4227 results about "Biochar" patented technology

The invention belongs to the field of biochar adsorbing materials, and relates to a method for preparing modified biochar with aquatic plant waste and hematite. The method includes the following steps: (1) naturally drying aquatic plants prior to crushing to obtain aquatic plant powder; (2) crushing the hematite to obtain hematite powder; (3) weighing the hematite powder prior to putting the hematite powder into deionized water, and performing ultrasonic treatment to obtain suspension; (4) weighing the aquatic plant powder, soaking the aquatic plant powder in the suspension, and stirring and drying to obtain fully mixed aquatic plant and hematite mixture; (5) weighing the fully mixed aquatic plant and hematite mixture, putting the mixture in a batch-type atmosphere furnace, and feeding nitrogen into the furnace; performing temperature programming to the target temperature, and maintaining final-temperature pyrolysis; after the pyrolysis process is finished, obtaining the target product, namely the modified biochar. The modified biochar has strong adsorbability in nitrate and phosphate, high in stability and reusable.

The invention discloses a microbial compound bacterial fertilizer for improving saline alkali soil and increasing the acting yield. A preparation method of the microbial compound bacterial fertilizer comprises the following steps: preparing a microbial agent containing phosphate-solubilizing bacteria, potassium-solubilizing bacteria, nitrogen-fixing bacteria, bacillus subtilis and actinomycetes; the preparation method comprises the following steps: preparing a sodium alginate solution, adding nano-hydroxyapatite and a microbial agent, uniformly mixing, dropwise adding a calcium chloride solution, and embedding an inner layer to obtain microbial embedded particles; uniformly mixing biochar, humic acid and attapulgite, taking a 2-3% HPMC solution as a binder, and carrying out middle-layer coating, so as to obtain prefabricated microbial fertilizer particles; and coating the chitosan-sodium alginate-nano ZnO outer layer to obtain the microbial compound bacterial fertilizer. The microbial compound bacterial fertilizer disclosed by the invention adopts a multi-layer and multifunctional collaborative design concept, realizes efficient protection and slow release of functional microorganisms in a saline-alkali environment, remarkably improves the physicochemical properties of soil and promotes the growth of crops.

The invention discloses a bio-organic fertilizer for repairing heavy metal cadmium in soil and a preparation method of the bio-organic fertilizer, and belongs to the technical field of organic fertilizers. The organic fertilizer is prepared from the following raw materials in parts by weight: 7-12 parts of a compound microbial agent, 30-40 parts of modified charcoal, 3-8 parts of sodium alginate, 6-8 parts of a chelating agent and 60-80 parts of decomposed edible fungus residues. The compound microbial agent is prepared from potassium-solubilizing paenibacillus mucilaginosus MSSW02, pseudomonas plecoglossicida and bacillus aryabhattai; the chelating agent is composed of calcium humate and nano-hydroxyapatite according to the mass ratio of 100: (3-5). The multi-component synergistic effect is achieved, the content of heavy metal in soil is effectively reduced, especially the content of heavy metal Cd, meanwhile, rich organic matter is contained, the physical and chemical properties of the soil can be remarkably improved, the water and fertilizer retention capacity of the soil is improved, and crop growth is promoted; the remediation effect on medium-light cadmium polluted farmland soil is good, and the growth promoting effect on crops is remarkable.

The invention discloses a rapid culture method of aerobic granular sludge, and belongs to the technical field of sewage treatment. According to the invention, pharmaceutical factory sludge is used as a raw material to prepare pharmaceutical factory sludge biochar; an SBR reactor is constructed and operates in a water inlet-anoxic-aeration-precipitation-drainage mode, and pharmaceutical factory sludge biochar is added in the sludge inoculation process to promote rapid formation of system particles and stable operation. According to the method disclosed by the invention, the mature aerobic granular sludge with the capabilities of removing organic matters and synchronously denitrifying can be obtained by culturing for 30 days on average, so that the granulation process of the sludge is effectively improved, the forming time of the aerobic granular sludge is remarkably shortened, and the aerobic granular sludge has higher long-term operation stability.

