958 results about "Separation method" patented technology

The invention relates to a Kr separation method and system based on selective desorption, a terminal and a storage medium, and relates to the technical field of rare gas purification. Calculating the difference between the quotient of the historical krypton loss amount and the adsorption column mass and the initial unit krypton adsorption amount to generate the actual unit krypton adsorption amount; calculating the quotient between the product of the actual unit krypton adsorption quantity and the mass of the adsorption column and the flow velocity of the single to-be-adsorbed air so as to generate actual adsorption time; controlling the first-stage adsorption column to adsorb the to-be-adsorbed air according to the actual adsorption time so as to generate a to-be-separated adsorption column; controlling the adsorption column cleaning device to clean the adsorption column to be separated according to the actual unit krypton adsorption quantity, and collecting desorbed gas after cleaning to the waste gas storage device; and performing desorption operation on the cleaned adsorption column, controlling a gas collection device to collect desorbed gas, and heating and activating the first-stage adsorption column to recover the adsorption capacity. The application has the effect of reducing krypton loss.

The invention discloses a molecular film type automotive nitrogen and oxygen separation device which comprises a turbocharger, a nitrogen and oxygen separator, a gas inlet valve, a gas outlet valve, a negative pressure pump and an electric control throttling valve. The turbocharger is driven by a turbine in an automobile turbocharger, so that the air is compressed to be conveyed to two paths of the nitrogen and oxygen separation device, the nitrogen and oxygen separation device can separate oxygen from the air, the air with high oxygen content is output, and the air is supplied to an engine for use through the gas outlet valve. The two paths of the nitrogen and oxygen separation device work alternately, when the temperature of the two paths of the nitrogen and oxygen separation device is too high to influence oxygen production efficiency, a main air inlet pipeline is opened to provide air normally by controlling the opening degree of the electric control throttling valve, and thus the phenomena of gas circuit plugging and engine stalling are avoided. According to the automotive nitrogen and oxygen separation device, the two branch paths work alternately, high concentration oxygen can be supplied to the engine continuously so that fuel can burn and act, and the burning utilization rate of the fuel is improved.

The invention provides an easy-to-scale efficient biological magnetic separation system and method and application. The magnetic separation method comprises the following steps: marking a target object in a to-be-detected suspension by adopting magnetic nanoparticles, and putting the marked to-be-detected suspension into a separation container; a modularized magnet array is arranged in the separation container, the modularized magnet array is composed of permanent magnets, and the permanent magnets are assembled into the cuboid modularized magnet array; the surface of the permanent magnet is coated with a polytetrafluoroethylene coating; the modularized magnet array moves in the suspension under the control of a driving magnet arranged outside the separation container to generate a dynamic gradient magnetic field, and a target object is captured by the modularized magnet array under the action of the gradient force of the magnetic field; removing the liquid in the separation container; adding the resuspension into a separation container, and recovering a target object by physical ultrasonic washing; or adding a chemical dissociation solution into the separation container to recover the target object.

The invention discloses a fly ash dioxin separation method, fly ash dioxin separation equipment, a fly ash treatment method and a fly ash treatment system, and solves the technical problems of high energy consumption, high cost and lack of efficient and low-energy-consumption dioxin dissociation and enrichment separation means in a fly ash treatment process in the prior art. Comprising the following steps: mixing fly ash with water to prepare fly ash slurry; the method comprises the following steps: adding an oxidizing agent into fly ash slurry to carry out oxidation reaction so as to carry out oxidation treatment on reducing substances on the surface of the fly ash, adding acid into the fly ash slurry subjected to oxidation treatment to carry out modification reaction so as to etch the fly ash by using the acid to dissociate dioxin particles from the surface of the fly ash and show hydrophobicity; or adding acid into the fly ash slurry to carry out modification reaction, and controlling the pH value of the fly ash slurry after the modification reaction to be 6-12.5; bubbles are generated or introduced into the fly ash slurry after the modification reaction, the dioxin particles are captured by the bubbles and float upwards to form scum, so that the scum is separated from mother liquor, and detoxified slurry is obtained.

