168 results about "Nitrification inhibitors" patented technology

The invention provides a nitrification inhibitor and a preparation method thereof as well as stable urea and a preparation method thereof, and relates to the technical field of fertilizers. The nitrification inhibitor provided by the invention is prepared from the following components in percentage by mass: 20 to 45 percent of 3, 4-dimethyl pyrazole phosphate (DMPP), 30 to 70 percent of amino acid and the balance of auxiliaries, the auxiliary agent is one or more of polysaccharide, polyvinylpyrrolidone, poloxamer and carbomer. According to the invention, the DMPP and the amino acid are compounded, the amino acid is used as a stabilizer of the DMPP, so that the stability of the DMPP can be remarkably improved, and meanwhile, the polymer additive is used as an adhesive, so that the stability of the DMPP can be further improved. The nitrification inhibitor provided by the invention has excellent stability; the stable urea can be obtained by adopting an endogenous adding mode and adding the stable urea into the urea with relatively low loss, and the stable urea has multiple effects of improving the urea utilization rate, improving the crop quality, improving the soil biological environment, improving the soil fertility and the like.

The invention discloses a biochar-based slow-release fertilizer and a preparation method thereof, and relates to the technical field of fertilizer production, the biochar-based slow-release fertilizer comprises a core, a carrier layer, a biological layer and a protective layer, the core is composed of macroelements, microelements and a nitrification inhibitor; the carrier layer comprises graphene quantum dot modified charcoal, chitosan, glycerol and cyclodextrin grafted starch; the biological layer is prepared from magnetic Fe3O4 and humic acid nanoparticles, alginic acid oligosaccharide and diatomite; the protective layer comprises a polylactic acid-polycaprolactone block copolymer, acetone, calcium lignosulphonate, a dynamic covalent cross-linking agent gelatin, nano cellulose and an anti-blocking agent. Therefore, by adopting the polylactic acid-polycaprolactone (PLA-PCL)-based segmented copolymer and the dynamic covalent network cross-linking agent, the self-repairing property is endowed. The slow-release fertilizer provided by the invention realizes precise regulation and control of the fertilizer efficiency release rate through a multi-level synergistic effect, has the functions of soil remediation and stress resistance, and significantly improves the utilization efficiency of the fertilizer and the crop adaptability.

The invention relates to a particulate composition comprising, or substantially consisting of, urea, an inhibitor, preferably a urease inhibitor and / or a nitrification inhibitor, and an additive, wherein the additive comprises components (i) and (ii): (i) a carboxylic acid or an anhydride, salt, or derivative thereof; preferably a carboxylic acid salt or a carboxylic acid derivative, more preferably a carboxylic acid salt; and (ii) a polar polymer; preferably a water-soluble polar polymer. The invention further relates to a process for preparing the particulate composition, an additive for a particulate composition, and the use of the particulate composition as a fertilizer.

The invention provides a fertilizer synergist for reducing nutrient loss and inhibiting nitrification and application of the fertilizer synergist. The fertilizer synergist is prepared from the following components in percentage by mass: 95 to 98 percent of carboxyl cross-linked modified montmorillonite, 0.05 to 0.1 percent of mannan oligosaccharide, 0.1 to 0.5 percent of mannan, 1 to 3 percent of polyaspartate and 0.5 to 2 percent of a nitrification inhibiting aid. According to the fertilizer synergist capable of reducing nutrient loss and inhibiting nitrification and the application of the fertilizer synergist, the fertilizer synergist serves as a plant nutrient loss control synergist and a nitrification inhibitor and can activate a crop stress resistance signal source, promote and induce synthesis of endogenous auxin in plants, root and growth, activate phosphorus and dissolve potassium, reduce nitrogen loss and improve the yield of the plants. The fertilizer utilization rate is improved.

The invention relates to a particulate composition comprising, or substantially consisting of, urea, an inhibitor, preferably a urease inhibitor and / or a nitrification inhibitor, and an additive, wherein the additive comprises components (i), (ii), and optionally (iii): (i) one or more polyhydric alcohols; preferably one or more carbohydrates, preferably selected from monosaccharides, disaccharides, and oligosaccharides; (ii) a first polymer, preferably an amine-containing polymer; more preferably a polyvinylamine or a polyalkyleneimine; and (ii) optionally, a second polymer, preferably a polar polymer; more preferably a water-soluble polar polymer. The invention further relates to a process for producing the particulate composition, an additive for a particulate composition, and the use of the particulate composition as a fertilizer.