The invention belongs to the technical field of soil fertilizers, and particularly relates to a soil conditioner and a preparation method thereof. Wherein the soil conditioner is prepared from the following raw materials in parts by weight: 30 to 40 parts of modified charcoal, 20 to 30 parts of microbial complexing agent, 15 to 25 parts of humic acid and 1 to 5 parts of biological enzyme; according to the microbial complexing agent, dopamine grafted and modified nano silicon dioxide and hydroxyapatite form a composite shell, pseudomonas aeruginosa and bacillus subtilis are wrapped, and the microbial complexing agent has the functions of protecting microorganisms, adsorbing heavy metals and slowly releasing phosphorus elements; the modified biochar is compounded with the attapulgite through acid-base treatment to form a porous structure with physical inlaying and chemical functional groups synergistic, so that the adsorption and fixation capability on heavy metals and organic pollutants is remarkably improved; the biological enzyme accelerates organic phosphorus conversion, and enzymatic hydrolysate provides a phosphorus source for microorganisms, promotes microorganism breeding, effectively increases the content of available phosphorus in soil, and enhances the stability of a remediation system.

The invention provides a special charcoal-based slow-release fertilizer for sandy soil as well as a preparation method and application thereof, and belongs to the technical field of fertilizers. The special charcoal-based slow-release fertilizer for the sandy soil is prepared from amino modified biomass charcoal, urea, urea formaldehyde, monoammonium phosphate, potassium sulfate, polyglutamic acid, fulvic acid, clay, attapulgite, a compound microbial agent and sodium alginate. The compound microbial agent is prepared from halomonas (ACCC 11681), bacillus subtilis (ACCC 60429) and bacillus mucilaginosus (ACCC 10094), and the compound microbial agent is prepared from bacillus subtilis (ACCC 60429) and bacillus mucilaginosus (ACCC 10094). The invention further provides a preparation method and application of the special charcoal-based slow-release fertilizer for the sandy soil. The special charcoal-based slow-release fertilizer for the sandy soil can remarkably improve the water and fertilizer retention capacity of the sandy soil, improve the farmland productivity of the sandy soil, save fertilizer and water input and improve the yield and quality of crops.

The invention discloses a biomass charcoal composite hydrogel slow-release fertilizer as well as a preparation method and application thereof, and belongs to the field of composite hydrogel and fertilizer preparation. The invention provides a biomass charcoal composite hydrogel slow release fertilizer, which comprises biomass charcoal, hydrogel fixed on the pores and surface of the biomass charcoal, and an element fertilizer mixed in the hydrogel, and the hydrogel is prepared from metal cations and alginate. The invention provides a strategy of'in-hole in-situ gelation ', hydrogel is prepared in situ in gaps of the biochar, and the biomass charcoal composite hydrogel slow-release fertilizer is prepared. The biochar and the hydrogel in the slow-release fertilizer are high in bonding strength and mechanical strength, so that the slow-release fertilizer has the slow-release function of the fertilizer and also has the capability of improving soil.

The invention discloses composite modified pig manure and sludge biochar, relates to the technical field of modified biochar, and mainly comprises pig manure and sludge. The invention also provides a preparation method of the compound modified pig manure and sludge biochar, pig manure and sludge are mixed and pyrolyzed to prepare the pig manure and sludge biochar, and the pig manure and sludge biochar is modified by sulfuric acid and a magnesium chloride solution to prepare the compound modified pig manure and sludge biochar. According to the composite modified pig manure and sludge biochar provided by the invention, pig manure and sludge are subjected to carbonization modification through a composite modification technology, so that heavy metal cadmium pollution is efficiently removed, and meanwhile, a new way is provided for resource utilization of organic wastes.

The invention discloses a large-scale pig breeding wastewater purification treatment system, and relates to the technical field of wastewater treatment.The large-scale pig breeding wastewater purification treatment system is characterized in that the ion concentration of anaerobic liquid is monitored through a multi-ion sensing array, and a multi-channel feeding system is controlled to synthesize customized struvite compound fertilizer; the AI prediction control unit predicts the optimal medicament dosage and realizes millisecond-level closed-loop regulation; the multi-dimensional synergistic biochemical treatment module comprises an A / O biochemical treatment unit and an electric field enhanced anaerobic ammonia oxidation reactor, the electric field enhanced anaerobic ammonia oxidation reactor applies a direct-current electric field through an electrode pair, and engineering conductive biochar is used as a carrier to accelerate microbial metabolism; the sludge low-temperature pyrolysis self-consistent circulation module is used for pyrolyzing and converting residual sludge into biochar, biofuel and wood vinegar, and the biochar activation treatment unit is used for preparing engineering conductive biochar and forming a substance closed loop through a self-consistent circulation conveying system; and the digital twinning intelligent management and control platform realizes intelligent management and control of the system.

