The application relates to a
molecular beam epitaxy preparation method of epitaxial high-quality AlN on a
Si substrate and an AlN epitaxial
wafer, and the preparation method comprises the following steps: S1, obtaining a substrate, performing
infrared lamp baking on the substrate, performing high-temperature
deoxidization after heating pretreatment, and obtaining a pretreated substrate; S2, adopting a
molecular beam epitaxy method to pre-deposit an Al layer on the pretreated substrate; S3, adopting the
molecular beam epitaxy method to grow an AlN epitaxial layer on the pre-deposited Al layer; and S4, continuously introducing a
nitrogen plasma post-treatment, and cooling to a
wafer transfer temperature to obtain an epitaxial
wafer. In the technical scheme, the pre-deposited Al layer can inhibit the reaction between the substrate and N in the AlN layer, the formation of amorphous particles is avoided, the AlN morphology is improved, meanwhile, the pre-deposited Al layer not only relieves the
lattice mismatch problem between the substrate material and the AlN, but also improves the Al atom migration rate for the growth of the subsequent AlN layer, promotes two-dimensional growth, and thus the AlN
crystal quality is improved.