3501results about How to "Accelerated corrosion" patented technology

The invention belongs to the technical field of polymer plastic materials, and particularly relates to a high-temperature-resistant anti-corrosion polytetrafluoroethylene material and a preparation method thereof. The polytetrafluoroethylene is prepared from the following raw materials in parts by weight: 50 to 60 parts of polytetrafluoroethylene, 5 to 10 parts of fluorinated modified graphene oxide, 3 to 5 parts of aluminum powder, 5 to 8 parts of modified silicon carbide fiber, 3 to 5 parts of silane modified nano silicon dioxide, 2 to 3 parts of polyphenylene sulfide, 2 to 3 parts of polyimide, 0.5 to 0.8 part of dispersing agent and 0.5 to 1 part of antioxidant. The heat conduction performance and the interface bonding force are improved through the fluorinated modified graphene oxide, the impact resistance and the wear resistance are enhanced through the silicon carbide fibers, and the corrosion resistance and the wear resistance are improved through the aluminum powder; silane modified silicon dioxide enhances the mechanical property of the composite material by improving the dispersity of the filler, and PPS and PI interact with the surface of the filler through polar groups in molecular chains, so that the interface strength is improved, and the toughness and the thermal stability are improved.

The invention discloses a copper alloy pipe and a preparation method and application thereof, and the copper alloy pipe comprises the following components in percentage by mass: 0.01%-0.80% of Sn, 0.005%-0.05% of P, 0.01%-0.10% of Zr, 0.001%-0.01% of B, 0.001%-0.01% of Mn and the balance of Cu and inevitable impurities. Wherein the copper alloy pipe contains MnZr and BMn compound particles, the number of the MnZr compound particles on the cross section of the copper alloy pipe is 0.005-0.15 / mu m < 2 >, and the number of the BMn compound particles on the cross section of the copper alloy pipe is 0.005-0.2 / mu m < 2 >. By adding Zr, B and Mn and controlling the content of Zr, B and Mn, the preparation process and the like, the number and uniformity of MnZr and MnB compounds are regulated and controlled, and the tensile strength, ductility, corrosion resistance, bending, flaring, welding, pressure resistance and other machining performance of the copper alloy pipe are improved; and the prepared copper alloy pipe fully meets the application requirements of heat conduction pipes of air conditioner heat exchangers, air conditioner indoor and outdoor unit connecting piping and the like.

The invention discloses a microencapsulation repairing agent and an intelligent self-repairing ultrahigh-strength ultrahigh-toughness cement-based structural material, the microencapsulation repairing agent is mainly composed of a humidity-responsive outer layer, a pH-responsive middle layer and a temperature-responsive inner layer, and the outer layer is modified with a silane coupling agent. The intelligent self-repairing ultrahigh-strength ultrahigh-toughness cement-based structural material is mainly prepared from the microencapsulated repairing agent, nano carbon black, nano montmorillonite, nano cellulose and other raw materials. According to the invention, by introducing the self-repairing microcapsule with a specific structure and materials such as nano carbon black, nano montmorillonite and nano cellulose, the strength, toughness and durability of the concrete are remarkably improved, and the concrete has an intelligent self-repairing function.

The invention discloses a method for harmlessly treating lithium slag and preparing a water-stable material from the treated lithium slag. The method comprises the following steps: crushing the lithium slag; mixing a sulfuric acid-containing material with the crushed lithium slag to obtain a pulpified mixture; roasting, and carrying out chemical modification to obtain roasted slag; adding a material containing activated aluminum oxide into the roasting slag to obtain a mixed material; the mixed material is subjected to water leaching and filtering, and leaching residues and leaching liquid are obtained; and drying the leaching slag, adding an exciting agent, and grinding to finally obtain the detoxified lithium slag. And preparing the water-stable material from the detoxified lithium slag. Under the condition of effectively improving the quality of the cement-stabilized layer, the lithium slag resource is effectively utilized, the resource utilization rate is improved, and the mechanical strength and corrosion resistance of the cement-stabilized layer concrete can be effectively improved by matching with the exciting agent and the curing agent.

