979results about How to "Increase crosslink density" patented technology

The invention discloses a photo-thermal aging resistant polyester composite material and a preparation method thereof, a modified monomer, a modified filler, benzophenone, terephthalic acid and neopentyl glycol are subjected to esterification condensation polymerization to prepare the composite material, and the modified monomer is added, so that the prepared polyester molecule is of a branched structure; the side chain of a polyester molecule and the surface of the modified filler both contain unsaturated double bonds which can react after being irradiated by ultraviolet light, so that the number of crosslinking points of the composite material is increased, the crosslinking density is further improved, and the anti-aging effect of the material is further improved; the modified filler can improve the high-temperature-resistant effect of the composite material, the modified filler is matched with the hindered phenol structure of the side chain to further improve the heat aging-resistant effect of the composite material, hydroxyl and ketone groups on the modified filler form intramolecular hydrogen bonds, light energy can be converted into heat energy to be released, and then the light aging-resistant effect of the composite material is improved.

The invention relates to an oil-resistant flame-retardant composite sealing material as well as a preparation method and application thereof, and belongs to the technical field of high polymer materials. Fluororubber, nitrile rubber, ethylene propylene diene monomer, chlorinated polyethylene and maleic anhydride grafted polypropylene are adopted to prepare composite rubber according to a certain proportion; then adding hydrogenated polyisobutene, a vinyl polydimethylsiloxane-polymethylsiloxane silsesquioxane cross-linked polymer, an E-GMA-VA terpolymer, magnesium hydroxide, basalt fiber powder, ammonium polyphosphate, triphenyl phosphate, expansible graphite, zinc borate, a vulcanizing agent, an accelerant, an anti-aging agent, a plasticizer and other components according to a proportion, and performing banburying in special steps; the prepared sealing material has good mechanical properties, especially has oil resistance and flame retardance, and the service life is greatly prolonged.

The invention relates to the field of hot melt adhesives, and discloses a biodegradable hot melt adhesive based on castor oil and rosin resin and a preparation process thereof, the biodegradable hot melt adhesive comprises EVA resin, modified castor oil, rosin resin, a modified additive, a lubricant and an antioxidant; the modified castor oil is prepared by crosslinking castor oil and isophorone diisocyanate and reacting lignin, 1, 4-butanediol and isocyanate groups; the modified castor oil and the modified additive are added, the modified castor oil and the modified additive are added, the modified castor oil and the modified additive are added, the modified castor oil and the modified additive are added, the modified castor oil and the modified additive are added, the modified castor oil and the modified additive are added, and the modified castor oil and the modified additive are added, so that the modified castor oil and the modified additive are added, and the modified castor oil and the modified additive are added; the tensile property and the adhesive property of the hot melt adhesive are improved, and meanwhile, the flame retardant property and the high and low temperature resistance of the hot melt adhesive can be improved.

The invention discloses a composite rubber material with wear resistance and high tear strength and a preparation method of the composite rubber material, and belongs to the technical field of rubber material processing. The technical problem that the enhancement effect of the filler on the wear resistance, tear resistance and mechanical strength of a rubber matrix needs to be further improved exists in the prior art. The composite material comprises the following components in parts by weight: 100-110 parts of internal mixed rubber, 1-2 parts of a vulcanization accelerator and 2-3 parts of a vulcanizing agent, modified polybutadiene is reinforced by aramid pulp, modified carbon black and modified graphene to prepare composite polybutadiene, and then styrene butadiene rubber is reinforced and modified by the prepared composite polybutadiene and silicone rubber to prepare the composite material. By improving the degree of crosslinking between material molecules and optimizing material composition, the wear resistance and tear resistance of the composite rubber material are effectively improved, and the mechanical property of the composite rubber material is also improved.

The invention discloses a low-loss resin composition, which is prepared from the following main components in parts by weight: 10 to 90 parts of acenaphthylene-p-vinylbiphenyl copolymer, 10 to 70 parts of cross-linking agent, 20 to 60 parts of elastomer, 0.1 to 3 parts of initiator and 10 to 90 parts of filler. The acenaphthylene-p-vinylbiphenyl copolymer is obtained by pre-polymerizing acenaphthylene and divinylbiphenyl, the acenaphthylene monomer residue is less, the acenaphthylene monomer is difficult to volatilize in a resin system, implosion caused by too fast curing reaction of the resin system is prevented while good reaction activity is maintained, and a subsequent curing product is high in crosslinking density and good in heat resistance; a machining window is wide, and subsequent production and machining are facilitated; and an acenaphthylene structure has high symmetry and rigidity and does not contain elements such as oxygen, sulfur and nitrogen, so that the resin composition has excellent dielectric properties and thermal properties and a low thermal expansion coefficient, and an elastomer as a cross-linking curing matrix material can provide the characteristics of low dielectric constant, low dielectric loss, low water absorption and the like.

