647results about "Fatty acid esterification" patented technology

The invention discloses a molasses-based biomass sulfonated carbon catalyst preparation method, which comprises: grinding and mixing solid molasses and sodium hydroxide, calcining at 500-650 DEG C in an inert atmosphere to obtain activated carbon, and carrying out a sulfonation reaction on the activated carbon and concentrated sulfuric acid to obtain the catalyst. According to the method, by-product molasses in the sugar industry is taken as a raw material, a carbon source is rich in source, low in price and easy to obtain, the process is simple, the catalyst has relatively high specific surface area and conversion rate, the by-product can be utilized in a high-valued manner, and the method has certain industrial practical value.

The invention discloses a resource regeneration method of waste lubricating oil, relates to the technical field of petrochemical engineering, and belongs to the patent classification number C10M175 / 06. The preparation method comprises the following steps: adding a composite flocculant into the waste lubricating oil, heating and stirring, and then carrying out magnetic separation to obtain pretreated waste lubricating oil; uniformly mixing the pretreated waste lubricating oil, glycerol and a Ni / Al2O3 catalyst, then heating and reacting under pressure, and cooling to room temperature to obtain a catalytic hydrogenation product; and carrying out reduced pressure distillation on the catalytic hydrogenation product, recovering the lubricant base oil fraction, adding methanol and concentrated sulfuric acid into the distillation residual liquid, heating for esterification reaction, and separating the liquid to obtain the biodiesel. In the pretreatment process, the composite flocculant is used for removing acid and particle impurities in the lubricating oil, a traditional alkali adding neutralization precipitation process is replaced, the method is environmentally friendly, and the recovery cost of enterprises is reduced.

The invention discloses a supported composite zinc catalyst and application thereof in biodiesel, and belongs to the technical field of catalyst preparation. The supported composite zinc catalyst provided by the invention comprises the following components: an AlPO4-SiO2 composite carrier, a zinc-cerium bimetallic active component supported on the carrier, and a hydrophobic modification layer coated outside the active component. The supported composite zinc catalyst has higher tolerance to moisture and free fatty acid in the waste grease, saponification side reaction is reduced, raw material pretreatment requirements are simplified, the catalyst is easy to recover and reuse, and production cost and environmental burden are remarkably reduced.

A composition is described comprising a mixture of at least one cetylated fatty acid or a mixture of cetylated fatty acids and an antioxidant in reduced percentages by weight, and related methods for treatment of arthritis and of inflammatory joint and musculoskeletal pain. Furthermore a composition is described comprising a mixture of at least one cetylated fatty acid or a mixture of cetylated fatty acids and, optionally, an antioxidant, and related treatment methods for protecting the gastric mucosa and for regulating the blood glucose levels. Additionally, a method is described for preparing the at least one cetylated fatty acid or mixture of cetylated fatty acids and for preparing compositions comprising the cetylated fatty acids and the antioxidant.

The invention relates to the field of biodiesel catalytic materials, and particularly discloses a catalyst for kitchen waste oil, a preparation method and biodiesel. The catalyst for the kitchen waste oil is prepared from a Fe3O4-SiO2-Pr < 3 + > nano-particle carrier and a lipase solution, the catalyst is prepared from a Pr (NO3) 3 solution doped with Pr < 3 + > being 0.88-0.92 wt%, the lipase solution is a pseudomonas lipase solution with the concentration being 22-28 mg / mL, and the pH is 7.0; the preparation method comprises the following steps: preparing Fe3O4 nanospheres, coating the surfaces of the Fe3O4 nanospheres with SiO2 layers, dipping the Fe3O4 nanospheres in a Pr (NO3) 3 solution, carrying out calcination treatment to obtain a Fe3O4-SiO2-Pr < 3 + > nanoparticle carrier, placing the carrier in a lipase solution, carrying out adsorption fixation, and separating out the carrier to obtain the catalyst. The catalyst is used for processing biodiesel and has the advantages of being easy to recycle, high in loading capacity, low in activity loss and good in stability.

