2409results about "Silicon organic compounds" patented technology

The invention provides a boron-nitrogen heterocyclic compound as well as an intermediate and a preparation method thereof, the boron-nitrogen heterocyclic compound has a structure as shown in a general formula (1), and is prepared by taking compounds as shown in a formula A, a formula B and a formula C as intermediates. Compared with similar carbon skeleton molecules, the boron-nitrogen heterocyclic compound provided by the invention shows an excellent narrow-band luminescence property. The half-peak width of the emission spectrum of the boron-aza compound is as low as 6.4 nm, and meanwhile, the fluorescence quantum yield is as high as 97%.

The invention belongs to the technical field of OLEDs, and provides a polycyclic compound containing triphenyl silicon and a polyalkyl substituent group and an organic electroluminescent device containing the polycyclic compound. The structural general formula of the polycyclic compound is as shown in formula I in the specification. Benzofuran with higher electronegativity is introduced to a ring structure composed of nitrogen atoms and boron atoms, triphenyl silicon is introduced to the para-position of boron, and the synergistic effect of benzofuran and triphenyl silicon can significantly enhance the multiple resonance of a light-emitting core and reduce vibration relaxation. Due to simultaneous use of the benzofuran and the triphenyl silicon, the problems of vibration relaxation increase, spectrum widening and the like caused by introduction of the polyalkyl substituent are remarkably improved, the luminous efficiency of the material is remarkably improved, and the color purity is improved, so that the requirement of BT.2020 wide color gamut display standard on a luminescent spectrum is met. I

The invention belongs to the technical field of pharmaceutical chemical processes, and particularly relates to a preparation method of a penem antibiotic intermediate 4-BMA, which comprises the following steps: adding Zn powder, chlorosilane, aliphatic tertiary amine, zinc salt and 4-AA in a formula (I) into THF (tetrahydrofuran), uniformly stirring, dropwise adding a THF solution of alpha-haloamide with an induction group in a formula (II) for reaction, filtering the reaction solution, removing the zinc powder, and drying to obtain the penem antibiotic intermediate 4-BMA. Extracting the filtrate to obtain a THF phase, washing with an aqueous solution of potassium oxalate, and recovering THF to obtain a formula (III); and carrying out oxidative hydrolysis, sulfur dioxide quenching, sulfur dioxide acid regulation crystallization and recrystallization on the formula (III) to obtain the intermediate 4-BMA. According to the preparation method disclosed by the invention, a zinc salt is used as a catalyst during preparation of the formula (III), potassium oxalate is used for removing residual Zn (II) in a THF phase, SO2 is used for quenching hydrogen peroxide and acid regulation and crystallization of 4-BMA, the oxygenolysis problem of 4-BMA is solved, and the preparation method has the characteristics of greenness, safety and high efficiency, is strong in product competitive advantage and is suitable for industrial production.

A surface treatment agent containing a hydrocarbon-terminal-group-containing compound of the following formula makes it possible to form a cured film that is exceptional in water repellency, slipperiness, dirt removability, and abrasion resistance, particularly steel wool abrasion resistance and wet abrasion resistance. (R1 is a C12-80 monovalent hydrocarbon group that includes a C12 or higher monovalent or divalent linear unsubstituted aliphatic saturated hydrocarbon group and does not contain a hydrocarbon branched structure, R2 is H, a halogen atom, a hydroxyl group, a siloxy group, an -OSi(CH3)3 group, an -OSi(C2H5)3 group, an amino group, an SH group, a monovalent hydrocarbon group, R1, -V-Z-(Y-A)m, or -Y-A, U is a single bond, C, or a trivalent or tetravalent organic group, V is a single bond or a divalent hydrocarbon group, Z is a single bond, C, Si, N, S, or a trivalent to octavalent organic group, Y is a single bond or a divalent hydrocarbon group, A is a monovalent reactive group, k is 0, 1, or 2, and m is 1-7.)

The present disclosure, among other things, provides technologies for synthesis, including reagents and methods for stereoselective synthesis. In some embodiments, the present disclosure provides compounds useful as chiral auxiliaries. In some embodiments, the present disclosure provides reagents and methods for oligonucleotide synthesis. In some embodiments, the present disclosure provides reagents and methods for chirally controlled preparation of oligonucleotides. In some embodiments, technologies of the present disclosure are particularly useful for constructing challenging internucleotidic linkages, providing high yields and stereoselectivity.