The invention discloses a mixed matrix membrane for efficient oxygen and nitrogen separation and a preparation method and application thereof. The mixed matrix membrane comprises a polymer continuous phase and an MOF filler uniformly dispersed in the polymer continuous phase, the MOF filler can separate nitrogen and oxygen, and the surface of the MOF filler is modified by the silane coupling agent, so that the MOF filler is well compatible with a polymer, and the oxygen-nitrogen separation effect is improved. The polymer solution and the MOF filler dispersion liquid are mixed, the mixed matrix membrane is prepared through the non-solvent induced phase separation method, and the method has the advantages of being simple in reaction condition, high in efficiency, easy to amplify and the like and has wide engineering prospects.

The application belongs to the technical field of membrane separation materials, and discloses an ultrahydrophilic oil-water separation membrane, a preparation method and application thereof, and comprises the following steps: 2-(2-bromoisobutyryloxy)ethyl methacrylate monomers are prepared from 2-hydroxyethyl methacrylate and 2-bromoisobutyryl bromide, and a polymer with an atom transfer radical polymerization initiator is prepared through a free radical polymerization reaction; the polymer with the atom transfer radical polymerization initiator and polyacrylonitrile are dissolved into a solvent, and a PAN / P(AN-g-BIEM) blended membrane is prepared through a non-solvent induced phase separation method; and a hydrophilic polymer brush is grafted to the surface of the PAN / P(AN-g-BIEM) blended membrane to obtain the ultrahydrophilic oil-water separation membrane; the ultrahydrophilic oil-water separation membrane prepared by the application has a high separation flux, excellent oil-water separation efficiency and separation performance for different oil-in-water emulsions.

The invention relates to the technical field of radionuclide separation, in particular to an Eu (III) / An (III) separation method based on a zirconium phosphonate-based metal organic framework adsorbent, which comprises the following steps: adding the zirconium phosphonate-based metal organic framework adsorbent into an Eu (III) and / or An (III) nuclide-containing aqueous solution with the acid concentration of 0.001-3M to carry out adsorption reaction, and then carrying out solid-liquid separation, wherein the zirconium phosphonate-based metal organic framework adsorbent is a zirconium phosphonate-based metal organic framework material exchanged by metal cations M; the metal cation M is selected from one of alkali metal ions, alkaline earth metal ions or divalent transition metal ions. According to the invention, the interlayer chemical properties of the material are regulated and controlled through ion exchange, so that the adsorbent has ultrahigh selectivity, rapid adsorption kinetics, high adsorption capacity and excellent structural stability on trivalent actinide / simulated nuclides in extremely high-acid, high-salt and intense-radiation environments; the key problems of low separation efficiency and poor stability in a high-acid complex system in the prior art are solved, and the method is suitable for treating high-level liquid waste.

The invention relates to the technical field of rare earth element separation methods, in particular to a method for separating ytterbium and lutetium by using a phosphate adsorbent, which comprises the following steps: loading a phosphate solution on a porous solid-phase carrier by using a vacuum impregnation method, and carrying out reduced pressure evaporation and drying to obtain a phosphate solid adsorbent; filling an exchange column with the solid adsorbent to obtain the exchange column filled with the solid adsorbent; enabling a nitric acid solution containing ytterbium and lutetium to flow through an exchange column filled with a solid adsorbent to complete a column adsorption process; and performing elution, performing desorption by using a desorption solution to obtain the regenerated exchange column filled with the solid adsorbent, respectively collecting the ytterbium solution and the lutetium solution, completing the separation process, and repeating the steps. By adopting the steps, the separation of ytterbium and lutetium is directly realized from the nitric acid solution containing ytterbium Yb and lutetium Lu through column adsorption separation, leaching and desorption processes, and high-purity ytterbium and lutetium products are prepared.

The application discloses a beneficiation separation method for high-copper and low-zinc high-sulfur polymetallic ore, which comprises the following steps: A, after crushing the raw ore, ball milling and grading are performed, the sand is returned to the ball mill, and the overflow product is fed into a copper roughing process; B, copper roughing is performed; C, the roughing concentrate is subjected to copper cleaning process to obtain copper concentrate, and the roughing tailings are fed into a copper scavenging process; D, copper scavenging is performed, the scavenging tailings are subjected to grading, the sand is returned to the ball mill, and the overflow product is fed into a zinc roughing process; E, zinc roughing is performed, the roughing concentrate is subjected to zinc cleaning process to obtain zinc concentrate, and the roughing tailings are subjected to zinc scavenging process to obtain zinc tailings. The application efficiently realizes the separation of copper concentrate and zinc concentrate by fully utilizing the mineral particle size distribution characteristics, introducing a particle size grading system and improving the flotation reagent, and has the technical characteristics of high separation yield, easy operation, stable separation index and the like.

