The invention discloses a coking wastewater deep treatment and reuse process and equipment thereof, belonging to the technical field of environmental protection, and the main steps are as follows: dosing a coagulant in biochemical treatment water, then leading the biochemical treatment water to enter into a sedimentation tank, discharging sludge from a sludge hopper, leading treated water to enter into a three-dimensional electrode reactor, leading the outlet water after electro-oxidation treatment to enter into a biological filter tank, and leading the water after the treatment of the biological filter tank to enter into a follow-up ultrafiltration treatment; the ultrafiltration outlet water has two selections, one is to reuse the outlet water as the process water directly, the other one is to continuously pass through a reverse osmosis membrane system for treatment; and the coagulation and sedimentation tank, the process equipment of the three-dimensional electrode reactor, the biological filter tank, the ultrafiltration system and the reverse osmosis desalination system are adopted during the treatment process, thereby achieving the purposes of removing residual refractory organic matters, suspended impurities and salt in the waste water, reusing the outlet water, simultaneously leading the content of the organic matters in the reverse osmosis concentrated water not to exceed the national environmental protection standard, also reusing the concentrated water in occasions with less stringent requirements on the water quality and achieving the purpose of zero emission of the wastewater.