A multifunctional organosilicon compound is provided which has the general formula XSi([OSiR2]p-0-SiR2Y)a(R1)3-a— ln the formula, X is selected from H and ethylenically un saturated moieties; each Y independently comprises a functional moiety selected from alkoxysilyl moieties, acryloxy moieties, and epoxide moieties; each R is an independently selected hydrocarbyl group; each R1 is an independently selected hydrocarbyl group; subscript a is 1, 2, or 3; and each subscript b is independently 0, 1, or 2. A method of preparing the multifunctional organosilicon compound is also provided. The method comprises reacting (A) an organosilanol compound and (B) a silane compound having at least two hydrolysable groups. A functionalized siloxane compound prepared from the multifunctional organosilicon compound, a method of preparing the functionalized siloxane compound, and an adhesive comprising the functionalized siloxane compound are also provided.

To provide a coolant which exhibits relatively excellent fluidity even at low temperatures and can be easily handled and stored due to having a high flash point.SOLUTION: This coolant contains an organopolysiloxane represented by formula (1) (wherein R1 moieties are each independently a methyl group or an ethyl group, and n is 2 or 3), and is characterized in that the organopolysiloxane has a kinematic viscosity of 100 mm2 / s or less at -80°C and 300 mm2 / s or less at -100°C.SELECTED DRAWING: None

The invention provides a compound containing a silicon group and an organic electroluminescent device thereof, and particularly relates to the technical field of organic electroluminescent materials. When the compound containing the silicon group is used as a covering layer material, the glass transition temperature is high, the thermal stability and the chemical stability are good, the light transmittance of a device can be improved, aging of the device is delayed, and therefore the service life of the device is effectively prolonged; and the compound has weak metal adsorption capacity, and can effectively inhibit the deposition of a metal electrode material on the surface of a nucleation inhibition layer when being applied to the nucleation inhibition layer, thereby improving the performance of the device. In conclusion, the silicon group-containing compound provided by the invention can be widely applied to the fields of panel display and the like, and has a good development prospect.

Disclosed herein are activatable inactive sonosensitizer compounds, referred to as locked sonosensitizer compounds, designed with a detachable stimuli-responsive tether acting as a trigger or safety, as these compounds restore their inherent sonosensitization activity upon the detachment of the tether. The invention further encompasses pharmaceutical compositions comprising the same, offering a strategic approach to sonodynamic therapy, whereas the compounds and compositions are formulated to be administered and applied under favorable conditions, enhancing their efficacy in the context of therapeutic applications, since the therapeutic methods presented herein are more versatile and efficient compared to presently known SDT methods due to the controlled activation of the sonosensitizer.

The invention relates to a compound, a composition, an organic optoelectronic device, and a display device. The compound is represented by Chemical Formula 1, where X1 and X2 are each independently NRa, O, S, Se, or Te, any one of R1 to R10 is a group represented by Chemical Formula A, the remaining ones of R1 to R10 and Ra are each independently hydrogen, deuterium, a substituted or unsubstituted C1 to C20 alkyl group, a substituted or unsubstituted C6 to C30 aryl group, a substituted or unsubstituted C2 to C30 heterocyclic group, a substituted or unsubstituted amine group, a substituted or unsubstituted silyl group, a cyano group, or a halogen, and R1 to R10 and Ra are each independently present, or adjacent two of R1 to R10 and Ra are linked to form a ring.

The invention relates to an organic compound, application of the compound and an organic electroluminescent device containing the compound. The organic compound has a structure as shown in a formula (1), ring A, ring B, ring C, ring D, ring E, ring F, ring G, ring H, ring I, ring J and ring K independently represent one of C5-C20 aromatic rings and C4-C20 heteroaromatic rings, X and Y are independently selected from C or Si, W1, W2 and W3 are independently selected from a single bond, O, CO, SO2, S, NR1, CR2R3 or SiR4R5, and m1, m2 and m3 are independently 0 or 1. After the compound is prepared and applied to the organic electroluminescent device, the device has good performance of high color purity and high luminous efficiency, meanwhile, low-efficiency roll-off of the electroluminescent device is achieved, and the service life of the device is extremely long. # imgabs0 #

