5871 results about "Calcination" patented technology

The invention discloses a preparation method of a high-compaction-density lithium iron phosphate material, through grading of large and small particle lithium iron phosphate, optimization of a sintering process and reasonable selection of a carbon source and a titanium dopant, the compaction density and the electrochemical performance of the material are remarkably improved, and the preparation method specifically comprises the following steps: mixing iron phosphate, lithium carbonate, the carbon source and auxiliary materials; the preparation method comprises the following steps: carrying out coarse grinding and fine grinding, respectively preparing large-particle lithium iron phosphate and small-particle lithium iron phosphate (a material A and a material B) by adopting spray drying and high-temperature calcination processes, mixing the material A and the material B according to a ratio, adding auxiliary materials, grinding, further carrying out spray drying, calcining and crushing to obtain a final lithium iron phosphate product, and the maximum compaction density of the prepared material can reach 2.712 g / cm < 3 >. According to the present invention, the maximum 1C discharge specific capacity can achieve 140.5 mAh / g, the maximum 1C 3.2 V discharge platform retention rate is 91.4%, and the prepared lithium ion battery negative electrode material has characteristics of excellent conductivity, high discharge capacity and good cycle stability, and is suitable for power batteries and energy storage batteries.

An integrated carbon honeycomb structure material and its preparation method are disclosed, belonging to the field of carbon materials technology. Based on a co-sacrificial template low-temperature pyrolysis strategy, the target material can be obtained through three main steps: preparation of a metal salt-colloidal microsphere template precursor, precursor pressing and molding, and subsequent calcination and carbonization. This technology has the characteristics and advantages of simple preparation process, regular and controllable macroscopic structure of the sample (such as shape, area, and thickness), rich and tunable chemical composition, and three-dimensional interconnection of graphene carbon matrix. It has great application potential in many fields such as electrochemical energy storage, catalysis, gas separation, adsorption, and electromagnetic shielding.

The invention relates to a preparation method and application of a manganese ion doped modified ferric sodium pyrophosphate positive electrode material, and belongs to the technical field of sodium ion battery positive electrodes. The preparation method comprises the following steps: adding a sodium source, a phosphorus source and a carbon source into ethanol, uniformly mixing to form a mixed solution, sequentially adding an iron source and a manganese source into the mixed solution, uniformly mixing to form slurry, and drying the slurry to obtain precursor powder; calcining in a protective atmosphere to obtain a manganese-doped carbon-coated ferric pyrophosphate sodium material; the calcining conditions are as follows: heating to the temperature of 300-350 DEG C at the heating rate of 2-3 DEG C / min, carrying out first-stage constant-temperature calcination for 2-3 hours, heating to the temperature of 500-550 DEG C at the heating rate of 5-8 DEG C / min, and carrying out second-stage constant-temperature calcination for 10-12 hours. By doping the manganese ions, the electronic conductivity and the ion diffusivity of the ferric sodium phosphate pyrophosphate composite material are improved, so that the discharge capacity of the ferric sodium phosphate pyrophosphate composite material at high rate is improved, and the battery has relatively high cycle stability.

The invention provides a cement decomposing furnace temperature prediction control method based on a KAN enhanced neural network, and belongs to the technical field of cement calcination. A CNN-LSTM-KAN network is established as an f-CaO and Nox prediction model, and a state parameter optimization objective function is established in connection with actual production requirements; and solving an optimal solution and an optimal solution interval of the state parameters of the decomposition furnace through a multi-target particle swarm optimization algorithm. A KAN-Enhanced-Informer network is established to predict the temperature of the decomposition furnace, a target function is established by combining a state optimization result with the more accurate prediction result, the less coal consumption and the reasonable alternative fuel quantity as targets, the optimal solutions of the coal feeding quantity and the alternative fuel quantity are obtained, and the optimal solutions are applied to a control model to ensure that the temperature of the decomposition furnace reaches the optimal set value. The problems that in the actual cement production process, energy consumption is too high, the yield is not ideal, and much sewage is discharged are solved.