The present application belongs to the field of rare earth separation, and particularly discloses a method for separating heavy rare earth ions. In the method, a vinyl complexing agent including at least one of vinyl phosphonic acid, vinyl sulfonic acid, vinyl acetic acid or 4-vinyl benzyl chloride is used to selectively complex heavy rare earth ions in an aqueous phase, so as to obviously increase the distribution coefficient between different heavy rare earth ions. Then, the aqueous phase containing the complex of heavy rare earth ions is subjected to extraction separation of different heavy rare earth ions with an organic phase containing an extractant, so as to achieve the purpose of improving the separation efficiency.

The invention discloses a separation method or an analysis method of astaxanthin geometric isomers and corresponding optical isomers thereof, and relates to the technical field of analysis. According to the method, four geometric isomers of all-trans astaxanthin, 9-cis astaxanthin and 13-cis / 15-cis astaxanthin can be effectively separated, and effective separation and detection of three optical isomers of all-trans astaxanthin, four optical isomers of 9-cis astaxanthin and eight optical isomers of 13-cis / 15-cis astaxanthin are further realized; therefore, effective separation and analysis of optical isomers corresponding to various geometric isomers can be realized. The method is high in specificity, good in separation degree and high in analysis accuracy of geometric isomers and optical isomers, and has important significance in developing research on the accurate correlation between the astaxanthin biological activity and the isomers.

The application discloses a flavonoid compound in eaglewood as well as a preparation method and application of the flavonoid compound, and relates to the technical field of medicines. The application extracts and separates a new compound from natural eaglewood, and the new compound is used in the preparation of anti-osteoporosis drugs. The compound is detected in vitro to obtain an induction effect of the compound on the differentiation of bone marrow mesenchymal stem cells (BMSCs) into osteoblasts, so as to affect the formation of osteoclasts. Meanwhile, the compound can promote the bone development of zebra fish through RT-qPCR detection, which indicates that the compound has anti-osteoporosis activity. The separation method of the compound is simple and easy to operate.

The invention belongs to the field of flotation, and particularly relates to a composite inhibitor for copper sulphide ore, an inhibition method, a copper-molybdenum separation method and a flotation reagent thereof.The composite inhibitor for the copper sulphide ore comprises a component A, a component B, a component C and a component D according to the weight ratio of (3-7): (1-2): (1-2): (1-3); wherein the component A is a compound shown in a formula 1 (1); the component B is a compound shown in a formula 2; the component C is konjac mannan; component D is a compound represented by formula 3. The research shows that the component A and the component D are innovatively combined, and flotation of the copper sulphide ore can be accidentally inhibited with high selectivity on the basis of combination and synergy of special groups between the component A and the component D.

The present application belongs to the technical field of aromatic hydrocarbon production, and relates to a method and system for producing trimethylbenzene and quarterphenyl by alkylation. Light aromatic hydrocarbons and methanol are used as raw materials, and alkylation is carried out under the catalysis of a modified molecular sieve catalyst and at a temperature of 250-600 DEG C. The material after alkylation is subjected to further alkylation under the catalysis of the modified molecular sieve catalyst and at a temperature of 250-600 DEG C. The modified molecular sieve catalyst is composed of a molecular sieve and a metal oxide supported in the molecular sieve, the molecular sieve is one or more of HY, Hbeta, IM-5, NU87, EU-1 and mordenite, and the metal in the metal oxide is one or more of Mg, Cu, La, Zn and Mo. The present application solves the technical problems of low content of trimethylbenzene and quarterphenyl components and difficult separation of trimethylbenzene and quarterphenyl in the industrial separation method by directly producing trimethylbenzene and quarterphenyl.

