4158 results about "Polyacrylic acid" patented technology

The invention relates to the technical field of adsorption materials, and discloses a preparation method and application of a hydrogel adsorption material prepared by copolymerizing cellulose with acrylic acid and acrylamide. The method comprises the following steps: extracting cellulose from corn straws; placing cellulose in a sodium hydroxide / urea / water system, stirring and dissolving; the preparation method comprises the following steps: uniformly mixing acrylamide and acrylic acid in water to prepare a modified solution; sequentially adding the modified solution, N, N '-methylene bisacrylamide and potassium persulfate into the cellulose solution, and stirring and mixing; putting the mixed solution into a drying oven for gelation to obtain the cellulose co-polyacrylamide and acrylic acid hydrogel adsorption material. A large number of groups such as hydroxyl and carboxyl are introduced to the surface of the hydrogel adsorption material prepared by the method, the adsorption capacities of heavy metals such as lead, cadmium and copper reach 434.8 mg / g, 277.7 mg / g and 261.8 mg / g respectively, and heavy metal ions in a water body can be effectively and quickly removed.

The invention relates to a photo-thermal super-hydrophobic multifunctional anti-icing coating as well as a preparation method and application thereof. The photo-thermal super-hydrophobic multifunctional anti-icing coating comprises primer and finish paint, the primer comprises the following raw materials in parts by weight: 20-25 parts of bisphenol A type epoxy resin and / or fluorine modified epoxy resin, 10-20 parts of fluorine modified polyacrylic resin and / or polyurethane resin, 5-10 parts of a curing agent and 40-55 parts of a solvent; the finish paint comprises the following components in parts by weight: 2-5 parts of polytetrafluoroethylene, 1-3 parts of soluble polytetrafluoroethylene, 1-5 parts of polydimethylsiloxane and 85-90 parts of fluorinated MOF dispersion liquid. Compared with the prior art, the photo-thermal super-hydrophobic multifunctional anti-icing coating provided by the invention has the characteristics of super-hydrophobicity, rapid ice melting, wear resistance, reduction of ice adhesion strength and reduction of icing amount, can effectively solve the problem of icing of an aluminum conductor of a power transmission line of a power system, and can be applied to power equipment such as the aluminum conductor of the power transmission line.

The invention relates to an insulating weather-resistant powder coating and a preparation method thereof, and belongs to the technical field of coatings, and the powder coating comprises composite modified resin, a dual curing agent, a functional filler, a polyacrylate leveling agent, fumed silica, a benzotriazole ultraviolet light absorber, polytetrafluoroethylene wax powder and the like. A core-shell structure of the composite modified resin is designed, high insulativity is kept through a silane modified epoxy core layer, a weather-proof barrier is provided through an acrylic acid shell layer, and the phase separation problem is solved through interface chemical bonding; a dual-curing mechanism is designed, and isocyanate and acrylic hydroxyl react to form an interpenetrating network while an epoxy core layer is cured by anhydride; a filler synergistic effect is designed, silane coupling agent modified nano boron nitride forms a three-dimensional heat-conducting insulating network, and rutile type titanium dioxide is coated with silicon dioxide, so that ultraviolet aging is resisted. All the components cooperate with one another, so that the coating has excellent insulativity, weather resistance, adhesiveness and the like at the same time.

The invention discloses a hydrophilic polyacrylate / epoxy silica sol composite coating and a preparation method thereof. The composite coating is prepared from a polyacrylate epoxy silica sol solution containing carboxyl and a polyethylene glycol side chain through blending, coating, drying and heating crosslinking. The polyacrylate is synthesized by taking methyl methacrylate, methacrylic acid, hydroxyethyl methylacrylate and allyl polyethylene glycol as comonomers through a solution free radical copolymerization method, and the epoxy silica sol solution is prepared by taking tetraethoxysilane and gamma-glycidoxypropyltrimethoxysilane as raw materials through a solution polymerization method. The composite material is prepared through a sol-gel and core-shell preparation process. The preparation method comprises the following steps: carrying out solution blending on polyacrylate and epoxy silica sol, and carrying out coating, drying and other processes to generate the cross-linked polyacrylate / epoxy silica sol composite coating through a cross-linking reaction between carboxyl and epoxy. The prepared composite coating has the characteristics of long durability, wear resistance, hydrophilicity, antifogging, protein adsorption resistance and the like.