The invention discloses a method for preparing asphalt-based porous carbon based on an MgO template, and belongs to the technical field of porous carbon, nano MgO and deionized water are mixed and placed in a synthesis kettle, hydrothermal synthesis is performed at 180 DEG C for 2 h, suction filtration and drying are performed, a dried filter cake is crushed and calcined, and porous flaky MgO is obtained; adding the asphalt solution into the MgO suspension, stirring, drying to obtain brown powder, transferring the brown powder into a corundum crucible, putting the corundum crucible into a tubular furnace, calcining to obtain a carbonized C / MgO composite material, and washing the carbonized C / MgO composite material with a diluted hydrochloric acid solution and deionized water to obtain a carbon material sample recorded as AC-75. Pouring the porous carbon material PCs and KOH into a mortar, fully grinding, mixing and calcining to obtain an activated product, pickling and washing the product to be neutral, and drying to obtain the porous carbon material PCs. The raw materials selected by the method are asphalt and flake magnesium oxide which are stable in performance, low in price, large in amount and easy to obtain, a magnesium source can be recycled, environmental protection is achieved, and resources are saved.

The invention discloses a method for preparing nano cerium oxide through supergravity reinforcement, which comprises the following steps: 1) completely dissolving cerium chloride hexahydrate serving as a cerium source with deionized water to prepare a cerium chloride solution; (2) inputting the cerium chloride solution into a supergravity reactor through a peristaltic pump at normal temperature, then inputting ammonia water into the supergravity reactor through a constant-flux pump, and carrying out premixing reaction in the supergravity reactor to form mixed slurry; and 3) after the premixing reaction is finished, taking out the mixed slurry, and carrying out suction filtration, washing, drying and high-temperature oxidation calcination to obtain the nano cerium oxide. According to the method, the production efficiency can be improved, the particle size of the prepared nano cerium oxide is small, the particle size distribution is narrowed, and the crystallinity of crystals is improved.

The invention provides a method for preparing high-purity and fine-particle-size lithium sulfide based on carbon thermal reduction. The method comprises the following steps: weighing lithium sulfate monohydrate, an insoluble inorganic carbon source and cysteine in a set proportion to form a raw material mixture; mixing the raw material mixture with water according to a set solid-to-liquid ratio, performing ultrasonic dispersion to obtain homogeneous dispersion liquid, and enabling the dispersion liquid to pass through a nitrogen circulating spray dryer to obtain uniform and dry precursor powder; in a vacuum environment, carrying out segmented calcination to obtain a crude product lithium sulfide; and in a dry and anhydrous environment, washing the crude product lithium sulfide for multiple times by using absolute ethyl alcohol according to a set liquid-solid ratio to obtain an alcoholic solution containing lithium sulfide, and then obtaining lithium sulfide fine powder through a nitrogen circulating spray dryer. The invention solves the problems of side reaction, low purity, large product particles, uncontrollable particle size and the like of lithium sulfide prepared by a carbon thermal reduction method in the prior art.

The invention discloses a magnesium-based cobalt precipitation agent and a preparation method and application thereof, and relates to the technical field of composite materials. The method comprises the following steps: performing calcination dissociation, enhanced leaching, carbonization separation, efficient pyrolysis, solid-liquid separation, drying and calcination on first magnesium ore to obtain active magnesium oxide; the second magnesium ore is subjected to calcination dissociation, hydration impurity removal, solid-liquid separation and low-temperature calcination, and then high-purity magnesium oxide is obtained; performing series-parallel modification on active magnesium oxide and high-purity magnesium oxide to obtain a magnesium-based cobalt precipitation agent; the mass ratio of the active magnesium oxide to the high-purity magnesium oxide is 1: (2-10), the modifier is quaternary ammonium salt organic powder, and the addition amount of the modifier is 0.02-1% of the total mass of the magnesium oxide. The magnesium-based cobalt precipitation agent prepared through the method is high in activity, has the advantages of being high in efficiency, low in price, low in unit consumption, environmentally friendly and the like in the aspect of nickel and cobalt precipitation through copper-cobalt ore and laterite-nickel ore wet smelting, and can greatly reduce the material cost in the nickel cobalt hydroxide production process.

