5038 results about "Biochar" patented technology

The invention belongs to the field of biochar adsorbing materials, and relates to a method for preparing modified biochar with aquatic plant waste and hematite. The method includes the following steps: (1) naturally drying aquatic plants prior to crushing to obtain aquatic plant powder; (2) crushing the hematite to obtain hematite powder; (3) weighing the hematite powder prior to putting the hematite powder into deionized water, and performing ultrasonic treatment to obtain suspension; (4) weighing the aquatic plant powder, soaking the aquatic plant powder in the suspension, and stirring and drying to obtain fully mixed aquatic plant and hematite mixture; (5) weighing the fully mixed aquatic plant and hematite mixture, putting the mixture in a batch-type atmosphere furnace, and feeding nitrogen into the furnace; performing temperature programming to the target temperature, and maintaining final-temperature pyrolysis; after the pyrolysis process is finished, obtaining the target product, namely the modified biochar. The modified biochar has strong adsorbability in nitrate and phosphate, high in stability and reusable.

The invention discloses a microbial compound bacterial fertilizer for improving saline alkali soil and increasing the acting yield. A preparation method of the microbial compound bacterial fertilizer comprises the following steps: preparing a microbial agent containing phosphate-solubilizing bacteria, potassium-solubilizing bacteria, nitrogen-fixing bacteria, bacillus subtilis and actinomycetes; the preparation method comprises the following steps: preparing a sodium alginate solution, adding nano-hydroxyapatite and a microbial agent, uniformly mixing, dropwise adding a calcium chloride solution, and embedding an inner layer to obtain microbial embedded particles; uniformly mixing biochar, humic acid and attapulgite, taking a 2-3% HPMC solution as a binder, and carrying out middle-layer coating, so as to obtain prefabricated microbial fertilizer particles; and coating the chitosan-sodium alginate-nano ZnO outer layer to obtain the microbial compound bacterial fertilizer. The microbial compound bacterial fertilizer disclosed by the invention adopts a multi-layer and multifunctional collaborative design concept, realizes efficient protection and slow release of functional microorganisms in a saline-alkali environment, remarkably improves the physicochemical properties of soil and promotes the growth of crops.

The invention provides a petroleum hydrocarbon pollution remediation method based on soil microorganisms, and provides an innovative solution aiming at the problems of high cost, high energy consumption and secondary pollution of an existing remediation technology. The method comprises the following steps: firstly, carrying out sampling analysis and pretreatment on polluted soil, screening out a microbial strain capable of efficiently degrading petroleum hydrocarbon, and fixing the microbial strain on a biochar carrier to form an immobilized microbial composite material; then, the material is added into the contaminated soil, and tolerant plants are planted to construct a combined remediation system. Meanwhile, nutrient substances such as nitrogen and phosphorus and a surfactant are added, so that the bioavailability and the microbial degradation efficiency of the petroleum hydrocarbon are improved. In the repairing process, the petroleum hydrocarbon content and the microbial activity are monitored regularly, and the repairing scheme is dynamically adjusted. According to the method, the biochar is prepared from agricultural waste, the cost is reduced, efficient and environment-friendly remediation is achieved by combining the synergistic effect of microorganisms and plants, and the method has remarkable economic and environmental benefits and is suitable for treatment of soil polluted by various petroleum hydrocarbons.

The invention discloses a culture method of anaerobic ammonia oxidation granular sludge with a polydopamine modified charcoal-loaded Fe-Cu sodium alginate microsphere kernel, which comprises the following steps: modifying charcoal by using polydopamine, then carrying out Fe-Cu ion loading, finally preparing sodium alginate microspheres, and taking the prepared sodium alginate microspheres as the kernel to prepare the anaerobic ammonia oxidation granular sludge with the polydopamine modified charcoal-loaded Fe-Cu sodium alginate microsphere kernel. And co-culturing the sodium alginate microspheres and activated bacillus DMF-4 in an oxygen-free environment, continuously culturing for 3 weeks, and collecting by using a gravity settling or centrifugal method to obtain the anaerobic ammonium oxidation granular sludge with the sodium alginate microsphere core. The sodium alginate microspheres serving as the core provide large density and good morphological support for sludge particles, the problem of sludge bulking is avoided, and the settling performance is improved. According to the present invention, the sludge anti-shearing performance is improved, the adsorption capacity of the slowly released and continuously slowly released iron ions on organic matters, ammonia nitrogen and heavy metals is enhanced, the sewage treatment effect is improved, and the iron ions are the biodegradable material so as not to cause secondary pollution in the use process.