The invention discloses a heat insulation aluminum profile and a preparation method thereof, and belongs to the technical field of aluminum profile preparation. The heat insulation coating is electrostatically sprayed on the surface of the aluminum profile, the coating takes epoxy resin as a matrix, the aluminum profile is separated from the external environment, and the corrosion resistance and the heat insulation performance of the aluminum profile are improved; compared with common nano ATO, the prepared modified nano ATO has better compatibility with an epoxy resin matrix, the agglomeration phenomenon is obviously reduced, and the heat insulation performance of the coating can be greatly enhanced; the prepared modifier can significantly enhance the flame retardance and heat resistance of the coating, can promote curing of epoxy resin, is grafted on nano ATO, and is stable in performance and not prone to falling off; therefore, the prepared aluminum profile is excellent in heat insulation property and corrosion resistance, the coating sprayed on the surface of the aluminum profile has stable and efficient flame retardance and heat resistance, and the aluminum profile has important application value in the technical field of aluminum profile preparation.

The invention discloses a synthetic method of a water soluble ultraviolet light absorber BP-9. The method mainly comprises the following process steps: (1) carrying out methylation on the main raw materials of 2, 2', 4, 4'-tetrahydroxyl benzophenone, a transition metal salt catalyst and a mixed solvent which is prepared from dichloroethane and anhydrous ethanol in equal parts by weight to obtain 2, 2'-dihydroxyl-4, 4'-dimethoxyl benzophenone; (2) carrying out sulfonation reaction on the main raw materials of methylate, sulfamic acid and C1-C3 halohydrocarbon to obtain 2, 2'-dihydroxyl-4, 4'-dimethoxyl benzophenone-5, 5'-disulfonic acid; and (3) carrying out neutral reaction on the main raw materials of sulfonated product, inorganic base and ethanol water to finally obtain the BP-9 product. The synthetic method disclosed by the invention is few in reaction step, low in cost, high in product purity and stable in quality, and raw materials are easily available.

The invention discloses thermosetting unsaturated polyester resin as well as a preparation method and application thereof, and belongs to the technical field of unsaturated polyester resin. The raw materials comprise the following components in parts by weight: 270 to 380 parts of neopentyl glycol, 90 to 150 parts of ethylene glycol, 400 to 570 parts of isophthalic acid, 0.4 to 1.0 part of an antioxidant, 0.3 to 0.8 part of a catalyst, 80 to 170 parts of propylene glycol, 260 to 380 parts of maleic anhydride, 0.03 to 0.09 part of a first polymerization inhibitor, 0.1 to 0.3 part of a second polymerization inhibitor, 0.1 to 0.4 part of a third polymerization inhibitor and 800 to 900 parts of styrene. The thermosetting unsaturated polyester resin disclosed by the invention has relatively high mechanical properties and corrosion resistance after being cured, still can keep relatively high mechanical properties after being corroded by acid and alkali, is high in bending deformation resistance, and can be applied to thermosetting trenchless repair of buildings or pipelines.

The invention relates to a high-toughness corrosion-resistant aluminum alloy and a preparation method thereof. The high-toughness and corrosion-resistant aluminum alloy is prepared from the following components in percentage by mass: 3.5 to 4.6 weight percent of Mg, 1.3 to 1.5 weight percent of Zn, 0.1 to 0.4 weight percent of Sc, 0.4 to 0.5 weight percent of Zr, 0.4 to 0.5 weight percent of Cu and the balance of Al. The optimized preparation method comprises the steps that aluminum alloy mixed powder serves as a raw material, laser additive manufacturing is adopted, and a printed product is obtained through printing; during printing, the laser power is controlled to range from 250 W to 350 W, the laser scanning speed ranges from 800 mm / s to 1200 mm / s, the laser spot diameter ranges from 60 micrometers to 80 micrometers, the scanning interval ranges from 0.02 mm to 0.05 mm, and the powder laying thickness ranges from 0.03 mm to 0.05 mm. Based on a cross alloy design strategy, the in-situ alloying powder manufacturing technology and the laser powder bed melting technology are combined, collaborative optimization of the mechanical property and the corrosion resistance is achieved, meanwhile, the material development and preparation cost is effectively reduced, and the application requirements of multiple fields are met.