The present invention discloses a sulfurized nano zero-valent iron material, its preparation method and application, including: a core-shell structure sulfurized nano zero-valent iron material and a preparation method, the inner core of the sulfurized nano zero-valent iron is zero-valent iron, and the outer shell is Fe9S 10 , calculated by the mass of the sulfurized nano zero-valent iron, the mass percentage of zero-valent iron is 70-80%, and the mass percentage of the iron sulfide is 20-30%; the preparation method includes: placing iron powder in an H2S gas atmosphere for calcination, after the calcination is completed, cooling to room temperature to obtain the sulfurized nano zero-valent iron material. This material can be used for in-situ remediation of chlorinated hydrocarbon organic pollutants in groundwater. Compared with the prior art, the prepared sulfurized nano zero-valent iron is less likely to be oxidized and can overcome the problem of rapid passivation of nano zero-valent iron during the remediation process.

The invention discloses alkali-activated porous carbon and a preparation method thereof, and relates to the field of new material preparation, and the preparation method comprises the following steps: uniformly mixing matrix carbon and a strong alkaline substance according to a mass ratio to obtain a mixed material, putting the mixed material into a crucible, and carrying out high-temperature calcination and cooling on the mixed material under the protection of an inert atmosphere; washing and filtering the mixed material subjected to high-temperature calcination for 3-6 times by using deionized water; after washing is completed, strong acid is used for soaking; and after soaking, filtering to obtain a mixed material filter cake, soaking the mixed material filter cake in ionized water, repeatedly washing, and drying until the pH value is neutral. The porous carbon material is prepared through alkali activation, the preparation steps are simple, expensive auxiliary equipment is not needed, the cost is low, preparation is safe, and the method has extremely high economic benefits and large-scale application prospects.

According to the invention, biomass rice hull ash and a sodium hydroxide solution are reacted to obtain water glass and carbon mud. And reacting the water glass with CO2 generated by calcining the limestone to produce a white carbon black product and a mixed waste liquid of sodium carbonate and sodium bicarbonate. Meanwhile, quick lime obtained by calcining limestone is digested and then reacts with sodium carbonate and sodium bicarbonate mixed waste liquid to generate a light calcium carbonate product and dilute sodium hydroxide waste liquid. And finally, the dilute sodium hydroxide waste liquid is concentrated and reused for water glass production, so that the waste liquid is recycled, and a complete process closed loop is formed. According to the process method disclosed by the invention, two leading-edge innovative processes, namely production of white carbon black by renewable resource biomass rice hull ash and production of white carbon black by a carbonization method, are organically combined and are coupled with production of light calcium carbonate by a limestone calcination process, so that the problem that a large amount of sodium sulfate-containing wastewater is discharged in a traditional process is solved; meanwhile, the carbon footprint of white carbon black and calcium carbonate products is greatly reduced.

The invention relates to the field of recycling of solid waste resources. The invention particularly relates to a method for synergistically recovering failed lithium iron phosphate black powder and a failed platinum-containing catalyst. The invention discloses a method for synergistically recovering failed lithium iron phosphate black powder and a failed platinum-containing catalyst. The method comprises the following steps: A, vacuum reduction smelting; b, oxidizing and dissolving; c, carbon thermal reduction; and D, ammonium salt precipitation and calcination. The method for recovering the platinum group metal does not need to add a trapping agent, has the advantages of being high in resource utilization rate, good in economic benefit and short in process, and effectively reduces the influence of solid waste resources on the environment.

The invention discloses a CoFe-coated NBC composite catalyst and a preparation method and application thereof.The preparation method includes the steps that collected wheat straw is pretreated, wheat straw biomass powder is obtained after pretreatment is finished, the wheat straw biomass powder, Co (NO3) 2.6 H2O and Fe (NO3) 3.9 H2O are dissolved in water, isopropanol and ammonia water are added, the mixture is stirred to be uniform, then the solution is transferred into a high-pressure autoclave, and the CoFe-coated NBC composite catalyst is prepared through a hydrothermal method; a hydrothermal reaction is carried out, and a CoFe-coated NBC precursor is obtained after the hydrothermal reaction is finished; the CoFe-coated NBC precursor is placed in a tube furnace in the N2 atmosphere to be calcined, after calcination is finished, the material is cooled to the room temperature, then the material is taken out and ground, and the CoFe-coated NBC composite catalyst is obtained, the prepared CoFe-coated NBC composite catalyst has the high specific surface area, rich pore structures and a large number of active sites, and activation of PMS and degradation of pollutants are facilitated.

