The invention provides a preparation method of high-selectivity single-ended vinyl
silicone oil, which comprises the following steps: adding a hydroxyl-terminated
polydimethylsiloxane linear body into low-
viscosity dimethyl
silicone oil, uniformly mixing, adding linear phosphonitrile
chloride for
catalysis, and vacuumizing to remove water; continuously raising the temperature, adding a
viscosity reduction catalyst, mixing a tetramethyl divinyl
disiloxane double-end sealing agent, a dimethyl vinyl ethyoxyl
silane single-end sealing agent and low-
viscosity dimethyl
silicone oil, dropwise adding the mixture into the reaction kettle, keeping the temperature, balancing, vacuumizing, and further removing water; then adding a hexamethyldisilazane neutralizing agent to carry out
neutralization treatment; and after the
neutralization is completed, entering a low-boiling-point removal process, carrying out reduced pressure
distillation to remove low-boiling-point substances, and thus obtaining single-end vinyl
polydimethylsiloxane. The single-ended vinyl
silicone oil is applied to mold
silica gel of liquid
silicone rubber and can replace low-viscosity dimethyl
silicone oil, the product
hardness is adjusted, the oil seepage rate of the
silicone oil is reduced, and the oil seepage phenomenon commonly existing in the industry is improved.