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1117results about How to "Good scrub resistance" patented technology

Super-amphiphobic polymer and super-amphiphobic surface prepared from super-amphiphobic polymer

The invention belongs to the field of macromolecule super-amphiphobic materials and discloses a super-amphiphobic polymer and a super-amphiphobic surface. The super-amphiphobic polymer is a random copolymer composed of structural units shown as a formula I and a formula II. The super-amphiphobic surface is obtained by comprising the following steps of: pre-processing a substrate material; placinga micro-balloon in a fluorine-containing solvent, and ultrasonically dissolving to obtain a micro-balloon supernatant solution; adding the super-amphiphobic polymer, a hydrochloric acid tetrahydrofuran solution and water into the micro-balloon solution while stirring, placing the substrate material, and reacting for 5-24 h; and taking out the substrate material, washing by using the fluorine-containing solvent, methanol and water in turn, drying in vacuum, and obtaining the super-amphiphobic surface. The super-amphiphobic polymer disclosed by the invention can give good surface hydrophobic ability and oleophobic ability to the substrate. Because the polymer has the characteristics of the fluorine-containing polymer so that the polymer can be chemically bonded with the surface of the substrate, the obtained super-amphiphobic surface has good scrubbing resistant property and corrosion resistant property.
Owner:GUANGZHOU CHEM CO LTD CHINESE ACADEMY OF SCI

Preparation method and application of modified polyurethane aqueous dispersions of polyisocyanate curing agents

The invention discloses a preparation method and application of modified polyurethane aqueous dispersions of polyisocyanate curing agents. The preparation method comprises the following steps of: carrying out prepolymerization reaction by using polyester polyol, vulcabond monomer and a polyisocyanate curing agent; reacting with a hydrophilic chain-extending agent and a micro-molecule chain-extending agent to obtain polyurethane prepolymer containing hydrophilic groups (carboxyl or sulfonic groups) and isocyanate(NCO)-terminated groups; neutralizing the polymer into salt, and then dispersing the salt into water; and preparing the modified polyurethane aqueous dispersions of the polyisocyanate curing agents by the chain extending of a polyamine chain-extending agent. The modified polyurethane aqueous dispersions of the polyisocyanate curing agents have self-crosslinking function at room temperature, and the self-crosslinking density is over 85%. Compared with non-modified polyurethane aqueous dispersions prepared under the same condition, the modified polyurethane aqueous dispersions have superior film forming property, water resistance, alcohol resistance, pollution resistance, cold resistance, dry/wet rubbing resistance and chemical solvent resistance; and coating films have especially high drying speed, high hardness increment speed and high final hardness.
Owner:SOUTH CHINA UNIV OF TECH

All-in-one water-borne inorganic-organic hybrid architectural coating and preparation method thereof

The invention relates to an all-in-one water-borne inorganic-organic hybrid architectural coating and a preparation method thereof, wherein the all-in-one water-borne inorganic-organic hybrid architectural coating is prepared by taking a compounded product of a water-borne inorganic film-forming matter and an organic polymer emulsion as a base material through the steps of adding various pigments / fillers and auxiliaries into the base material, then carrying out beating, grinding and paint mixing on the obtained mixture. In the invention, through a Si-O-Si polymer net structure which can be formed by compounding alkali metal silicates and small-particle-size silica sols in the process of film forming, the early water resistance of a paint film is greatly increased, and the eventual hardness, scraping resistance and stain resistance of the paint film are greatly increased; and through adding the organic polymer emulsion, the film-forming performance of the coating can be improved, and the defects that the traditional two-component inorganic coating is easy to crack, bad in decorative properties, poor in storage stability, and the like are overcome. The coating prepared by using the method disclosed by the invention has various functions of environmental friendliness, non-toxicity, thermal insulation, ultra scrubbing resistance, abrasion resistance, yellowing resistance, ageing resistance, fouling resistance, good air permeability, sound insulation, and the like.
Owner:SOUTH CHINA UNIV OF TECH

High-efficiency environment-friendly antibacterial mould-proof inorganic composite nano paint and preparation method thereof

