851 results about "Biomass carbon" patented technology

The invention provides a silicon-carbon material and a preparation method thereof, a porous carbon substrate, a negative electrode material and a battery, and relates to the technical field of battery materials. The core point provided by the invention is controllable synthesis of the porous carbon substrate in the silicon-carbon material, a phenolic monomer and an aldehyde monomer are polymerized in the presence of a catalyst and a dispersing agent, meanwhile, a doping agent and a pre-carbonized biomass carbon precursor are added into a solution, the phenolic resin formed by polymerization is of a spherical structure, and the silicon-carbon composite material is obtained. Homogeneous doping of elements is completed in the synthesis process, the added biomass carbon precursor is of a blocky structure, matching of carbon-based particles of different structures can better exert respective beneficial effects and complement each other, the battery performance is comprehensively improved, and the battery has excellent cycle performance and conductivity.

The invention discloses a zinc-iodine battery positive electrode material based on corn straw shell derived porous carbon and a preparation method of the zinc-iodine battery positive electrode material. According to the material, corn straw shells serve as the sole carbon source, an indigenous nitrogen-doped biomass charcoal carrier with a hierarchical pore structure is prepared through pre-carbonization and KOH activation processes, and the material is characterized in that the specific surface area is larger than or equal to 1500 m < 2 > / g, and the micropore proportion is larger than 90%. The iodine is loaded on the carrier (the iodine content is greater than or equal to 45wt%) through a vacuum sublimation method to form the indigenous nitrogen-doped biomass charcoal / iodine composite material. According to the positive electrode material, through the synergistic effect of physical confinement and pyridine nitrogen chemical adsorption, the multi-iodide shuttle effect is effectively inhibited, so that the capacity retention rate of the zinc-iodine battery is greater than or equal to 93% after 40000 cycles under the current density of 2A g <-1 >, and the capacity retention rate is greater than 45% under the rate of 10A / g. The method has double benefits of agricultural waste resource utilization and high-performance energy storage device development.

The invention discloses a hard carbon material, a preparation method and application thereof and a sodium ion battery. The preparation method of the hard carbon material comprises the following steps: S1, mixing a biomass carbon source and mixed molten salt to obtain a mixture, and carrying out heat treatment on the mixture to obtain porous carbon; the mixed molten salt at least comprises two kinds of molten salt; s2, carrying out surface coating treatment on the porous carbon by adopting a coating agent to obtain a hard carbon precursor; and S3, carrying out carbonization treatment on the hard carbon precursor to obtain the hard carbon material. The obtained hard carbon material has proper pore size distribution, closed pore volume and specific surface area, has excellent electrochemical performance when being applied to the sodium ion battery, and can simultaneously take both high sodium storage capacity and excellent first effect into account. Moreover, the preparation method is low in cost, green and environment-friendly, and large-scale production is easy to realize.

The invention discloses a preparation method of a biomass hard carbon negative electrode material with low specific surface area, which comprises the following steps: S1, pretreating a biomass raw material to obtain a carbon precursor; s2, carbonizing the carbon precursor at low temperature; s3, crushing and processing low-temperature carbides; s4, preparing a pickling solution for pickling; s5, fine grinding after acid pickling; s6, fusion: fusing a product obtained after fine grinding with asphalt to form a carbon precursor; s7, performing air oxidation modification to obtain an oxidized carbon precursor; s8, carrying out high-temperature carbonization treatment on the oxidized carbon precursor; S9, scattering and dissociating; s10, screening is carried out; and preparing the sodium-ion battery hard carbon negative electrode material. The surface of the biomass carbon material is coated with asphalt, macropores or mesopores on the surface are filled and coated with the asphalt, and then a hard carbon structure is formed through air oxidation and high-temperature carbonization, so that the specific surface area and the first charge-discharge irreversible capacity of the material are reduced, and the coulombic efficiency and the specific capacity are improved.