The invention provides a luminescent material containing a cyclobutadiene structure, and a preparation method and application thereof, and relates to the technical field of organic electroluminescent materials. According to the cyclobutadiene-containing luminescent material provided by the invention, the anti-aromatic cyclobutadiene is fused into a binary nitrogen-containing fused heterocyclic skeleton, and excitation state vibration relaxation is inhibited by using the special electronic structure and high ring tension of the anti-aromatic cyclobutadiene, so that narrow-band luminescence is realized. By introducing the steric hindrance effect group, the aggregation fluorescence quenching phenomenon between luminescent parent nuclei is weakened, and the fluorescence quantum yield is improved. Different from a current mainstream multi-resonance mechanism, the design of the narrow-spectrum light-emitting molecule provided by the invention does not need to depend on the construction of a B / N-fused ring, and the molecular structure can be simplified to realize full-light-color ultra-narrow-band light emission. When the organic light-emitting diode is applied to an organic light-emitting device, an ultra-narrow full-width-at-half-peak electroluminescent spectrum and high device efficiency can be realized, and a better solution is provided for an ultra-high-definition organic light-emitting diode display technology.

The utility model relates to the technical field of chemical separation, and provides a dividing wall column and a rectification device.The dividing wall column comprises a column body, a partition plate, a first distributor and a first liquid collection tray, the partition plate is arranged in the column body and extends in the height direction of the column body, and the top face of the partition plate and the inner top wall of the column body are arranged at intervals in the height direction of the column body; the bottom surface of the partition plate and the inner bottom wall of the tower body are arranged at intervals; in the height direction intersecting with the tower body, one side wall face of the partition plate and a part of the inner wall of the tower body define a feeding section, the other side wall face of the partition plate and the other part of the tower body define a discharging section, the first distributor is arranged in the feeding section and connected with the tower body and the partition plate, and the first liquid collecting disc is arranged in the discharging section and connected with the tower body and the partition plate. According to the invention, the problems of high energy consumption and large occupied area when silicate ester is separated in a double-tower rectification mode can be solved.

The invention belongs to the technical field of 4-BMA mother liquor recycling, and relates to a method for recycling 4-BMA in mother liquor by adopting a membrane treatment technology, which comprises the following steps: dropwise adding isopropylamine into 4-BMA refining wastewater, adjusting the pH value to 8-9, selecting a proper filter membrane, and filtering by using membrane filtering equipment at a certain temperature to obtain concentrated liquor and permeate liquid; the maximum separation effect is achieved by controlling the volume ratio of the permeate to the concentrated solution, and the 4-BMA isopropylamine salt concentrated solution is obtained; ethyl acetate is added into the 4-BMA isopropylamine salt concentrated solution for extraction, then 13.5 wt% hydrochloric acid is dropwise added for crystallization, and a 4-BMA product is obtained. According to different solubility of 4-BMA, isomer and isopropylamine after salification in water, the isomer salt is dissolved in water to be removed, 4-BMA salt with high purity is obtained, qualified 4-BMA with the purity larger than or equal to 98.00% is obtained through acid adjustment, and the purity of 4-BMA is larger than or equal to 98.00%. The method is low in energy consumption, simple in process, simpler to operate and easier to convert.

Novel compositions and systems for closure of wounds with antimicrobial effectiveness are disclosed. The compositions provide devices of improved flexibility and elasticity and are readily applied to wound sites or over wound closure devices. The present invention is also directed to a novel platinum catalyst for use in such compositions. The catalyst provides for rapid curing on topical surfaces such as skin and bonds to such surfaces in about 2-5 minutes.

The invention relates to a continuous production method of high-purity tetraethoxysilane, and belongs to the technical field of tetraethoxysilane preparation. The method comprises a raw material pretreatment stage and a purification and rectification stage: in the pretreatment stage, silicon tetrachloride and ethanol are subjected to an esterification reaction in a molar ratio of 1: (3-4) under the protection of nitrogen, the pH is adjusted to be neutral through triethylamine, and triethylamine hydrochloride is removed through reduced pressure distillation; then, a cerium oxide-molecular sieve composite adsorbent with the specific surface area larger than or equal to 800 m / g and the pore diameter of 2-5 nm is adopted for dehydration under the pressure of 0.8-1.2 MPa till the water content is smaller than or equal to 5 ppm, and volatile impurities are removed through high-purity nitrogen purging; in the purification stage, metal ions and Cl are synergistically removed through a titanate modified resin layer and a nano TiOtube layer, and then step-by-step separation is performed through a four-stage differential pressure rectifying tower. Through collaborative optimization of structural design of the composite adsorbent, construction of an organic-inorganic hybrid interface of the resin layer and pressure gradient rectification, 72-hour continuous production is achieved, the single-pass yield of the product is 92%, and the total amount of metal impurities is smaller than or equal to 5 ppb.