The invention relates to the field of fertilizers, in particular to a macroelement water-soluble fertilizer and a preparation method thereof.The preparation method comprises the steps that a composite biochar material is prepared from biochar, loaded metal modified biochar and an iron metal material, and then the composite biochar material is compounded with tripotassium phosphate, monopotassium phosphate, disodium octoborate tetrahydrate, zinc sulfate monohydrate and the like; the finally prepared fertilizer can realize accurate fertilizer supply, the iron metal organic framework material efficiently converts nitrate nitrogen into ammonium nitrogen and cooperates with a large amount of trace elements such as tripotassium phosphate, the requirements of crops at all stages are met, nutrients in key periods are guaranteed, pores of the composite biochar material adsorb the nutrients, nutrient slow release is realized, root system interpenetration resistance is reduced, stress resistance is enhanced, and the yield of the crops is increased. The soil conditioner has the advantages of simple preparation process, reduction of growth hindrance, optimization of soil aggregates, increase of pores, reduction of volume weight, improvement of ventilation, water permeability and water and fertilizer retention capabilities, substantial agricultural economy energization, substantial yield increase of crops, and wide application prospects.

The invention discloses biochar coupled bacteria-algae granular sludge as well as a culture method and application thereof. According to the invention, in an optical sequencing batch reactor, activated sludge in a secondary sedimentation tank of a sewage treatment plant, chlorella and biochar are utilized for culturing to obtain biochar coupled bacteria-algae granular sludge, and pollutants such as COD, NH4 < + >-N, PO4 < 3->-P and antibiotics (such as enrofloxacin) contained in aquaculture wastewater can be efficiently removed by utilizing the biochar coupled bacteria-algae granular sludge under the condition that the salinity is 0.3%. Besides, the biochar coupled bacteria-algae granular sludge is good in stability, when the biochar coupled bacteria-algae granular sludge is used for treating antibiotic pollutants, the situation that the removal rate of the antibiotic pollutants is reduced along with the prolonging of time is avoided, pollutants such as COD, NH4 < + >-N, PO4 < 3-P > and antibiotics can be efficiently and stably removed, and the biochar coupled bacteria-algae granular sludge has good application prospects. The method has a good application prospect in aquaculture wastewater treatment.

The invention discloses a bio-organic fertilizer for repairing heavy metal cadmium in soil and a preparation method of the bio-organic fertilizer, and belongs to the technical field of organic fertilizers. The organic fertilizer is prepared from the following raw materials in parts by weight: 7-12 parts of a compound microbial agent, 30-40 parts of modified charcoal, 3-8 parts of sodium alginate, 6-8 parts of a chelating agent and 60-80 parts of decomposed edible fungus residues. The compound microbial agent is prepared from potassium-solubilizing paenibacillus mucilaginosus MSSW02, pseudomonas plecoglossicida and bacillus aryabhattai; the chelating agent is composed of calcium humate and nano-hydroxyapatite according to the mass ratio of 100: (3-5). The multi-component synergistic effect is achieved, the content of heavy metal in soil is effectively reduced, especially the content of heavy metal Cd, meanwhile, rich organic matter is contained, the physical and chemical properties of the soil can be remarkably improved, the water and fertilizer retention capacity of the soil is improved, and crop growth is promoted; the remediation effect on medium-light cadmium polluted farmland soil is good, and the growth promoting effect on crops is remarkable.

The invention discloses a magnetic biochar composite adsorbent as well as a preparation method and water treatment application thereof, and relates to the technical field of adsorption materials. The preparation method consists of a biochar matrix and magnetic particles loaded on the surface and in pores of the biochar matrix, and comprises the following steps: preparation of the biochar matrix: step 1, firstly, selecting a biomass raw material; the magnetic charcoal composite adsorbent has unique structure and performance advantages, abundant pore structures and surface functional groups of the adsorbent can provide a large number of adsorption sites for pollutants, and due to the existence of magnetic particles, after the adsorption process is completed, the adsorbent only needs to be placed in an external magnetic field such as an electromagnet and a permanent magnet, so that the magnetic charcoal composite adsorbent can be used for adsorbing the pollutants. The adsorbent can be rapidly separated from the solution or the suspension, the separation time can be controlled within 1-10 minutes, the recovery efficiency of the adsorbent is greatly improved, the treatment cost is reduced, and the adsorbent can be repeatedly used and has good economical efficiency and environmental protection property.