The invention relates to a paint technology, an environment-friendly technology and an antibacterial mould-proof technology, in particular to high-efficiency environment-friendly antibacterial mould-proof inorganic composite nano paint and a preparation method thereof. The high-efficiency environment-friendly antibacterial mould-proof inorganic composite nano paint comprises the following components in percentage by weight: 0.5 to 5 percent of wetting dispersant, 0.01 to 20 percent of inorganic composite nano antibacterial agent concentrated pulp, 0.5 to 10 percent of hydrophobing agent, 0.5 to 10 percent of anionic powder, 0.5 to 8 percent of film-forming aid, 0.1 to 2 percent of anti-settling agent, 0.8 to 10 percent of antifreezing agent, 0.1 to 3 percent of defoaming agent, 4 to 30 percent of pigment, 0 to 30 percent of filler, 15 to 45 percent of emulsion, 0.1 to 4 percent of thickening agent, 0.1 to 3 percent of flatting agent, 0 to 3 percent of pH regulator and 0.5 to 45 percent of water. The high-efficiency environment-friendly antibacterial mould-proof inorganic composite nano paint is mainly prepared by adding the inorganic composite nano antibacterial agent into the basic materials, so that the paint has the coating characteristic of high performance, is low is cost, and has a function of purifying air, can eliminate harmful gas volatile organic compounds (VOC), formaldehyde and the like and also has a durable and high-efficiency antibacterial mould-proof function, so that the sterilizing rate within 6 hours reaches 100 percent and the mould-proof grade reaches the first grade. By the high-efficiency environment-friendly antibacterial mould-proof inorganic composite nano paint and the preparation method thereof, self-cleaning performance, hydrophobicity, scrubbing resistance, dirt resistance and weather resistance of the coating are improved; and the high-efficiency and durable antibacterial and mould-proof effect is achieved.
Owner:广东腐蚀科学与技术创新研究院

Waterborne energy-saving building coating and preparation method thereof

ActiveCN106700789AGet rid of the shortcomings of severely limited application fieldsIncreased hemispherical emissivityAntifouling/underwater paintsPaints with biocidesGreen environmentEmulsion
The invention specifically relates to a multifunctional green environment-friendly waterborne energy-saving building coating and a preparation method thereof, belonging to the technical field of energy-saving building coatings. The multifunctional high-efficiency energy-saving building coating comprises, by weight, 25 to 50% of a high polymer emulsion, 5 to 30% of a light-reflection filling material, 1 to 5% of aerogel powder, 5 to 10% of a heat-insulation filling material, 5 to 15% of a common filling material, 1 to 2% of a surface modifier, 1 to 5% of a dispersing agent, 0.1 to 4% of a film-forming aid, 0.1 to 2% of a thickening agent, 0 to 1% of an antifoaming agent, 0.01 to 0.5% of a pH regulating agent, 0.1 to 2% of a wetting agent and 0.5 to 2% of an antifreezing agent, with the balance being deionized water. The coating provided by the invention has heat-insulation and cooling effect in summer and heat preservation effect in winter, is applicable to energy-saving reconstruction of buildings in tropical zones and subtropical zones, and has the characteristics of safety, no toxicity, environment friendliness and no pollution; moreover, the coating has good weatherability, contamination resistance, flexibility and scrubbing resistance.
Owner:SHENYANG RES INST OF CHEM IND

Polyurethane aqueous dispersion and preparation method thereof

The invention discloses a polyurethane aqueous dispersion and a preparation method thereof. The preparation method comprises the following steps: firstly, mixing trimethylolpropane or glycerol and acid anhydride and preparing a carboxylic acid type hydrophilic monomer; on the basis of molar parts, adding 20-60 parts of polymer dibasic alcohol, 4-10 parts of carboxylic acid type hydrophilic monomer and 30-60 parts of a diisocyanate monomer into a reactor, heating to 60 DEG C-100 DEG C and carrying out heat preservation; adding1-10 parts of small-molecular dibasic alcohol, 2-10 parts of a non-ionic hydrophilic chain extender and 1-6 parts of a cross-linking agent and reacting until the content of NCO is less than 5%; and adjusting the viscosity of the reactant, cooling, adding a neutralizing agent for neutralizing, adding water for emulsifying, adding an amine chain extender and removing the solvent by distillation to obtain the polyurethane aqueous dispersion. The carboxylic acid type hydrophilic monomer has stable performance and low cost, the polyurethane aqueous dispersion prepared from the carboxylic acid type hydrophilic monomer has high content of solids and the coating has relatively high hardness and excellent chemical product resistance.
Owner:SOUTH CHINA UNIV OF TECH