The invention relates to the field of solar cells, and discloses an organic compound, application thereof and a perovskite solar cell, and the organic compound has a structure shown in a formula (I). The organic compound provided by the invention has a proper energy level, is an organic semiconductor material with excellent performance, and can improve the efficiency of a perovskite solar cell device.

The invention provides a boron-containing organic compound and an organic electroluminescent device thereof, and relates to the technical field of organic electroluminescent materials. According to the boron-containing organic compound as shown in the formula 1, a spiro structure is added on a classic boron-nitrogen parent nucleus, and arylamine / carbazole groups are introduced on the spiro structure, so that steric hindrance is increased, molecular vibration is reduced, and pi-pi accumulation interaction among planar boron-containing / nitride molecules is effectively inhibited. The boron-containing organic compound as shown in the formula 1 is applied to the organic electroluminescent device as a doping material, not only can the spectrum be narrowed and the color purity be improved, but also the quenching caused by aggregation can be overcome, the luminous efficiency of the organic electroluminescent device is improved, and the service life of the organic electroluminescent device is prolonged. The material can be applied to the fields of information display, illumination, organic solar cells and the like, and has a very good market prospect.

The invention discloses a preparation method of silane or siloxane containing adamantyl. According to the invention, adamantane carboxylic acid is taken as a starting raw material, an adamantane compound containing double bonds at the tail end is obtained through an esterification reaction, and then the adamantane compound and hydrogen-containing silane or hydrogen-containing siloxane are subjected to a hydrosilylation reaction to prepare adamantyl-containing silane or siloxane. The method is mild in reaction condition, simple, convenient and easy to operate, capable of achieving preparation of adamantyl silane or siloxane of various structures, wide in application range and capable of providing diversified choices for development of novel adamantyl modified organic silicon materials.

The invention provides a heterocyclic compound and an organic electroluminescent device thereof, and belongs to the technical field of organic electroluminescence. The heterocyclic compound provided by the invention has relatively weak metal adsorption capacity, can effectively inhibit metal from being deposited on the surface of a thin layer when being used as a nucleation inhibition layer material to be applied to the organic electroluminescent device, and can effectively improve the light emitting effect of the organic electroluminescent device when being used as a covering layer material, so that the light emitting efficiency of the organic electroluminescent device is improved. And the service life of the device is further prolonged. The heterocyclic compound and the organic electroluminescent device thereof have good application effect and industrialization prospect.

The invention relates to the technical field of medical chemistry, in particular to a bridge oxygen site regulatively modified rhodamine anti-cancer fluorescent compound as well as a preparation method and application thereof. The invention develops the rhodamine anti-cancer fluorescent compound of which the meso site is functionalized by tetraarylethene and the bridge oxygen site can be regulated and modified, the fluorescent compound has adjustable red light-near infrared fluorescence emission and excellent fluorescence quantum yield, and the quantum yield can be as high as 99%; the fluorescent compound specifically targets mitochondria, and mainly inhibits growth of tumor cells by inducing para-apoptosis; under irradiation of 655 nm near-infrared laser, ferroptosis is further triggered, efficient treatment of tumor cells is achieved through chemical-photodynamic synergistic effect, and a new treatment thought is provided for overcoming tumor drug resistance.

The invention provides a sulfinate organic positive alkali metal ion supplement for a secondary battery, and relates to the technical field of secondary batteries. The organic positive electrode alkali metal ion supplement has a structure as shown in the following general formula: [R-SO2]-M < + >, wherein M < + > is a metal cation and is selected from at least one of Li < + >, Na < + > and K < + >; [R-SO2]-is a sulfinate anion, and wherein R is an organic group. The supplement compensates irreversible capacity loss by efficiently releasing active ions, so that the energy density of the battery is improved; the oxidation potential is proper, the environmental stability is excellent, and the catalyst is not needed to decompose and easy to process; decomposition products are harmless, an electrode interface can be optimized, and the cycle life of the battery is remarkably prolonged.

The present disclosure provides siloxane derivatives of amino acids that have surface-active properties. The amino acid can be naturally-occurring or synthetic, or they may be obtained via a ring-opening reaction of a lactam, such as caprolactam. The amino acid may be functionalized with a siloxane group to form a compound that is surface-active and has surfactant characteristics. The compounds have low critical micelle concentrations (CMC) as well as the ability to lower the surface tension of a liquid.