The invention provides application of 3-methyl-2-oxazolidinone as a nitrification inhibitor and a nitrification inhibition method, and relates to the technical field of soil treatment. Specifically, the invention relates to application of 3-methyl-2-oxazolidinone as a nitrification inhibitor in soil treatment and / or sewage treatment and inhibition of nitrosation activity of ammonia oxidizing bacteria. The method for inhibiting nitrification comprises the step of treating soil or water containing ammonium nitrogen and ammonia oxidizing bacteria by using 3-methyl-2-oxazolidinone. The concentration of the 3-methyl-2-oxazolidinone is not less than 0.01% w / v by taking the volume of the soil or the water body as 100%. The nitrification inhibition activity of the 3-methyl-2-oxazolidinone is found, so that the variety selection of nitrification inhibitors is enriched.

The invention discloses a saline-alkali soil rhizosphere microdomain soil improvement and fertilization fertilizer and a preparation method thereof, and belongs to the technical field of saline-alkali soil treatment. The fertilizer is composed of a microbial inner core, a slow release fertilizer secondary outer layer and a soil conditioner outer layer, the microbial inner core is composed of a compound microbial agent (composed of nitrogen-fixing bacteria, phosphate solubilizing bacteria and live potassium bacteria), biochar and a polymer organic membrane material, the slow release fertilizer secondary outer layer is composed of a chemical fertilizer, an inhibitor (a nitrification inhibitor and / or a urease inhibitor) and amino acid, and the soil conditioner outer layer is composed of a soil conditioner outer layer. The soil conditioner outer layer is composed of a soil conditioner special for saline-alkali soil improvement. The method has the beneficial effects that (1) the pH value of the soil is adjusted and the soil structure is improved, so that the microbial flora can better adapt to the soil environment of the saline-alkali soil; and (2) the biochar and the isolating membrane effectively protect the activity of microorganisms, and the microorganisms are released when the pH value and the salt-based ions of the soil around the rhizosphere reach a lower level, so that the saline-alkaline obstacle of the growth of the microorganisms is overcome.

The invention relates to a soil conditioner based on nitrification inhibition and a soil acid control method, and belongs to the technical field of soil conditioning, the soil conditioner comprises the following components by weight: 20-22 parts of humic acid, 32-36 parts of syringic acid-linoleic acid modified porous hydroxyapatite, 4-5 parts of complete nitrifying bacteria, 2-5 parts of syringic acid, and 2.8-4.2 parts of sodium carboxymethyl cellulose. According to the technical scheme, syringic acid and linoleic acid serve as nitrification inhibitors, the nitrification inhibition rate can be effectively increased, ecological niches of ammonia-oxidizing archaea and ammonia-oxidizing bacteria can be reduced through competitive occupation due to addition of complete nitrifying bacteria, the nitrification rate of the ammonia-oxidizing archaea and the ammonia-oxidizing bacteria is inhibited, and N2O emission is reduced. Humic acid and hydroxyapatite can be used as pH buffer substances to regulate and control soil acidity, aluminum toxicity can be relieved, and physical and chemical properties of soil can be improved; meanwhile, the complete nitrifying bacteria can be ensured to have relatively high activity under the condition that the pH is 5.5-6.5.

An inhibited aqueous fertilizer composition and methods of use thereof.

The invention discloses a water-retention synergistic coated slow-release fertilizer and a preparation method thereof, and relates to the technical field of water-retention slow-release fertilizers. The coated slow-release fertilizer sequentially comprises a fertilizer core, an inhibitor layer, a slow-release coating layer, a bonding layer and a water-retaining slow-release layer from inside to outside. Wherein the inhibitor layer is composed of a urease / nitrification inhibitor, the slow-release coating layer is composed of organic polymer resin, the bonding layer is composed of an ethyl cellulose binder, and the water-retaining slow-release layer is composed of a modified water-retaining agent. The coated slow-release fertilizer prepared by the invention has good water retention performance, controlled release performance and salt resistance, is suitable for high-salt soil, and can obviously improve the nitrogen fertilizer utilization rate. Meanwhile, the combination of polyglutamic acid and sulfonic acid groups is used for modifying polyacrylic acid to prepare the modified water-retaining agent, so that a synergistic effect on improving the salt resistance of the coated slow-release fertilizer is achieved, the fertilizer efficiency can be improved, the loss is reduced, the soil environment is improved, and the water-retaining capacity of soil and the utilization rate of the fertilizer are improved.

