The invention provides a self-repairing hydrated salt
phase change microcapsule as well as a preparation method and application thereof, and belongs to the field of
phase change materials. The preparation method comprises the following steps: preparing a hydrated salt
phase change material and
sorbitol into eutectic melt by adopting a melting method;
strontium carbonate,
sorbitol grafted nano
titanium dioxide, SiO2-coated
silicone rubber microspheres, hollow Al2O3 microspheres,
tannic acid microcapsules, alpha-
zirconium phosphate,
melamine polyphosphate, diethyl aluminum
hypophosphite, carboxylated multi-walled carbon nanotubes, polydopamine modified
boron nitride nanosheets and hydrophilic
fumed silica are added into the eutectic melt, and blending is performed to obtain a core material; The preparation method comprises the following steps: adding
strontium carbonate,
sorbitol grafted nano
titanium dioxide, SiO2-coated
silicone rubber microspheres, hollow Al2O3 microspheres,
tannic acid microcapsules, alpha-
zirconium phosphate,
melamine polyphosphate, diethyl aluminum
hypophosphite, carboxylated multi-walled carbon nanotubes, polydopamine modified
boron nitride nanosheets and hydrophilic
fumed silica into the eutectic melt; bio-based
polyurethane-
polyurea is used as a shell material, the core material is coated in the shell to prepare the microcapsule, and the temperature of the
coating operation is not higher than the
phase change temperature of the hydrated salt
phase change material; the surface is coated with a super-hydrophobic
coating. According to the invention, a
solid filler
system is constructed, and a low-temperature preparation process is combined, so that the phase-change microcapsule with high performance, high reliability and high safety is developed.