The invention relates to the technical field of rice bran processing, and discloses a rice bran degreasing and nutrition retention edible process synergistic treatment method which comprises the following steps: (a) in an NADES-aqueous solution medium, adding an immobilized catalyst A, and hydrolyzing ferulate bonds and phospholipids in rice bran at low temperature; (b) carrying out intermediate dehydration on the slurry obtained in the step (a) to reduce the water activity; (c) adding an immobilized catalyst B into the dehydrated slurry in the step (b), carrying out esterification reaction, and grafting free ferulic acid generated by hydrolysis to glyceride in situ; and (d) carrying out solid-liquid separation on the slurry obtained in the step (c) to obtain finished oil and finished powder. According to the method, an NADES medium is adopted to replace an organic solvent, the whole process is carried out at low temperature, degradation of heat-sensitive nutrient substances is avoided, and resource utilization of ferulic acid is achieved. The prepared functional rice bran oil is rich in feruloyl glyceride, total tocopherol and oryzanol, and is low in acid value and peroxide value.

The present invention provides a method, application and product for preparing diglyceride with weight loss effect by enzymolysis, which belongs to the field of enzyme engineering technology. The method comprises the following steps: S1, mixing lipase, ammonium heptamolybdate tetrahydrate with water, adding glycerol precipitation, filtering, and obtaining an enzyme preparation; S2, mixing plant raw material oil, glycerol, fatty acid, sodium fatty acid with the enzyme preparation obtained in step S1, reacting under inert gas conditions, and obtaining an enzymolysate; S3, molecularly distilling the enzymolysate obtained in step S2 to obtain diglyceride; wherein the lipase is a mixture of Rhizomucor miehei lipase and Candida antarctica Aspergillus niger lipase. The present invention uses ammonium heptamolybdate tetrahydrate to load a specific lipase mixture, and at the same time optimizes the component types and ratios of the raw materials in the enzymolysis process, effectively improving the mass percentage content and diglyceride yield of enzymolysis production of diglyceride.

The present disclosure provides for improved compositions of ionizable lipid nanoparticles for the delivery of therapeutic nucleic acids to cells. Cationic ionizable lipids are engineered with improved stability to oxidative degradation while in storage, while retaining high transfection activity or potency in cells. These lipids are designed to be biodegradable, thus improving the tolerability of nanoparticles formed with them in vivo. In addition, targeting of these nanoparticles in a highly specific manner to dendritic cells is provided for through inclusion of antibody conjugates directed against cell surface receptors.

The subject invention provides compositions and methods for reducing the carbon footprint of producing biofuels. Microbe-based soil treatment compositions are utilized to reduce greenhouse gas emissions resulting from the agricultural practices of producing feedstock crops.

The invention discloses coconut oil rich in diglyceride and a preparation method thereof, and belongs to the technical field of coconut oil deep processing, and the preparation method comprises the following steps: heating coconut oil and monoglyceride as substrates, adding Novozym 435 lipase as a catalyst, and carrying out a catalytic reaction at 40-80 DEG C to obtain the coconut oil rich in diglyceride. The coconut oil and the monoglyceride are used as main raw materials, and the Novozym 435 lipase is selected as a catalyst, so that the conversion efficiency of the diglyceride is improved, the content of the diglyceride in the coconut oil is greatly increased, the nutritional characteristics of the coconut oil are combined with the functional characteristics of the diglyceride, and the nutritional value of the coconut oil is further improved. Meanwhile, the preparation method provided by the invention is mild in reaction condition, low in energy consumption and good in reaction specificity.

A composition is described comprising a mixture of at least one cetylated fatty acid or a mixture of cetylated fatty acids and an antioxidant in reduced percentages by weight, and related methods for treatment of arthritis and of inflammatory joint and musculoskeletal pain. Furthermore a composition is described comprising a mixture of at least one cetylated fatty acid or a mixture of cetylated fatty acids and, optionally, an antioxidant, and related treatment methods for protecting the gastric mucosa and for regulating the blood glucose levels. Additionally, a method is described for preparing the at least one cetylated fatty acid or mixture of cetylated fatty acids and for preparing compositions comprising the cetylated fatty acids and the antioxidant.

