and has an antibacterial function, and an assembled strain sensor can monitor a human motion signal in real time and is suitable for the fields of wearable equipment, electronic skin and medical monitoring in an extreme environment. Through material system and process innovation, integration of high performance and multiple functions is achieved, and wide application prospects are achieved.

The invention provides a perovskite solar cell, a preparation method thereof and a photovoltaic module. The perovskite solar cell comprises a first electrode, a hole transport layer, a perovskite layer, an electron transport layer and a second electrode which are stacked in sequence. The material of the hole transport layer comprises a biomolecular material which is fixed on a self-assembly monomolecular layer material through an intermolecular force, and the biomolecular material comprises one or more of guanine, adenine, thymine, uracil, cytosine, hydroxymethylcytosine, xanthine, hypoxanthine, 6-mercaptopurine and corrin. According to the perovskite cell provided by the invention, the biomolecular material with a plurality of nitrogen heterocyclic structures and amino groups is added to generate multipoint hydrogen-bond interaction and pi-pi accumulation with the tail end of the SAM, so that the orderliness of molecular arrangement is improved, and the dipole direction and strength of the whole interface are regulated and controlled; and a coordination bond or hydrogen bond network is formed by the coordination compound and uncoordinated cations or anions in perovskite, so that interface defects are effectively passivated, and the thermal stability and the humid and hot life of a device are enhanced.

The invention provides a hole transport layer precursor solution, a hole transport layer, a preparation method and application of the hole transport layer, and a perovskite cell, and belongs to the technical field of hole transport layers. The hole transport layer precursor solution comprises a self-assembled single molecule and an organic solvent; the organic solvent comprises a solvent A, a solvent B and a solvent C; the solvent A comprises more than one of a phosphate ester solvent and an alcohol ether solvent; the solvent A contains four hydrogen bond receptors; the boiling point of the solvent A is 215-290 DEG C; the solvent B comprises more than one of ethanol, isopropanol, normal propyl alcohol, butanol, ethylene glycol and N, N-dimethylformamide; the solvent C comprises more than one of ethyl acetate and normal hexane. A ternary hydrogen bond network is formed through the solvent A, the solvent B and the solvent C, the agglomeration degree of SAM molecules is remarkably reduced, and the device performance is improved.

The invention discloses a membrane material for an alkaline system, which is prepared by the following method: introducing hydrophilic micromolecules with double bonds into an inorganic material with alkali-resistant stability, polymerizing the hydrophilic micromolecules with double bonds into alkali-resistant hydrophilic macromolecules in the pore channels of the inorganic material, and then adding the alkali-resistant hydrophilic macromolecules into the inorganic material. The alkali-resistant hydrophilic macromolecule material (represented by the material A) is encapsulated in the alkali-resistant stable inorganic material. Alkali-resistant hydrophilic macromolecules form a continuous hydrogen bond network structure in pore channels of the inorganic material, inlet activation energy of ions at pore openings is reduced, the diffusion rate of the ions in the pore openings is increased, and the ionic conductivity of the material is improved. The composite membrane prepared by blending and compounding the material A and an organic polymer has high ionic conductivity and high ionic selectivity, and has good performance on an alkaline flow battery system and an alkaline water electrolysis hydrogen production device.

The invention belongs to the technical field of sustainable battery electrolyte design, is applied to an aqueous ammonium ion energy storage system, and particularly relates to a design method and a preparation method of an ammonium ion battery electrolyte additive adaptive to a high-voltage Prussian blue positive electrode material. According to the design method, electrostatic potentials (ESP) of different aprotic solvents are compared through quantum chemistry calculation, and finally acetone (ACE) is selected as an electrolyte additive to construct a weak solvation electrolyte system based on hydrogen bond interaction. The saturated addition amount of acetone in 1.0 mol L <-1 > (NH4) 2SO4 aqueous solution is determined through a pre-experiment, and is marked as 25% ACE. The electrolyte shows high suitability with a high-voltage Prussian blue positive electrode material (N-VHCF). Benefited from the construction of a competitive water-poor solvation structure and the blocking of a hydrogen bond network, the hydrogen evolution reaction and the oxygen evolution reaction in a 25% ACE electrolyte are inhibited, and the excellent performance of the Prussian blue positive electrode material (N-VHCF) under high discharge voltage is realized.