The invention belongs to the technical field of cement manufacturing, and particularly relates to high-strength weather-resistant environment-friendly cement and a preparation method thereof. The environment-friendly cement is prepared from the following raw materials in parts by mass: 40 to 55 parts of Portland cement, 15 to 25 parts of fly ash, 10 to 15 parts of slag powder, 6 to 12 parts of biomass reinforced composite mineral material, 2 to 4 parts of nano silicon dioxide, 1 to 4 parts of modified polymer emulsion and 1 to 3 parts of additive. The biomass reinforced composite mineral material is prepared from zeolite, bentonite, sepiolite and chitosan; the modified polymer emulsion comprises a modified polyacrylate emulsion and a modified polystyrene-butadiene emulsion in a mass ratio of (1-3): 1; the additive is prepared from basalt fiber, sodium lignin sulfonate, a rosin thermopolymer and sodium gluconate. The environment-friendly cement prepared by the invention not only has high strength and good weather resistance, but also remarkably reduces carbon footprint and saves natural resources.

The invention provides a low-swelling low-temperature adhesion polyacrylate water-based binder as well as a preparation method and application thereof. The polyacrylate water-based binder is a core-shell polymer obtained by polymerizing a polymeric monomer, polymeric monomers of a core polymer of the core-shell polymer comprise the following monomers in percentage by weight: 50-90% of a hard monomer, 5-30% of a soft monomer and 1-20% of a functional monomer; polymeric monomers of a shell polymer of the core-shell polymer comprise the following monomers in percentage by weight: 35-85% of a hard monomer, 15-60% of a soft monomer and 0-5% of a functional monomer. The polyacrylate aqueous binder provided by the invention is suitable for the lithium ion battery diaphragm, and solves the problems of low adhesion, high energy consumption, no environmental protection, high price and the like of the current binder for the lithium ion battery diaphragm.

A biodegradable polymer composite, a method of making the same and use for same are provided. The biodegradable polymer composite has about 30 to 99.5% by weight of a polymer selected from a group consisting of polybutylene adipate terephthalate (PBAT), polybutylene succinate (PBS), polyhydroxyalkanoates (PHA), and polycaprolactone (PCL) grafted with a compatibilizer selected from a group consisting of maleic anhydride, glycidyl methacrylate, pyromellitic anhydride, acrylic acid, polyacrylic acid, methylene diphenyl diisocyanate, poly(glycidyl methacrylate, copolymer(s) of glycidyl methacrylate; and about 0.5 to 50 % by weight a nano-filler or a micro-filler. The biodegradable polymer composite does not contain polylactic acid. Surfaces of the nano-filler or the micro-filler may be modified using a grafting agent so that the biodegradable polymer composite has enhanced mechanical properties, increased heat resistance, compostablity and / or improved processability. The biodegradable polymer composite may be used to make flexible articles, such as a freezer wrap and a farming sheet.

The invention provides a carbon-coated current collector and a preparation method and application thereof. The carbon-coated current collector comprises a current collector base material and a carbon-coated layer on at least one side of the current collector base material; the carbon coating layer comprises a conductive agent, a binder and a cross-linking agent; the binder comprises a polyacrylic acid polymer and polystyrene microspheres. According to the carbon-coated current collector provided by the invention, the cohesive force between the current collector and an electrode active material layer is improved through the synergistic effect of the polyacrylic acid polymer, the polystyrene microspheres and the cross-linking agent, the interface resistance is also reduced, and meanwhile, the electrochemical performance of a pole piece is improved.