The invention relates to the technical field of catalysts, and particularly discloses a Ni-Cu-CeO2 / ZrO catalyst for improving oxidation stability of biodiesel and a preparation method of the Ni-Cu-CeO2 / ZrO catalyst. The invention discloses a Ni-Cu-CeO2 / ZrO catalyst for improving oxidation stability of biodiesel. The Ni-Cu-CeO2 / ZrO catalyst comprises a carrier, an active component and an auxiliary agent, the carrier is a CeO2-ZrO2 composite oxide; the active components are Ni and Cu; ni accounts for 3-5 wt% of the mass of the catalyst, and Cu accounts for 1-3 wt% of the mass of the catalyst; the auxiliary agent is La2O3; the preparation method comprises the following steps: firstly preparing the CeO2-ZrO2 carrier by adopting a coprecipitation method, then impregnating nickel nitrate, copper nitrate and lanthanum nitrate in an isopyknic manner, and then carrying out stepped roasting to obtain the catalyst. The catalyst has high catalytic activity and stability, unsaturated fatty acid ester in biodiesel can be removed, the oxidation stability of the biodiesel is improved, and the cost of the catalyst is lower than that of a noble metal catalyst.

The present invention provides a wax formulation that includes about 5 weight percent (wt %) to about 85 wt % of a natural oil-based petrolatum composition based on total weight of the wax formulation; and about 1 wt % to about 95 wt % of a wax material based on total weight of the wax formulation; wherein the natural oil-based petrolatum composition a triglyceride component containing a plurality of hydroxyl containing fatty acid chains and wherein a plurality of the hydroxyl containing fatty acid chains are esterified with a C8-C22 branched or straight chain fatty acid and wherein the natural oil-based petrolatum composition has a drop melting point measured by AOCS Standard Procedure Cc 18-80 of between 35 and 70° C.

The invention relates to the technical field of catalysis, and particularly discloses a method for preparing pure biodiesel from kitchen waste oil through enzyme catalytic desulfurization. The method comprises the following steps: adding a Sm2O3 / ZrO2 solid acid catalyst into the kitchen waste oil for pretreatment to obtain pretreated waste oil, and then adding lipase into the pretreated waste oil for catalyzing transesterification to obtain the biodiesel. According to the method for preparing the pure biodiesel from the kitchen waste oil through enzyme catalytic desulfurization, in-situ esterification and synchronous desulfurization of free fatty acid can be completed in a single-step reaction, the stability of a conversion reaction is effectively improved, the production process is simplified, and the conversion efficiency of preparing the biodiesel from the kitchen waste oil is improved.

The invention relates to the technical field of chemical production, and discloses an isooctyl stearate continuous production device and method based on a green catalyst, and the isooctyl stearate continuous production device based on the green catalyst comprises a feeding mechanism, a preheating mechanism, a reactor and a separation mechanism, the reactor comprises a reaction kettle and a catalytic bed, the catalytic bed is arranged in the reaction kettle, a material distributing mechanism, a stirring mechanism, a driving mechanism and a linkage mechanism are arranged in the reaction kettle, and a first temperature sensor and a second temperature sensor are fixedly installed on the inner wall of the reaction kettle. The reaction kettle is reasonable in design, raw materials can be preheated through the arranged preheating mechanism, the temperatures of different positions in the reaction kettle can be monitored through the arranged material distributing mechanism, stirring mechanism, linkage mechanism and driving mechanism, the stirring speed and the feeding rate are adjusted in real time, it is ensured that the reaction is conducted in a relatively stable temperature environment, and the reaction efficiency is improved. Therefore, the purity and quality of the product are improved.

The invention provides sulfonated ionic liquid as well as a preparation method and application thereof, the preparation method of the sulfonated ionic liquid comprises the following steps: dropwise adding sultone into an organic solution of 2-amino-5-sulfydryl-1, 3, 4-thiadiazole, and carrying out condensation reflux reaction at 90 DEG C for 24 hours; carrying out reduced pressure suction filtration to remove the solvent, washing the solid, and drying to obtain an ionic liquid onium salt precursor; dissolving the ionic liquid onium salt precursor in water, slowly dropwise adding inorganic acid, and reacting at 90 DEG C for 10 hours; and after the reaction is finished, performing reduced pressure distillation to remove water, washing the solid to remove the inorganic acid, the residual raw materials and byproducts, performing reduced pressure distillation to obtain a solid, and drying to obtain the sulfonated ionic liquid. The sulfonated ionic liquid does not corrode equipment, can efficiently catalyze oleic acid esterification reaction to prepare biodiesel, and can be recycled. The sulfonated ionic liquid disclosed by the invention has good application prospects and large-scale popularization potential in the field of catalyzing oleic acid to prepare biodiesel.