The invention discloses a high-quality formed ginkgo wood furniture manufacturing and processing technology, and relates to the technical field of furniture production, and the high-quality formed ginkgo wood furniture manufacturing and processing technology comprises ginkgo wood selection, ginkgo wood treatment, wood modification, part processing and surface treatment. Before drying, the cut ginkgo biloba boards are subjected to primary treatment, surface impurities are removed, and primary balance treatment is carried out, so that stress concentration in the later drying process is reduced; primarily drying the primarily treated wood, adjusting the thickness and the drying temperature and humidity of the wood, adjusting the temperature in the drying chamber according to the thickness and the initial water content of the wood by using a combined drying technology, and controlling the distance between the wood to be 1 / 10-1 / 8 of the width of the wood through a circulating air drying system. By means of the combined drying technology, dynamic control over the ginkgo wood drying quality is achieved, the problems that the drying process is complex and wood is prone to warping or cracking during drying are solved, the drying period is shortened, wood deformation and cracking are reduced, the physical performance of the wood is improved, and the drying efficiency is improved.

The invention relates to the technical field of metal material protective coatings, in particular to high-wear-resistance and corrosion-resistance mechanical steel and a preparation method thereof. Comprising the following steps that S1, the surface of a mechanical steel base body is pretreated, and pretreated mechanical steel is obtained; s2, a base coat and a metal layer are sequentially arranged on the surface of the pretreated mechanical steel; S21, base coat powder is sprayed to the surface of the pretreated mechanical steel through the high velocity oxy-fuel spraying technology, and the base coat is obtained; s22, metal layer powder is sprayed on the surface of the priming layer through the high velocity oxy-fuel spraying technology, and a metal layer is obtained; s3, the surface of the metal layer is evenly coated with a reinforcing coating in a brushing mode, and after drying and curing, a coating layer is obtained; and the high-wear-resistance and corrosion-resistance mechanical steel is prepared.

The invention discloses a pure smelting method for nickel-based superalloy, which relates to the technical field of metal smelting and comprises the following steps: (1) screening high-purity raw materials; (2) selecting a vacuum induction melting furnace and carrying out vacuumizing treatment; (3) sequentially adding the pretreated raw materials into a vacuum induction melting furnace, and heating and melting the raw materials; (4) carrying out electromagnetic stirring; (5) preparing special electroslag, and drying and crushing the electroslag; and (6) casting the alloy liquid subjected to vacuum melting into a consumable electrode, inserting the consumable electrode into the slag of the electroslag remelting furnace, and electrifying. According to the design scheme, impurities in the nickel-based superalloy are effectively removed, the purity and uniformity of the alloy are improved, the mechanical property and thermal stability of the alloy are improved, the service life is prolonged, and a better purification effect is achieved.

The invention relates to an offshore floating type wind power steel shell concrete composite structure platform and a construction method, the platform comprises a steel shell, and the steel shell comprises an outer side steel shell and an inner side steel shell which are arranged at an interval; the inner concrete filling layer is filled between the outer side steel shell and the inner side steel shell; the connecting structure is arranged at the joint of the steel shell and the internal concrete filling layer and used for enhancing the connecting rigidity and stability of the steel shell and the concrete; the connecting structure comprises transverse reinforcing rib plates, longitudinal reinforcing rib plates, partition plates and anti-shear studs, the transverse reinforcing rib plates and the longitudinal reinforcing rib plates are arranged in a grid shape, the space between the outer side steel shell and the inner side steel shell is divided into a plurality of areas through the partition plates, and the anti-shear studs are used for enhancing the anti-shear capacity between the steel shells and concrete. Through innovative connection structure design, a steel structure is combined with concrete, efficient and intelligent hole design is combined with an advanced sensing technology, automatic control and intelligent monitoring, the construction quality of the structure is guaranteed, and an efficient and low-maintenance structural form is provided.