The invention discloses a straw returning water-nitrogen synergistic method based on a biochemical inhibitor, and belongs to the technical field of agricultural resources and environments. The straw returning water-nitrogen synergistic method based on the biochemical inhibitor comprises the following steps that in an annona squamosa-soybean interplanting system, a water-nitrogen synergistic agent is added into an annona squamosa-soybean interplanting system; the nitrogen release and straw decomposition process is regulated and controlled through the synergistic effect of the biochemical inhibitor and water management, short-term crop requirements and long-term soil fertilization are both considered, and the water and nitrogen utilization efficiency is improved. According to the invention, a comprehensive strategy of'regulation and control of nitrogen release by a biochemical inhibitor and collaborative management of water and nitrogen 'is adopted. Release of nitrogen fertilizer is delayed through the urease inhibitor, straw decomposition and crop requirements are matched, and short-term nitrogen starvation of soybeans is avoided; generation of nitrate nitrogen is reduced through the nitrification inhibitor, nitrogen leaching and denitrification loss are reduced, and the nitrogen fertilizer utilization rate is increased; the irrigation amount is adjusted according to the straw decomposition stage and the crop growth stage, microbial decomposition is driven, and meanwhile the carbon conversion efficiency is improved.

This invention discloses a soil improvement and fertilization fertilizer for rhizosphere micro-domains in saline-alkali land and its preparation method, belonging to the field of saline-alkali land management technology. The fertilizer consists of a microbial core, a slow-release fertilizer sub-outer layer, and a soil conditioner outer layer. The microbial core is composed of a compound microbial agent (composed of nitrogen-fixing bacteria, phosphate-solubilizing bacteria, and potassium-active bacteria), biochar, and a high-molecular organic membrane material. The slow-release fertilizer sub-outer layer is composed of chemical fertilizers, inhibitors (nitrification inhibitors and / or urease inhibitors), and amino acids. The soil conditioner outer layer is composed of a soil conditioner specifically for saline-alkali land improvement. The advantages of this invention are: (1) it first adjusts the soil pH and improves the soil structure, so that the microbial community can better adapt to the soil environment of saline-alkali land; (2) the biochar and the isolation membrane effectively protect the microbial activity, and release the microorganisms when the soil pH and base ions around the rhizosphere reach a low level, overcoming the saline-alkali barrier to microbial growth.

The invention relates to the field of fertilizers, in particular to a stable fertilizer for nitrogen fixation and emission reduction of a rice field and a preparation method of the stable fertilizer. The fertilizer core comprises the following components: 28-32 parts of ammonium sulfate, 4-6 parts of monoammonium phosphate, 8-12 parts of potassium sulfate, 0.15-0.50 part of a composite nitrification inhibitor, 1-3.5 parts of zinc sulfate monohydrate and 1-2 parts of borax; wherein the composite nitrification inhibitor is obtained by mixing 3, 4-dimethyl-pyrazole phosphate and a phenylboronic acid-phosphoryl compound in a mass ratio of (2-7): 1. The fertilizer product has a scientific and reasonable formula, the long-acting nutrient content and the trace element substance composition are reasonable, the controlled release function is achieved, nutrients needed by rice growth can be met, the fertilizer utilization rate is increased, and the yield and the quality are improved.

The invention relates to the technical field of environmental engineering, agricultural chemistry or microbiology, and provides a nitrification inhibitor and application thereof. The nitrification inhibitor is N-ethylpiperazine, the growth of AOB can be inhibited at a low dosage (10 mg / L or 0.1 g / kg) so as to inhibit nitrification, and the ecological toxicity and potential biological accumulation of the nitrification inhibitor are not reported in a chemical safety technical specification (SDS), so that the nitrification inhibitor is environment-friendly and can be applied to water treatment and nitrification inhibition in soil.