The present technology provides a wax formulation that includes about 5 wt % to about 85 wt % of a natural oil-based petrolatum composition based on total weight of the wax formulation; and about 1 wt % to about 95 wt % of a wax material based on total weight of the wax formulation; wherein the natural oil-based petrolatum composition that includes an esterification product of a pre-esterification mixture that includes: about 0.1 wt % to about 40 wt % a fatty acid dimer based on total weight of the pre-esterification mixture, about 99.9 wt % to about 60 wt % of one or more components selected from the group consisting of C2-C6 polyols, natural oils, hydrogenated natural oils, fatty acids, and acyl glycerols, based on total weight of the pre-esterification mixture, wherein the natural oil-based petrolatum composition has a cone penetration value of greater than 10 and a polydispersity index of greater than 1.3.

In the present invention, a novel synthesis method for fatty acid methyl esters and fatty acid ethyl esters is provided. More specifically, a fatty oil composition obtained from dry insects by mechanical treatment is reacted with an aliphatic alcohol in the presence of an alkali metal alkoxide, such as methoxide or ethoxide, to obtain fatty acid methyl esters (FAME) or fatty acid ethyl esters (FAEE).

The invention relates to an edible fat-containing product comprising an aqueous phase and 20 - 39 wt.% of a fat phase, wt.% calculated on the weight of the product. The fat phase comprises a liquid vegetable oil and 5 - 90 wt.% of a structuring fat, wt.% calculated on the fat phase, wherein the structuring fat is an interesterified blend of fats wherein one of the fats in the blend to be interesterified has > 95 wt.% C18:0 calculated on the amount of fatty acids of the triglycerides of the fat. The fats in the blend to be interesterified do not contain palm oil or palm oil-derived fractions, and the fats in the blend to be interesterified and the liquid vegetable oil do not contain hydrogenated oil or fat or fractions thereof. The fat phase comprises, calculated on the amount fatty acids of the triglycerides of the fat phase, an amount of C18:0 (stearic acid) from 5 to 25 wt.%.

The present invention relates to light-colored corn wax oxides, to a process for their preparation, and to their use for agricultural or forestry purposes, as additives in plastic processing, in care products, in printing inks and / or in paints, and to saponified or esterified corn wax oxides prepared by saponification or esterification of the said corn wax oxides.

The present invention relates to a confectionery product comprising 20% to 70% by weight of a sweetener; and 20% to 70% by weight of a plant-based fat phase; wherein the plant-based fat phase has from 1.0% to 10.0% by weight of total lauric acid (C12: 0) and myristic acid (C14: 0); and from 20.0% to 70.0% by weight of total palmitic acid (C16: 0) and stearic acid (C18: 0); the percentage of acid is an acid bound as an acyl group in the glyceride of the plant-based fat phase and based on the total weight of C8 to C24 fatty acids; total palmitic acid (C16: 0) and stearic acid (C18: 0) in the second position of the triglycerides, which accounts for at least 1.0% of the percentage of total palmitic acid (C16: 0) and stearic acid (C18: 0) in the triglycerides of the plant-based fat phase (Sn-2 total palmitic acid and stearic acid%); up to 10.0% by weight of a total CN32 triglyceride, CN34 triglyceride, CN36 triglyceride, CN38 triglyceride, and CN40 triglyceride; the plant-based fat phase is based on total triglycerides present in the plant-based fat phase. The invention also relates to a method for preparing said confectionery product.

The present application provides a kind of waste oil transesterification reaction catalytic system, belong to biomass refining field.The preparation steps of catalyst include: in the solution containing Ni (NO3) 2 And Fe (NO3) 3 Carboxymethyl cellulose is added, then urea is added, reaction is carried out, and nano-porous NiFe2O4 is obtained, MgCl2 / ZnCl2 Solution and KOH / K2CO3 Solution are added to NiFe2O4 water dispersion, reaction is carried out, solid product is collected, calcination is carried out, and catalyst is obtained.Catalyst is added to waste oil to carry out catalytic reaction.The present application adopts carboxymethyl cellulose to regulate the crystal form, grain size and dispersity of catalyst carrier, and the obtained solid magnetic catalyst can improve the production efficiency of waste oil for preparing biodiesel.The catalyst has high active site, fast reaction rate, mild reaction condition, can reduce reaction energy consumption and production cost.The catalyst also has good magnetic property, is convenient for recovery.The catalyst has good stability, improves the controllability and stability of reaction.