The invention discloses a clean, efficient and low-cost lithium extraction slag utilization method which comprises the following steps: mixing lithium extraction slag with a fluxing agent, and sequentially carrying out roasting treatment, solid-liquid separation treatment, aging treatment and water leaching treatment to obtain a second solid-liquid mixture; carrying out solid-liquid separation treatment on the second solid-liquid mixture to obtain a second filter residue and a second filtrate; performing carbon separation method treatment on the first filtrate to obtain a third solid-liquid mixture; carrying out solid-liquid separation treatment on the third solid-liquid mixture to obtain a third filter residue and a third filtrate; the main component of the second filter residue and the third filter residue is white carbon black; performing heat treatment on the second filtrate and the third filtrate to obtain a fourth solid-liquid mixture; performing solid-liquid separation treatment on the fourth solid-liquid mixture to obtain fourth filter residues and fourth filtrate; the main components of the fourth filter residue are aluminum hydroxide and ferric hydroxide; and separating the fourth filtrate to obtain a sodium sulfate crystal substance and a potassium sulfate crystal substance.

A separation membrane complex includes a porous support and a separation membrane formed on the support. The separation membrane has a small void. A small void index Ik expressed by (Σ(Sk1.5)) / (Sm1.5) and indicating the abundance ratio of small voids is higher than or equal to 10×10−15, and a large void index Ip expressed by (Σ(Sp2)) / (Sm2) and indicating the abundance ratio of large voids is lower than 200×10−22, where Sm is the surface area of the separation membrane, Sk is the area per small void, and Sp is the area per large void. Accordingly, the separation membrane complex can achieve a high separation ratio.

The invention relates to the technical field of micro-plastic collection, in particular to surface environment micro-plastic synchronous collection and separation integrated equipment and a synchronous collection and separation method. The equipment comprises a gas collecting device, a circulating gas pump, a circulating water pump, a cooling ring and a flotation tower, a cooling ring is arranged on the upper portion of the flotation tower, a corundum aeration device is arranged at the bottom of the flotation tower, one end of a circulating air pump is connected with two sets of air inlets of the air collecting device through pipelines, and the other end of the circulating air pump is connected with an outlet in the top of the flotation tower through a pipeline. When the equipment works, the operation of the equipment needs to be ensured in a closed circulation process. The equipment can collect micro-plastics with various particle sizes in the surface environment and other impurities capable of diffusing through natural conditions, synchronously enrich the micro-plastics and separate the impurities, so that the purpose of efficiently collecting micro-plastic samples is achieved.

The invention discloses a green preparation method for realizing a high-performance chitosan film through pH regulation and control of a citric acid buffering agent, and belongs to the field of food packaging and high polymer materials. According to the method, a water phase separation method is adopted, a citric acid buffering agent serves as a water phase environment, and a chitosan solution is induced to be subjected to phase separation and gelation by regulating and controlling the pH value (preferably 5.0-5.5) of the citric acid buffering agent. The preparation method comprises the following specific steps: dissolving chitosan powder in an alkali urea solvent (KOH: urea: water = 7: 12: 81), inducing gelation through a citric acid buffer agent, carrying out solvent replacement through an ethanol solution, and drying and curing. According to the method, a chemical cross-linking agent does not need to be used, and the core is that a buffer system is used for regulating and controlling the phase separation process to promote aggregation among chitosan molecular chains, so that a compact physical structure network is constructed. The prepared chitosan film has excellent mechanical strength, water resistance, gas barrier property, biocompatibility and degradability, and is suitable for the fields of food, medicine packaging and the like.

The invention discloses a process and a control method for continuous separation of hydrogen isotopes, and belongs to the technical field of hydrogen isotope separation. According to the process, a countercurrent continuous operation mode is adopted, an adsorption tower is divided into an adsorption area, a replacement area and a regeneration area, and reverse movement of an adsorbent and a material is simulated by periodically switching the material inlet and outlet positions of the adsorption tower; the adsorption towers and connecting pipelines are soaked in a constant-temperature coolant, and separation is realized by virtue of acting force difference of an adsorbent on hydrogen isotopes; according to the control method, digital control logic is adopted, the valve state is edited through a spreadsheet, software is controlled to analyze data, a PLC executes valve switching, and accurate regulation and control of the multi-tower operation state under different working conditions are achieved. The method provided by the invention solves the problems of high equipment investment and large energy consumption of a traditional separation method, has the advantages of high separation factor, high recovery rate and stable continuous operation, and is suitable for hydrogen isotope separation requirements of different feed gas proportions and different treatment capacities.