The invention provides a thick electrode and a preparation method thereof, and a lithium battery, the thick electrode comprises a current collector and an active coating, the active coating comprises an active material, a conductive agent, a dispersant and a composite binder, the composite binder comprises a binder A and a binder B, the binder A comprises at least two of sodium carboxymethyl cellulose, a polyacrylic acid binder and an acrylonitrile multipolymer, and the binder B comprises at least one of polytetrafluoroethylene and butadiene styrene rubber. The thick electrode has the characteristics of stable structure, good conductivity and high ion transmission efficiency, and the cycling stability of the battery using the thick electrode can be improved.

The invention belongs to the technical field of electrochemical materials, and discloses an epoxy resin solid electrolyte as well as a preparation method and application thereof. The preparation raw materials are as follows: 100 parts of epoxy resin, 5-15 parts of an ionic conductive group compound, 5-15 parts of a high ionic conductive lithium salt, 2-20 parts of an ionic liquid, 10-30 parts of a flexible chain segment compound, 1-20 parts of a pore forming agent and 20-50 parts of a curing agent. The ionic conductive group compound comprises a sulfonic compound, a quaternary ammonium salt or a carboxyl compound; the flexible chain segment compound comprises one or more of polyester, polyurethane, polyacrylate, polyacrylic acid, polyamide and polyether-ether-ketone. According to the invention, the epoxy resin is used as a main matrix, the ionic liquid provides an ionic migration path, meanwhile, an ionic conductive group is grafted into an epoxy resin molecule, a flexible chain segment is introduced to reduce the crosslinking density, and the cured electrolyte matrix can form an effective ion channel, so that the conductivity is improved.

The invention provides a solid electrolyte slurry, an electrode slurry, a solid electrolyte sheet, an electrode sheet, a solid battery monomer, a battery device and a power utilization device.The solid electrolyte slurry comprises a sulfide solid electrolyte material, a solvent and a binder dissolved in the solvent, and the solvent is a non-polar solvent, a weak-polar solvent or a mixed solvent of the non-polar solvent and the weak-polar solvent; the binding agent comprises a polyacrylate binding agent and a non-polar polyolefin binding agent. The slurry disclosed by the invention has high dispersity, high suspension property and good cohesiveness, and can enable the solid-state battery monomer to have high initial coulombic efficiency when being used in the solid-state battery monomer.

Provided in the present invention are a polyacrylic acid or polyacrylate water-based binder, and a preparation method therefor and the use thereof. The polyacrylic acid or polyacrylate water-based binder is a polymer obtained by polymerizing polymeric monomers, the polymeric monomers comprising a hard monomer, a soft monomer and a functional monomer. The polyacrylic acid or polyacrylate water-based binder provided by the present invention has relatively high binding power and relatively good flexibility and electrochemical stability, and has good application prospects in the field of negative electrode sheets of lithium-ion batteries.

The invention discloses water-based formaldehyde-free woodworking glue and a preparation method thereof, and relates to the technical field of woodworking glue. When the water-based formaldehyde-free woodworking glue is prepared, firstly, n-butyllithium is used as an initiator to initiate cyclosiloxane and an acrylate monomer to be polymerized, then dimethyl chlorosilane is used for blocking to obtain pre-modified polyacrylate, and the pre-modified polyacrylate is used for preparing the water-based formaldehyde-free woodworking glue. Reacting the pre-modified polyacrylate with vinyl diphenylphosphine, and then reacting with 3-(4-bromophenyl)-1-propylene to obtain modified polyacrylate; secondly, reacting the 4-(trimethoxysilyl) butyraldehyde modified silicon dioxide with chitosan, and then reacting with mercaptoacetic acid to obtain modified silicon dioxide; finally, mixing the modified polyacrylate, the modified silicon dioxide, an emulsifier, a defoaming agent, pure water and a photoinitiator to obtain the water-based formaldehyde-free woodworking glue. The water-based formaldehyde-free woodworking glue prepared by the invention has flame retardance and antibacterial property.