The invention relates to the technical field of carbon sink calculation, in particular to a forestry carbon sink calculation model, a forestry carbon credit calculation method and a storage medium. The model comprises an overground biological carbon sink amount estimation module used for calculating overground biological carbon sink data of a target area, an underground soil carbon sink amount estimation module used for calculating soil carbon sink data of the target area, and a litter carbon reserve estimation module used for calculating litter carbon sink data of the target area. The combined loss calculation module is used for calculating carbon loss data; and the final carbon sink total quantity fusion module is used for calculating the carbon sink quantity according to the aboveground biological carbon sink data, the soil carbon sink data, the litter carbon sink data and the carbon loss data. A forestry carbon sink calculation model based on multiple dimensions is established through multiple types of carbon sink estimation modules, and the problem that the requirement for rapid authentication of the global carbon market cannot be met due to high manual dependency is solved; the problems of low calculation precision, high cost and the like caused by insufficient model dynamics, single model calculation dimension and the like are solved.

The invention provides a quick-charge and quick-discharge type lithium battery and a preparation method thereof, and belongs to the technical field of lithium battery preparation. The preparation process comprises the following steps: preparing a fluorinated carbon nanotube based on biomass carbon; preparing a positive electrode plate; preparing the dendritic mesoporous silicon dioxide nano particles; preparing a cerium oxide-loaded two-dimensional hierarchical porous composite material; preparing a negative electrode plate; and assembling the lithium battery. According to the preparation method, the eutectic and the carbon fluoride nanotubes are added in the preparation of the positive electrode plate, and the cerium oxide-loaded two-dimensional hierarchical porous composite material and the carbon fluoride nanotubes are added in the preparation of the negative electrode plate, so that the prepared positive electrode plate and the prepared negative electrode plate have relatively high conductivity; and moreover, the ion transmission efficiency is improved, the rapid ion transmission is beneficial to reducing the polarization phenomenon of the battery, improving the charging and discharging rate and the power performance of the battery, enhancing the structural stability of the electrode, improving the performance and the safety of the battery, and being more beneficial to rapid charging and rapid discharging.

The invention discloses an SBS modifier and a preparation method and application thereof, an asphalt coating material composition and a preparation method thereof, and a waterproof coiled material. The preparation method of the SBS modifier comprises the following steps: dissolving SBS in a first solvent to obtain an SBS solution; the method comprises the following steps: adding a sulfydryl compound into an SBS solution, and carrying out solution graft polymerization at 50-90 DEG C to obtain graft modified SBS which is grafted with alkyl containing any one of hydroxyl and carboxyl through sulfydryl, or grafted with sulfydryl and grafted with hydroxyl substituted or unsubstituted alkyl through sulfydryl; adding the biomass carbon aerogel and the graft modified SBS into a second solvent according to a mass ratio of 1: (0.5-1.5) to obtain a first mixed solution; adding concentrated sulfuric acid and sodium hypophosphite into the first mixed solution, and reacting at the temperature of 120-130 DEG C to obtain the SBS modifier. According to the preparation method of the SBS modifier, the polarity of the SBS is changed through sulfydryl grafting of the SBS, namely the polarity of the SBS is closer to that of asphalt; and the grafted modified SBS reacts with the biomass carbon aerogel to form a macromolecular compound, so that the performance degradation in the aging process of the coiled material is prevented.

The present invention discloses a method for preparing a flexible polyaniline / biomass carbon electromagnetic shielding material. After high-temperature carbonization of a fiber fabric, a structurally ordered biomass carbon matrix is ​​obtained. Under the synergistic action of an oxidant and a dopant, aniline monomer is in situ oxidatively polymerized to generate polyaniline that is adsorbed on the surface of the biomass carbon matrix, thereby obtaining the polyaniline / biomass carbon electromagnetic shielding material. The electromagnetic shielding material of the present invention has an intricate and ordered two-dimensional network structure, which helps to establish a conductive network and exhibits excellent electromagnetic shielding effectiveness. In addition, the unique flexibility can fully meet the special requirements of flexible wearable electronic devices, electromagnetic shielding clothing fillers, etc. for the performance of electromagnetic shielding materials. The synthesis process of this method is safe and environmentally friendly, and the required consumables are cheap and abundant, making it suitable for commercialization and industrialization requirements.

The invention discloses a preparation method for preparing a biomass porous carbon material through high-temperature carbonization of molten salt and application of the biomass porous carbon material, and belongs to the technical field of synthesis of inorganic functional materials. According to the technical scheme, the method is characterized in that sodium chloride and potassium chloride are mixed into mixed salt according to different proportions, then the mixed salt is mixed with enteromorpha biomass according to a certain proportion, the mixture is placed in a porcelain crucible, the mixed salt is added for covering, the porcelain crucible is placed in a muffle furnace to be heated and carbonized, and the porous biomass carbon material is obtained after water washing and drying. The enteromorpha biomass is selected as the raw material, the operation is simple and controllable, the cost is low, batch production can be realized, and the prepared novel porous biomass carbon material has a complex porous structure, a large specific surface area, a very good catalytic effect, strong adsorption capacity and good conductivity, and shows excellent performance when being applied to the field of advanced oxidation.