The invention discloses a waterborne epoxy resin coating, a preparation method and application in bridge protection, and belongs to the technical field of coatings. The water-borne epoxy resin coating comprises the following raw material components in parts by weight: 15-25 parts of epoxy composite resin emulsion, 100 parts of emulsified asphalt, 3-5 parts of a curing agent and 6-10 parts of water, wherein the epoxy composite resin emulsion is obtained by carrying out a composite reaction on 30-60 parts by mass of epoxy resin, 2-3 parts by mass of an emulsifier, 6-9 parts by mass of an acrylate composition and 1.4-1.6 parts by mass of a co-stabilizer; the acrylate composition is prepared by prepolymerizing 15 to 16 parts by mass of butyl methacrylate, 10 to 12 parts by mass of 2-isopropenyl aniline, 5 to 7 parts by mass of allyl glycidyl ether and 1 to 1.2 parts by mass of allyl polyhedral oligomeric silsesquioxane and then combining the prepolymerized materials with 1 to 3 parts by mass of acrylic acid.

The invention relates to the technical field of epoxy molding compounds, in particular to a low-shrinkage and high-heat-resistance epoxy molding compound and a preparation method thereof. The low-shrinkage and high-heat-resistance epoxy molding compound is prepared from the following raw materials in parts by weight: 6 to 8 parts of epoxy resin, 3 to 7 parts of phenolic resin, 80 to 90 parts of filler, 0.6 to 1 part of modifier, 0.1 to 0.5 part of accelerant, 0.2 to 0.4 part of coupling agent, 0.3 to 0.8 part of flexibilizer, 0.2 to 0.4 part of release agent, 0.2 to 0.4 part of coloring agent and 0.3 to 0.5 part of flame retardant, the modifier is a mixture of 1-phenyl-5-mercaptotetrazole and 5-aminotetrazole according to a weight ratio of 5: (1 to 5); the prepared epoxy molding compound has the characteristics of low shrinkage and high heat resistance.

The invention provides soft environment-friendly automobile interior leather, which comprises a polyolefin base material layer and a surface coating, the polyolefin base material layer comprises: a component (A): a mixture composed of 10-90 parts by weight of an ethylene copolymer elastomer and 10-90 parts by weight of ethylene-propylene-diene monomer, the sum of the weight parts of the ethylene copolymer elastomer and the ethylene-propylene-diene monomer being 100; and a component (B): 0-5 parts by weight of an assistant cross-linking agent. The automotive trim leather provided by the invention is soft, anti-aging and low-volatility, has good tensile strength, low-temperature folding resistance and flexibility, and is wide in processing window, simple in process and low in cost.

The invention relates to the technical field of high polymer materials, and discloses rosin-based bio-based ultraviolet curing resin as well as a preparation method and application thereof. The structural formula of the rosin-based bio-based ultraviolet curing resin provided by the invention is shown as a formula (I). The ultraviolet curing resin has a tricyclic diterpene rigid structure and carbon-carbon double bonds, has good crosslinking density, adhesion property, mechanical property and thermal stability after being cured into a film, and can be applied to the fields of adhesives, sealants or ultraviolet curing coatings and the like. The ultraviolet curing resin is prepared by taking a bio-based material as a raw material, and the preparation method is simple, green and environment-friendly. # imgabs0 #

The invention relates to the technical field of adhesives, and discloses an antibacterial mildew-proof water-based adhesive and a preparation method thereof. The preparation method of the antibacterial and mildew-proof water-based adhesive comprises the following steps: reacting 2, 2-dimethylolpropionic acid with castor oil to obtain hyperbranched bio-based polyol; modifying the hyperbranched bio-based polyol by using a modifier to obtain modified bio-based polyol; the preparation method comprises the following steps: preparing a waterborne polyurethane dispersion liquid by taking modified bio-based polyol, a hybrid modified BN / MOF composite material and hexamethylene diisocyanate as raw materials and 1, 4-butanediol as a chain extender; the preparation method comprises the following steps: mixing a waterborne polyurethane dispersion liquid, a wetting agent, a defoaming agent, a thickening agent and water to obtain a component A; an aliphatic curing agent is used as a component B; during use, the component A and the component B are mixed and stirred. The antibacterial and mildewproof water-based adhesive disclosed by the invention has excellent adhesion performance, water resistance, self-repairing performance and lasting antibacterial and mildewproof performance.