The invention belongs to the field of wastewater treatment, and particularly relates to a selective separation method for zinc and cadmium in a low-concentration-difference difficult-to-separate zinc-cadmium-containing solution, which comprises the following steps: carrying out co-precipitation reaction on the low-concentration-difference difficult-to-separate zinc-cadmium-containing solution and an alkaline precipitator to obtain co-precipitation slag enriched with zinc and cadmium; the low-concentration-difference difficult-to-separate zinc-cadmium-containing solution is a solution in which the ratio of the concentration of high-concentration ions to the concentration of low-concentration ions in zinc and cadmium is 0.9-2; the concentration of cadmium is 8-40g / L; the coprecipitation slag is subjected to size mixing with water, selective cadmium dissolving is carried out under the condition that the pH of size obtained after size mixing is controlled to be 6-7.1, then solid-liquid separation is carried out, and zinc-rich slag and cadmium-rich leachate are obtained; the solid-to-liquid ratio in the slurry is 85-150g / L; carrying out deep zinc removal treatment on the cadmium-rich leachate to obtain a cadmium purification solution, and preparing the cadmium purification solution into a high-purity cadmium product with the grade of 3N or above; and the zinc-rich slag is subjected to acid leaching and deep cadmium removal treatment, a zinc purification solution is obtained, and then the zinc purification solution is prepared into a 2N-grade high-purity zinc product. According to the method disclosed by the invention, high-quality cadmium and zinc can be obtained at high yield.

The invention belongs to the technical field of micro-plastic detection, and particularly relates to a method for separating and detecting micro-plastic in a sample. The separation method comprises the following steps: cracking a sample, and then separating by using gas chromatography; the cracking temperature is 500-600 DEG C, and the gas chromatography heating procedure comprises the following steps: keeping the initial temperature of 35-45 DEG C for 1-2 minutes, heating to 310-330 DEG C at 25-35 DEG C / min, and keeping the temperature for 1-15 minutes. According to the separation method, eight micro-plastics (PS, PVC, NY-6, PP, ABS, PC, PU and PMMA) can be separated out at the same time within 10 min, the separation efficiency is high, and subsequent qualitative and / or quantitative analysis of the micro-plastics is facilitated.

To provide a porous membrane capable of suitably separating predetermined components from a material to be filtered, a method for manufacturing a porous membrane, and a separation method. [Solution] A porous membrane comprising a porous body and a polymer having a crosslinked structure on the porous body between a first monomer containing a positively charged cationic group and a second monomer containing a pH-responsive anionic group.

The application discloses an asphaltene separation device and an asphaltene separation method. The asphaltene separation device comprises a separation cabin, the separation cabin is in a cylindrical structure, electric heating wires are filled between the inner wall and the outer wall of the separation cabin, the electric heating wires are connected with temperature sensors, a stirring shaft is penetrated through the center of the end face of the bottom end of the separation cabin, stirring blades are sleeved with the end part of the stirring shaft, the stirring blades are in the separation cabin, the end part of the stirring shaft is connected with a stirring motor, and the stirring motor is outside the separation cabin. The asphaltene separation device and the separation method solve the problem that a long time is consumed in the asphaltene separation process, and meet the demand of people for rapid asphaltene separation. The asphaltene separation device is provided with a stirring device composed of a stirring shaft and stirring blades, the dissolution and separation time is reduced through the stirring mode, and the temperature sensors and the electric heating wires are provided, so that the temperature in the separation cabin can be accurately controlled, and the dissolution speed of solutes is accelerated.

The application provides a hydrate membrane, a preparation method thereof, a membrane assembly and a membrane separation method. The hydrate membrane comprises a porous support layer and a hydrate separation layer located on at least one side surface of the porous support layer; the hydrate separation layer comprises cage-type hydrate crystals formed in situ through phase transition under the condition that the temperature is 0-20 DEG C and the pressure is 0.1-6 MPa by using a hydrate mother liquor containing a thermodynamic promoter, and the average pore size of the hydrate separation layer is 0.35-0.55 nm. The hydrate membrane has high separation selectivity and high permeation flux, and has good rigidity and uniformity of membrane pores, high long-term operation stability, is convenient for in-situ preparation of large-area separation membranes, and can realize efficient recovery and utilization of helium in a hydrocarbon raw gas.