The invention discloses a high-content steel slag-based functionalized nano-composite cementing material and a preparation method thereof, and belongs to the technical field of solid waste resource comprehensive utilization. The nano composite cementing material is prepared from the following raw materials in parts by mass: 50 to 65 parts of steel slag, 10 to 20 parts of fly ash, 10 to 25 parts of carbide slag, 8 to 15 parts of desulfurized gypsum, 0.3 to 1.0 part of nano silicon dioxide and 0.003 to 0.03 part of silane coupling agent. On the basis of a solid waste synergism theory and an internal alkali excitation effect, quaternary solid wastes such as steel slag and fly ash are optimized and compounded by adopting methods of mechanical-thermal activation, addition of modified nano silicon dioxide, synergistic gelling between solid wastes and the like; the paint is prepared through gradient grinding and a medium-temperature wet curing process. The preparation method is simple, high-temperature calcination is not needed, cement clinker and exogenous excitant do not need to be added, the obtained cementing material can replace part of cement to be applied to the fields of road bases, mine filling, low-carbon building material products and the like, resource utilization and high-value utilization of regional bulk industrial solid waste can be achieved, and carbon emission and production cost are effectively reduced.

The invention discloses a preparation method of an In2O3-Cu-Cu2O ternary heterojunction catalyst and a preparation method of the In2O3-Cu-Cu2O ternary heterojunction catalyst. The method comprises the following steps: at room temperature and normal pressure, firstly, dissolving indium chloride tetrahydrate in a mixed solvent of ethylenediamine-ethylene glycol (the volume ratio is 1: 20-1: 30) and dihydric alcohol amine to obtain a homogeneous solution; then transferring the solution to a hydrothermal kettle, adding deionized water and Cu2O powder with different volumes, and carrying out hydrothermal crystallization at 160-200 DEG C for 10-14 hours; and centrifuging the obtained precipitate, alternately washing with water and alcohol for 2-3 times, carrying out vacuum drying at 60 DEG C for 5-7 hours, heating to 600 + / -10 DEG C at a speed of 3-5 DEG C / min in an N2 atmosphere, calcining for 3 hours, and cooling along with a furnace to obtain a target product. By adjusting the adding amount of the deionized water, the mass proportion of the three phases of In2O3, Cu and Cu2O can be continuously adjusted and controlled, and controllable preparation from'rich copper 'to'rich cuprous oxide' and'stable ternary 'is achieved.

The invention discloses an A-site high-entropy solid oxide fuel cell cathode material as well as a preparation method and application thereof, and provides an A-site high-entropy solid oxide fuel cell cathode material Pr < 0.2 > M < 0.2 > La < 0.2 > Ba < 0.2 > Sr < 0.2 > Co < 0.8 > Fe < 0.2 > O < 3-delta > with a perovskite phase. The preparation method comprises the following steps: S1, weighing multi-element metal nitrates, and mixing to obtain a first mixed solution; s2, dissolving ethylenediamine tetraacetic acid in ammonia water to obtain a second mixed solution; mixing the first mixed solution, the second mixed solution and citric acid to form a mixed precursor solution; s3, carrying out second heating treatment on the mixed precursor solution, and adjusting the pH value to form a gel precursor; and S4, carrying out pre-sintering treatment, third heat treatment and calcination treatment on the gel precursor to obtain a high-grade powder precursor, and carrying out ball milling and sieving treatment to obtain the A-site high-entropy solid oxide fuel cell cathode material. The cathode material is high in stability and good in chemical compatibility with a barrier layer GDC, provides high-quality mass transfer channels and active sites for O2 / O- / O2-, and has good electrochemical performance at medium and low temperatures.