The invention relates to the technical field of polymer composite materials, and discloses a refining treatment method of a bamboo fiber ultra-nano micro powder and natural polymer blended material, which comprises the following steps: (a) premixing bamboo fiber ultra-nano micro powder and a deep eutectic solvent to obtain a premix and realize in-situ activation; (b) adding the premix and a natural polymer matrix from a main feed port of a double-screw extruder; and (c) in the melt blending process, adding a dynamic interface locking agent through a side feeding port arranged at the downstream of the main feeding port, and then extruding and granulating. A staged dynamic compatibilization process is adopted, a hydrogen bond network of bamboo fibers is destroyed by using a deep eutectic solvent to promote shearing dispersion of the bamboo fibers in the front section, and stable interface bonding is constructed in the rear section through a dynamic interface locking agent after dispersion is completed. The method synergistically solves the conflict between dispersion and interfacial compatibilization, so that the composite material has good comprehensive performance.

The invention discloses an aqueous zinc ion battery electrolyte as well as a preparation method and application thereof, and belongs to the technical field of zinc ion batteries. The vanadic acid additive takes a Zn-sulfonated hydrogen bond organic framework as a carrier, and 4-6wt% of vanadate is loaded on the surface of the carrier. Sulfonic acid groups contained in the carrier can cooperate with vanadate to preferentially adsorb free water molecules in an aqueous electrolyte, the erosion activity of the water molecules on the positive electrode material is reduced, a hydrogen bond network structure of the hydrogen bond organic framework can selectively intercept active water molecules, and the water molecules are prevented from participating in oxidation reduction dissolution of the vanadium-based positive electrode material. Meanwhile, the zinc metal ions doped in the carrier can cooperate with the strong polarity of the sulfonic group, regulate and control the solvation structure, reduce the interface impedance and inhibit the growth of zinc dendrites, so that the long-term stability of the aqueous zinc ion battery is improved, and the aqueous zinc ion battery electrolyte capable of inhibiting the dissolution of a positive electrode and stabilizing a zinc negative electrode is obtained.

The invention belongs to the technical field of automotive coatings, and particularly relates to finishing-free water-based plain finish paint and a preparation method thereof. The water-based blocked isocyanate and the water-based hydroxyl acrylate are crosslinked to form a carbamate bond and construct a three-dimensional hydrogen bond network, so that the mechanical strength, the sagging resistance and the chemical resistance of the finish paint are remarkably improved; amino resin is modified through dialdehyde lignin, hydrophilic groups in the amino resin are eliminated, reversible imine bonds are generated, and the acid-base hydrolysis resistance of the finish paint is enhanced; the polyether-polysiloxane is grafted with the water-based blocked isocyanate, so that the storage stability of the finish paint is ensured, the sagging phenomenon of a vertical surface is inhibited, the surface tension of the finish paint is reduced, orange peel is eliminated, and the integrated performance improvement of high weather resistance, sagging resistance and low orange peel of the finish paint is realized.

The invention belongs to the field of aqueous zinc ion batteries, and particularly relates to an electrolyte of an aqueous zinc ion battery, which is an aqueous solution in which zinc salt and additives are dissolved, and the additives comprise NaCl, NaF, NaBr and NaI. The invention also comprises application of the electrolyte. By innovatively combining the sodium quaternary anion additive, a hydrogen bond network of water can be effectively stabilized to inhibit the activity of the water, the ultralow temperature performance can be deeply optimized, in addition, high-temperature gas production can be effectively inhibited, the high-temperature performance can be improved, and the service life is prolonged. The electrolyte provided by the invention can significantly improve the ultra-wide temperature range performance and long cycle performance of the aqueous zinc ion battery.