The invention discloses a rapid culture method of aerobic granular sludge, and belongs to the technical field of sewage treatment. According to the invention, pharmaceutical factory sludge is used as a raw material to prepare pharmaceutical factory sludge biochar; an SBR reactor is constructed and operates in a water inlet-anoxic-aeration-precipitation-drainage mode, and pharmaceutical factory sludge biochar is added in the sludge inoculation process to promote rapid formation of system particles and stable operation. According to the method disclosed by the invention, the mature aerobic granular sludge with the capabilities of removing organic matters and synchronously denitrifying can be obtained by culturing for 30 days on average, so that the granulation process of the sludge is effectively improved, the forming time of the aerobic granular sludge is remarkably shortened, and the aerobic granular sludge has higher long-term operation stability.

The invention relates to the field of agricultural soil improvement and ecological fertilization, and discloses an ecological fertilization method for improving the organic matter content of soil in a dry-hot valley region, and the method comprises the following steps: soil matrix improvement: improving the porosity and water binding capacity of the soil by adding charcoal and humic acid particles; the functional microbial preparation is put, and the activity of soil microorganisms is activated through the combined effect of cellulose decomposition bacteria, stabilization promoting flora and water retention flora; green manure crop planting and covering management: planting sweet clover and other leguminous crops to provide a carbon source and a nitrogen source for soil, and meanwhile, utilizing straw covering to inhibit water evaporation; turning over and stabilizing the green manure crops, namely turning over and stabilizing the organic matters in a blooming period of the green manure crops and combining with a stabilization promoting bacterial liquid and an adsorptive carrier; dynamic balance is maintained, and dynamic balance of decomposition, conversion and accumulation of organic matter is achieved step by step through multi-cycle planting and turning and pressing. The organic matter content and fertility of the soil can be improved, and the water-retaining property and microbial ecosystem of the soil are improved.

The invention belongs to the technical field of soil fertilizers, and particularly relates to a soil conditioner and a preparation method thereof. Wherein the soil conditioner is prepared from the following raw materials in parts by weight: 30 to 40 parts of modified charcoal, 20 to 30 parts of microbial complexing agent, 15 to 25 parts of humic acid and 1 to 5 parts of biological enzyme; according to the microbial complexing agent, dopamine grafted and modified nano silicon dioxide and hydroxyapatite form a composite shell, pseudomonas aeruginosa and bacillus subtilis are wrapped, and the microbial complexing agent has the functions of protecting microorganisms, adsorbing heavy metals and slowly releasing phosphorus elements; the modified biochar is compounded with the attapulgite through acid-base treatment to form a porous structure with physical inlaying and chemical functional groups synergistic, so that the adsorption and fixation capability on heavy metals and organic pollutants is remarkably improved; the biological enzyme accelerates organic phosphorus conversion, and enzymatic hydrolysate provides a phosphorus source for microorganisms, promotes microorganism breeding, effectively increases the content of available phosphorus in soil, and enhances the stability of a remediation system.

The invention provides a special charcoal-based slow-release fertilizer for sandy soil as well as a preparation method and application thereof, and belongs to the technical field of fertilizers. The special charcoal-based slow-release fertilizer for the sandy soil is prepared from amino modified biomass charcoal, urea, urea formaldehyde, monoammonium phosphate, potassium sulfate, polyglutamic acid, fulvic acid, clay, attapulgite, a compound microbial agent and sodium alginate. The compound microbial agent is prepared from halomonas (ACCC 11681), bacillus subtilis (ACCC 60429) and bacillus mucilaginosus (ACCC 10094), and the compound microbial agent is prepared from bacillus subtilis (ACCC 60429) and bacillus mucilaginosus (ACCC 10094). The invention further provides a preparation method and application of the special charcoal-based slow-release fertilizer for the sandy soil. The special charcoal-based slow-release fertilizer for the sandy soil can remarkably improve the water and fertilizer retention capacity of the sandy soil, improve the farmland productivity of the sandy soil, save fertilizer and water input and improve the yield and quality of crops.