The invention relates to the technical field of ozone catalysts, in particular to an iron-manganese bimetallic ozone catalyst as well as a preparation method and application thereof. The iron-manganese bimetallic ozone catalyst comprises an activated carbon carrier and an iron-manganese bimetallic oxide loaded on the activated carbon carrier, in the preparation process of the iron-manganese double-metal ozone oxidizing agent, anhydrous nitrate of ferric iron and divalent manganese is adopted and dissolved in absolute ethyl alcohol, then activated carbon is added for excessive dipping, drying and under-pressure calcination, and the iron-manganese double-metal ozone oxidizing agent can be obtained. When the ferro-manganese bimetallic ozone oxidizing agent is combined with ozone to remove refractory COD (Chemical Oxygen Demand) in advanced sewage treatment, the ferro-manganese bimetallic ozone oxidizing agent shows relatively good catalytic activity, the removal rate of the refractory COD in the advanced sewage treatment can reach 57.9 percent within 60 minutes, and the ferro-manganese bimetallic ozone oxidizing agent has a wide application prospect.

The present invention discloses a CMO / SO / BVO photoanode and a preparation method and application thereof, and relates to the field of photoelectrochemical technology. The method comprises the following steps in sequence: electrodepositing a BiOI film on a substrate material, and then dripping a dimethyl sulfoxide solution containing vanadium acetylacetonate to obtain a BVO electrode; placing in a NaOH solution containing tetraethyl orthosilicate to obtain a SO / BVO electrode; placing in a CoMoO4 precursor solution, hydrothermally reacting, calcining, and obtaining a CMO / SO / BVO photoanode. The CMO / SO / BVO of the present invention exhibits superior photocurrent and charge separation efficiency compared to the CMO / BVO photoanode under 1.23V vs.RHE conditions. The present invention solves the problem of poor photoelectrochemical performance of the photoanode in the prior art.

The invention discloses a method for synthesizing GaOOH and beta-Ga2O3 materials with relatively good crystal quality and relatively uniform phase by taking gallium nitrate as a gallium source through a hydrothermal method and high-temperature calcination treatment, and characterizing the GaOOH and beta-Ga2O3 materials. The hydrothermal method adopted by the method has the advantages of simplicity in operation, low cost and the like, and has great advantages in the aspect of synthesizing gallium oxide. And compared with the traditional methods such as CVD (Chemical Vapor Deposition) and the like, which need to introduce noble metal elements as catalysts, easily cause reduction of material crystal quality and introduce unnecessary impurity elements, the method disclosed by the invention can be used for synthesizing the gallium oxide material with relatively good crystal quality and relatively uniform phase by combining a hydrothermal method and high-temperature calcination treatment. GaOOH powder is synthesized by adding an anionic surfactant sodium dodecyl benzene sulfonate (SDBS) solution with different concentrations, and then the GaOOH powder is calcined at the high temperature of 900 DEG C to obtain beta-Ga2O3 materials with different sizes.

The invention discloses a preparation method of a perovskite type high-temperature-resistant CO2 methanation catalyst, which comprises the following steps: firstly, preparing CaZrO3, then dissolving CaZrO3 powder, a nickel source, a soluble organic fuel and a certain amount of ethylene glycol in deionized water according to a molar ratio of 1: (0.2-0.8): (0.1-0.5), stirring to obtain a dispersion liquid, then putting carrier monoclinic ZrO2 powder in the dispersion liquid, and stirring to obtain the perovskite type high-temperature-resistant CO2 methanation catalyst. The preparation method comprises the following steps: uniformly mixing the raw materials, carrying out ultrasonic treatment for 5-12 hours, heating the obtained mixture at 300-550 DEG C until spontaneous combustion, carrying out high-temperature calcination at 800-900 DEG C for 1-2 hours after flame is extinguished, collecting the calcined product, and carrying out ball milling and granulation to obtain the NiO-CaZrO3 / ZrO2 catalyst with a certain mesh number. According to the preparation method of the catalyst, a solution combustion method is introduced in the preparation process, so that active components of the prepared catalyst are fully dispersed, and further high-temperature calcination is performed on the basis, so that the active components are stably anchored on the surface of the ZrO2 carrier, and the catalytic activity and the stability of the catalyst are improved.