The invention relates to a structural design, synthesis and application of a biomass carbon dot modified poly L-cysteine-S-S-carboxylic acid amphiphilic polypeptide. The invention provides a structural design, synthesis and application of poly (L-cysteine-S-S-carboxylic acid) amphiphilic polypeptide (P-L-cys) modified by biomass carbon dots (CDs). Comprising synthesis of P-L-cys which contains hydrophobic groups, provides hydrophilic and functionalized carboxyl and provides reduction response by disulfide bonds, synthesis of CDs and CDs modified P-L-cys (CDs (at) P-L-cys), and the macroscopic performance change of the polypeptide is explored from regulation factors of a polypeptide secondary structure and a self-assembly nanostructure assembly mechanism. The P-L-cys and the CDs (at) P-L-cys prepared by the invention have functionalization, fluorescence imaging and dual-response drug release and have particle sizes suitable for drug delivery and enrichment, and the CDs also provide a photo-thermal and photodynamic synergistic treatment effect and have good application prospects in the fields of drug delivery, cancer resistance and the like.

The invention belongs to the field of battery materials, and discloses a ferric sodium pyrophosphate material as well as a preparation method and application thereof. The preparation method of the ferric sodium pyrophosphate comprises the following steps: step 1, mixing a phosphorus source, an iron source, a sodium source, a biomass carbon source and an alcohol additive, and uniformly stirring to obtain a mixed material A; step 2, carrying out hydrothermal reaction on the mixed material A, and then centrifuging and drying to obtain an intermediate product B; and 3, roasting the intermediate product C in a protective atmosphere to obtain the carbon-coated ferric sodium pyrophosphate. A three-dimensional conductive network is formed after the biomass carbon source and the NFPP are compounded, the interface resistance is reduced, the charge transfer efficiency is improved, and after the biomass carbon source is carbonized, biomass carbon with mechanical supporting and buffering effects can relieve volume expansion of the NFPP in the charge-discharge or reaction process and inhibit material pulverization, so that the cycling stability is improved.

The invention discloses a method for preparing methanol from carbon dioxide by coupling biomass direct combustion with wind, light, green and hydrogen. The method comprises the following steps: feeding biomass into a biomass boiler through a screw feeder and a trestle for direct combustion to obtain flue gas with high carbon dioxide content; the flue gas is treated to generate carbon dioxide gas with the pressure ranging from 1.4 MPaG to 1.6 MPaG; the method comprises the following steps: mixing carbon dioxide gas and hydrogen according to a molar ratio of about 1: 3, and compressing the mixture into 9.0 MPaG synthesis gas through a synthesis gas compressor; the synthesis gas flows to a gas-gas heat exchanger for heat exchange and temperature rise, and then is introduced into a methanol synthesis tower to form a material; the materials are subjected to heat exchange and cooling through a gas-gas heat exchanger and then flow to a high-pressure flash tank to be separated to form first gas and first liquid; the first liquid flows to a low-pressure flash tank to be separated to form second gas and second liquid conveyed to a crude methanol rectifying tower; separating and purifying the crude methanol in a rectifying tower to form methanol, fusel and overhead gas flowing to the biomass boiler; the utilization rate of the biomass carbon is improved.

The invention belongs to the field of coupling power generation, and provides a coupling pulverized coal fired boiler low-load stable combustion and blending combustion system and a control method. According to the system, cold air from a boiler primary air fan is divided into two paths, one path is directly conveyed to a cold air main pipe, and the other path is conveyed to a hot air main pipe after being preheated by a preheater; the coal mill correspondingly takes cold air and hot air from the cold air mother pipe and the hot air mother pipe, the cold air and the hot air are mixed to a set temperature and then enter the coal mill for pulverized coal drying, and the dried pulverized coal is conveyed to the pulverized coal boiler to enter a hearth for combustion; the biomass gasification furnace takes cold air and hot air from the cold air mother pipe and the hot air mother pipe correspondingly, and the cold air and the hot air enter the biomass gasification furnace after being mixed to a set temperature; the biomass material is gasified in the biomass gasification furnace to generate carbonized products, namely biomass charcoal and biogas; the carbonized product biomass charcoal is conveyed to a coal mill to be milled together with the raw coal, and then is blown to a pulverized coal boiler to enter a hearth for combustion; biogas directly enters the pulverized coal boiler and enters a hearth for combustion.

