569 results about "Pitting corrosion" patented technology

A photodiode is formed in a recessed germanium (Ge) region in a silicon (Si) substrate. The Ge region may be fabricated by etching a hole through a passivation layer on the Si substrate and into the Si substrate and then growing Ge in the hole by a selective epitaxial process. The Ge appears to grow better selectively in the hole than on a Si or oxide surface. The Ge may grow up some or all of the passivation sidewall of the hole to conformally fill the hole and produce a recessed Ge region that is approximately flush with the surface of the substrate, without characteristic slanted sides of a mesa. The hole may be etched deep enough so the photodiode is thick enough to obtain good coupling efficiencies to vertical, free-space light entering the photodiode.

The invention relates to a welding method of 22Cr duplex stainless steel corrosion resistant alloy pipe, which adopts a gas mixture of 99.995 percent pure Ar and 98 to 99 percent Ar plus 2 percent N2 or a gas mixture of 90 to 95 percent of N2 plus 5 to 10 percent H2 to weld the two laterals within the range equal to or more than 100mm inside the pipe; back welding, fill welding and cap welding are implemented when the oxygen content is equal to or less than 50ppm; the welding and filling metal deposit includes the following components according to the weight percentage: C is equal to or less than 0.04, Cr is 22.0 to 23.5, Ni is 8.5 to 10.5, Mo is 3.0 to 3.5, Mn is 0.5 to 2.0, Si is equal to or less than 0.9, P is equal to or less than 0.04, S is equal to or less than 0.03, N is 0.15 to 0.20 and Cu is equal to or less than 0.75. A balanced austenitic-ferritic microstructure is obtained with good joint tensility and low-temperature shock toughness, as well as good corrosion performances of anti-pitting corrosion of chloride, stress corrosion and simulated environment medium corrosion resistance.

The invention relates to a process for welding duplex stainless steel, in particular to the process for welding the duplex stainless steel used for high-sulfur content refining equipment, highly-corrosive petrochemical equipment and pipelines, high-parameter power devices, and the chloridion-corroded environments of seawater and the like. In the process, a specific protective gas favorable for the welding of the duplex stainless steel is adopted, and simultaneously limited linear energy and inter-layer temperature are regulated in the welding process, so that the unfavorable defects of the conventional welding process can be overcome, and a metallographic structure with the ferrite content of 30 to 70 percent and a ferritic phase in percentage equivalent to that of an austenitic phase is obtained. A welding joint obtained by the welding process has high mechanical properties, high strength and hardness, particularly high yield strength which is about twice that of austenitic stainless steel, high thermal fatigue resistance, pitting corrosion resistance, crevice corrosion resistance, intercrystalline corrosion resistance and high weldability.

A method for predicting the residual life of a corroded casing of a high-temperature and high-pressure well mainly comprises the following steps: (1) predicting the inner average corrosion rate and the outer average corrosion rate of the casing by adopting the gray neural network algorithm; (2) establishing an finite element model for the corroded casing, and simulating the corrosion process of the casing by utilizing the element birth-death technology, so as to acquire the critical failure wall thickness of the casing when the casing loses efficacy; (3) establishing a residual life prediction model for the corroded casing, and computing the residual life of the casing subjected to uniform corrosion, local corrosion and pitting corrosion by utilizing the approximate analytical method; (4) establishing a relation equation for zero dimension residual intensity and zero dimension internal pressure and steam temperature by utilizing the regression analysis method. Aiming at the limitation of the theoretical study, laboratory test and field data on prediction of the service life of the casing, the method can effectively predict the residual life of the casing in shorter time, and the established residual intensity relation equation enables the engineering personnel to perform comprehensive evaluation on the service capability of the casing.

The invention relates to a stainless steel seamless pipe in metallurgical industry and the manufacturing process for the stainless steel seamless pipe; wherein, the steel pipe is made of 00Cr24Ni6Mo2N dual phase stainless steel; the manufacturing process for preparing the ship borne stainless steel seamless pipe comprises the following production steps of a. round steel preparation; b. heating; c. hot-puncturing process; d. end cropping; e. pickling; f. repair grinding; g. lubrication; h. cold rolling processing; i. degreasing; j. solution heat treatment; k. straightening; l. pipe cutting; m. pickling; n. inspection of finished products. The invention solves the problems of lower mechanical strength and extensibility, shorter service life and high prices in present 316L stainless steel pipes used in ship seawater channels and provides a novel ship borne dual phase stainless steel seamless pipe and the manufacturing process and has the advantages of no production of pitting corrosion and grain boundary corrosion of the steel pipes, higher mechanical strength and extensibility, longer service life as well as low price and low cost.