The invention relates to the technical field of packaging materials, and discloses an antibacterial functional food packaging film and a preparation method thereof.The packaging film is formed by taking low-density polyethylene as a main raw material, adding a compatilizer, a synergistic antibacterial agent, a fiber coating material and the like and carrying out blending, extrusion and film blowing processes. The synergistic antibacterial component is nano-zinc oxide with the surface grafted with biomass antibacterial agent tannic acid, after being immobilized on the surface of the nano-zinc oxide, the tannic acid cannot be easily volatilized and migrated, the broad-spectrum antibacterial performance of the tannic acid is continuously exerted, and the tannic acid and the photocatalytic antibacterial effect of the nano-zinc oxide are mutually cooperated, so that the synergistic antibacterial effect is achieved. Due to the addition of the fiber coating material, the density of the polyethylene film can be improved, and the air tightness and the high-temperature-resistant effect can be improved. In addition, the fiber coating material can exert stress load transfer and absorption effects, so that the prepared polyethylene film has excellent mechanical strength.

The invention relates to a mussel-like polylipoic acid-based hydrogel adhesive as well as a preparation method and application thereof, and the preparation method comprises the following steps: (1) uniformly mixing a sericin solution and a caffeic acid solution, then carrying out grafting reaction to obtain a reaction solution, and carrying out dialysis treatment and drying on the reaction solution to obtain sericin grafted caffeic acid; (2) adding lipoic acid into the lithium hydroxide solution, stirring until the lipoic acid is completely dissolved, then adding sericin grafted caffeic acid, and heating for reaction to obtain a PTALi-CAS mixture; and (3) cooling the PTALi-CAS mixture, so as to obtain the mussel-like polylipoic acid-based hydrogel adhesive. The dual-network PTALi-CAS hydrogel adhesive obtained in the invention realizes wet adhesion and rapid hemostasis, has excellent comprehensive performance, and is beneficial to providing a good repair environment for wounds as a wound dressing.

The invention relates to the technical field of adhesives, and discloses a weather-resistant transparent adhesive, a preparation method and application of the weather-resistant transparent adhesive to adhesion of a weather-resistant and wear-resistant transparent film and a color-coated sheet. The preparation method of the weather-resistant transparent adhesive comprises the following steps: reacting 4-(2, 3-ethylene oxide) benzaldehyde with tetrakis (3-mercaptopropionic acid) pentaerythritol ester to obtain an intermediate product A; reacting the intermediate product A with 4, 5-diaminobenzene-1, 2-diphenol to obtain an intermediate product B; preparing nano zinc oxide, performing surface modification on the nano zinc oxide, and grafting the intermediate product B to obtain an organic-inorganic hybrid curing agent; modifying epoxy resin by using the composite modifier to obtain modified epoxy resin; the modified epoxy resin, the organic-inorganic hybrid curing agent and the accelerant are mixed and stirred, and the weather-resistant transparent adhesive is obtained; the weather-resistant transparent adhesive disclosed by the invention is high in transparency and has excellent mechanical strength, toughness, adhesiveness and weather resistance.

The invention relates to the technical field of silicone rubber, and discloses a preparation method of a modified silicone rubber elastomer, the modified silicone rubber elastomer comprises 100 parts by weight of methyl vinyl silicone rubber, 5-25 parts by weight of organosilicon grafted cellulose microcrystalline, 12-20 parts by weight of white carbon black, 1.7-2.4 parts by weight of a vulcanizing agent, 2.6-4.2 parts by weight of a cross-linking agent, and 1.5-2 parts by weight of an auxiliary agent, 1.2 to 1.6 parts by weight of an anti-aging agent; the organic silicon grafted cellulose microcrystal contains a siloxane structure and has good compatibility with the methyl vinyl silicone rubber, and in the high-temperature vulcanization process, alkenyl of the organic silicon grafted cellulose microcrystal can be subjected to a cross-linking reaction with the methyl vinyl silicone rubber and triallyl isocyanurate, so that the organic silicon grafted cellulose microcrystal can be used for curing the methyl vinyl silicone rubber and the triallyl isocyanurate. The interface bonding strength between the cellulose microcrystal and the methyl vinyl silicone rubber is enhanced, so that the silicone rubber elastomer shows higher tensile property, hardness and tearing strength.