The invention provides a treatment method of ammonia-nitrogen-containing wastewater, and belongs to the technical field of wastewater treatment. The preparation process comprises the following steps: preparing the wastewater treatment agent; preparing an immobilized microbial compound; and treating the ammonia-nitrogen-containing wastewater. According to the immobilized microbial carrier prepared by the invention, a stable dual-network structure and proper pore channels are formed through the synergistic effect of the polyvinyl alcohol, the carboxymethyl chitosan and the polyurethane; secondary cross-linking significantly enhances the stability of the carrier, optimizes internal pore channels, and is beneficial to attachment and proliferation of microorganisms; after the corn straw biochar is modified by Ca / Al, the specific surface area and functional groups are increased, and the physicochemical adsorption of ammonia nitrogen is enhanced. The three are combined, and ammonia nitrogen in wastewater is efficiently removed through synergism of carrier adsorption and microbial metabolism.

Low-carbon, carbon-neutral, and carbon-negative asphalt composites are disclosed. The composites comprise an asphalt binder and a functionalized biochar incorporated as a partial replacement for the binder and / or mineral filler. The biochar is physically, chemically, or mineralogically modified to enhance dispersion, interfacial bonding, mechanical performance, and carbon sequestration. The invention further includes methods for producing such composites, biochar-based additive compositions, and kits for practical implementation. Applications include asphalt pavements, waterproofing membranes, crack sealants, conductive deicing systems, and VOC-reducing asphalt mixtures. The resulting materials demonstrate improved durability, thermal and electrical properties, and significant reductions in greenhouse gas emissions.

The invention belongs to the technical field of organic pollution treatment, and relates to a biochar-LDH-nZVI-GO composite material for organic pollution remediation and a preparation method and application thereof.The preparation method comprises the steps that graphene oxide is ultrasonically dispersed in deionized water, magnesium salt and aluminum salt are added to form uniform suspension liquid, then the uniform suspension liquid is mixed with biochar suspension liquid, and the biochar-nZVI-GO composite material is obtained; carrying out pH (Potential of Hydrogen) regulation and a hydrothermal crystallization reaction, so as to prepare a biochar-Mg / Al-LDH-GO compound; and dispersing the compound in an organic solvent, sequentially adding FeSO4. 7H2O and a NaBH4 solution in an inert atmosphere to carry out a reduction reaction, and finally washing and drying to obtain the biochar-LDH-nZVI-GO composite material. The material shows high-efficiency removal capacity on various organic pollutants such as trichloroethylene, chlorobenzene and polychlorinated biphenyl, is suitable for high-efficiency green remediation of organic pollutants in soil and water, and has good popularization and application prospects.

The invention discloses a method for restoring soil heavy metal pollution by coupling soybean urease with a charcoal cementing agent, and relates to the technical field of soil heavy metal pollution restoration, and the method comprises the following steps: dynamic microbiome regulation and control: introducing photosensitive protein into soil functional bacteria; the acyl homoserine lactone analogue is synthesized and applied to soil, and is competitively combined with a microbial quorum sensing receptor to block an inhibitor to secrete a signal channel; according to the method, microbial urease secretion is regulated and controlled through optogenetics, an inhibitor signal is blocked through quorum sensing interference, and a microbiome is precisely regulated and controlled; the pH-responsive nanocapsule releases an inhibitor in a targeted manner, and the magnetic-responsive nanochain dynamically captures interfering bacteria, so that the limitation of passive adsorption is broken through; the gene editing plant releases coumarin to inhibit fungal metabolism, and the engineering mycorrhizal fungi physically shields an inhibitor to construct cross-biosphere cooperative defense; the urease activity and the heavy metal removal rate are remarkably improved, meanwhile, the soil microbial diversity is maintained, and the soil specificity interference problem is solved.