Elastic polyurethane silver paint and preparation method and use method thereof

The invention discloses elastic polyurethane silver paint. Main paint of the elastic polyurethane silver paint is prepared from compositions according to the following weight proportion: 65 to 85 percent of a hydroxy acrylic acid resin, 2 to 5 percent of 20 percent CAB381-0.5, 0.3 to 0.5 percent of a dispersant, 0.4 to 0.6 percent of an anti-settling agent, 0.3 to 0.5 percent of a flatting agent, 0.4 to 0.8 percent of wax powder, 7 to 10 percent of non-leafing aluminum paste, 7 to 10 percent of dimethylbenzene, and 15 to 22 percent of mixed solvent; a curing agent of the elastic polyurethane silver paint is formed by mixing compositions according to the following weight percent: 75 percent of elastic HDI curing agent, and 25 percent of absolute butyl acetate; and the weight proportion of the main paint to the curing agent is calculated based on a hydroxyl value of acrylic acid resin and the NCO content of the curing agent, and OH/NCO is equal to 1 to (1.05-1.15). The elastic polyurethane silver paint has excellent weather resistance, stain resistance, scrubbing resistance and decoration property, is a coating variety with excellent performance which is second only to fluorocarbon paint, also has good elasticity at normal temperature and low temperature, can resist fine cracks, can prevent cracks on the surface of a coating caused by the fine cracks of a putty layer, and can also be used as finish for a complete anti-cracking aluminum-imitation plate coating system that flexible putty is matched with an elastic primer and an elastic middle coating.
Owner:SHENZHEN GRANDLAND ENVIRONMENTAL COATING CO LTD

Styrene acrylic emulsion for interior wall coating material, and preparation method thereof

The invention provides a styrene acrylic emulsion for interior wall coating material, and a preparation method of the styrene acrylic emulsion; the preparation method comprises the following steps of: (1) mixing water, composite emulsifying agent, acrylate monomer and functional monomer, and emulsifying to obtain pre-emulsified liquid A; (2) adding reactive organic silicon into the pre-emulsified liquid A, and emulsifying to obtain pre-emulsified liquid B; (3) adding mixture of water, composite emulsifying agent, methyl alcohol and sodium bicarbonate into the pre-emulsified liquid A obtained in the step (1), and adding initiator for reaction to obtain seed emulsion C; (4) adding the pre-emulsified liquid B into the seed emulsion C obtained in the step (3), and simultaneously adding initiator water solution into the mixed solution; carrying out heat preservation after dripping, and cooling the emulsion; and (5) removing residual monomer, and adjusting the pH to be 7-8 to obtain the styrene acrylic emulsion for the interior wall coating material. The styrene acrylic emulsion can be used for preparing the interior wall coating material, and is less in adding quantity and better in scrub resistance than that of other emulsions, thus reducing the cost of coating and saving resources.
Owner:上海展辰涂料有限公司 +4

Preparation of nano silicone-acrylate core shell type composite latex for latex paints

The invention relates to a preparation method of nano silicone-acrylate core shell type composite latex for latex paints. The preparation method solves the problem that latex paints prepared from the common latex is insufficient to meet the demands of people at the performance aspects of water resistance, weather resistance, pollution resistance and the like, and simultaneously reduces the restraint degrees of a region domain and a time and season domain for latex construction. In the preparation method, active organic silicon and acrylate monomers are mainly used as raw materials, and then the nano silicone-acrylate core shell type composite latex using polyacrylate as a core and using silicone-acrylate composite resin as a shell is synthesized by adopting a monomer pre-emulsifying process and a seed semi-continuous latex polymerization method, so that the preparation method has the advantages of stable polymerization process and convenient large-scale production. When used for preparing the latex paints of outer walls, the synthesized latex can greatly improve all performance of the latex paints, also solve the conflicts between the lowest film-forming temperature and film hardness and simultaneously realize the unification of the cost and the performance.
Owner:SHAANXI UNIV OF SCI & TECH
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