The invention belongs to the field of material preparation and chemical engineering, and particularly relates to an N-doped modified MOFs (Metal-Organic Frameworks) derived core-shell nanoreactor as well as a preparation method and application thereof. The preparation method comprises the following steps: taking cobalt as a node metal, synthesizing an N-doped modified MOFs material with an organic ligand and a nitrogen source through a hydrothermal reaction, then coating the surface of the material with porous silicon dioxide, and preparing the N-doped modified MOFs derived core-shell nanoreactor through a two-step calcination method. The MOFs derived core-shell nanoreactor prepared by the invention has a large specific surface area, a rich pore structure and excellent catalytic activity and stability, and is high in catalytic activity, good in recycling stability and suitable for large-scale popularization and application when being used as a catalyst for alpha, beta-unsaturated aldehyde transfer hydrogenation.

The invention discloses a method for preparing a platinum-based alloy catalyst by using a plasma enhanced chemical vapor deposition low-temperature technology, relates to a preparation method of a platinum-based alloy catalyst, and aims to solve the technical problems that a carbon layer is not uniformly coated and metal particles of the catalyst are easy to agglomerate in a high-temperature calcination process in the existing platinum-based alloy catalyst prepared by carbon coating. The method comprises the following steps: 1, preparing Pt / C by a polyhydric alcohol reduction method; 2, pre-treating a Pt / C catalyst; 3, preparing M-Pt / C by a dipping evaporation method; 4, PECVD carbon shell coating is carried out; (5) alloying; and 6, removing a part of carbon shell to obtain the platinum-based alloy catalyst. When the Pt / C catalyst is used for preparing a membrane electrode of a proton exchange membrane fuel cell, the peak power density can reach 1.72-1.89 W / cm < 2 > under a hydrogen-air condition, which is improved by 20.3% and 32.2% compared with a membrane electrode of a commercial 20% Pt / C catalyst, and the Pt / C catalyst can be used in the field of proton exchange membrane fuel cells.

The invention relates to the field of building materials, and particularly discloses a coal gangue activation treatment method, prepared calcined coal gangue and application, the treatment method comprises the following steps: pretreatment: crushing and screening coal gangue to obtain coal gangue particles; the coal gangue particles are treated in a eutectic solvent, ultrasonic-assisted treatment is carried out for 2-3 h, pretreated coal gangue is obtained after water washing, the eutectic solvent comprises an HBA component and an HBD component, the HBA component is a mixture of choline chloride and an amide compound, and the HBD component is a mixture of a carboxylic acid mixture and polyhydric alcohol; calcining: calcining the pretreated coal gangue at 400-450 DEG C to obtain calcined coal gangue, the invention also discloses the calcined coal gangue prepared by the method, and the method has the characteristic of realizing coal gangue activation treatment under lower energy consumption.

The invention provides a titanium dioxide calcination control method, device and system, and relates to the technical field of automatic control, and the control method comprises the steps: obtaining the current batch production information of to-be-produced titanium dioxide and the corresponding preset batch quality information; inputting the current batch production information and the corresponding preset batch quality information into the calcination control model to obtain a final control strategy; and controlling the rotary kiln system according to the final control strategy. Through accurate data analysis and processing, the method can optimize the calcination process, so that the final quality of titanium dioxide is improved.

The invention relates to the technical field of crushers, and discloses a crusher for bulk materials after sodium sulfide calcination and a crushing process thereof.The crusher mainly comprises a dust removal mechanism, the dust removal mechanism is fixedly arranged on the right side of the bottom end of a working shell and used for cleaning dust in the working shell, and the dust removal mechanism comprises a dust storage box; a moving assembly is arranged in the dust storage box and used for cleaning the first filter screen and the second filter screen. When the moving assembly works, the moving piston drives the moving shaft to work, so that the moving part moves in the dust storage box, the second filter screen is effectively rubbed, the first filter screen is impacted, dust on the first filter screen and the second filter screen is fully cleaned, and the dust removal mechanism is effectively and timely self-cleaned; and resistance increase and suction reduction caused by dust accumulation are prevented, so that the dust removal efficiency is improved, the working shell does not need to be shut down to treat dust, and the working efficiency is improved.

The invention discloses a rare earth oxide modified high-entropy hard alloy and a preparation method thereof. A high-entropy hard phase (high-temperature calcination), a high-entropy binding phase and rare earth oxide are adopted, grinding, pressing and air pressure sintering at the temperature of 1450-1550 DEG C are conducted, and the high-entropy hard phase is prepared from tungsten carbide, titanium carbide, zirconium carbide, yttrium carbide, manganese carbide, chromium carbide and molybdenum carbide; the high-entropy binding phase comprises the following components: cobalt and a CoCrFeNi-series high-entropy alloy; and the component of the rare earth oxide is Y2O3 or Nd2O3. The prepared rare earth oxide modified high-entropy hard alloy has the advantages of high strength, high compactness, high hardness, high wear resistance and the like.