The invention discloses a charcoal nano lanthanum material capable of synchronously removing organic phosphorus and inorganic phosphorus, and belongs to the field of environmental functional materials. The adsorbent comprises biochar and nano lanthanum loaded on the biochar, wherein the biochar is bamboo biochar; the nano lanthanum is in a La (OH) 3 form, the particle size of the nano lanthanum is 1-250nm, and the loading capacity of the nano lanthanum is 3-20wt%; the pore diameter of the biochar nano lanthanum material is 1-30nm, and the specific surface area is 100-250m < 2 > / g. Compared with a biochar-loaded nano lanthanum composite material in the prior art, the composite material has the inorganic phosphorus adsorption performance and also has the organic phosphorus adsorption effect, and inorganic phosphorus and organic phosphorus can be synchronously removed. According to the charcoal nano lanthanum material, organic phosphorus is adsorbed and removed by regulating and controlling the defect form of lanthanum, especially organic phosphonate can be hydrolyzed and removed, meanwhile, large pore channels of bamboo charcoal are beneficial to diffusion of macromolecular organic phosphorus to action sites of lanthanum, and the adsorption and hydrolysis effects of lanthanum on the organic phosphorus are further enhanced.

The invention discloses a preparation method of an intelligent response type soil conditioner based on a nano composite material, and belongs to the technical field of soil improvement. The modifier is prepared from 10 to 15 parts of modified chitosan, 15 to 25 parts of nano silicon dioxide, 20 to 30 parts of biochar-loaded polyglutamic acid, 8 to 15 parts of humic acid-sodium alginate microcapsules, 3 to 5 parts of trace element slow-release particles, 1 to 2 parts of a pH response type cross-linking agent and 15 to 25 parts of a functional agent. The soil conditioner researched and developed by the invention can flexibly adapt to complex and changeable soil environments, can sensitively sense dynamic changes of key environmental indexes such as soil humidity, pH value and temperature, automatically and accurately regulates and controls the release rate and the action effect of the soil conditioner, realizes multiple functions such as water retention, acid regulation, fertility increase and pollution resistance in a one-stop manner, and has a wide application prospect. High efficiency, long-term effect and ecological environment friendliness of soil improvement are comprehensively achieved, a new road is opened up for global soil improvement, and agricultural yield increase, ecological restoration and urban green development are assisted.

The invention belongs to the technical field of soil improvement, and discloses a preparation method of a manganese slag-coconut shell charcoal-desulfurized gypsum composite soil improvement agent, the soil improvement agent and application. The preparation method of the soil conditioner comprises the working procedures of manganese residue pretreatment, coconut shell pretreatment, precursor preparation, precursor calcination and conditioner compounding, the pretreated coconut shell and the pretreated manganese residue are mixed and then subjected to ball milling, and a manganese residue-coconut shell precursor is obtained; calcining the prepared manganese residue-coconut shell precursor for 1-4 hours at the temperature of 450-650 DEG C in a protective gas atmosphere to obtain manganese residue-coconut shell biochar; and doping desulfurized gypsum powder into the prepared manganese slag-coconut shell charcoal, and uniformly dispersing to obtain the manganese slag-coconut shell charcoal-desulfurized gypsum composite soil conditioner. The method disclosed by the invention has the advantages of low energy consumption, low cost and capability of treating waste with waste, and the prepared soil conditioner has the advantages of improving soil nutrient balance, reducing nutrient loss and stabilizing pH, and is suitable for modifying the acid soil of the rubber plantation in the tropical region.

The invention discloses a method for preparing a supercapacitor electrode through high-temperature alkali activation. The method comprises the steps of preparing porous carbon, preparing an electrode plate, preparing a supercapacitor, and carrying out electrochemical performance testing and material characterization testing. When the carbon precursor of the supercapacitor electrode material is prepared, organic components in walnut shells can be refined and removed and biochar is left by utilizing the effect of removing organic matters in biomass at high temperature of a tubular furnace; the potassium hydroxide with different concentrations is used as the activating agent to activate the biochar, the porosity and the internal structure richness of the porous carbon can be greatly improved, and compared with traditional solid alkali activation, the aqueous solution alkali activation has the advantages that the reliability and the possibility are improved, and the contact area of the activating agent and substances is increased. The electrode material prepared by the method has the advantages of low manufacturing cost, small environmental pollution and excellent service life, and is an ideal electrode material.