The invention discloses a preparation method and application of a sulfonylurea structure thermosensitive color developing agent, and relates to the technical field of color developing agents. The core of the thermosensitive color developing agent is a # imgabs0 # compound in a formula 1 containing a sulfonylurea structure. The preparation method comprises the following three steps: synthesizing an intermediate 1 through esterification of raw materials, obtaining an intermediate 2 through boric acidification, and synthesizing a target compound through Suzuki reaction. Through the synergistic effect of sulfonyl and ureido, hydrogen bond network regulation and electron transfer efficiency optimization are realized, and the technical bottlenecks of high-temperature activation requirements and insufficient color development stability of a traditional thermosensitive color developing agent are solved.

The invention belongs to the technical field of membrane separation, and particularly relates to a preparation method and application of a high-permeability polyamide reverse osmosis membrane. According to the invention, the problems of high energy consumption and poor water production quality caused by non-ideal flux and rejection rate of the current reverse osmosis membrane product are solved, tetrabutylammonium bromide and acyl chloride form ion pairs to reduce hydrophobicity, a hydrogen bond network of urea destroys a hydrophobic barrier of an organic phase, and migration of acyl chloride to a water phase interface is promoted; the eutectic solvent is adsorbed on a water phase interface to form a'catalytic microenvironment ', amido of an amine monomer is attracted to be close to the interface, and the concentration of a reaction area is increased. During reaction, tetrabutylammonium bromide enables an amine monomer to stably attack a transition state of acyl chloride through electrostatic interaction, and reaction activation energy is reduced; urea and sodium hydroxide in a water phase can be jointly used as an acid-binding agent to neutralize generated hydrochloric acid so as to prevent amido protonation inactivation. The method is simple to operate and suitable for large-scale production.

The invention relates to the technical field of composite materials, in particular to a high-strength elastic composite aerogel and a preparation method thereof.Negative Poisson ratio composite aerogel designed with a centripetal structure cooperating with a supramolecular system is prepared, the supramolecular system design is adopted, a hydrogen bond network of nanofibers serves as a weak interface bonding layer, and the elastic composite aerogel with the high strength is prepared. The fiber and the silane-based material interface are covalently interlocked to form a firm supramolecular system, and a centripetal structure is cooperated to realize a coupling effect between resistance and deformation. Through the cooperative strategy, the composite aerogel obtains excellent specific modulus and good recovery speed, and can be qualified for high-impact and high-strength application scenarios.

The invention belongs to the field of electrochemical energy storage, and particularly relates to a water-based zinc ion battery electrolyte, a battery and a zinc negative electrode protection method of the battery, zinc negative electrode corrosion, hydrogen evolution reaction and dendritic crystal growth are effectively inhibited by regulating and controlling the electrolyte, changing a hydrogen bond network of the electrolyte and optimizing a zinc ion solvation structure, and the cycle life of the zinc negative electrode is prolonged. The solvent of the electrolyte is water, and the solute is zinc sulfate and shikimic acid. When the prepared electrolyte is used for assembling the zinc symmetric battery, the interface impedance is obviously reduced, the deposition morphology is optimized, the formation of dendritic crystals is inhibited, hydrogen evolution reaction and side reaction are inhibited, and the cycle life of a zinc negative electrode can be effectively prolonged.

The invention discloses a wet non-slip wear-resistant thermoplastic polyurethane elastomer material and a preparation method thereof. The polyester resin is prepared from the following raw materials: A) 45-85% of polyhydric alcohol; b) 10 to 45 percent of polyisocyanate; c) 1-20% of a micromolecular dihydric alcohol chain extender; d) 0.1 to 1.5 percent of an acyclic heterocyclic oxygen atom chain extender; and E) 0.1 to 0.5 percent of an acyclic nitrogen atom chain extender. According to the invention, an acyclic heteroatom chain is introduced at the reaction rear end to form a local hyperbranched structure, and the local hyperbranched structure is combined with multiple hydrogen bonds of polyurethane to form a high-density hydrogen bond network. When the dynamic hydrogen bond network is damaged on a damaged section, an activation layer is formed when the dynamic hydrogen bond network encounters water, rapid recombination and recovery of the hydrogen bond network between the sections are promoted through a water bridge, and the wet non-slip property and the wear resistance of the material are greatly improved. The method can be used in the fields of sole materials, blending modification, industrial products and the like.