The invention discloses a method for preparing a catalyst by using red mud and titanium dioxide acidolysis waste residues as well as a product and application thereof. The method comprises the following steps: calcining red mud, adding titanium dioxide acidolysis waste residues and an auxiliary agent, uniformly stirring, adding a desulfurization waste liquid, uniformly stirring, carrying out a hydrothermal reaction, carrying out solid-liquid separation, and calcining to obtain the catalyst material. The preparation process is simple, and efficient resource utilization of the red mud and the titanium dioxide acidolysis waste residues can be achieved. The catalyst prepared through a hydrothermal reaction and a secondary calcination process realizes efficient removal of COD, ammonia nitrogen, total phosphorus and heavy metal pollutants in waste liquid through a photocatalytic function.

The invention discloses spherical silicon dioxide, a high-frequency high-speed copper-clad plate and a preparation method of the spherical silicon dioxide. The dielectric constant Dk of the spherical silicon dioxide is 3.5 F / m-4. 0F / m, the dielectric loss Df is 0.0001-0.005, the amorphous state proportion is larger than or equal to 99%, the spheroidization rate is larger than or equal to 99%, and the porosity is 0.1%-2%. During preparation, the hydrolysis degree is controlled till partial polycondensation is achieved, then under the oxygen introduction condition, pre-oxidation is conducted at the low temperature to remove alkyl, gradient calcination is conducted at the high temperature, local crystallization influence and defect influence caused by powder spontaneous combustion are prevented, meanwhile, viscous bodies in the microspheres are accurately controlled to flow to fill nanoscale pores, and the particle size is reduced. The spherical silicon dioxide with high purity, high spheroidization rate and low dielectric loss is obtained, the dielectric property of the high-frequency and high-speed copper-clad plate can be met, and the high thermal stability and high reliability of the high-frequency and high-speed copper-clad plate are improved.

A combustor component is disclosed comprising a combustion chamber, which comprises an oxidant inlet configured to receive a gas flow of an oxidant, a fuel inlet configured to receive a gas flow of a fuel into the combustion chamber, and a gases outlet configured to allow passage of a flow of exhaust gases from the combustion chamber. The combustor component is configured to facilitate separation of the gas flows of the oxidant and the fuel entering the combustion chamber prior to combustion of the fuel with the oxidant. A combustor assembly comprising a plurality of combustor components for staged combustion of a fuel with an oxidant, and related systems and methods for control and use of the combustor assembly, including in calcination processes, are also disclosed. A pyrolysis component, a pyrolysis assembly comprising a plurality of pyrolysis components, and related systems and methods using the pyrolysis component are also disclosed.

The invention relates to a glass bead, in particular to a high-refractive-index large-particle-size glass bead for road marking and a spheroidizing forming preparation method of the high-refractive-index large-particle-size glass bead. The material comprises the following components in parts by weight: 30 to 40 parts of titanium dioxide, 30 to 40 parts of silicon dioxide, 10 to 15 parts of barium nitrate, 10 to 15 parts of zirconium nitrate, 5 to 7 parts of zinc oxide, 3 to 5 parts of boric acid, 3 to 5 parts of calcium fluoride, 5 to 110 parts of Nb2O5 and 5 to 15 parts of a La2O3-ZrO2 compound. According to the invention, calcination is carried out at 900 DEG C for 12 hours, which is helpful for improving the thermal stability and mechanical strength of the glass beads, so that the glass beads can be used for a long time in a severe outdoor environment and are not easy to damage. And at the high temperature of 1300 DEG C and the spraying speed of 75 m / s, through precise intersection of the two nozzles in the combustion chamber, precise control over the melting and forming process of the glass beads is ensured, and therefore the high-quality high-refractive-index glass beads are obtained. The Nb2O5 and La2O3-ZrO2 compound is added, so that the refractive index of the glass beads is improved, and a relatively high yield is maintained.