The invention discloses a preparation method of metal ion liquid modified co-doped biochar and application of the metal ion liquid modified co-doped biochar in tetracycline removal, and belongs to the technical field of water pollution treatment and adsorption material preparation. The preparation method comprises the following steps: mixing a biochar precursor with a metal ion liquid containing transition metal and a heteroatom source, and carrying out high-temperature carbonization to obtain the metal ion liquid modified co-doped biochar. Multiple modification of the biochar is realized through one-time high-temperature carbonization (transition metal elements and heteroatoms are introduced into a biochar skeleton, abundant surface active sites are provided, and the specific surface area and pore volume of the biochar are improved), so that the adsorption performance of the biochar on tetracycline antibiotics is remarkably improved. The preparation method is simple in process, raw materials are easy to obtain, and the obtained metal ion liquid modified co-doped biochar has excellent adsorption performance on antibiotic pollutants such as tetracycline and is suitable for purification treatment of water polluted by antibiotics.

The invention discloses a heavy metal chelating agent for industrial wastewater and a preparation method of the heavy metal chelating agent, and belongs to the technical field of sewage treatment.The preparation method comprises the steps that 2-hydroxyphenylboronic acid is subjected to graft modification through acrylic acid and polymerized on the surface of activated biomass porous carbon powder with acrylic acid, boron-containing polymer modified porous carbon is obtained, and then ferric chloride hexahydrate serves as an iron source; a boron-containing polymer modified porous carbon surface and aminated magnetic adsorption nanospheres are obtained, B-N coordination is formed between the aminated magnetic adsorption nanospheres and the boron-containing polymer modified porous carbon surface, boron element fixation is achieved through modified copolymerization, loss caused by long-time use of the boron element is avoided, lasting and stable chelation is guaranteed, activated biomass porous carbon serves as a carrier, and macromolecular resin serves as a coating layer. The environment-friendly biochar has the advantages of favorable degradability, greenness, degradability, safety and high efficiency, and avoids the problem of secondary pollution caused by the use of a chelating agent.

The invention discloses a preparation process of a soil conditioner and application of the soil conditioner in soil improvement, and the preparation process comprises the following steps: S1, preparation of pretreated biomass; s2, preparation of composite biochar; s3, preparation of sulfhydrylated biochar; s4, preparing the modified composite biochar; and S5, uniformly mixing the modified composite charcoal, kaolin, humic acid, fly ash, slaked lime and vermiculite to obtain the soil conditioner. According to the soil conditioner, modified composite biochar prepared through specific functionalization is blended with kaolin, humic acid, fly ash, slaked lime and vermiculite according to a certain proportion, and the prepared soil conditioner has unique advantages in the aspects of improving soil organic matter, fixing carbon, providing microelements and especially regulating and controlling the activity of soil microorganisms; advanced complementation and synergistic interaction of all the components are achieved, and the comprehensive treatment requirement of complex degraded soil can be better met.

The invention relates to the technical field of environmental restoration, in particular to a slow-release material for synergistically restoring heavy metal and organic compound contaminated soil based on modified biochar and microorganisms and an application method thereof.The slow-release material is prepared from, by weight, 50-80 parts of modified biochar, 30-40 parts of sodium alginate, 10-20 parts of gelatin, 5-10 parts of glycerin and 3-5 parts of calcium carbonate. The multi-modified biochar is prepared from, by weight, 300-400 parts of a functional flora mixed solution and 5-10 parts of mixed nutrient elements of glucose, yeast extract and KHPO, and through the synergistic effect of the multi-modified biochar and the functional flora, efficient immobilization (the immobilization rate gt is 60%) of heavy metal (lead, cadmium and chromium) and efficient degradation (the degradation rate gt is 70%) of organic pollutants (polycyclic aromatic hydrocarbon and petroleum hydrocarbon) are achieved.