The invention relates to the technical field of epoxy resin coatings, and discloses an inorganic composite nano anticorrosive coating material and a preparation method thereof. The inorganic composite nano anticorrosive coating material comprises a component A, a component B and a component C, wherein the component C is obtained by mixing a functional modified inorganic composite nano material and aluminum sorbate; the component A is obtained by mixing modified epoxy resin, a defoaming agent and an anti-settling agent, and the component B comprises a polyamide curing agent. The inorganic composite nano anticorrosive coating material disclosed by the invention has excellent toughness, wear resistance, corrosion resistance, antibacterial and antifouling properties and ultraviolet resistance.

The invention belongs to the field of electrode paste preparation, and provides low-temperature curing silver-coated copper paste for a heterojunction solar cell and a preparation method of the low-temperature curing silver-coated copper paste. Ethyl cellulose is adopted as a matrix material, a stable matrix network is provided for slurry through good cohesiveness and dispersity of ethyl cellulose, and a network structure with a high crosslinking degree is formed by adding modified phenolic resin, organic silicon modified epoxy acrylate and other chemical modification materials into the slurry. The mechanical strength and adhesive force of the slurry are further enhanced, surface modification is carried out on inorganic filler such as silver-coated copper powder and bismuth oxide through a silane coupling agent and a titanate coupling agent, and the interface bonding force between the filler and an organic matrix is enhanced through silicon-oxygen bonds formed on the surface of the filler; by adding the carboxylated polyamide wax and the organic bentonite, the agglomeration tendency of the filler is reduced by utilizing the adsorption and electrostatic repulsion effects of the carboxylated polyamide wax and the organic bentonite on filler particles, and the obtained conductive slurry has the characteristics of excellent conductivity and low-temperature rapid curing.

The invention relates to the technical field of cutter manufacturing, in particular to a high-strength and high-toughness ceramic cutter and a preparation method thereof. The metal ions are loaded on the boron nitride nanosheets, the agglomeration phenomenon of the boron nitride nanosheets can be improved through loading of the metal ions, the interaction force between the boron nitride nanosheets is enhanced, and therefore the mechanical strength of boron nitride is improved. According to the preparation method disclosed by the invention, a complex with adhesion is formed on a boron nitride nanosheet by utilizing the chelation of tannic acid and iron ions, and boron nitride loaded with the iron ions and modified hydrotalcite are adhered together by utilizing the adhesion of the complex. The prepared modified soybean protein has a large number of amino groups, the boron nitride-hydrotalcite compound with the amino groups has better compatibility with a modified soybean protein binder, the dispersity of the boron nitride-hydrotalcite compound in a matrix is improved, and the strength and toughness of the ceramic cutting tool are improved.

The invention relates to an anti-yellowing automobile composite film and a preparation method thereof, and belongs to the technical field of high polymer materials. The yellow-resistant automobile composite film is prepared from the following components in parts by weight: 60 to 70 parts of PVC (Polyvinyl Chloride) master batch, 10 to 20 parts of TPU (Thermoplastic Polyurethane) master batch, 1 to 2 parts of plasticizer, 0.5 to 0.8 part of flatting agent, 0.1 to 2 parts of yellowing-resistant modifier and 0.1 to 2 parts of modified flame retardant, sym-triazine cyanuric chloride and a benzotriazole intermediate in the anti-yellowing modifier absorb ultraviolet rays and reduce yellowing of the ultraviolet rays on the composite material, and maleimide groups, maleic anhydride and isocyanurate rings for increasing the crosslinking density cooperate with one another, so that the heat resistance of the material is improved, and the yellowing is reduced; phosphorus and nitrogen main chains of phosphonitrilic chloride trimer in the modified flame retardant have a conjugation effect, so that a protective film is formed, oxygen is isolated, and the phosphonitrilic chloride trimer and nitrogen are synergistically flame-retardant; the anti-yellowing automobile composite film prepared by the invention not only has excellent ultraviolet absorption performance, heat resistance and anti-yellowing effects, but also has a good flame retardant effect.