To provide an agent for inhibiting the loss of aroma volatile components, capable of improving volatility and instability of aroma volatile components in a beverage or food product, and capable of being used simply and easily.SOLUTION: An agent for inhibiting the loss of aroma volatile components in a beverage or food product, the agent comprising sterol ester obtained from rice bran.SELECTED DRAWING: None

An object is to provide an oil and / or fat with low trans fatty acid content. The oil and / or fat reduces graining in chocolate-based products. The oil and / or fat is a randomly interesterified oil in which in constituent fatty acid composition, a content of a saturated fatty acid having from 12 to 18 carbons is 20 mass% or more, and in the constituent fatty acid composition, when X denotes the content of the saturated fatty acid having from 12 to 18 carbons and Y denotes a content of a saturated fatty acid having from 12 to 14 carbons, Y / X is 0.2 or more and 1.0 or less.

The utility model relates to the technical field of deep processing of grease, in particular to a transesterification grease treatment device which comprises a separation device and a vacuum heating device, a funnel is arranged at a top inlet of the separation device and penetrates through the separation device, and the lower end of the funnel is suspended; a first outlet and a second outlet are formed in the side wall of the separation device, and the separation device is connected with a vacuum heating device through the first outlet; a heating structure, a third outlet and a fourth outlet are arranged in the vacuum heating device, and the third outlet and the fourth outlet are arranged on the side wall of the vacuum heating device. According to different conditions of the oil-water separation layer, the flowing-out position of the grease can be accurately adjusted, the oil-water separation accuracy is improved, meanwhile, impurities such as water and methyl alcohol in the grease are effectively removed, and the purity of the grease is remarkably improved.

The invention relates to the production of a triglyceride with Palmitic acid (P) in the middle position (XPX). A first transesterification process is used to produce a vegetable fat composition rich in palmitic acid and said intermediate composition is then further processed to produce triglycerides having a high proportion of its palmitic acid in the middle position.

The present invention relates to a preparation method and application of a black soldier fly worm sand biomass carbon-based solid acid catalyst. The preparation method comprises the following steps: first, the black soldier fly worm sand is sieved with a sieve, and then the sieved black soldier fly worm sand is added to a sodium hydrosulfide solution and stirred and soaked for several hours. The pretreated black soldier fly worm sand is washed three times with deionized water and dried in an oven for 24 hours. Finally, the pretreated and dried worm sand is pyrolyzed and carbonized at high temperature in a nitrogen atmosphere for several hours to obtain a biochar-based solid acid catalyst material. The present invention uses biomass worm sand as raw material, which is cheap and easily available, reduces the production cost of solid acid catalysts and biodiesel, and improves the utilization value of renewable resources. In the present invention, the carbon-based material is pretreated with a sodium hydrosulfide solution, which not only improves the acid catalytic activity of the catalyst, but also improves the pore structure of the catalyst, thereby improving the catalytic activity of the carbon-based material as a whole, and is expected to become a highly competitive clean process route.

Edible, pourable, fat-containing product, preferably in the form of a water-in-oil emulsion or a full fat product, comprising 40 to 99.9 wt. % liquid vegetable oil; 0.1 to 10 wt. % of hard stock fat; water up to 100 wt. %, wt. % calculated on the total weight of the product, wherein the hard stock fat is free from palm or palm-derived fats or fat fractions; free from hydrogenated fats or fat fractions and has a C22:0 (behenic acid) content of at least 10 wt. %, wt. % calculated on the amount of fatty acids in the hard stock.

The invention relates to compositions comprising glycerol and glyceryl esters of nonanoic acid, their preparation and use.

Provided is a method for producing a transesterified oil / fat rich in diacylglycerol with a small amount of by-products without changing a glyceride composition of a reaction oil.　The present invention provides a production method for a transesterified oil / fat, the method including subjecting an oil / fat and glycerin to a transesterification reaction, subsequently performing a process of reducing glycerin dissolved in a reaction oil, and subsequently performing a process of bringing an adsorbent into contact with the glycerin-free oil.