The invention belongs to the field of rail manufacturing, and specifically discloses a manufacturing method for improving the low temperature fracture resistance and contact fatigue damage resistance of rails and the rails obtained thereby. The method comprises the following steps: converter smelting, LF refining, RH vacuum treatment, billet continuous casting, billet cleaning and cooling, billet heating, rail rolling, online heat treatment and post-treatment, wherein: during the converter smelting process, bottom blowing of nitrogen is performed; after the RH vacuum treatment, iron-calcium wire feeding treatment is performed. Calculated by mass percentage, the chemical composition of the steel billet includes: C: 0.50-0.65%, Si: 0.45-0.95%, Mn: 0.35-0.85%, Cr: 030-0.80%, Cu: 0.20-0.55%, Ni: 0.10-0.30%, N: 0.007-0.030%, and the chemical composition of the steel billet also includes at least one of V, Nb, and Ti, wherein V: 0.02-0.15%, Ti: 0.001-0.030%, Nb: 0.01-0.08%, and the rest is Fe and unavoidable impurities. The steel rail obtained by the method provided by the present invention has excellent comprehensive properties such as resistance to low-temperature fracture, resistance to contact fatigue, corrosion resistance and weldability.

The invention relates to the field of aluminum alloy plates, and discloses a high-strength corrosion-resistant marine aluminum alloy plate and a processing technology thereof.The aluminum alloy plate comprises an aluminum alloy base material and a corrosion-resistant coating, and the aluminum alloy base material is prepared from, by weight, 0.4%-0.8% of Si, 0.5%-0.7% of Fe, 0.15%-0.4% of Cu, 0.1%-0.15% of Mn, 0.8%-1.2% of Mg, 0.04%-0.35% of Cr, 0.1%-0.25% of Zn, 0.05%-0.15% of Ti and the balance Al and inevitable impurities; the anticorrosive coating comprises the following raw materials in parts by weight: 40-65 parts of epoxy resin, 5-15 parts of a composite nano material, 3-7 parts of a modified curing agent, 1-5 parts of a curing agent, 1-3 parts of a wetting agent, 0.5-1 part of a defoaming agent, 0.1-1 part of a flatting agent and 0.1-0.5 part of a dispersing agent; the surface of the prepared aluminum alloy base material is coated with the anti-corrosion coating, the plate is subjected to subzero treatment after casting forming, and the composite nano material and the modified curing agent are added, so that the plate is endowed with excellent impact strength, corrosion resistance and flame retardance.

The invention is applicable to the technical field of titanium alloy pipe processing, and particularly relates to a preparation method of a high-plasticity TA15 titanium alloy pipe, which comprises the following steps: step S1, selecting sponge titanium, pure metal and intermediate alloy, preparing according to standard components of TA15 titanium alloy to obtain a prepared raw material, and smelting the prepared raw material for three times by adopting a vacuum consumable smelting furnace to obtain a high-plasticity TA15 titanium alloy pipe; and the TA15 titanium alloy cast ingot with the diameter being 600 mm is obtained. According to the method, the mechanical property and plasticity of the titanium alloy pipe are remarkably improved by accurately controlling the temperature and deformation of each machining step. And three-time upsetting and three-time drawing forging is carried out within the temperature range of T beta or above, coarse grains are effectively crushed, and grain structures are refined. And then, the metallographic structure of the wool rod is gradually optimized by accurately controlling the forging temperature and the deformation amount.