The invention provides a polymer elastomer and a preparation method and application thereof, and relates to the field of self-powered strain sensors. The preparation method of the polymer elastomer provided by the invention comprises the following steps: mixing cellulose and a deep eutectic solvent, and carrying out hydrogen bond bonding to obtain a hydrogen bond network system; mixing the hydrogen bond network system with an acrylic anhydride compound, and carrying out esterification reaction to obtain a modified cellulose system; and mixing the modified cellulose system, an acrylic monomer and an initiator, and carrying out in-situ free radical polymerization to obtain the polymer elastomer, the hydrogen bond donor of the deep-eutectic solvent is ethylene glycol and / or glycerol, and the hydrogen bond acceptor is choline chloride. Elastomer polymerization is carried out in an anhydrous system, the eutectic solvent is grafted to the surface of cellulose, based on the Seebeck principle, temperature difference can be generated at the two ends of the material through body temperature, potential difference is finally formed at the cold end and the hot end, and low-temperature waste heat is recycled and converted into electric energy.

The application belongs to the technical field of deep eutectic solvents, and particularly relates to a ternary deep eutectic solvent and preparation and application thereof. The ternary deep eutectic solvent is composed of choline chloride, 5-sulfosalicylic acid and gamma valerolactone according to a molar ratio of 1:4:(3-25). The strong hydrogen bond network structure between the green solvent system first destroys the ester bond between lignin and hemicellulose, then cuts off the beta-O-4 bond between lignin molecules, so as to separate lignin. Meanwhile, the deep eutectic solvent can improve the stability of carbon cations due to the conjugation effect between the lone pair electrons on the heteroatom oxygen and the central carbon in the molecular structure of gamma valerolactone, so as to inhibit the condensation reaction of lignin.

The invention discloses a method for improving moso bamboo cellulase hydrolysis conversion efficiency through amino acid-based deep eutectic solvent pretreatment, and belongs to the technical field of biomass recycling. The method comprises the following steps: mixing an L-cysteine solid and a formic acid solution, performing water bath heating to prepare an acidic eutectic solvent, performing microwave-assisted eutectic solvent pretreatment on moso bamboos, and performing filtration separation and enzymolysis; wherein the molar ratio of the L-cysteine to the formic acid is 1: (4-5). A deep eutectic solvent formed by formic acid and cysteine has a strong hydrogen bond network and an acid environment, beta-O-4 ether bonds in lignin are promoted to be broken, sulfydryl of cysteine participates in nucleophilic attack, a lignin-carbohydrate complex is further destroyed, formic acid can hydrolyze acetyl and glucosidic bonds in hemicellulose, and the lignin-carbohydrate complex is further destroyed. And degrading into an oligomer or monosaccharide. The phyllostachys pubescens components are efficiently separated, the cellulose enzymolysis saccharification capacity is improved, and effective utilization of all the phyllostachys pubescens components is facilitated.

