This invention relates to a
metal-doped three-dimensional
covalent organic framework material, formed by linking a 9,10-dihydro-9,10-[1,2]
benzanthracene framework and a
metal-doped β-tetraroxyporphyrin framework via
nitrogen atoms. The 9,10-dihydro-9,10-[1,2]
benzanthracene framework includes two first-dimensional linking sites, two second-dimensional linking sites, and two third-dimensional linking sites. For any 9,10-dihydro-9,10-[1,2]
benzanthracene framework, at least one first-dimensional linking site is connected to a
nitrogen atom via a
double bond, at least one second-dimensional linking site is connected to a
nitrogen atom via a
double bond, and at least one third-dimensional linking site is connected to a
nitrogen atom via a
double bond. The four R groups of the
metal-doped β-tetraroxyporphyrin framework are each connected to a
nitrogen atom via a
single bond. The metal includes one of
cerium,
iridium,
platinum, and gold. The material of this invention can shorten the
mass transfer path, reduce charge hindrance, improve the
conductivity and catalytic activity of the material, accelerate
proton conduction, and enhance
mass transfer reaction
kinetics, providing a highly efficient catalytic platform for electrochemical reactions.