The invention relates to a hybrid hydrogel immobilized double-enzyme cascade reactor as well as a preparation method and application thereof. A biomimetic mineralization method is adopted for preparing a metal organic framework compound embedded with combined enzyme, the metal organic framework compound is dispersed in a water-soluble monomer, combined enzyme cascade reaction enzyme is utilized for catalyzing monomer polymerization, in-situ immobilization without damage to double enzymes is achieved while a hybrid hydrogel network structure is formed, and the immobilized double-enzyme cascade reactor is obtained. The hybrid hydrogel immobilized double-enzyme cascade reactor prepared by the invention is high in enzyme immobilization rate, good in enzyme stability, controllable in double-enzyme immobilization proportion, simple to operate, mild in condition and easy to implement; the prepared hybrid hydrogel immobilized double-enzyme cascade reactor has adsorption and degradation functions, phenolic compounds in water can be effectively enriched, the local concentration of the phenolic compounds near immobilized double enzymes is improved, the efficiency of catalytic degradation of the phenolic compounds through double-enzyme cascade reaction is improved, and the service life of the reactor is prolonged. The method can be applied to efficient treatment of wastewater containing phenolic compounds.

The invention relates to a polypropylene insulated power cable and a preparation method thereof, and belongs to the technical field of cables. The polypropylene insulation power cable comprises a copper conductive wire core, a metal shielding layer and a sheath layer, the metal shielding layer comprises a conductor shielding layer, a polypropylene insulation layer and an insulation shielding layer which are arranged from inside to outside, and the sheath layer comprises polypropylene, organic modified graphene, lignite wax, an antioxidant and an anti-UV agent; graphene and agarose form a firm covalent bond compound, then glycidyl methacrylate and eugenol are used for coating the outer layer of a graphene / agarose particle core, the dispersity and compatibility of graphene in a system are remarkably improved, and then the tensile strength and elongation at break of a polypropylene sheath layer material are remarkably improved; therefore, the polypropylene insulated power cable has excellent mechanical properties.

The invention relates to a polyorganosilicone cyclophosphazene modified epoxy resin and a preparation method thereof, and belongs to the field of flame retardant materials, and the preparation method of the polyorganosilicone cyclophosphazene flame retardant comprises the following steps: taking hexachlorotripolyphosphazene, p-hydroxybenzaldehyde, p-aminobenzoic acid, DOPO and diphenyl silanediol as raw materials, and carrying out four-step reaction to prepare the polyorganosilicone cyclophosphazene modified epoxy resin. The preparation method comprises the following steps: by taking m-phenylenediamine as a curing agent, adding the series gradient polyorganosilicone cyclophosphazene flame retardant into the epoxy resin, and curing twice to obtain the modified epoxy resin. The preparation method is mainly used for preparing the polyorganosilicone cyclophosphazene flame retardant and the polyorganosilicone cyclophosphazene modified epoxy resin.

The invention relates to a low-smoke halogen-free flame-retardant polyolefin insulation material for an in-vehicle high-voltage cable. The low-smoke halogen-free flame-retardant polyolefin insulation material comprises the following raw materials in parts by mass: 30-50 parts of SEBS, 30-50 parts of an ethylene-propylene-butylene block copolymer elastomer, 10-20 parts of a polyethylene grafted maleic anhydride compatilizer, 3-5 parts of color master batch, 1.5-2.5 parts of an antioxidant, 110-130 parts of aluminum hydroxide, 1.5-3 parts of phosphorus-containing silane, 1-2 parts of a cross-linking agent and 3-5 parts of silicone master batch. The SEBS is in the form of an unoil-filled particle; the aluminum hydroxide is powdery and is modified by phosphorus-containing silane; the cross-linking agent is a polyfunctional group cross-linking sensitizer, and the number of functional groups is not less than 2. The preparation method of the insulating material comprises the following steps: S1, modifying aluminum hydroxide powder by using phosphorus-containing silane; s2, uniformly mixing the matrix resin; s3, granulating by adopting a double-screw extruder with a large length-diameter ratio; s4, the materials obtained in the step S3, the materials obtained in the step S1 and other raw materials are subjected to banburying and double-stage production granulation, and a finished product is obtained.