The invention provides a high-safety flexible pole piece, a preparation method and a flexible lithium ion battery, the pole piece comprises a current collector and a coating arranged on the surface of the current collector, the coating comprises a flexible isolation structure and a plurality of electrode units, the flexible isolation structure constructs a plurality of accommodating areas isolated from each other on the surface of the current collector, the number of the electrode units is multiple, and the flexible isolation structure is arranged in the accommodating areas. The plurality of electrode units are respectively and independently arranged in different accommodating areas. According to the invention, accurate prevention and control of thermal runaway are realized through the electrode structure design of partition isolation and a material system with multiple hydrogen bonds synergistic effect. The electrode is divided into independent units by the flexible isolation structure, so that heat spreading is effectively blocked; and a hydrogen bond network formed by the hydroxyl-containing comonomer I, PI, PET and hexaphenoxy cyclotriphosphazene significantly enhances the interface stability and flame retardant efficiency of the electrode and the isolation structure, and improves the intrinsic safety of the battery while ensuring the flexibility of the battery.

The invention discloses a polyether polyurethane solid polymer, a preparation method thereof and application of the polyether polyurethane solid polymer in a solid electrolyte, and belongs to the technical field of polymer electrolytes and preparation of the polymer electrolytes. The problems that an existing solid polymer electrolyte is low in ionic conductivity and poor in interface stability are solved. According to the invention, polyether amine and cyclic carbonate are subjected to an in-situ polymerization reaction to synthesize a series of polyether polyurethane solid polymer electrolytes with different molecular weights and monomer proportions. The obtained polyether polyurethane solid polymer electrolyte contains rich carbamate groups, hydroxyl groups, fluorine ions and the like, and can form a strong reversible hydrogen bond network, so that the electrolyte has excellent mechanical properties, can be used as a self-supporting electrolyte membrane, and does not need an additional diaphragm. Meanwhile, a large number of dynamic reversible hydrogen bonds also enable the solid polymer electrolyte to have excellent self-healing ability, and can be self-repaired when the battery is damaged by external force in the operation process, so that the structural stability of the solid polymer electrolyte is remarkably improved.

The invention relates to the technical field of electrochemical energy storage materials, and discloses a gel polyelectrolyte, a preparation method and application and an aqueous zinc metal battery. The electrolyte is of a micron-sized micropore three-dimensional internet porous structure, and the three-dimensional internet porous structure is formed by copolymerization of polymer monomers; the polymer monomers are acrylamide and zinc 2-acrylamide-2-methylpropanesulfonate, the acrylamide provides a hydrophilic amide group, the hydrophilic amide group and a sulfonate group in the zinc 2-acrylamide-2-methylpropanesulfonate form a dynamic hydrogen bond network, the sulfonate group is covalently anchored to a polymer main chain, and the polymer main chain is covalently anchored to form a dynamic hydrogen bond network. And a main carrier Zn < + > is coordinated with-O-and-N-atoms on a polymer chain. According to the invention, salt-free single ion conduction is realized, concentration polarization is inhibited by sulfonate covalent anchoring, a dynamic hydrogen bond network provides excellent water-retaining property, the problem of moisture evaporation of traditional gel is solved, the interface stability is enhanced by coordination of Zn < + > and a polymer chain, the dendritic crystal inhibition effect is remarkable, and the ion transference number is far greater than that of traditional double-ion electrolyte.

The invention relates to the technical field of high polymer materials, in particular to a corrosion-resistant cable sheath material and a preparation method thereof. The sheath material is prepared by taking an ethylene-octylene copolymer as a matrix and compounding functional fillers such as an aminated magnesium ion exchange A type molecular sieve, dopamine shell silicon dioxide nanoparticles and phenylboronic acid / octadecyl double-grafted silicon dioxide nanoparticles. Wherein the aminated Mg-A molecular sieve is used for efficiently capturing and fixing chloride ions through an ion-dipole effect and a hydrogen bond network; the dopamine shell layer silicon dioxide enhances the interface bonding strength through dual active groups of catechol and amido; phenylboronic acid / octadecyl double-grafted silicon dioxide constructs a dynamic boric acid ester cross-linked network and a hydrophobic barrier, and synergistic protection of crack self-healing and moisture barrier is achieved. The sheath material remarkably improves the long-term corrosion resistance and mechanical stability of the cable in a severe environment.

