The invention discloses an MOF material for synergistically recycling organic-
inorganic pollutants, a preparation method and application of the MOF material in olefin oxidation reaction, and the technical scheme is as follows: S1, adding p-formylbenzoic acid and 1, 3-diamino-2-hydroxypropane into a
mixed solution, reacting for 15-30 hours at 60-80 DEG C in an Ar
atmosphere, removing a
solvent, filtering, washing, and
drying to obtain the MOF material for synergistically recycling organic-
inorganic pollutants. Washing the sample, and performing
vacuum drying to obtain a sample I; s2, adding the sample I and ZrCl4 into a
solvent, then adding an HCl solution, heating at 100-140 DEG C for 40-50 hours after the sample I and ZrCl4 are completely dissolved, performing
centrifugal separation after the reaction is finished, collecting solids, and performing
vacuum drying to obtain a sample II; s3, the
metal salt solution and deionized water are added to be mixed and oscillated for 20-40 h, after the oscillation is finished, solids are collected in a centrifugal mode, the obtained solids are washed and dried,
calcination is conducted for 3-6 h in a tubular furnace at the
nitrogen atmosphere of 400-600 DEG C, and the
metal-organic framework material is obtained. The MOF material for synergic recycling of organic-
inorganic pollutants has higher
epoxide selectivity when being used for olefin oxidation, and can be used for efficiently preparing
epoxide from olefin.