A flux-cored wire for stainless steel arc welding including an outer sheath made of stainless steel and flux filled up in the outer sheath contains, as percentage to the total mass of the wire, Cr: 22.0-30.0 mass %, Ni: 6.0-12.0 mass %, Mo: 2.0-5.0 mass %, N: 0.20-0.35 mass %, TiO₂: 4.0-9.0 mass %, SiO₂: 0.1-2.0 mass %, ZrO₂: 0.5-4.0 mass %, total of Li₂O, Na₂O and K₂O: 0.50-1.50 mass %, metal fluoride in terms of fluorine amount: 0.10-0.90 mass %, and rare earth element component: 0.10-1.00 mass %, limits C to 0.04 mass % or below, W to 4.0 mass % or below, Cu to 2.0 mass % or below, Bi₂O₃ to 0.01 mass % or below, and limits oxides other than the above to 3.0 mass % or below. With such a composition, it is possible to obtain a weld bead which is excellent in the weldability in welding in all attitudes and is more excellent in the low temperature toughness while keeping excellent pitting corrosion resistance in arc welding of duplex stainless steel and the like.

Provided are a coated steel sheet, a hot press formed product using the steel sheet, and a producing method thereof. Conditions for hot-dip coating bath are optimized when an aluminum-coated steel sheet is produced using a hot rolled steel sheet or a cold rolled steel sheet, and processes are controlled during production of a hot press formed product from the steel sheet, thereby forming a coating layer having a high ratio of (Fe₃Al+FeAl) compound layer on the surface of the steel sheet. In cases where the (Fe₃Al+FeAl) compound layer has an appropriate occupancy ratio with respect to the whole thickness of the coating layer, good resistance against crack and corrosion can be achieved to improve a local corrosion resistance of the hot press formed product, particularly, a pitting corrosion resistance. Therefore, high-quality hot press formed products can be produced with high productivity and lower costs.

A bioabsorbable wire material includes manganese (Mn) and iron (Fe). One or more additional constituent materials (X) are added to control corrosion in an in vivo environment and, in particular, to prevent and/or substantially reduce the potential for pitting corrosion. For example, the (X) element in the Fe—Mn—X system may include nitrogen (N), molybdenum (Mo) or chromium (Cr), or a combination of these. This promotes controlled degradation of the wire material, such that a high percentage loss of material the overall material mass and volume may occur without fracture of the wire material into multiple wire fragments. In some embodiments, the wire material may have retained cold work for enhanced strength, such as for medical applications. In some applications, the wire material may be a fine wire suitable for use in resorbable in vivo structures such as stents.

Disclosed herein is a metal sheet with anticorrosive coating which exhibits outstanding corrosion resistance, pitting corrosion resistance, and red rust resistance. It has the anticorrosive coating on at least one side thereof. The anticorrosive coating is formed from an anticorrosive paint which contains a metallic zinc powder and at least one kind of metal salt rust inhibitor. The metal salt is a salt of a metal which is more base than zinc. The metal sheet may be a steel sheet. The metal salt rust inhibitor may be a phosphate or a phosphomolybdate.

The invention provides a nondestructive flaw detector for steel wire ropes, and solves the problem that quantitative detection of wire break and wear in steel wire ropes cannot be realized by the prior art. The nondestructive flaw detector for steel wire ropes comprises a steel wire rope walking positioning mechanism, a magnetic leakage flux detector, an optical detector, a photoelectric encoder, and an embedded signal processing system. The steel wire rope walking positioning mechanism is provided with a steel wire rope channel, the inner wall surface of which is fixed with the magnetic leakage flux detector, the optical detector and the photoelectric encoder. The embedded signal processing system is fixed on the steel wire rope walking positioning mechanism, and the magnetic leakage flux detector, the optical detector and the photoelectric encoder are connected to the embedded signal processing system. By combining a magnetic leakage flux technology and an optical determination technology to perform signal feature extraction and quantitative analysis on wire break, pitting corrosion, wear and other defects of steel wire ropes, the nondestructive flaw detector realizes online high speed and high accuracy detection of the steel wire ropes.

A method for determining the time-varying reliability of prestressed concrete box girder bridges based on the stochastic finite element method. For prestressed concrete box girders that are widely used in highway bridge systems and have common early-stage diseases, by combining degenerate shell elements, material constitutive relations and The crack model simulates the nonlinear characteristics of the box girder in the cracking stage, and the embedded concrete creep, shrinkage and steel strand stress relaxation model considers the deformation, prestress loss and internal force redistribution of the box girder during its entire life, through the reinforcement The uniform corrosion model and the pitting corrosion model calculate the section loss of steel bars (steel strands) in carbonization environment and chloride ion environment respectively. Finally, through the definition of random variables, sampling, calling finite element program calculation and extracting stress and strain results, the reliability calculation of the box girder bridge is realized and used to guide the subsequent maintenance and reinforcement work.