The utility model relates to the technical field of carbon source feeding, and discloses a biomass carbon source feeding device in a low-temperature environment, which comprises a biological tank body and a feed port arranged at the top of the biological tank body, and crushing equipment and auxiliary equipment are arranged in the feed port. And the auxiliary equipment comprises a fixed disc, a sleeve, a baffle, a fixed rod, a sliding groove, a sliding frame, a reset spring, a sleeve rod, an extrusion plate, a fixed plate and a spiral sliding groove. According to the biomass carbon source adding device in the low-temperature environment, through the arranged crushing equipment and the auxiliary equipment, after a carbon source is preliminarily crushed by the crushing equipment, the carbon source is continuously accumulated in the sliding frame along with the carbon source, and the carbon source is discharged; the sliding frame moves downwards under the action of gravity, the sliding frame drives the sleeve rod to move downwards together, the fixed rod slides in the spiral sliding groove in the inner side of the sleeve rod, the sleeve rod drives the extrusion plate to rotate, the extrusion plate is matched with the fixed plate to extrude the carbon source, secondary crushing is achieved, and the situation that the organic matter carbon source is caked due to low temperature, and dissolution of the carbon source is affected is avoided.

The invention belongs to the technical field of microorganisms, and particularly relates to a synthetic flora for promoting growth of macadamia nuts as well as a construction method and application of the synthetic flora. The invention relates to a synthetic flora. The synthetic flora is prepared by mixing bacillus subtilis X17, pseudomonas fluorescens X62 and trichoderma harzianum Z27 in equal volume. According to the invention, strains are separated and screened from healthy rhizosphere soil, and the strains which grow well are subjected to a pairwise confrontation test, so that the strains which have no antagonism in pairwise are screened out. According to molecular biology identification, three strains with the growth promoting effect, namely bacillus subtilis X17, pseudomonas fluorescens X62 and trichoderma harzianum Z27, are screened, then the three strains are constructed into a synthetic flora, pot experiment verification shows that the constructed synthetic flora can promote growth of macadimia nut plants and accumulation of biomass, meanwhile, soil can be activated, the yield of macadimia nut plants is increased, and the yield of macadimia nut plants is increased. The soil nutrient content, the enzyme activity and the microbial biomass carbon, nitrogen and phosphorus content are improved, and support can be provided for planting and economic development of macadamia nuts.

The invention discloses a sulfur-doped composite hard carbon material as well as a preparation method and application thereof. Sulfonated resin is used as a carbon source and a sulfur source, and non-metal sulfur atoms with the atomic radius larger than that of carbon are doped in situ, so that the carbon layer spacing of hard carbon is increased, and the rate capability of the hard carbon is improved; and the sulfonated resin is subjected to surface pre-coating modification by using a cheap biomass carbon source, so that the specific surface area and defect sites of hard carbon are reduced, the number of closed pores is increased, and the specific capacity and the first coulombic efficiency of the hard carbon are improved.

The invention relates to the technical field of electro-catalysis, in particular to a modified iron monatomic catalyst based on biomass carbon as well as a preparation method and application of the modified iron monatomic catalyst. The preparation method comprises the following steps: mixing and stirring chitosan, an acetic acid solution, thiourea and ferric chloride, adjusting the pH value to 7.5-8.5, and freeze-drying to obtain an aerogel precursor; pre-carbonizing the aerogel precursor to obtain a pre-carbonized product; mixing the pre-carbonized product with an alkali reagent, and calcining to obtain a metal nanoparticle doped monatomic catalyst; and carrying out ultrasonic treatment on the metal nanoparticle doped monatomic catalyst by using a mixed acid solution, washing to be neutral, and drying to obtain the modified iron monatomic catalyst. By adopting the modified iron monatomic catalyst provided by the invention, non-polar CO2 molecules and NO3 <-> are efficiently converted into urea under mild conditions, the yield of the urea is up to 2978.6 mu g h <-1 > mgcat <-1 >, and the maximum Faraday efficiency is up to 30.4%.