The invention relates to the technical field of soil function improvement, in particular to a rice field soil recarburization and capacity expansion method based on a charcoal-based organic fertilizer. The method comprises the following steps: crushing a biomass raw material, pyrolyzing and cooling to obtain biochar; immersing the biochar in a functional bacteria solution containing actinomycetes and bacillus for activating treatment to obtain modified biochar; mixing the modified biochar and decomposed straw, composting and fermenting to obtain organic fertilizers with different particle sizes; the large-particle-size organic fertilizer is applied to deep soil, the soil is covered with soil after straw is laid on the soil, and the small-particle-size organic fertilizer is applied to surface soil. Through layered application, the large-particle-size biochar repairs the deep soil structure and expands the carbon storage capacity, and meanwhile, the carbon stability is improved through carbon-nitrogen synergistic metabolism driven by functional bacteria, so that the carbon immobilization efficiency is improved, meanwhile, soil recarburization and expansion are achieved, the contradiction between carbon sequestration and structure degradation and nutrient imbalance in a traditional recarburization and expansion technology is solved, and the soil recarburization and expansion efficiency is improved. Synergic improvement of a carbon sink function and agricultural productivity is promoted.

The invention discloses a solid waste admixture prepared based on microbiological treatment of regenerated micro-powder and a preparation method, and aims to overcome the defect that the dilution effect is remarkable when regenerated micro-powder is directly used as an admixture in the prior art. The method comprises the following steps: treating waste concrete to obtain regenerated micro powder; culturing bacillus pasteurii, and preparing a bacterial solution with a target OD value; mixing the regenerated micro-powder and a bacterial solution according to a certain solid-to-liquid ratio, adding urea and biochar, and reacting in a magnetic stirrer for a set time to obtain modified regenerated micro-powder; and taking out the modified regenerated micro powder, filtering, drying to constant weight, and fully scattering to obtain the solid waste admixture. According to the present invention, the bacteria-containing culture solution is subjected to centrifugal treatment and the low concentration of the bacteria solution is adopted, such that the by-products generated by the metabolism of the bacillus pasteurii are reduced on the premise of ensuring the sufficient decomposition of the urea, and the prepared regenerated micro-powder contains rich ultrafine calcium carbonate on the surface, and can be adopted as the solid waste admixture to significantly enhance the compressive strength of the cement matrix.

The invention relates to a cultivation nutrient medium and a preparation method thereof. According to the nutrient medium, peat is completely abandoned, the coco coir, the straw and the biochar are combined to reduce ecological burden, the nutrient medium is an environment-friendly medium, the biochar fixes carbon and reduces emission, and the soil structure can be improved after long-term use; vermiculite improves the water-holding capacity, perlite and straw form a stable pore structure, and the ventilation porosity reaches 25% or above. Wormcast and a microbial agent synergistically release nitrogen, phosphorus and potassium, and the fertilizer efficiency is lasting. The microbial agent can inhibit soil-borne diseases such as fusarium and reduce the death rate of cultivated seedlings. The biochar adsorbs salt and toxins, and the EC value is stabilized at 1.2-1.8 mS / cm. The cost of the selected raw materials is reduced by 35% compared with that of a traditional substrate, and the substrate is suitable for large-scale production, suitable for vegetable seedling culture, potted flowers, organic farms and soilless culture systems, and especially suitable for saline-alkali soil or continuous cropping obstacle areas.

A method of fabricating a biochar composite product comprises thermally treating a precursor composition by heating the precursor composition according to a heating profile to provide a biochar composite product, the precursor composition comprising biochar and a natural binder other than lignin, wherein the natural binder forms a solid, porous, covalently bound carbon matrix at or above a threshold temperature, wherein the biochar composite product comprises a plurality of porous, carbonaceous particles and the solid, porous, covalently bound carbon matrix on surfaces of particles in the plurality such that neighboring particles are adhered together. The biochar composite products and methods of using the products are also provided.

The invention discloses a method and device for removing polyfluorinated perfluorides in a water body, and the method comprises the following steps: 1, pretreatment: removing large-particle impurities in the water body to be treated through a grid, then feeding the water body to be treated into a pH adjusting tank, and adding an acidic mixed solution to reduce the pH value to 4.0; 2, electrochemical oxidation: enabling the water body to flow into an electrochemical oxidation module, and reacting for 20-40 minutes under the voltage of 10V; when the method is implemented, long-chain PFAS is decomposed into short-chain products through three-stage cooperation of electrochemical oxidation, adsorption enrichment and membrane separation, so that subsequent removal of the short-chain PFAS is facilitated, the removal rate can be improved, the whole process is simpler compared with the prior art, and a large amount of cost is saved; the boron-doped diamond anode and the iron-cobalt bimetallic cathode are combined, and the modified biochar adsorbent is combined, so that the PFAS degradation rate is increased, and meanwhile, the electrode loss can be reduced.