The invention discloses a biomass charcoal composite hydrogel slow-release fertilizer as well as a preparation method and application thereof, and belongs to the field of composite hydrogel and fertilizer preparation. The invention provides a biomass charcoal composite hydrogel slow release fertilizer, which comprises biomass charcoal, hydrogel fixed on the pores and surface of the biomass charcoal, and an element fertilizer mixed in the hydrogel, and the hydrogel is prepared from metal cations and alginate. The invention provides a strategy of'in-hole in-situ gelation ', hydrogel is prepared in situ in gaps of the biochar, and the biomass charcoal composite hydrogel slow-release fertilizer is prepared. The biochar and the hydrogel in the slow-release fertilizer are high in bonding strength and mechanical strength, so that the slow-release fertilizer has the slow-release function of the fertilizer and also has the capability of improving soil.

The invention discloses composite modified pig manure and sludge biochar, relates to the technical field of modified biochar, and mainly comprises pig manure and sludge. The invention also provides a preparation method of the compound modified pig manure and sludge biochar, pig manure and sludge are mixed and pyrolyzed to prepare the pig manure and sludge biochar, and the pig manure and sludge biochar is modified by sulfuric acid and a magnesium chloride solution to prepare the compound modified pig manure and sludge biochar. According to the composite modified pig manure and sludge biochar provided by the invention, pig manure and sludge are subjected to carbonization modification through a composite modification technology, so that heavy metal cadmium pollution is efficiently removed, and meanwhile, a new way is provided for resource utilization of organic wastes.

The invention discloses magnetic modified biochar, a preparation method and application of the magnetic modified biochar to adsorption of micro-plastics, and belongs to the technical field of biochar. The method comprises the following steps: pretreating industrial hemp straws, pyrolyzing at 700 DEG C in a nitrogen atmosphere to obtain original biochar, activating with potassium hydroxide, and continuously pyrolyzing in the nitrogen atmosphere to obtain activated biochar powder; soaking the obtained activated charcoal powder in an iron nitrate nonahydrate solution, mixing and stirring, drying and pyrolyzing, washing and drying to obtain the magnetic modified charcoal. Compared with traditional biochar, after the activated biochar is subjected to impregnation-pyrolysis treatment, Fe < 3 + > is introduced into the formed magnetic modified biochar, so that the specific surface area, the pore diameter, the adsorption performance and the magnetism are improved; meanwhile, in the application process of adsorbing the micro-plastics, a magnet can be used for separating the magnetic modified charcoal adsorbent from the micro-plastics, and the effects of recycling and cyclic regeneration are achieved.

The invention relates to the technical field of soil conditioners, and particularly discloses an intelligent controlled-release core-shell alginate soil conditioner and a preparation method thereof.The conditioner is of a core-shell-layer three-layer structure and comprises a core layer, a middle shell layer and an outer layer, the three layers account for 30%, 40% and 30% of the total weight respectively, and the core layer mainly comprises improved alginate and nutrients; the middle shell layer mainly comprises chitosan and a microbial preparation; and the outer layer mainly comprises modified charcoal and magnetic nano # imgabs0 #. The preparation method comprises the four steps of core layer preparation, middle shell layer coating, outer layer coating and forming post-treatment, and multiple functions of accurate nutrient supply, efficient heavy metal fixation and soil microenvironment regulation and control are achieved through a core-shell-layer three-layer structure design and a pH / temperature / microorganism triple response mechanism by adopting a coaxial electronic injection and layer-by-layer self-assembly technology; the fertilizer has a remarkable improvement effect on sandy soil and saline-alkali soil, and the organic matter increasing rate reaches 40%.

According to the method disclosed by the invention, arbuscular mycorrhizal fungi and biochar are added while multiple-leaf goldenrain trees are planted in cadmium-polluted soil. Compared with a traditional remediation mode of independently utilizing plants or microorganisms or biochar, the microorganism-plant-biochar combined remediation has the advantages that the plants, the microorganisms and the biochar are co-cultured to form a symbiotic system, so that the cadmium content in the soil is remarkably reduced, the remediation capacity of the plants is enhanced, and meanwhile, the growth of the plants is remarkably improved. The strategy breaks through the limitation that in the prior art, only improvement of plant resistance is concerned, and the strategy more focuses on the double effects of improving the phytoremediation capacity and promoting the growth effect, so that the maximization of the phytoremediation effect is achieved.