The invention belongs to the technical field of high polymer materials, and relates to a negative OC photoresist with low residual stress and high refractive index as well as a preparation method and application of the negative OC photoresist. The negative photoresist with the high refractive index at least comprises the following raw materials in parts by weight: 10-22 parts of nanoparticles with the high refractive index, 2-3 parts of an epoxy monomer, 3-10 parts of acrylic resin, 1-3 parts of an acrylic monomer, 1.5-4 parts of a photoinitiator, 0-4 parts of a photosensitizer, 0.01-0.5 part of a surfactant, 0-2 parts of a curing agent and 30-70 parts of a solvent. According to the invention, the epoxy monomer (spiro orthocarbonate compound) is added in the formula to form stable interaction with the nanoparticles, so that the dispersity of the nanoparticles in a polymer matrix is improved, and the overall performance of the photoresist is optimized.

The invention discloses a bending-resistant, high-rubber and wear-resistant anti-reflection film and a preparation method thereof. The anti-reflection film comprises a base material layer, a hardened layer, a high-refractive-index layer and a low-refractive-index layer which are sequentially stacked, the hardened layer is obtained by coating the base material layer with hardened layer coating liquid and then curing the hardened layer coating liquid; the hardened layer coating liquid is prepared from the following raw materials in parts by weight: 50-80 parts of hardened resin; 10 to 30 parts of flexible resin; 5-20 parts of a modified inorganic nanoparticle dispersion liquid; 3-6 parts of a first photoinitiator; 50 to 100 parts of a first solvent; wherein the flexible resin is flexible vinyl resin which is prepared by modifying epoxy vinyl ester resin through carbamic acid ester. According to the invention, optical design, formula design, thickness design and the like are carried out on a plurality of coatings, so that the requirements of appearance uniformity, hue uniformity and strong bonding force among laminated layers of the three coatings can be met, and the anti-reflection film has excellent antifouling, scratch-resistant, rubber friction-resistant and bending-resistant properties.

The invention discloses a high-strength cold-resistant cable material and a preparation method thereof. The cable material disclosed by the invention has the advantages of high strength, cold resistance, corrosion resistance, flame retardance and the like, and is widely applied to severe cold rural areas, wind power stations, solar equipment and the like. According to the cable material, the PVC resin serves as a main raw material, nitrile rubber with excellent cold resistance is added as an auxiliary raw material, various auxiliaries are added, the comprehensive performance of a matrix is improved, the toughness of the matrix is improved through the synergistic effect of the modified filler and the macromolecular plasticizer, and then the matrix still has good performance at low temperature; and the matrix has the advantages of high strength, cold resistance, corrosion resistance, flame retardance and the like.

The invention provides impact-resistant high-toughness plastic as well as a preparation method and application thereof, and relates to the technical field of high polymer materials. Comprising the following raw materials in parts by weight: 35-45 parts of hydroxyl-terminated hyperbranched polycarbonate, 15-25 parts of LDPE (Low-Density Polyethylene) resin, 8-12 parts of inorganic filler, 4-6 parts of isocyano ethyl methacrylate, 1-3 parts of bis (1-vinyl imidazole-2-) ketone, 1-3 parts of bis (trimethylsilylated) vinyl phosphate, 1-3 parts of 1, 3, 5-triglycidyl-S-triazinetrione, 1-3 parts of 3, 3 '-diamino-4, 4'-diphenyl-1, 3, 4-triazole-2-ketone, 1-3 parts of 1, 3, 5-triazole-2-ketone, 1-3 parts of 1, 3 '-trimethylsilylated vinyl phosphate, 1-3 parts of 2, 3'-diphenyl-1, 3, 4, 5- The material is prepared from the following components in parts by weight: 1-3 parts of 4, 4 '-difluorodiphenyl sulfone, 2-4 parts of a coupling agent, 0.5-1.5 parts of an antioxidant, 0.8-1.2 parts of a compatilizer, 0.7-1 part of a catalyst and 0.8-1 part of an initiator. The plastic has the advantages of favorable mechanical properties, favorable heat aging resistance, favorable impact toughness, favorable flame retardancy and favorable environmental friendliness.