The invention relates to the technical field of water-based zinc ion batteries, in particular to a functional water-based zinc ion battery electrolyte and a preparation method and application thereof, and the functional water-based zinc ion battery electrolyte comprises soluble zinc salt, an electrolyte additive and deionized water; the electrolyte additive is one or more of stevioside, mogroside, glycyrrhizin, lactitol, raffinose, stachyose and sweet protein (thaumatin). Zinc-philic groups (-COOH,-OH-) of the additive preferentially adsorb a Zn anode to establish a dynamic interface so as to stabilize the Zn anode and inhibit zinc dendrite growth of a zinc cathode. Then the Zn anode is stabilized through chelation interaction between polysaccharide and Zn < 2 + >, a hydrogen bond network in the electrolyte is reconstructed, a solvent structure is adjusted, the activity of original H2O molecules is effectively reduced, dendritic crystal growth, side reaction and corrosion are synergistically inhibited, reversibility of the zinc anode is promoted, the cycle performance of the aqueous zinc ion battery is remarkably improved, and the service life of the aqueous zinc ion battery is prolonged. And the service life of the aqueous zinc ion battery is prolonged.

The invention provides a binary / ternary eutectic solvent viscosity reducer as well as a preparation method and application thereof, and belongs to the technical field of crude oil extraction, gathering and transportation. The binary eutectic solvent mixture provided by the invention comprises the formation water, and the metal chlorate in the formation water can enhance the viscosity reduction capacity of the glycerol-choline chloride eutectic solvent; the ternary eutectic solvent comprises aluminum chloride hexahydrate, aluminum ions and chloride ions are provided to form a synergistic coordination effect with hydroxyl of glycerol, and the hydrogen bond acceptance of the ternary eutectic solvent is remarkably enhanced, so that a hydrogen bond network structure in the heavy oil can be effectively competed and damaged, and the intermolecular force of the heavy oil is weakened; by introducing the pure eutectic solvent, the molecular structure of the thick oil can become looser, the interlocking structure of asphaltene can be easily damaged, meanwhile, the eutectic solvent and the metal chlorate or aluminum chloride hexahydrate in the formation water can self-emulsify the thick oil, the viscosity of the extra-thick oil can be reduced, and therefore the effect of remarkably reducing the viscosity of the extra-thick oil from the molecular level is achieved.

The invention discloses a blue-light perovskite light-emitting diode based on a hydrogen bond network and a preparation method thereof, 3-(5-fluoropyridine-2-yl) acrylic acid hydrochloride molecules are added into a perovskite precursor solution, non-radiative recombination is reduced by passivating defects, and the molecules cooperate with ligands and octahedrons to construct the hydrogen bond network in the crystallization process, so that the blue-light perovskite light-emitting diode based on the hydrogen bond network is obtained. The stability of the octahedral framework is enhanced, ion migration is effectively inhibited, the high-efficiency and high-stability blue-light PeLED is finally obtained, and the external quantum efficiency and the operation stability of the blue-light PeLED are remarkably improved.

The invention belongs to the technical field of dynamic simulation, and discloses a construction method of a molecular dynamic model for different bubble contents of ice and methane hydrate, and the method comprises the following specific steps: 1, selecting a crystal structure of the ice and methane hydrate as a model basis for initial structure construction; by constructing a molecular dynamic model of an ice and methane hydrate coexistence system, the problem of extensive quantitative regulation and control of bubble content is solved, accurate association of microscopic molecule removal and macroscopic volume fraction is realized, force field parameter suitability of a cross-phase interface is optimized, interaction of a hydrogen bond network and molecules at an ice and methane hydrate interface is accurately described, and the method has the advantages of simple operation and low cost. The simulation precision of the molecular diffusion behavior and the structural stability of the interface area is improved, meanwhile, the bubble form diversity and the temperature and pressure coupling environment are comprehensively considered, a multi-dimensional experimental verification system is established, and the influences of different bubble contents on the thermodynamic property, the dynamic behavior and the mechanical property of the system can be systematically evaluated.