The invention discloses a large-scale pig breeding wastewater purification treatment system, and relates to the technical field of wastewater treatment.The large-scale pig breeding wastewater purification treatment system is characterized in that the ion concentration of anaerobic liquid is monitored through a multi-ion sensing array, and a multi-channel feeding system is controlled to synthesize customized struvite compound fertilizer; the AI prediction control unit predicts the optimal medicament dosage and realizes millisecond-level closed-loop regulation; the multi-dimensional synergistic biochemical treatment module comprises an A / O biochemical treatment unit and an electric field enhanced anaerobic ammonia oxidation reactor, the electric field enhanced anaerobic ammonia oxidation reactor applies a direct-current electric field through an electrode pair, and engineering conductive biochar is used as a carrier to accelerate microbial metabolism; the sludge low-temperature pyrolysis self-consistent circulation module is used for pyrolyzing and converting residual sludge into biochar, biofuel and wood vinegar, and the biochar activation treatment unit is used for preparing engineering conductive biochar and forming a substance closed loop through a self-consistent circulation conveying system; and the digital twinning intelligent management and control platform realizes intelligent management and control of the system.

The invention provides a southern red soil dry land deacidification soil conditioner and a preparation method thereof, and belongs to the technical field of soil conditioners. The preparation method comprises the following steps: embedding bacillus subtilis, bacillus licheniformis and bacillus amyloliquefaciens to prepare bacterial microspheres, adding the bacterial microspheres into gel formed by carboxymethyl chitosan and silk fibroin peptide to prepare sustained-release bacterial microsphere gel, uniformly mixing the sustained-release bacterial microsphere gel with porous silicon dioxide loaded with basalt and charcoal, and drying to prepare the acid-reducing soil conditioner for the southern red soil dry land. The acid-reducing soil conditioner for the southern red soil dry land not only improves the pH value of the soil, but also can loosen the soil and improve the air permeability of the soil to a certain extent, and promotes the absorption of crops to moisture and nutrient elements by improving the physical and chemical properties of the soil, so that the normal growth of the crops is ensured, and the acid-reducing soil conditioner has a wide application prospect.

The invention provides a treatment method of ammonia-nitrogen-containing wastewater, and belongs to the technical field of wastewater treatment. The preparation process comprises the following steps: preparing the wastewater treatment agent; preparing an immobilized microbial compound; and treating the ammonia-nitrogen-containing wastewater. According to the immobilized microbial carrier prepared by the invention, a stable dual-network structure and proper pore channels are formed through the synergistic effect of the polyvinyl alcohol, the carboxymethyl chitosan and the polyurethane; secondary cross-linking significantly enhances the stability of the carrier, optimizes internal pore channels, and is beneficial to attachment and proliferation of microorganisms; after the corn straw biochar is modified by Ca / Al, the specific surface area and functional groups are increased, and the physicochemical adsorption of ammonia nitrogen is enhanced. The three are combined, and ammonia nitrogen in wastewater is efficiently removed through synergism of carrier adsorption and microbial metabolism.

The invention relates to the field of saline-alkali soil remediation, and particularly discloses a saline-alkali soil improvement and remediation method which comprises the following steps: step 1, soil pretreatment: performing deep scarification operation on saline-alkali soil at the depth of 40-60cm, and applying desulfurized gypsum particles with the particle size of less than or equal to 5mm at the dosage of 3-5t / ha; step 2, paving a biochar-based composite material: mixing biochar, humic acid and nano-hydroxyapatite according to a mass ratio of 4: 1: 0.5 to form composite particles with the particle size of less than or equal to 2mm, and burying the composite particles into soil in a layered manner according to the dosage of 8-12t / ha; through physical and chemical regulation and control of the biochar-based composite material, biological metabolism activation of the composite microbial agent and dynamic optimization of intelligent water and salt management, a cascade remediation system of material salt resistance-microbial soil improvement-plant salt absorption is constructed, all technical modules are mutually coupled, the salt reduction efficiency is remarkably improved, and the comprehensive utilization rate of the biochar-based composite material is increased. Meanwhile, the soil nutrient circulation capacity is enhanced, and the problems that a traditional single technology is limited in action range and long in remediation period are solved.