The invention discloses a method for preparing a silicon-carbon composite negative electrode material through an electrostatic self-assembly technology, and belongs to the technical field of lithium ion battery negative electrode materials. According to the invention, lignin is used as a biomass carbon source and lauryl sodium sulfate (SDS) and poly (diallyldimethylammonium chloride) (PDDA) are used as activators through a simple electrostatic self-assembly technology; a proper amount of nano silicon and PDDA are subjected to in-situ adsorption, and lignin and SDS are subjected to in-situ adsorption; a self-assembly process is carried out through the positive and negative charge attraction effect among colloidal particles, so that effective compounding of the nano silicon particles and the biomass carbon is realized; and performing vacuum drying, and performing one-stage sintering in a tubular furnace to obtain the silicon-carbon composite negative electrode material. Based on the problems of non-uniform particle size, easy agglomeration and great abrasion of a silicon-carbon composite material in a traditional mechanical synthesis technology, the invention improves the compounding efficiency of the silicon-carbon material and improves the problems of volume expansion of a silicon negative electrode, slow migration rate of lithium ions, poor cycle performance and the like.

The invention relates to the technical field of lithium ion battery negative electrode materials, in particular to a preparation process of a silicon-carbon coated negative electrode material which takes bamboo wood as a biomass carbon source and is combined with nano silicon and a dual carbon coating technology, and the preparation process comprises the following steps: step a, sol loading, step b, vacuum impregnation, step c, interface bonding, step d, inner layer coating and step e, outer layer coating. A silicon-carbon interface in-situ bonding technology and a double-layer carbon coating technology are utilized, a sol-gel method is adopted to construct a Si-O-C chemical bond on the surface of bamboo-based carbon, molecular-level anchoring of silicon particles (20-50 nm) on the surface of a carbon skeleton is achieved, the interface separation problem of traditional mechanical mixing is solved, meanwhile, inner-layer amorphous carbon (2-3 nm) is generated in cooperation with bamboo wood pyrolysis gas, and the surface of the bamboo-based carbon is separated. Then bamboo vinegar is carbonized to form an outer graphitized carbon shell (5-8nm), and the double carbon layers cooperate to inhibit volume expansion of silicon, so that the problem of volume expansion of silicon is solved, and the first charge-discharge efficiency of the battery and the capacity retention rate after circulation are effectively improved.

The invention discloses a lycium ruthenicum biomass carbon dot as well as a preparation method and application thereof. The novel lycium ruthenicum carbon dots are prepared by taking lycium ruthenicum as a raw material and adopting a one-step hydrothermal method, and the novel lycium ruthenicum carbon dots are used for detecting residual herbicides in soil without being interfered by other substances. The method for detecting the herbicide residues in the soil by adopting the prepared novel carbon dots is superior to a large instrument, the detection method has the advantages of simplicity in operation, low cost, high sensitivity and the like, the source of the lycium ruthenicum is wide, and the preparation process is green and environment-friendly. Therefore, the prepared carbon dots provide a new method for detection of the fine phosphinate ammonium salt, and a thought and a method are provided for specific application in agricultural production.

The invention relates to the technical field of battery negative electrode materials, and discloses a biomass derived carbon material as well as a preparation method and application thereof. The surface of the biomass derived carbon material is loaded with nano-clusters or nano-particles of a metal simple substance or a metal compound. The preparation method comprises the following steps: mixing a biomass precursor and a metal salt, and carrying out one-step pyrolysis to obtain the biomass derived carbon material. The biomass derived carbon material can be used as an alkali metal ion battery negative electrode material. Through the unique technical means of loading the metal simple substance / metal compound with the nano-cluster or nano-particle form on the surface of the biomass charcoal, the fast charging performance of the negative electrode material is practically and effectively improved. The battery prepared from the negative electrode material shows excellent comprehensive performance, and has excellent key performance indexes such as charge-discharge efficiency, cycle stability and energy density.