The invention relates to the technical field of phase change microcapsules, in particular to a polyurea / polyacrylate double-layer shell material phase change microcapsule and a preparation method thereof. The microcapsule sequentially comprises a phase change material core material, a polyacrylate shell material and a polyurea shell material from inside to outside, and is prepared from the following raw materials: a polyisocyanate monomer, an acrylate monomer, an acrylate functional monomer, an acrylate cross-linking agent, a chain extender, an initiator, a surfactant, a phase change material and water. According to the invention, polyurea interfacial polymerization and polyacrylate suspension polymerization are combined to form a double-layer shell material for coating to prepare the phase change microcapsule, so that the phase change microcapsule has excellent sealing property, durability and high enthalpy value performance.

The invention discloses a waterborne acrylic acid-polyurethane composite emulsion, a waterborne acrylic acid-polyurethane composite paint, and a preparation method and application of the waterborne acrylic acid-polyurethane composite emulsion. According to the preparation method of the water-based acrylic acid-polyurethane composite emulsion, a core-shell structure polyacrylic acid-polyurethane emulsion is synthesized in situ by utilizing a core-layer monomer pre-emulsion and a shell-layer monomer pre-emulsion through a semi-continuous seed emulsion polymerization method. The shell layer of the core-shell structure has hydrophilic functional groups including carboxyl, sulfo group and hydroxyl, so that the emulsion has a self-thickening effect, and rheological properties and good constructability required by the coating can be provided. A nonionic hydrophilic group composite sodium sulfonate type post chain extender is selected as waterborne polyurethane, the emulsifying capacity is high, the emulsion stability is good, strong-acid monomers such as acrylic acid and methacrylic acid can be selected, high-thixotropy resin can be obtained through adjustment, meanwhile, the PA content can be effectively increased, the water resistance and weather resistance of a paint film can be improved, and the water resistance and weather resistance of the paint film can be improved. Therefore, the requirements of the automobile paint on moisture resistance, especially high-pressure flushing resistance, are met.

The invention discloses segmented copolymer grafted graphene oxide and a preparation method and application thereof, and relates to the technical field of cement-based material preparation.The method comprises the following steps that graphene oxide is dispersed in a solvent, an RAFT reagent is added, and RAFT reagent modified graphene oxide is prepared; adding a polyether copolymer to prepare copolymer grafted graphene oxide; and adding poly (propanesulfonic acid) to prepare the segmented copolymer grafted graphene oxide. The graphene oxide is chemically modified, the block copolymer is grafted through RAFT polymerization, the polyether-polyacrylic acid block copolymer is synthesized, the polyether-polyacrylic acid block copolymer has a good promotion effect in the cement hydration process, the workability of a cement-based material can be improved, the mechanical property of the cement-based material can be enhanced, and good economic benefits can be obtained. The invention solves the problem that the performance of the cement-based material improved by physical modification and chemical modification of graphene oxide in the prior art is not ideal.

Electrospun poly(acrylic) acid (PAA) / poly(vinyl) alcohol PVA nanofibers and integrated filtration membranes generated therefrom are disclosed herein. The membranes are suitable for use in selectively removing heavy metals such as lead and cadmium from water. The surface of the nanofibers is preferably functionalized with one or more chelating agents. The membranes have a high removal efficiency and adsorption capacity with well-distributed high-density heavy metal adsorption sites with strong binding affinities for targeted heavy metals.

The invention provides a high-temperature-resistant magnesia-carbon composite refractory brick and a preparation method thereof, and belongs to the technical field of magnesium oxide refractory wall bricks, the refractory brick comprises the following raw materials: double-layer modified magnesium oxide, modified crystalline flake graphite, zircon powder, modified liquid phenolic resin and a benzoxazine cross-linking agent; the double-layer modified magnesium oxide is obtained by firstly coating magnesium oxide with powder phenolic resin, aluminum oxide and zirconium oxide and then coating magnesium oxide with asphalt, micron magnesium oxide, zirconium oxide and calcium oxide; the modified crystalline flake graphite is obtained by coating crystalline flake graphite with strontium hydroxide, asphalt and boron carbide; the modified liquid phenolic resin is formed by mixing liquid phenolic resin with a silane coupling agent and a polyacrylate cross-linked polymer. Double-layer modified magnesium oxide, modified crystalline flake graphite and modified liquid phenolic resin are prepared by adopting special components and a method and are matched with zircon powder and a benzoxazine cross-linking agent for use, and a reasonable forming and sintering process is designed, so that the refractory brick has good high-temperature stability, oxidation resistance, thermal shock resistance and the like.