Low-carbon, carbon-neutral, and carbon-negative asphalt composites are disclosed. The composites comprise an asphalt binder and a functionalized biochar incorporated as a partial replacement for the binder and / or mineral filler. The biochar is physically, chemically, or mineralogically modified to enhance dispersion, interfacial bonding, mechanical performance, and carbon sequestration. The invention further includes methods for producing such composites, biochar-based additive compositions, and kits for practical implementation. Applications include asphalt pavements, waterproofing membranes, crack sealants, conductive deicing systems, and VOC-reducing asphalt mixtures. The resulting materials demonstrate improved durability, thermal and electrical properties, and significant reductions in greenhouse gas emissions.

The invention belongs to the technical field of data processing, and particularly relates to a rice field soil emission reduction potential estimation method and system based on carbon-nitrogen coupling and a medium, and the method comprises the steps: collecting rice field nitrogen application information in a target area through literature statistics, dividing rice fields with similar nitrogen application into the same type, and selecting a plurality of typical areas from each type; carrying out soil sampling at fixed intervals in the typical rice field area, analyzing the nitrogen concentration level of the soil, and obtaining representative samples; performing soil column experimental simulation by using the representative sample, and estimating the average emission of specific gas; and determining significant influence factors, setting different carbon-nitrogen coupling situations to carry out an orthogonal simulation experiment, quantifying factor importance, carrying out weighted accumulation to obtain a comprehensive emission estimation value, and evaluating the carbon-nitrogen coupling-based biochar rice field emission reduction capability. The method can effectively estimate the rice field soil emission reduction potential.

The invention belongs to the technical field of organic pollution treatment, and relates to a biochar-LDH-nZVI-GO composite material for organic pollution remediation and a preparation method and application thereof.The preparation method comprises the steps that graphene oxide is ultrasonically dispersed in deionized water, magnesium salt and aluminum salt are added to form uniform suspension liquid, then the uniform suspension liquid is mixed with biochar suspension liquid, and the biochar-nZVI-GO composite material is obtained; carrying out pH (Potential of Hydrogen) regulation and a hydrothermal crystallization reaction, so as to prepare a biochar-Mg / Al-LDH-GO compound; and dispersing the compound in an organic solvent, sequentially adding FeSO4. 7H2O and a NaBH4 solution in an inert atmosphere to carry out a reduction reaction, and finally washing and drying to obtain the biochar-LDH-nZVI-GO composite material. The material shows high-efficiency removal capacity on various organic pollutants such as trichloroethylene, chlorobenzene and polychlorinated biphenyl, is suitable for high-efficiency green remediation of organic pollutants in soil and water, and has good popularization and application prospects.

The invention discloses a method for restoring soil heavy metal pollution by coupling soybean urease with a charcoal cementing agent, and relates to the technical field of soil heavy metal pollution restoration, and the method comprises the following steps: dynamic microbiome regulation and control: introducing photosensitive protein into soil functional bacteria; the acyl homoserine lactone analogue is synthesized and applied to soil, and is competitively combined with a microbial quorum sensing receptor to block an inhibitor to secrete a signal channel; according to the method, microbial urease secretion is regulated and controlled through optogenetics, an inhibitor signal is blocked through quorum sensing interference, and a microbiome is precisely regulated and controlled; the pH-responsive nanocapsule releases an inhibitor in a targeted manner, and the magnetic-responsive nanochain dynamically captures interfering bacteria, so that the limitation of passive adsorption is broken through; the gene editing plant releases coumarin to inhibit fungal metabolism, and the engineering mycorrhizal fungi physically shields an inhibitor to construct cross-biosphere cooperative defense; the urease activity and the heavy metal removal rate are remarkably improved, meanwhile, the soil microbial diversity is maintained, and the soil specificity interference problem is solved.

The invention discloses a biochar-based slow-release fertilizer and a preparation method thereof, and relates to the technical field of fertilizer production, the biochar-based slow-release fertilizer comprises a core, a carrier layer, a biological layer and a protective layer, the core is composed of macroelements, microelements and a nitrification inhibitor; the carrier layer comprises graphene quantum dot modified charcoal, chitosan, glycerol and cyclodextrin grafted starch; the biological layer is prepared from magnetic Fe3O4 and humic acid nanoparticles, alginic acid oligosaccharide and diatomite; the protective layer comprises a polylactic acid-polycaprolactone block copolymer, acetone, calcium lignosulphonate, a dynamic covalent cross-linking agent gelatin, nano cellulose and an anti-blocking agent. Therefore, by adopting the polylactic acid-polycaprolactone (PLA-PCL)-based segmented copolymer and the dynamic covalent network cross-linking agent, the self-repairing property is endowed. The slow-release fertilizer provided by the invention realizes precise regulation and control of the fertilizer efficiency release rate through a multi-level synergistic effect, has the functions of soil remediation and stress resistance, and significantly improves the utilization efficiency of the fertilizer and the crop adaptability.