The invention discloses a magnetorheological polishing processing method for a NiP modified reflector, which comprises the following steps of: preparing a NiP modified layer, and carrying out ultra-precision turning processing and magnetorheological polishing modification processing on the NiP modified layer until the NiP modified layer meets index requirements. According to the magnetorheological polishing machining method for the NiP modified reflecting mirror, the NiP modified reflecting mirror blank workpiece is machined through ultra-precision turning and magnetorheological polishing, so that surface defects generated in the machining process of the NiP modified reflecting mirror blank workpiece can be effectively eliminated, and the machining efficiency can be improved; meanwhile, the surface shape precision and the surface quality of machining can be improved, the NiP modified reflector blank workpiece can be machined into the high-quality NiP modified reflector, and the method has the advantages of being few in machining defect, high in machining quality, high in machining efficiency, good in repeatability and the like; the method is of great significance in promoting wide application of the NiP modified reflector in the optical fields of visible light wave bands, shorter wavelength wave bands and the like.

The invention discloses a double-liquid water-soluble polyurethane ground grouting flowing water blocking method. The method comprises the steps that A, ground penetrating roadway drilling construction is conducted; b, a double-pipe grouting device is installed; c, pressing water before grouting; step D, preparing a double-liquid water-soluble polyurethane grouting liquid; e, the double-fluid water-soluble polyurethane grouting fluid is mixed through a double-pipe grouting device and then grouted to a target position; and F, water pressing is conducted after grouting. The method is a more efficient, environment-friendly and economical water gushing treatment scheme, the treatment effect of flowing water plugging in the complex underground environment can be effectively enhanced, and therefore construction and operation safety of the deep-buried tunnel is guaranteed.

The invention relates to the technical field of coating preparation, and particularly discloses a multifunctional composite filler modified water-based coating and a preparation method thereof.The water-based coating is prepared from, by weight, 80-100 parts of modified core-shell acrylic acid dispersoid, 5-7 parts of multifunctional composite filler, 0.5-1 part of defoaming agent, 0.5-1 part of wetting agent, 2-5 parts of thickening agent, 1-2 parts of coalescing agent and 25-35 parts of deionized water. The water-based paint provided by the invention is modified by adding a proper amount of multifunctional composite filler, the performance is excellent, the stability is good, the components in the water-based paint have good compatibility by optimizing the preparation process conditions of the water-based paint, and the preparation method is simple to operate and suitable for industrial production.

The invention discloses a PCBN (Polycrystalline Cubic Boron Nitride) composite sheet and a sintering process thereof. The sintering process of the PCBN composite sheet comprises the steps of material mixing, hot prepressing sintering, hot prepressing cooling, cubic pressure sintering and cooling to the room temperature, and raw materials in the mixed material comprise, by mass, 30%-85% of CBN micro powder and 15%-70% of binding agent micro powder. The PCBN composite sheet prepared by the sintering process is high in surface flatness and has relatively high hardness and cutting output.

The invention provides a method for sterile sowing and efficient propagation of cymbidium faberi. The method comprises the following steps: pretreatment of cymbidium faberi seeds, sterile germination of the cymbidium faberi seeds, protocorm proliferation, differentiation, seedling strengthening and acclimatization and transplantation. The pretreatment comprises the steps of refrigerating hybrid seeds of cymbidium orchid at 4 DEG C, performing secondary disinfection with sodium hypochlorite, performing dark culture for 10-30 days after sowing, and then performing light culture, and the germination culture medium is prepared by taking 1 / 4 MS as a basic culture medium and adding 100-200ml / L of coconut water, 0.5-1.0 mg / L of 6-benayl aminopurine, 0.1-0.5 mg / L of naphthylacetic acid, 0.5-2.0 g / L of peptone and 0.5-1.0 g / L of activated carbon. According to the method, the seed germination rate can be effectively increased, the 60d seed germination rate reaches up to 85%, the pollution rate is reduced to 5% or below, 50.0 g / L inositol, 2.0 mg / L glycine and 2.0 mg / L nicotinic acid are added into a differentiation culture formula, the differentiation rate can be effectively increased, the leaf bud differentiation rate reaches up to 90%, meanwhile, rooting can be induced, the growth time of cymbidium faberi from seeds to seedlings is greatly shortened, a large number of high-quality seedlings can be obtained within a short time, and the method is suitable for large-scale popularization and application. Technical data are accumulated for cymbidium resource protection and new variety cultivation.