The invention discloses a high-strength cold-resistant fiber and a preparation method thereof, and relates to the field of fibers. When the high-strength cold-resistant fiber is prepared, diphenylphosphine sequentially reacts with triallylmethoxysilane and nickel bromide, and a silicon-phosphorus-nickel complex is prepared; the preparation method comprises the following steps: reacting an alkene mixed solution, azodiisobutyronitrile, a hydrochloric acid solution and a silicon mixed solution, diluting with 4-methyl cyclohexanone, and reacting with zinc bromide to prepare a pre-modified polyacrylate emulsion; the preparation method comprises the following steps: carrying out a batch reaction on graphene oxide and 1-aminopyrrole to prepare modified graphene oxide; the modified graphene oxide, 2, 5-dihydroxy terephthalaldehyde and the pre-modified polyacrylate emulsion react and then electrostatic spinning is conducted, and the high-strength cold-resistant fiber is prepared. The high-strength cold-resistant fiber prepared by the invention has antibacterial, anti-aging, flame-retardant and antistatic capabilities.

The invention discloses a concrete composite tackifier and a preparation method thereof, and relates to the technical field of concrete. When the concrete composite tackifier is prepared, firstly, polyacrylic resin obtained by polymerizing acrylic acid, methyl methacrylate, acrylamide and vinyl diphenylphosphine reacts with modified porphyrin, and then sulfonation is performed to obtain modified polyacrylic resin; the preparation method comprises the following steps: firstly, pre-treating silica fume with vinyltrimethoxysilane, then carrying out a reaction on the silica fume pre-treated with vinyltrimethoxysilane, tetravinyltetramethylcyclotetrasiloxane and vinylboronic acid pinacol ester to obtain modified silica fume, and finally, mixing polyacrylic resin and the modified silica fume to obtain the concrete composite tackifier. The concrete composite tackifier prepared by the invention has good working performance and antibacterial property.

The invention provides a self-healing modified binder for a silicon negative electrode of a lithium battery as well as a preparation method and application of the self-healing modified binder. The self-healing modified binder at least comprises tannic acid, polyacrylic acid and a modified nano silicon dioxide composite material. The self-healing modified adhesive has rich dynamic hydrogen bonds among molecules, and is combined with a doped modified nano silicon dioxide composite material, so that the hydrophobicity of the self-healing modified adhesive is improved, and meanwhile, the self-healing modified adhesive is endowed with excellent self-healing performance, so that the self-healing modified adhesive can quickly recover the integrity when subjected to mechanical damage, and the service life of the self-healing modified adhesive is prolonged. Therefore, the problem of poor battery performance caused by volume expansion of the silicon negative electrode in the charging and discharging process is effectively solved.

Provided are a secondary cured UV pressure-sensitive adhesive, and preparation methods for same and an explosion-proof film. The secondary cured UV pressure-sensitive adhesive is composed of the following materials, in percentages by mass: 31-35% of a hydroxyl-containing polyacrylate prepolymer, 6-9% of pentaerythritol triacrylate, 3-5% of 2-hydroxyl-3-phenoxy propane acrylate, 2-3% of an isocyanate curing agent, 2-3% of photo initiator 184, and 50% of ethyl acetate. The secondary cured UV pressure-sensitive adhesive is prepared by carrying out a thermal curing cross-linking reaction of a hydroxyl-containing polyacrylate prepolymer, pentaerythritol triacrylate and 2-hydroxyl-3-phenoxy propane acrylate by using an isocyanate curing agent, and initiating a free radical polymerization of pentaerythritol triacrylate and 2-hydroxyl-3-phenoxy propane acrylate by using photo initiator 184.