The invention discloses a bifunctional alicyclic epoxy fluorosilicone monomer as well as a preparation method and application thereof. The invention relates to compounds of formula (I) wherein the variables n, m, x, R1, R2, R3 and R4 are as defined in the description. The compound of the formula (I) can be photopolymerized, and has the advantages of good tensile property, excellent hydrophobic property, good heat resistance and the like after being photocured. The invention also relates to preparation of the compound shown in the formula (I), a photocurable composition containing the compound shown in the formula (I) and a photocurable material obtained by photocuring the photocurable composition. # imgabs0 #

The invention discloses an ether chain modified rhodamine fluorescent dye, an ether chain modified rhodamine fluorescent dye probe and a preparation method and application thereof, through modification of an ether chain, the water solubility of the rhodamine dye is improved, the aggregation quenching effect is reduced, meanwhile, the intramolecular torsional charge transfer (TICT) is reduced through the electron withdrawing effect of oxygen atoms, and the fluorescence sensitivity is improved. Finally, the quantum yield of the rhodamine dye is greatly improved. The quantum yield of ether chain modified oxygen rhodamine water is increased from 0.31 to 0.70, and the quantum yield of silicon-based rhodamine water is increased from 0.19 to 0.41. The rhodamine dye disclosed by the invention has the characteristics of high brightness, easiness in functional derivation and the like, and has application prospects in the fields of fluorescent probes, fluorescent labels, super-resolution fluorescence imaging and the like.

The invention provides a host material, a dual-host-containing organic electroluminescent material and a preparation method and application thereof, the host material has a structure as shown in a general formula 1, the dual-host-containing organic electroluminescent material comprises a first host material and a second host material, and the mass ratio of the first host material to the second host material is 1: 99-99: 1, the first main body material is a compound with a structure as shown in a general formula 1, and the second main body material has a structure as shown in a general formula 2. Triplet excitons are dispersed on two main bodies by using the double main body material, so that triplet-triplet annihilation (TTA) is reduced, the driving voltage of the organic electroluminescent device is reduced, and the driving efficiency of the organic electroluminescent device is improved. And the luminous efficiency and the service life of the device can be improved.

The invention provides phenyl-containing polysiloxane silicone oil for personal care and a preparation method of the phenyl-containing polysiloxane silicone oil. The mass of dichlorobenzene in the phenyl-containing polysiloxane silicone oil is 1-20 ppm, the dichlorobenzene has two structures, and the proportion of p-dichlorobenzene in the total content of dichlorobenzene is less than 75 wt%. The phenyl-containing polysiloxane silicone oil has the advantages of being colorless, odorless and low in residue, can be used as an additive of personal care products such as skin care products and hair conditioners, is extremely low in color number, completely odorless and good in compatibility with most personal care product raw materials, and solves the use problem of low-odor and low-color-number additives in the daily chemical industry.

The present invention discloses a strong, non-toxic, antibacterial and antiviral nano-functional material and a preparation method thereof. The nano-functional material is green, non-toxic and harmless, and its antibacterial and antiviral effect can reach more than 99%. The new nano-material innovatively uses the natural antibacterial agent meta-dichlorostyrene meta-dichloroacetophenone as the main body of the material to exert its antibacterial and antiviral effects. This makes the new nano-material not only have extremely strong antibacterial and antiviral effects, but also as a natural antibacterial agent, when it is used as a textile material, it can be non-toxic and harmless to the human body, green and healthy. It has a better inhibitory effect on both Gram-negative and Gram-positive bacteria than nano-copper oxide and meta-dichlorophenylethanol and meta-dichloroacetophenone. The present invention also provides a preparation method for the nano-functional material, which includes chemical reaction processes such as boron hydrolysis reaction, catalytic oxidation reaction, electrocarboxylation reaction, and esterification reaction.

The invention provides a heterocyclic derivative and an organic electroluminescent device thereof, and belongs to the technical field of organic electroluminescence. The heterocyclic derivative provided by the invention has relatively weak metal adsorption capacity, when the heterocyclic derivative is used as a nucleation inhibition layer material to be applied to the organic electroluminescent device, deposition of metal on the surface of a thin layer can be effectively inhibited, and meanwhile, the heterocyclic derivative is used as a covering layer material to improve the optical coupling efficiency of the organic electroluminescent device, so that the organic electroluminescent device can be applied to the field of organic electroluminescent devices. And the luminous efficiency of the device is effectively improved. The heterocyclic derivative and the organic electroluminescent device thereof have good application effect and industrialization prospect.