The invention discloses a biomass-based hard carbon composite material quantitatively prepared based on a hard carbon pore volume and a method thereof, a negative electrode material and a battery. The method provided by the invention comprises the following steps: firstly, uniformly dispersing a pore-forming agent in biomass powder, pre-carbonizing, and washing to obtain a porous carbon matrix; according to the steps, pore forming is completed while pre-carbonization is completed, the porous carbon matrix with a certain pore volume is prepared, the dosage of the soft carbon precursor is designed based on the total pore volume in the subsequent steps, quantification and rationalization of the dosage of the soft carbon precursor can be achieved, the obtained product is good in performance consistency, and industrial production can be achieved. And the problem that subsequent soft carbon raw materials cannot be scientifically matched due to diversity of raw materials of biomass with different sources can also be avoided. Besides, by utilizing the chemical cross-linking reaction of asphalt and biomass carbon, not only is the carbon residue rate improved, but also a unique structure rich in closed pores and ultra-micropores is constructed, and the problems of low initial coulombic efficiency and insufficient platform capacity of traditional hard carbon are effectively solved.

The invention provides a composite porous carbon material and a preparation method thereof, and a silicon-carbon negative electrode material and a preparation method thereof, and belongs to the technical field of silicon-carbon negative electrode materials. Liquid resin, biomass carbon and carbon nanotubes are fully mixed in an organic solvent, a high-strength spherical porous carbon material is obtained through processes of spray drying, carbonization, activation and the like, and finally the silicon-carbon negative electrode material is obtained through silicon deposition and carbon coating. The resin coating, the carbon nanotubes and the spherical structure cooperate with one another, so that the strength of the porous carbon structure is greatly enhanced; the high-strength porous carbon base material can effectively relieve the problem of pore fracture caused by silicon expansion and high compaction of the pole piece, improve the first efficiency and slow down long-cycle capacity attenuation.

The invention discloses a preparation method and application of a biomass-based hard carbon negative electrode material based on a microwave solvothermal method, and the preparation method comprises the following steps: fully mixing a pretreated biomass carbon source with a sulfuric acid solution, transferring into a microwave hydrothermal reaction kettle, and carrying out microwave hydrothermal treatment to obtain a hydrothermal reaction product; carrying out solid-liquid separation on a hydrothermal reaction product, collecting filter residues, cleaning until filtrate is neutral, and drying to obtain a hard carbon precursor; performing high-temperature carbonization on the hard carbon precursor under the protection of an inert atmosphere to obtain the biomass-based hard carbon negative electrode material; according to the method, a mixed system of the biomass carbon source and sulfuric acid is pre-carbonized in a microwave solvothermal mode, uniform deliming of the biomass carbon source is achieved under the controllable acidity condition, and the uniformity of the biomass carbon source is improved; the pre-carbonized biomass material is subjected to high-temperature carbonization in an inert atmosphere, so that a hard carbon material with a moderate extension interlayer spacing can be obtained, and the synergistic improvement of high-rate charge-discharge performance and long cycle stability is realized.

A self-supporting cotton biomass carbon loaded red-phosphorus sodium ion battery negative electrode material and a preparation method therefor. The self-supporting cotton biomass carbon loaded red-phosphorus sodium ion battery negative electrode material comprises a carbon matrix and nanoscale red phosphorus loaded in pores of the carbon matrix; the carbon matrix is obtained by taking cotton as a biomass carbon precursor and carrying out high-temperature carbonization and etching treatment in argon / ammonia mixed gas. The preparation method comprises: placing cotton in an argon / ammonia mixed gas atmosphere for high-temperature treatment; cooling in an inert gas atmosphere to obtain a carbon matrix; and mixing the carbon matrix with red phosphorus, and carrying out packaging, calcining, cooling, washing and drying to obtain the self-supporting cotton biomass carbon loaded red-phosphorus sodium ion battery negative electrode material. The self-supporting cotton biomass carbon loaded red-phosphorus sodium ion battery negative electrode material has the advantages of high reversible specific capacity and excellent cycling stability.

The invention relates to the technical field of steel sintering processes, in particular to a biomass gasification coupling system for a steel sintering process, which comprises a biomass gasification system, a circular cooler waste heat utilization system and a waste heat power generation system, the biomass gasification system comprises a biomass drying system, a raw material conveying belt system, a biomass gasification furnace, a biomass gas heat insulation combustion chamber, a sintered coke powder preparation system and a biomass gas purification system, and the biomass drying system is used for drying biomass raw materials; and the dried biomass raw materials are conveyed to the biomass gasification furnace through the raw material conveying belt system. According to the coupling system for biomass gasification for the steel sintering process and the control method, biomass serves as zero-carbon energy, and biomass charcoal obtained after biomass gasification can replace part of solid fuel to achieve the carbon reduction effect. Meanwhile, the biomass gasified gas can replace a part of coal gas, and the carbon reduction effect can also be achieved.