A method for separating VdF and acetylene, the method comprising: a step for mixing a first mixture containing VdF and acetylene with an extraction solvent, which is at least one compound selected from the group consisting of methanol, acetone, chloroform, and 1-chloro-2, 3, 3-trifluoro-1-propene, to obtain a mixture for extraction; and a step in which the mixture for extraction is distilled to obtain a distillate having VdF as the main component and a bottom product having an extraction solvent as the main component and further containing acetylene, respectively.

The application discloses a household garbage fine separation method and system suitable for pyrolysis and fermentation, and belongs to the technical field of solid waste treatment and resource utilization, and comprises pre-crushing, first magnetic separation, drum screening, air separation, fine crushing, second magnetic separation and Raman light selection; a separation equipment integrating a visual sensor and a laser Raman spectrum probe is adopted to identify and separate the material after the second magnetic separation, so that different kinds of plastics are separated based on the molecular vibration fingerprint information of the material; wherein each step is uniformly scheduled and controlled by an automatic control system according to a preset program or real-time feedback parameters, and the dust generated in the whole process is collected and purified by a tail gas dust removal control system. Through the construction of a multi-stage collaborative process route, the material is fully dissociated and purified step by step, and the problems of low separation precision and poor system collaboration are solved by cooperating with automatic unified scheduling and full-process dust removal.

The purpose of the present invention is to provide a technique whereby it becomes possible to operate for a longer period of time in an aqueous system equipped with a membrane separation apparatus. The present invention can provide a membrane separation method, the method comprising containing a combined-chlorine-based oxidizing agent to water of interest, and allowing the water of interest which contains the combined-chlorine-based oxidizing agent to pass through a membrane separation apparatus, in which the water of interest which contains the combined-chlorine-based oxidizing agent has a Free 300-second value of 0.036 mg / L-Cl2 or more wherein the Free 300-second value is a result of the measurement of a chlorine concentration after 300 seconds using a free chlorine measurement reagent.

Method for producing a gas enriched in carbon dioxide from a feed synthesis gas comprising at least one condensable component and in particular hydrogen, characterized in that the method further comprises: a step referred to as a desaturation step during which at least a portion of the condensable component contained in the feed synthesis gas is, upstream of said pressure swing adsorption separation unit, condensed by cooling to a temperature below 10° C., in particular below or equal to 5° C., and separated, producing said desaturated synthesis gas and at least one condensate; the feed synthesis gas exchanging heat with the desaturated synthesis gas so as to heat said desaturated synthesis gas.

The invention relates to the technical field of formaldehyde copolymer production, and discloses a trioxymethylene static crystallization separation method which comprises the following steps: S1, cooling crystallization: the crystallization temperature is 25-30 DEG C, and the crystallization time is 3-4 hours; s2, discharging mother liquor; s3, sweating, wherein the sweating temperature is 50-55 DEG C, and the sweating time is 2-2.5 h; and S4, melting to obtain a high-purity product. According to the invention, the characteristic that the solubility of trioxymethylene is reduced along with temperature reduction is utilized, and separation and purification are realized through temperature gradient regulation and control. The content of trioxymethylene in the prepared finished product reaches 94-96% and is higher than that in the prior art by 90-92%, the formaldehyde content is only 0.1-0.2%, and the impurity content is lower.

The invention belongs to a resin separation method, and particularly relates to an ion exchange tower for uranium water separation of resin with different particle sizes and a separation method. The ion exchange tower for uranium water separation of resin with different particle sizes comprises a tower body, a resin discharge pipe and a liquid inlet pipe are respectively arranged at the bottom end of the tower body, a resin input pipe and a liquid outlet pipe are arranged at the top end of the tower body, an organic glass pipe is further arranged at the top end of the tower body, and a liquid accumulation disc is arranged at the top end of the tower body. The method has the remarkable effects that the mass difference of the resins with different particle sizes is utilized, and the liquid inlet flow speed of the bottom of the ion exchange tower is controlled, so that the small-particle-size resin is separated from the large-particle-size resin, and the small-particle-size resin flows out of the top of the ion exchange tower along with the rinsing tail liquid and enters the evaporation pond through the liquid discharging system; and the large-particle-size resin is left in the ion exchange tower. And the proportion of small-particle-size resin in a process system is effectively reduced.