A modular porous swale. The modular porous swale may comprise a porous concrete block and filtration joint. The porous concrete block may snugly fit within a trench having a lower portion filled with an absorption media. The absorption media may include gravel, activated alumina, bone char, biochar, bone char and activated alumina mixture, and biochar and activated alumina mixture. The porous concrete block may have a top surface inwardly-sloped to a nadir. The filtration joint may be disposed within the porous concrete block and along the nadir. The liner may cover one or more sides of the porous concrete block. The perforated pipe may be located within the absorption media. The filtration joint may substantially align above a portion of the perforated pipe when the modular porous swale is installed within the trench.

The invention discloses a charcoal nano lanthanum material capable of synchronously removing organic phosphorus and inorganic phosphorus, and belongs to the field of environmental functional materials. The adsorbent comprises biochar and nano lanthanum loaded on the biochar, wherein the biochar is bamboo biochar; the nano lanthanum is in a La (OH) 3 form, the particle size of the nano lanthanum is 1-250nm, and the loading capacity of the nano lanthanum is 3-20wt%; the pore diameter of the biochar nano lanthanum material is 1-30nm, and the specific surface area is 100-250m < 2 > / g. Compared with a biochar-loaded nano lanthanum composite material in the prior art, the composite material has the inorganic phosphorus adsorption performance and also has the organic phosphorus adsorption effect, and inorganic phosphorus and organic phosphorus can be synchronously removed. According to the charcoal nano lanthanum material, organic phosphorus is adsorbed and removed by regulating and controlling the defect form of lanthanum, especially organic phosphonate can be hydrolyzed and removed, meanwhile, large pore channels of bamboo charcoal are beneficial to diffusion of macromolecular organic phosphorus to action sites of lanthanum, and the adsorption and hydrolysis effects of lanthanum on the organic phosphorus are further enhanced.

The invention discloses a Ca / Mg-based modified biochar material and a preparation method and application thereof, and the preparation method comprises the following steps: pretreatment: drying a biomass material shaddock peel, crushing, sieving, washing and drying, then carrying out acid leaching activation, washing again and drying to obtain high-activity biomass powder for later use; dipping modification: fully mixing the high-activity biomass powder obtained in the pretreatment step with CaO and MgO, adding distilled water, dipping under heating and stirring conditions, then carrying out solid-liquid separation, washing a filter cake for multiple times, freeze-drying, and sieving to obtain an intermediate product; the intermediate product is calcined, naturally cooled, washed and dried, and the Ca / Mg-based modified bimetallic modified charcoal material is obtained and can be applied to adsorption of phosphate in a wastewater solution as an adsorbent. The preparation method is simple, the raw materials are easy to obtain, the cost is low, the material stability is good, the pH adaptability is good, the adsorption effect is good, and the method is suitable for water environments with more complex pollution factors.

The invention discloses a preparation method of an intelligent response type soil conditioner based on a nano composite material, and belongs to the technical field of soil improvement. The modifier is prepared from 10 to 15 parts of modified chitosan, 15 to 25 parts of nano silicon dioxide, 20 to 30 parts of biochar-loaded polyglutamic acid, 8 to 15 parts of humic acid-sodium alginate microcapsules, 3 to 5 parts of trace element slow-release particles, 1 to 2 parts of a pH response type cross-linking agent and 15 to 25 parts of a functional agent. The soil conditioner researched and developed by the invention can flexibly adapt to complex and changeable soil environments, can sensitively sense dynamic changes of key environmental indexes such as soil humidity, pH value and temperature, automatically and accurately regulates and controls the release rate and the action effect of the soil conditioner, realizes multiple functions such as water retention, acid regulation, fertility increase and pollution resistance in a one-stop manner, and has a wide application prospect. High efficiency, long-term effect and ecological environment friendliness of soil improvement are comprehensively achieved, a new road is opened up for global soil improvement, and agricultural yield increase, ecological restoration and urban green development are assisted.