The invention provides a fault diagnosis method of a variable-speed rotation machine based on time-frequency spectrum segmentation. The method includes following steps: step 1, obtaining normalized time-frequency spectrums of signals through multi-resolution generalized S transform, and generating multi-resolution binarized time frequency spectrums; step 2, combining the binarized time-frequency spectrums with all resolutions, and obtaining an optimal binarized time-frequency spectrum; step 3, segmenting the optimal binarized time-frequency spectrum into a plurality of connected domains, and performing information annotation on each connected domain; step 4, extracting an optimal expression atom of each connected domain, forming an optimal atom set, and calculating the expression of a fault signal in the optimal atom set; and step 5, calculating the appearance time and amplitude of an impact theory, and realizing fault diagnosis of variable-sped mechanical equipment through informationcomparison. According to the method, most strong background noises can be filtered, and fault diagnosis of impact type faults including cracking, pitting corrosion or spalling etc. of the variable-speed rotation machine can be realized.

The invention discloses a blade surface pitting corrosion resistant coating and preparation method thereof. The coating comprises a bonding layer, a blocking layer, and a surface layer from the inside to the outside, wherein, the bonding layer consists of pure metal Ti, the blocking layer consists of TiN and TiC from the inside to the outside, and the surface layer consists of TiCN. The preparation method is characterized by using an arc ion plating machine to successively depositing the bonding layer, the blocking layer, and the surface layer on the blade matrix. The multi-layer pitting corrosion resistant coating structure disclosed herein has low friction coefficient, high hardness, good wear resistance, good bonding force between the coating and the substrate, and excellent pitting corrosion resistance. According to the invention, in the preparation process, vacuum degree of the furnace body is at least 6.7*10<-3> Pa, the temperature of the furnace body is 250-450 DEG C, so that the marked impact on blade matrix material microstructure in the deposition process can be reduced; by using specific arc current, large particles, liquid drop and cavity on the coating surface in the deposition process can be reduced, so that the coating surface is smooth, compact, and uniform, and the corrosion resistance is improved.

The invention belongs to the technical field of pitting corrosion evaluation of stainless steel and relates to a method for controlling and evaluating occurrence and development of pitting corrosion of the stainless steel, in particular to an electrochemical method for evaluating pitting resistance of the stainless steel. In the method, by adopting rotary pulse technique, selecting a proper temperature and medium, controlling pulse waveform and the number of pulses and effectively controlling the quantity and the size of pitting corrosion on the surface of the stainless steel, the evaluation of development positions, quantity, size and shape of corrosion pit and the like of the pitting corrosion in the stainless steel is realized. By the method, a large amount of information on the pitting corrosion is qualitatively and quantitatively obtained, and an important basis is provided for the research on the corrosion resistance of the stainless steel, so that the method has great research and application significance.

The invention discloses a duplex stainless steel with pitting corrosion resistance and favourable cold temperature flexibility and a manufacturing method thereof. The duplex stainless steel comprisesthe following components in mass percentage: 0.01-0.10% of C, 0.2-1.0% of Si, more than 0% and less than 1.5% of Mn, 20.0-22.0% of Cr, 1.8-4.0% of Ni, 0.08-0.2% of N, more than 0% and less than 0.5% of Mo, less than or equal to 1.0% of one or more than one of W and Cu and the balance Fe and inevitable impurities. The invention controls Mn content below 1.5% until zero and simultaneously adjusts the content of elements of N, Ni and the like to ensure that steel has high strength, favourable corrosion resistance and favourable impact toughness at room temperature and low temperature when steel contains no or small amount of noble element Mo; meanwhile, the duplex stainless steel has low cost and small hot working difficulty, can be largely applied in the fields of buildings along the coast,petrochemical industry and the like and can replace 304 austenitic stainless steel of which the nickel content is above 8% at room temperature and lower temperature.

The invention discloses a corrosion testing device capable of simulating the complex environment and a testing method thereof. The device comprises a dynamic high-temperature autoclave system, a medium circulation system and a gas mixing system which can be used for conducting corrosion tests on a sample; the medium circulation system cooperates with the dynamic high-temperature autoclave system so that the medium in the testing environment can be replaced or circulated, and thus the solution medium or flow velocity under the actual working condition is simulated; the gas mixing system is communicated with and cooperate with the dynamic high-temperature autoclave system to simulate the gas composition and pressure environment required by the tests; the dynamic high-temperature autoclave system is internally provided with a medium temperature controller which is used for simulating the temperature under the actual working condition. According to the testing device, multiple types of testing parameters are considered comprehensively, an expansion interface is provided, multiple types of actual working conditions can be effectively simulated, corrosion performance evaluation and research of multiple types of materials, such as stress corrosion, uniform corrosion, erosion corrosion, pitting corrosion, crevice corrosion, electrochemical corrosion, coating corrosion resistance evaluation and corrosion inhibitor efficiency evaluation, in the complex environment are completed, and correctness and scientificity of the test result are guaranteed.