The invention discloses an ultra-wideband carbon / boron doped high-entropy alloy wave-absorbing material which is prepared by adjusting Fe and Ni elements, adding Si and Al elements and doping a small amount of C or B. The specific component of the wave-absorbing material is (FeaCobSicAldNie) 100-xMx. In addition, the invention also discloses a preparation method of the wave-absorbing material, and the preparation method comprises the following steps: 1, high-entropy alloy smelting; 2, preparing high-entropy alloy spherical powder; 3, carrying out flaky treatment; and 4, stress relief annealing. On the basis of FeCoNi medium-entropy alloy, the content of the Fe element with low cost is increased, the content of the Ni element with high cost is reduced, the Si element and the Al element are added at the same time, then a small amount of non-metal C and B elements are doped to serve as interstitial atoms, lattice distortion is increased, the wave-absorbing performance and corrosion resistance are improved, and the ultra-wideband carbon / boron doped high-entropy alloy wave-absorbing material is obtained.

The invention discloses a carbon ceramic composite conductive microsphere, a ceramic resistor and a preparation method, and belongs to the technical field of production of special materials of electrical equipment, and the method comprises the following steps: sequentially dipping porous mullite in a precursor solution of carbon and slurry containing carbon black, and carrying out drying treatment and carbon burying sintering to obtain the carbon ceramic composite conductive microsphere; the preparation method comprises the following steps: preparing a ceramic raw material, performing vacuum-assisted centrifugal impregnation on the ceramic raw material and slurry consisting of a binder in pug consisting of the ceramic raw material and a surfactant, sequentially performing drying and glue discharging treatment, primary isostatic pressing forming and air pressure sintering, cooling to room temperature, and performing mechanical treatment and electrode spraying to obtain the ceramic resistor. Impregnation improves the dispersibility and uniformity of the carbon material in the porous mullite to form a continuous conductive path, the carbon black-containing slurry improves the conductivity of the ceramic resistor, carbon-buried sintering generates in-situ carbon with abundant types, the combination of carbon and a ceramic interface is promoted, and the oxidation resistance, mechanical properties and electrical properties of the ceramic resistor are improved.

The invention discloses a high-adhesion super-hydrophobic protective coating process method and a coating. The high-adhesion super-hydrophobic protective coating process method comprises the following steps: S1, preparing magnetic nano iron oxide particles; s2, performing neodymium modification on the magnetic nano iron oxide particles to obtain ferromagnetic neodymium modified iron oxide; s3, preparing and spraying a neodymium modified iron oxide coating; s4, preparing and coating a negative charge modified polymer microsphere coating; s5, preparing and spraying a positive charge modified polymer microsphere coating; and S6, preparing and spraying a modified nano silicon dioxide super-hydrophobic coating. According to the method, neodymium-modified magnetic nanometer iron oxide serves as a first layer of the surface of a steel substrate and is sprayed and dried in a magnetic field, it is guaranteed that the neodymium-modified magnetic nanometer iron oxide is tightly adsorbed to the steel surface, a magnetic transition layer is formed, and then coatings with different charges are alternately coated through the electrostatic attraction effect; and finally, a high-adhesive-force super-hydrophobic coating is formed on the steel surface in a layer-by-layer self-assembly mode, and the problem that the adhesive force of the super-hydrophobic coating is poor is obviously solved.