The invention discloses an antibacterial bamboo joint pull rope material for tampons and a preparation method of the antibacterial bamboo joint pull rope material. Modified bentonite is introduced into an acrylic acid-acrylamide polymer, and a layered structure of the bentonite endows the antibacterial bamboo joint pull rope material with certain water absorption and water retention capacities; meanwhile, amino groups on the modified bentonite are chemically combined with carboxyl groups in the acrylic acid-acrylamide polymer, so that the modified bentonite is not easy to lose; according to the preparation method, firstly, water-absorbing fibers are soaked in a carboxymethyl chitosan solution, the surfaces of the water-absorbing fibers are coated with carboxymethyl chitosan, the carboxymethyl chitosan has excellent water-retaining and antibacterial properties, an antibacterial water-retaining layer is formed on the surfaces of the water-absorbing fibers, and then under the action of a cross-linking agent ethylene glycol diglycidyl ether, the antibacterial water-retaining layer is formed on the surfaces of the water-absorbing fibers. Hydroxyl groups and amino groups in the carboxymethyl chitosan and carboxyl groups and amino groups on the water-absorbing fibers are subjected to a cross-linking effect, so that the bonding strength and the cross-linking density between the carboxymethyl chitosan and the water-absorbing fibers are improved, liquid seepage is effectively prevented, and the water retention performance of the fiber material is further improved.

The invention relates to the technical field of preparation of high-performance composite materials, and discloses a multilayer fabric laying method for improving interlayer bonding strength of a carbon fiber material, which comprises the following steps: step 1, selecting carbon nanotubes or graphene sheets as nanoparticles, carrying out chemical oxidation treatment to introduce functional groups, and carrying out functionalization treatment by using a silane coupling agent; step 2, mixing the functionalized nano particles with epoxy resin in a high-shear-force mixing device to form uniform nano reinforced resin; and 3, weaving the carbon fibers according to a predetermined three-dimensional structure mode by using a three-dimensional weaving machine, and monitoring the fiber tension and the weaving density in real time in the weaving process. By using nanoparticles to reinforce the composite material and carrying out chemical oxidation and coupling agent functionalization treatment, the interface adhesive force between the carbon fibers and the epoxy resin is improved, functional groups can form stronger chemical bonds with the resin, the interlaminar shear strength of the composite material is improved, and the overall structural integrity and durability of the material are enhanced.

The invention provides a thermosetting resin composition, a resin adhesive film and application thereof. The thermosetting resin composition comprises the following components in parts by mass: 5-95 parts of benzocyclobutene resin, 5-95 parts of a component containing C = C unsaturated bonds, 5-300 parts of a modified filler and 0.1-10 parts of an initiator, the modified filler is an inorganic filler subjected to surface treatment by a coupling agent containing unsaturated groups, and the unsaturated groups are selected from any one or a combination of at least two of styryl, acryloyloxy, methacryloyloxy and polybutadiene groups. A resin adhesive film prepared from the thermosetting resin composition is excellent in dielectric property, low in dielectric loss tangent Df, good in dielectric stability, small in Df (10GHz) variation amplitude after HAST, high in chemical copper binding force and capable of fully meeting the performance requirement for preparing a high-frequency and high-speed printed circuit board through a semi-addition method or an addition method.

The invention relates to the technical field of polyester resin, and discloses outdoor hydrolysis-resistant polyester resin and a preparation method and application thereof.The outdoor hydrolysis-resistant polyester resin is prepared from, by weight, 30-38 parts of polyhydric alcohol, 48-50 parts of binary acid, 20.5-28.5 parts of acidolysis agent and 0.1-0.12 part of onium salt curing accelerator; according to the invention, 2-butyl-2-ethyl-1, 3-propylene glycol is used as polyol, and an alkyl side chain is introduced into polyester molecules to generate steric hindrance and shielding effects, so that water molecules are difficult to attack adjacent lipid bonds, and the hydrolysis resistance of the polyester resin is improved. 2, 2 '-[(2-hydroxy-3-phenoxy propyl) azadiyl] diethanol contains a benzene ring structure with thermal stability, and is crosslinked into a polyester molecular chain, so that the glass transition temperature of the polyester resin can be increased, the heat resistance can be improved, and the boiling water resistance of a resin coating can be improved.