The invention relates to a Cr 23 Ni 6 ferrite-austenitic stainless steel which is manufactured from stainless steel materials containing components by weight percentage as follows: 22 percent to 24 percent of Cr, 5 percent to 7 percent of Ni, 3 percent to 4 percent of Mo, 0.15 percent to 0.25 percent of N, less than or equal to 0.03 percent of C and 1 percent to 2 percent of Mn, and the rest is Fe. The manufacturing technology of the Cr 23 Ni 6 ferrite-austenitic stainless steel of the invention is characterized in that: in hot piercing process, the hot piercing temperature is controlled to be 1150 DEG C to 1200 DEG C; the prior compression coefficient of a piercing plug is controlled to be 5 percent; the reduction of roller waist is controlled to be 12 percent and the ovality is controlled to be 1.08 to 1.11; in cold drawing/cold rolling process, cold deformation quantity is controlled to be below 50 percent; in heat treatment process, the solid solution temperature of products is controlled to be 1080 DEG C to 1100 DEG C and the solid solution temperature of finished products is controlled to be 1050 DEG C to 1100 DEG C. The Cr 23 Ni 6 ferrite-austenitic stainless steel has good chloride stress corrosion resistance, good pit corrosion resistance, high tensile strength and yield strength and good corrosion fatigue resistance and erosion corrosion resistance, and is widely used in the fields such as petroleum industry, chemical industry, natural gas industry and marine shipping and the like.

Simultaneous determination of general corrosion and localized corrosion rate measurements is achieved with polarization applied by the electrodes themselves rather than externally applied polarization. Two or more working electrodes may be galvanically coupled. A localized pitting corrosion event on one of the electrodes will lead to a potential transient. The area within the potential transient is measured with the baseline being the initial starting potential. This gives localized corrosion as a function of time. The relationship Rp=ΔV/ΔI is calculated, where Rp is the polarization resistance of the working electrodes and is a measure of generalized corrosion rate.

The invention relates to the technical field of electrolytic capacitors, in particular to a corrosion method of middle-high-voltage anode aluminum foil. The corrosion method comprises two electrochemical corrosion processes of pitting corrosion and pore-enlarging corrostion, wherein the pitting corrosion is carried out in a mixed solution of hydrochloric acid and acid which can generate filam, and the pore-enlarging corrosion is carried out in hydrochloric acid solution or nitric acid solution and is completed by two steps. The invention has a plurality of advantages of high production efficiency, energy conservation, environmental protection, and the like.

Disclosed herein is a method of preventing corrosion degradation in a defective region including an expansion transition region and/or an expansion region of a heat transfer tube of a steam generator in a nuclear power plant by using nickel (Ni) plating or nickel (Ni) alloy plating. The method can prevent various types of corrosion damage, such as pitting corrosion, abrasion, stress corrosion cracking, lead-induced stress corrosion cracking and the like, occurring during the operation of the steam generator, and particularly, pitting corrosion or primary and secondary stress corrosion cracking, so that the life span of the steam generator is increased, maintenance costs are reduced, and the operation rate of a nuclear power plant is increased, with the result that the unit cost of the production of electric power can be decreased, thereby improving economic efficiency. Further, the method can be usefully used to prevent the corrosion damage of parts and equipment of nuclear, hydroelectric or thermoelectric power plants or of petrochemical plants, and that of industrial and machine parts and equipment, and parts and equipment in a defense industry.

The invention relates to the technical field of anode foil corrosion for aluminum electrolytic capacitors, in particular to an acid-mixed reaming corrosion method for high-voltage anode foil in aluminum electrolysis. The method comprises six steps of pre-treatment, first-stage pitting corrosion, second-stage reaming corrosion, third-stage reaming corrosion, post-treatment and formation treatment,and is characterized in that the aluminum foil after the first-stage pitting corrosion is subjected to second-stage and third-stage acid-mixed reaming corrosion, respective characteristics of hydrochloric acid and nitric acid are fully utilized for common reaming, so that defects of single acid reaming corrosion can be overcome; 520 Vt specific volume of the aluminum foil is 0.750-0.799 uF/cm<2>,which is increased by 1.57%-3.03% than the specific volume of the aluminum foil in single acid reaming corrosion; 375 Vt specific volume is 1.265-1.293 uF/cm<2>, which is increased by 1.59%-3.60% thanthe specific volume of the aluminum foil in single acid reaming corrosion.