The invention provides a high-temperature alloy for manufacturing a nickel-copper alloy hot extrusion die, which is characterized by comprising the following components in percentage by weight: 0.02 to 0.08 percent of C, less than or equal to 0.15 percent of Si, less than or equal to 0.15 percent of Mn, less than or equal to 0.01 percent of P, less than or equal to 0.01 percent of S, 14.0 to 17.0 percent of Cr, 7.5 to 9.5 percent of Mo, 2.2 to 2.6 percent of Nb, 1.0 to 1.6 percent of Al, 2.2 to 2.8 percent of Ti, 0.005 to 0.015 percent of B, 0.01 to 0.05 percent of Zr, 21.0 to 24.0 percent of Fe and the balance of Ni. The preparation method of the alloy comprises the following processes: firstly, alloy raw materials are subjected to vacuum induction melting and then cast into ingots, then electroslag ingots are obtained through electroslag remelting, then the electroslag ingots are subjected to multi-heating-number forging, and then heat treatment is carried out. The highest use temperature of the alloy reaches 1000 DEG C, and the oxidation rate at 1000 DEG C is as low as 0.08 g / m < 2 >. H; at the temperature of 650 DEG C, the tensile strength reaches 1000 MPa, the yield strength reaches 850 MPa, the fatigue strength is higher than 400 MPa, and the lasting time of the load of 700 MPa reaches 80 h; the service life of a nickel-copper alloy hot extrusion die made of the alloy can reach 25000 times.

The invention discloses a surface passivating inert metal, a plating solution thereof and a passivating method, and belongs to the technical field of inert metal surface treatment. The plating solution comprises sulfydryl silane, amino silane, acid, deionized water and absolute ethyl alcohol. And the inert metal subjected to surface pretreatment is put into a plating solution to be subjected to electrolytic treatment and dipping treatment correspondingly, and then the inert metal with the silane composite passive film on the surface is obtained through stepped curing treatment. The plating solution is simple in component, stable in system and low in price; the preparation method of the plating solution is simple and easy to operate; the passivating treatment method is short in technological process and high in preparation efficiency; the prepared silane composite passivation film is uniform and compact in structure, colorless and transparent, can keep good gloss of the inert metal surface, and has excellent properties such as oxidation resistance, corrosion resistance and insulation.

The invention relates to the field of waterproof sealing materials, and discloses a composite high-weather-resistance rubber waterstop which is composed of an outer layer, a middle layer and an inner layer. The outer layer contains 3%-8% of nano titanium dioxide, 2%-5% of nano zinc oxide, 50%-70% of a rubber matrix and 1%-3% of an ultraviolet light absorber, and the total proportion of the outer layer is 10%-20%. The middle layer is composed of 70%-85% of EPDM, 5%-10% of carbon fiber and 5%-10% of plasticizer, and the total proportion of the middle layer is 60%-75%. The inner layer is a dynamic covalent bond rubber material and contains 5%-10% of a vulcanizing agent and 1%-3% of an antioxidant, the rubber material accounts for 80%-90%, and the inner layer accounts for 15%-25% in total. Through a multi-layer composite structure, a dynamic covalent bond self-repairing material and an optimized vulcanization process, the comprehensive performance of the water-stop belt is remarkably improved, and particularly the durability and the service life of the water-stop belt in a long-term exposure environment are improved.

The invention relates to the field of cables, and discloses a high-strength corrosion-resistant ship cable and a preparation method thereof.The high-strength corrosion-resistant ship cable comprises a guide core, an insulating layer wrapping the outer portion of the guide core, a shielding layer wrapping the outer portion of the insulating layer and a sheath layer wrapping the outer portion of the shielding layer; the sheath layer comprises the following components in parts by weight: 40-55 parts of polyvinyl chloride, 20-30 parts of nitrile rubber, 5-15 parts of modified basalt fiber, 3-8 parts of a flame retardant, 1-2 parts of a lubricant and 0.1-1 part of a light stabilizer; the modified basalt fiber is a basalt fiber grafted macromolecular antioxidant modified basalt fiber, and the flame retardant is prepared from the following raw materials: phosphonitrilic chloride trimer, DOPO (9, 10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide) and a hydroxyl-terminated phosphorus-containing intermediate. The cable is endowed with excellent mechanical property, salt spray corrosion resistance, thermo-oxidative aging resistance and flame retardant property.

