The invention relates to a red organic electroluminescence device and a fabrication method thereof. By using vacuum evaporation technique, a red organic electroluminescence device is fabricated, and the host materials are 4, 4'-N, N'-dicarbazole-diphenyl/ 2, 9-dimethyl-4, 7-diphenyl-1, 10- phenanthroline/ 8-hydroxyl quinoline/ lithium fluoride (LiF)/ aluminum (Al) with a configuration of indium tin oxide (ITO)/ 4, 4'-di[N-(p-methylphenyl)-N-phenyl-amino]dimethyl/ Eu(TTA)3phen, wherein Eu(TTA)3phen is the classical europium complex with trifluoroacetyl thiophene acetone (TTA) and o-phenanthroline (phen) as the first and the second ligands. The low-pressure oxygen plasma treatment on ITO anode is used to enhance hole injection, and the thickness of LiF and Al is precisely adjusted to suitably limit electron injection. The maximum electroluminescence current efficiency of the device is 9.53cd/A, the maximum power efficiency is 5.35lm/W, the maximum external quantum efficiency is 5.15 percent, and the corresponding maximum recombination rate of the device is 85.8 percent.