The invention relates to the technical field of soil remediation, in particular to a soil remediation formula optimization method based on solid waste raw material charcoal improvement, which comprises the following steps: acquiring a coal gangue powder material flow and a sludge material flow, respectively performing component detection on a soil sample set, the coal gangue powder material flow and the sludge material flow to obtain a component content report, performing multi-factor combination on the plurality of biochar, the plurality of microbiota and the plurality of enrichment plants to obtain a plurality of first initial raw material combinations; and constructing a plurality of unit soil remediation experiment groups based on the component content report, the plurality of first initial raw material combinations, the soil sample set, the coal gangue powder material flow and the sludge material flow, and performing a soil remediation experiment on the plurality of unit soil remediation experiment groups based on a preset test pause condition to obtain an optimal scheme. According to the invention, the formula optimization of targeted soil remediation can be realized by utilizing the charcoal, the coal gangue and the municipal sludge.

The invention belongs to the technical field of soil improvement, and relates to a soil conditioner for saline-alkali soil and a soil improvement method. The soil conditioner comprises vinegar residues, chitin, glucose, a composite biological preparation, a modified gel and a functional additive, the composite biological agent comprises bacillus subtilis powder, bacillus licheniformis powder, trichoderma spore powder, brown algae powder and light calcium carbonate; the functional auxiliary agent comprises modified bentonite, polyglutamic acid, pregelatinized starch and biochar potassium humate. Through the synergistic effect of multiple components and structural design optimization, systematic remediation of physical properties, chemical properties and biological activity of the saline-alkali soil is achieved. According to the technology, the limitation of single function of a traditional improvement measure is broken through, and the long-standing technical problems of return salt rebound, low fertility, microbial community imbalance and the like in saline-alkali soil treatment are effectively solved by constructing a multi-layer and multi-dimensional soil improvement system.

The invention provides a biochar composite porous material for heavy metal contaminated soil remediation and a preparation method and application of the biochar composite porous material. The preparation method comprises the steps that biomass raw materials are subjected to high-temperature pyrolysis carbonization and then smashed, ground and sieved, and biochar powder is obtained; dispersing in a phosphoric acid solution to obtain a biochar solution, and filtering, washing and drying after a hydrothermal activation reaction to obtain activated biochar; dispersing in a chitosan solution, carrying out ultrasonic oscillation, filtering, washing and drying to obtain modified charcoal; mixing sodium bentonite, attapulgite and deionized water, uniformly mixing the modified charcoal, the functional slurry and a sodium carboxymethyl cellulose solution to obtain composite slurry, performing compression molding to obtain a green body, and then drying and calcining the green body. The biochar composite porous material prepared by the invention can simultaneously play multiple roles of physical adsorption, chemical chelation, ion exchange and the like in a heavy metal contaminated soil treatment process, so that efficient fixation of various heavy metal ions is realized.

The invention relates to the technical field of solid waste resource utilization, and particularly discloses a waste incineration fly ash resource treatment method which comprises the following steps: firstly, efficiently removing dioxin in fly ash in a manner of adding a vanadium-cerium-loaded charcoal catalyst and co-pyrolyzing with fluidized bed combustion ash; the method comprises the following steps: preparing fly ash from fly ash, washing the fly ash with micro-nano bubble water containing carbon dioxide for dechlorination, adding an iron-manganese-silicon biochar adsorbent after dechlorination to adsorb heavy metals in the fly ash, sintering the fly ash after adsorption and fly ash under an alkaline condition to further stabilize residual soluble chlorine and heavy metals in the fly ash, and finally, recycling the residual soluble chlorine and heavy metals in the fly ash. And the treated fly ash and cement are processed into cement building blocks with good mechanical properties, so that resource utilization of the waste incineration fly ash is realized.