The invention discloses an anti-leaching nutrient slow-release synergistic compound fertilizer, and particularly discloses an anti-leaching nutrient slow-release synergistic compound fertilizer and a preparation method thereof. The compound fertilizer comprises the following components in parts by weight: 30-50 parts of urea particles, 15-25 parts of monoammonium phosphate, 20-30 parts of potassium sulfate, 2-5 parts of a slow-release synergistic coating agent, 1-3 parts of a bonding wrapping layer and 10-20 parts of a filling material. The slow-release synergistic coating agent comprises polyaspartic acid (PASP) and a composite inhibitor (a urease inhibitor and a nitrification inhibitor), and the bonding wrapping layer is made of a polyvinyl alcohol / sodium polyethylene acid-based cementing material. The preparation method comprises the following steps: mixing and granulating raw materials, carrying out primary coating (slow-release synergist), carrying out secondary coating (bonding a coating layer), and drying and screening. Through the synergistic effect of the double coating technology and the compound inhibitor, the nitrogen conversion and release are obviously delayed, the nutrient leaching loss is reduced by 20-40%, the fertilizer utilization rate is improved by 25-30%, and the compound fertilizer is suitable for high-temperature and rainy areas.

The invention provides an application of a nitrification inhibitor and biochar as a soil conditioner in enhancing drought resistance of plants, a preparation method of the biochar is as follows: moso bamboo stalks are taken as raw materials, pyrolysis is performed for 4-8 hours under an anoxic state of 250-400 DEG C, soil is red soil, and the plant is polygonatum cyrtonema, and an application method comprises the following steps: adding a nitrogen fertilizer into the soil, the addition amount of the nitrification inhibitor is 1% of the content of nitrogen added to the soil, and the addition amount of the biochar is 3% of the mass of the soil. Through combined application of the biochar and the dicyandiamide, the drought resistance of the polygonatum cyrtonema and the benefits of soil microbial communities are remarkably improved.

Fertilizers with urease inhibitors and / or nitrification inhibitors are described. The fertilizer can include an extruded granule containing urea, a polymeric binder, and a nitrification inhibitor and / or an urease inhibitor.

The present invention comprises one or more organic solvents that create a non-aqueous organo solvent delivery system, (NOSDS), and one or more Organo Polycarboxylate functionalities, OPCF, that results in a stable, non-aqueous solution that can easily, safely, evenly and economically coat nitrogen source granules and / or be added to a mobile liquid form of a nitrogen source such as an aqueous dispersion, pressurized ammonia gas or molten urea and / or molten modified urea. Using these solvents provides more flexibility for nitrogen source manufacturers to produce nitrogen sources designed for a particular soil or plant. The liquid solutions are comprised of NOSDS and OPCFs and one or more of a) nitrification inhibitors, b) urease inhibitors, c) pesticides, d) fungicides, e) herbicides, f) insecticides and g) micronutrients.

The invention relates to a method for producing particles comprising urea and at least one urease inhibitor and / or at least one nitrification inhibitor, and to a suitable apparatus for carrying out the method.

The invention relates to a stabilized fertilizer containing antibacterial peptide and a preparation method thereof, the stabilized fertilizer containing antibacterial peptide is characterized by containing jerusalem artichoke antibacterial peptide; the jerusalem artichoke antibacterial peptide is a product obtained after jerusalem artichoke residues are subjected to enzymolysis. The enzymolysis is protease enzymolysis; the protease is acid protease or alkaline protease. The antibacterial peptide-containing fertilizer prepared by the invention can meet the requirement of a stable fertilizer without additionally adding a nitrification inhibitor or a urease inhibitor.

The present invention relates generally to nitrification inhibitors and their use to prevent nitrate leaching or nitrous oxide emissions and to increase forage or crop yield. The present invention also relates to nitrification inhibitors and formulations comprising the same for direct or indirect application to soil or pasture.