The invention relates to a chenille waterproof floor mat and a production process thereof, a base cloth used by the chenille waterproof floor mat is modified, namely polyacrylic acid is used as an adhesive, antibacterial water-absorbing microspheres are arranged into the base cloth to prepare the modified base cloth, and the antibacterial water-absorbing microspheres have good water-absorbing performance and antibacterial performance, so that the antibacterial water-absorbing microspheres have good water-absorbing performance and antibacterial performance. The chenille waterproof floor mat can rapidly absorb water and maintain the antibacterial performance in the using process, modified polyester is prepared and used as a raw material to prepare modified polyester filaments, then the modified polyester filaments serve as decorative yarn of chenille yarn, and due to the fact that the modified polyester contains zwitter-ion side chains, the antibacterial performance of the chenille waterproof floor mat is improved, and the antibacterial performance of the chenille waterproof floor mat is improved. The chenille yarn has the anti-fouling and anti-bacterial performance, the hydrophilic performance of the chenille yarn is improved, and then the chenille waterproof floor mat has the good water-absorbing, anti-bacterial and anti-fouling performance.

The invention relates to the technical field of high polymer material chemistry, and discloses a high and low temperature resistant anti-yellowing optical adhesive and a preparation process thereof, the high and low temperature resistant anti-yellowing optical adhesive comprises the following components by weight: 40-60% of modified organic silicon resin, 20-30% of urethane acrylate, 10-15% of alicyclic epoxy resin, 0.5-5% of a nano inorganic filler, 0.8-2.5% of an anti-yellowing composite reagent, and the balance of a solvent. The coating is prepared from the following components in percentage by weight: 0.5 to 1.5 percent of 2-hydroxy-2-methyl-1-phenyl-1-acetone, 0.1 to 0.3 percent of fluorine modified polyacrylate flatting agent and 0.3 to 1.0 percent of chloroplatinic acid-divinyl tetramethyl disiloxane complex catalyst. The preparation method comprises the following steps: mixing alpha, omega-dihydroxy polydimethylsiloxane and phenyltrimethoxysilane according to a mass ratio of 8: 2-7: 3, adding 0.3-1.0% of a chloroplatinic acid-divinyl tetramethyl disiloxane complex catalyst, and raising the temperature by stages under the protection of nitrogen, so that the glass transition temperature of the adhesive can reach 120 DEG C below zero and 125 DEG C, and the temperature of the adhesive can reach 120 DEG C below zero and 125 DEG C below zero. And the long-term service requirement of the optical device in an extreme temperature environment is met.

The invention provides sodium-ion battery positive electrode slurry, a positive electrode plate, a preparation method of the positive electrode plate and a sodium-ion battery, and relates to the technical field of sodium-ion batteries, the sodium-ion battery positive electrode slurry comprises a positive electrode active material, a conductive agent, a binder, a composite dispersant and a solvent; the composite dispersing agent is a product formed by mechanically mixing an ionic dispersing agent and a polyoxyethylene ether nonionic dispersing agent or a compound formed by chemically reacting the ionic dispersing agent and the polyoxyethylene ether nonionic dispersing agent, and the ionic dispersing agent is polyacrylic acid and a derivative thereof; and the positive electrode active material is a polyanion material. According to the positive electrode slurry disclosed by the invention, the ionic dispersant of polyacrylic acid and a derivative thereof and the polyoxyethylene ether nonionic dispersant are compounded for use, so that the positive electrode slurry has good dispersity and stability, the provided positive electrode slurry is good in dispersity, the resistance of a positive electrode plate is low, and the cycle performance of the sodium ion battery is excellent.