The invention relates to the technical field of heavy metal contaminated soil remediation, in particular to a plant-microorganism-passivator synergistic remediation method for a heavy metal contaminated farmland, which comprises the following steps: step 1, constructing a soil digital twinborn model; step 2, intelligent decision making and verification of a collaborative restoration scheme; 3, soil pretreatment before remediation; step 4, hierarchical collaborative restoration and dynamic regulation and control; 5, performing long-term verification on the repair effect and performing model iteration; physical heat treatment is used as strengthening pretreatment, the occurrence form of heavy metal is changed through high temperature, biomass charcoal is generated in situ, passivation immobilization-microbial strengthening-plant extraction three-stage collaborative operation is carried out according to the time sequence, pollutants are rapidly locked through a passivating agent, rhizosphere immobilization is strengthened through functional microorganisms, plant growth is promoted, and the quality of plants is improved. And the hyperaccumulator finally removes the heavy metals from the soil, so that the unification of short-term control and long-term reduction is realized.

The invention provides a phosphorus-based porous carbon composite material, a preparation method thereof, a negative electrode and a lithium ion battery, and the preparation method comprises the following steps: S1, carrying out etching treatment on a biomass carbon source by adopting an acidic etching agent to obtain a precursor; s2, performing first heat treatment on the precursor to obtain a porous carbon material; the temperature of the first heat treatment is 600-1000 DEG C; s3, carrying out second heat treatment on the porous carbon material and red phosphorus to obtain a phosphorus-based porous carbon composite material; the temperature of the second heat treatment is 460-800 DEG C. According to the preparation method of the phosphorus-based porous carbon composite material provided by the invention, the porous carbon material with a specific pore structure is prepared by taking biomass as a carbon source, and red phosphorus is effectively anchored on the obtained porous carbon material; the lithium ion battery subsequently prepared from the phosphorus-based porous carbon composite material disclosed by the invention has relatively high specific discharge capacity and excellent long-term rapid charging stability.

The invention relates to the technical field of silicon-carbon negative electrodes, in particular to a silicon-carbon negative electrode precursor material, a silicon-carbon negative electrode material and a preparation method of the silicon-carbon negative electrode precursor material. Preparing a porous carbon material; performing vapor deposition on a silicon source on the porous carbon material to obtain a silicon / porous carbon material; putting boron oxide and the silicon / porous carbon material into a ball milling tank according to a mass ratio of (1-5): (80-200), and carrying out ball milling for 1-3 hours to obtain a silicon-carbon negative electrode precursor material; according to the silicon-carbon negative electrode precursor material, the silicon-carbon negative electrode material and the preparation method of the silicon-carbon negative electrode material, the porous carbon material is prepared from the biomass carbon material, the silicon element is deposited on the porous carbon material, the boron element is doped on the porous carbon material, and the obtained silicon-carbon negative electrode material has excellent capacity and capacity retention rate and high electrochemical stability.

The invention relates to the technical field of carbon reserve estimation, and discloses a mangrove forest biomass carbon reserve estimation method based on a different-speed growth inversion model, and the method comprises the following steps: 1, setting a quadrat region; 2, collecting aerial images, kandelia candel morphological data, kandelia candel destructive data and soil profile organic carbon density data; step 3, establishing an allotropical growth inversion model; processing the kandelia candel destructive sampling parameters to obtain a kandelia candel carbon conversion coefficient; performing image processing and visual interpretation on the aerial image of the research area to obtain the crown breadth coverage total area and the mud flat coverage area of the kandelia candel in the research area; 4, the overall kandelia candel carbon reserve is obtained by combining the kandelia candel morphological data, the total crown breadth coverage area of the kandelia candel, the different-speed growth inversion model and the kandelia candel carbon conversion coefficient; and combining the organic carbon density data of the soil profile and the mud flat coverage area to obtain the overall soil carbon reserve. Meanwhile, the invention further provides a mangrove forest biomass carbon reserve estimation system based on the different-speed growth inversion model.