The invention provides an organic-inorganic multifunctional compound fertilizer applicable to tea trees. The organic-inorganic multifunctional compound fertilizer applicable to the tea trees is prepared from the following raw materials in parts by mass: 30 parts of tea tree pruning branch organic fertilizer, 25 to 35 parts of urea, 15 to 20 parts of monopotassium phosphate, 10 to 15 parts of potassium sulfate, 1 part of nitrogen nitrification inhibitor dicyandiamide and 0.5 part of hydroquinone. The organic-inorganic multifunctional compound fertilizer applicable to the tea trees, provided by the invention, has the advantages that the organic-inorganic multifunctional compound fertilizer can be developed on the basis of nutrient requirements and quality formation rules of the tea trees, scientific and effective utilization of pruned tea trees and a nutrient coupling effect of biochar are realized, slow release of fertilizer nutrients is realized, and the yield of the tea trees is increased. Therefore, the nutrient utilization efficiency is improved, the growth of the tea trees is promoted, and the quality is improved.

This invention provides a method for increasing wheat yield without topdressing, using a compound fertilizer in granular form, comprising, from the inside out: an inner core containing fast-acting nitrogen fertilizer, a urease inhibitor, and a nitrification inhibitor; a middle layer containing slow-release nitrogen fertilizer and enzyme activating substances; and an outer layer containing controlled-release nitrogen fertilizer and sugar-enhancing substances. The inner, middle, and outer layers form a functional spatiotemporal coupling structure, matching nitrogen release with the nitrogen requirements of wheat during its growth period, with an effective fertilizer period of 110-120 days. In the inner core, the urease inhibitor is selected from NBPT (n-butylthiophosphoric triamine) or its derivatives, and the nitrification inhibitor is selected from DMPP (3,4-dimethylpyrazole phosphate) or DCD (dicyandiamide). This invention's compound fertilizer provides effective nitrogen supply for 110-120 days, covering the entire wheat growth period, achieving a single basal application and eliminating the need for topdressing throughout the entire growth period, reducing fertilization operations by 2-3 times and significantly lowering labor costs.

This invention relates to the field of soil treatment technology, specifically a method and its application for reducing compound fungicides in soil-plant systems by combining nano-silica and nitrification inhibitors. Nitrification inhibitors are used as a nitrogen management measure, and the application of nanomaterials influences soil abiotic properties and bacterial communities to drive the degradation of paclobutrazol and carbendazim. The application of nitrification inhibitors (DCD) produces multiple effects: significantly reducing carbendazim residues in soil-plant systems, paclobutrazol residues in soil, and NO3 in plants. ‑ -N and promote the content of soluble sugars and proline in plants. DCD reduces the activity of the soil electron transport system and β-glucosidase activity, while the addition of nano-SiO2 can mitigate this negative effect. Nano-SiO2 selectively enhances the performance of DCD in reducing compound fungicide residues in pak choi and reducing paclobutrazol residues, but hinders the degradation of carbendazim in pak choi.

Nitrification inhibitor compositions and methods for inhibiting nitrification of ammonia in soil are disclosed. Methods of preparing the nitrification inhibitors are also disclosed.

The present invention provides a novel fertilizer synergist and its preparation method and application. The novel fertilizer synergist comprises the following raw materials in parts by weight: 15-30 parts of a nitrification inhibitor, 10-25 parts of polyaspartate, 30-50 parts of polyepoxysuccinate, and 1-10 parts of trace elements. The fertilizer synergist of the present invention can effectively improve the utilization efficiency of nitrogen and phosphorus nutrients in fertilizers. The synergistic effect of DMPP, polyaspartate, and polyepoxysuccinate in the present invention can reduce nitrogen loss and phosphorus fixation, and can simultaneously improve the utilization efficiency of nitrogen and phosphorus in fertilizers, thereby reducing fertilizer losses. The delayed release characteristics of synergistic nitrogen and phosphorus in the fertilizer formula of the present invention further promote the absorption of quick-acting nitrogen and phosphorus in the soil by plants, improve the utilization efficiency of nitrogen and phosphorus, and promote the rapid growth of crops.

The present invention relates to the use of novel nitrification inhibitors of formula I, which are N-functionalized alkoxy pyrazole compounds. Moreover, the invention relates to the use of compounds of formula I as nitrification inhibitors, i.e. for reducing nitrification, as well as agrochemical mixtures and compositions comprising the nitrification inhibitors of formula I.

The present invention relates to the use of compounds of formula (I), which are strigolactone derivatives and analogues, as nitrification inhibiting compounds, i.e. for reducing nitrification, in nitrifying microorganisms, as well as agrochemical mixtures and compositions comprising a nitrification inhibiting compound of formula (I).