The invention discloses a high-hydrolysis-resistance glass fiber reinforced polyester material, which is prepared from the following raw materials in parts by weight: 36 to 65 parts of mixed modified polyester resin, 9 to 25 parts of glass fiber, 6 to 11 parts of hydrolysis-resistant agent, 4 to 15 parts of toughening agent, 2 to 8 parts of buffering agent, 0.2 to 0.5 part of compatilizer, 0.1 to 1.0 part of lubricating agent and 3 to 10 parts of halogen-free flame retardant, the modified polyester resin comprises organic silicon modified polyester resin and acrylate modified polyester resin. The modified mixed polyester resin material is used as the raw material of the polyester material, so that the polyester material can fully combine the advantages of the organic silicon modified polyester resin and the polyacrylate modified polyester resin, and terminal carboxyl groups in a polyester molecular chain are reduced by using the mixed modified polyester resin, so that the hydrolysis reaction is inhibited, and the service life of the polyester material is prolonged. Therefore, the hydrolysis resistance of the polyester material is improved.

The invention belongs to the technical field of lithium ion batteries, and discloses an amidated polyacrylic acid water-based polymer binder for a silicon-based negative electrode of a lithium ion battery and a preparation method and application of the amidated polyacrylic acid water-based polymer binder for the silicon-based negative electrode of the lithium ion battery. The preparation method comprises the following steps: under a protective atmosphere, sequentially adding 1-ethyl-(3-dimethylaminopropyl) carbodiimide hydrochloride, N-hydroxysuccinimide and levodopa, stirring to fully react, carrying out dialysis freeze-drying treatment to obtain a primary product PL, and uniformly mixing the PL with glycerol to obtain the product. According to the binder, a dynamic bond is successfully introduced, the transportation efficiency of lithium ions is improved, a three-dimensional network structure is constructed, adverse stress generated by volume expansion of a SiOx negative electrode material in the charging and discharging process of an electrode can be effectively inhibited, and the SiOx negative electrode shows good cycling stability.

The present invention provides an electrically-conductive composite water-based binder as well as a preparation method therefor and the use thereof. The electrically-conductive composite water-based binder comprises in parts by weight: 90-100 parts of a polyacrylic acid or polyacrylate water-based binder and 0.1-10 parts of an electrically-conductive filler. By means of introducing the electrically-conductive filler into the binder, the electrically-conductive composite water-based binder for lithium ion batteries which has flexibility, low swelling, good binding force and high conductivity is prepared, so that the binder plays a better role in lithium ion batteries.

The invention discloses an improved protein kapok silk fiber material and a preparation method thereof, and belongs to the technical field of natural fiber modification. Comprising the following steps: soaking pretreated kapok fibers obtained by soaking kapok fibers in an alkaline solution in an oxidizing agent solution to obtain oxidized kapok fibers; dipping the oxidized kapok fiber in a polyacrylic acid-levodopa solution, adding a diamine cross-linking agent, and mixing to obtain polyacrylic acid-levodopa modified kapok fiber; the polyacrylic acid-levodopa modified kapok fibers are soaked in the impregnation liquid, and the improved protein kapok silk fibers are obtained. The improved protein kapok fiber yarn fiber material prepared by the preparation method disclosed by the invention has good waterproof performance, mechanical strength and softness.

The invention is applicable to the technical field of daily cleaning chemicals, and provides a double-shell probiotic microcapsule which comprises probiotics, a fat-soluble plant extract, cellulose nanocrystals, a polyacrylic acid-chitosan compound, a surfactant, diisocyanate, polyethylene glycol and ethyl acetate. A wall material of the microcapsule is formed by compounding a polyacrylic acid-chitosan compound and a fat-soluble plant extract, the particle size D50 is smaller than or equal to 5 microns, the microcapsule is stable in an environment with the pH being 8-10, and the microcapsule is broken to release probiotics when the pH is smaller than or equal to 6. The outer layer is polyacrylic acid / chitosan compound / polyurethane crosslinking (pH response), the inner layer is coconut oil and soybean oil (fat-soluble core), meanwhile, the material preparation process is simple, the controllable degree is high, and the material is suitable for batch preparation.