The invention relates to the technical field of cement-based anticorrosive materials, and particularly discloses a modified magnesium phosphate cement anticorrosive material as well as a use method and application thereof. The anticorrosive material comprises the following components in parts by weight: 100 parts of modified magnesium phosphate cement, 3-15 parts of a retarder, 1-10 parts of an epoxy resin glue solution, 0.5-5 parts of metakaolin and 15-20 parts of water. The modified magnesium phosphate cement comprises dead burned magnesium oxide and modified phosphate in a mass ratio of (1-4): 1. The modified phosphate is prepared from the following raw materials: nano aluminum oxide, sodium citrate and phosphate in a mass ratio of (0.5-1.5): (0.5-1.5): (20-25). The epoxy resin glue solution comprises uncured epoxy resin glue and a curing agent. The anti-corrosion material provided by the invention has the technical advantages of strong adhesive property and excellent anti-corrosion property, and can better provide protection for a steel structure serving in a marine environment.

The invention discloses high-performance corrosion-resistant maritime work steel and a production method thereof, and the steel comprises the following chemical components: 0.02%-0.07% of C, 0.10%-0.25% of Si, 1.75%-2.50% of Mn, 0.022%-0.026% of P, less than or equal to 0.008% of S, 0.055%-0.060% of Nb, 0.035%-0.045% of Als, 0.90%-1.00% of Cr, 0.90%-1.00% of Ni, 0.20%-0.25% of Co, 0.0130%-0.0114% of N, 0.06%-0.065% of V, 0.035%-0.042% of Ti, 0.45%-0.52% of Cu, 0.03%-0.05% of Sn and 0.03%-0.05% of RE. Through smelting, slab continuous casting, casting blank heating, rolling and cooling, the Rp0.2 of the steel is 550-582 MPa, A is larger than or equal to 20%, the impact energy at the temperature of-80 DEG C is larger than or equal to 200 J, the corrosion resistance rate is smaller than 0.090 mm / a, the fatigue life under the load of the peak stress of 280 MPa is longer than 2 million times, the maximum thickness can reach 150 mm, and the Z-direction performance is larger than or equal to 40%. The problems that an existing steel plate for ocean engineering is low in strength, poor in low-temperature impact toughness and insufficient in corrosion resistance and fatigue resistance are solved.

The invention relates to the technical field of welding, in particular to a lead-free solder composition and a preparation method thereof. The composition comprises brazing filler metal and a brazing flux, wherein the brazing filler metal comprises 55 to 65 parts of copper, 30 to 40 parts of zinc, 0.5 to 1 part of silver, 0.1 to 1 part of tin, 0.1 to 0.5 part of nickel, 0.02 to 0.15 part of lanthanum, 0.03 to 0.15 part of cerium and 0.05 to 0.2 part of indium; the brazing flux comprises 18-22 parts of borax, 13-17 parts of boric acid, 25-32 parts of a potassium fluoride and potassium fluoborate compound, 3-5 parts of calcium fluoride, 12-16 parts of aluminum oxide and 8-11 parts of magnesium oxide. The lead-free solder composition does not contain toxic lead elements, pollution to the environment and the ecological system is little, the wettability, corrosion resistance, strength, stability and the like of the lead-free solder composition are improved, and the welding quality is comprehensively improved. According to the preparation method, uniform distribution and accurate control of the brazing filler metal and the brazing flux are guaranteed, stability and consistency of product quality are guaranteed, and the preparation method is easy and convenient to operate and suitable for mass production.