32 results about "Hypophosphite" patented technology

The invention relates to the technical field of electroplating, and particularly discloses a nickel-tungsten-phosphorus plating layer electroplating process which comprises the following steps: S1, preparing a nano composite electroplating solution which comprises nickel salt, tungstate, hypophosphite, nano silicon carbide powder, ZIF-67 (at) MXene core-shell nanosheets, a composite complexing agent and water; s2, plasma mixed gas is adopted for conducting etching treatment on the surface of the workpiece to be plated; s3, electroplating the to-be-electroplated workpiece subjected to surface treatment under the action of pulse current and an alternating magnetic field, and performing ultrasonic stirring on the composite electroplating liquid in the electroplating process; and S4, under nitrogen protection, the workpiece is subjected to annealing treatment. According to the electroplating process, through the synergistic effect of the nano SiC and the ZIF-67 (at) MXene, the component uniformity and the structural compactness of the nickel-tungsten-phosphorus coating can be effectively improved, and then the corrosion resistance of the nickel-tungsten-phosphorus coating in the complex oil gas environment is effectively improved.

The invention discloses an efficient and stable electroplating hydrogen evolution electrode and a preparation method and application thereof. The preparation method comprises the following steps that S1, a conductive substrate material is prepared and pretreated; s2, an electroplating solution is prepared, wherein the electroplating solution comprises a solvent, nickel salt, hypophosphite, a buffering agent and a complexing agent; and S3, three-electrode deposition is carried out with the electroplating liquid as an electrolyte and the pretreated conductive substrate material as a working electrode, and the efficient and stable electroplating hydrogen evolution electrode is obtained. The prepared electrode is a phosphate material with an amorphous structure, has a larger catalytic interface and more reaction active sites, and is beneficial to rapid diffusion of ions or small molecules due to the fact that open active pore channels of the electrode form permeable channels; through the synergistic effect of electrochemical parameters, the composite material has the capability of being stable for a long time under high current density. The preparation method disclosed by the invention is simple to operate, low in cost, low in equipment and process condition requirements and easy for industrial large-scale production.

The invention discloses preparation and application of a nickel selenide / ferronickel phosphate crystal / amorphous heterogeneous catalyst, and relates to the technical field of electrochemistry. Selenizing the foamed nickel at low temperature in an inert atmosphere to generate a crystalline NiSex layer in situ; and by taking the obtained electrode as a working electrode, carrying out electrodeposition in a deposition solution containing nickel salt, ferric salt, hypophosphite and acetate by adopting a cyclic voltammetry method, so that amorphous NiFePOy is deposited on the surface of NiSex, and a NiSex / NiFePOy crystal / amorphous heterostructure nanosheet layer is constructed and is used for an alkaline medium urea oxidation reaction. The invention has the following beneficial effects: crystalline / amorphous interface coupling and a nanosheet self-supporting structure synergistically improve active sites and charge transfer capability, reduce energy consumption and improve current output; meanwhile, the electrode stability and durability are enhanced; the method has the advantages of low material cost, mild and simple process, suitableness for amplified preparation, and application potential of urea-assisted water electrolysis energy-saving hydrogen production.

This invention relates to the field of electroless plating technology, and more particularly to a low-phosphorus electroless nickel plating solution and a method for nickel plating on an aluminum alloy substrate. The low-phosphorus electroless nickel plating solution comprises the following components by mass concentration: a nickel ion source in the form of Ni... 2+ Calculated as 1.0~5.0 g / L; hypophosphite as H2PO2 ‑ The concentrations are calculated as follows: 20–45 g / L; glycine 5–40 g / L, gluconate 5–60 g / L; polyaspartic acid and / or its salts 0.2–5.0 g / L; pH buffer 2–25 g / L; alkyl glycosides 0.05–1.0 g / L; iodate stabilizer, in IO3... ‑ The concentration is calculated to be 0.2~5.0 mg / L. This invention maintains a high deposition rate and significantly improves the tolerance of by-products in the bath solution under low nickel ion concentration conditions. It is also free of heavy metals and sulfur-containing organic stabilizers, reducing the metal load and environmental risk of the waste liquid. It is suitable for various aluminum alloy matrices treated with double zinc replacement.

The present invention relates to the field of halogen-free organophosphorus flame-retardant nylon, and in particular to a nylon composite material, and a preparation method therefor and a use thereof. Specifically, the nylon composite material disclosed in the present invention comprises: 65-82 parts of polyamide resin, 12-18 parts of a hypophosphite flame retardant, 10-50 parts of a reinforcing agent, 0.5-2 parts of hydrotalcite, 3-8 parts of boehmite, and 1-3 parts of PET resin. The present invention solves the problem of corrosion of organophosphorus flame-retardant nylon materials to silicone under high-temperature conditions, and provides an organophosphorus flame-retardant nylon composite material resistant to silicone corrosion under high-temperature conditions, having a high CTI value and meeting the UL94 V0 flame retardant rating.

The application discloses nitrogen-doped iron phosphide and a preparation method thereof, a negative electrode material, a secondary battery and an electric equipment, and the preparation method comprises the following steps: S1, dissolving iron salt and urea in an organic solvent to obtain a mixed solution; then, performing a solvothermal reaction on the mixed solution to obtain an iron phosphide precursor; and S2, performing phosphorization treatment on the iron phosphide precursor by using a hypophosphite under a protective atmosphere to obtain the nitrogen-doped iron phosphide. The nitrogen-doped iron phosphide prepared by the method overcomes the problems of large irreversible capacity and low electronic conductivity of the iron phosphide negative electrode material.

The application discloses a fire-resistant and burn-resistant nylon composition and a preparation method and application thereof. The nylon composition comprises the following components in parts by weight: 28-60 parts of aliphatic nylon resin, 4-15 parts of semi-aromatic nylon resin, 18-32 parts of glass fiber, 12-21 parts of hypophosphite, 3-9 parts of flame-retardant synergist, and 1-4 parts of carbonation promoter, wherein a mass ratio of the hypophosphite to the flame-retardant synergist is (2-4) to 1; a relative viscosity of the aliphatic nylon resin is 2.6-2.9; and the carbonation promoter is rare earth oxide or zinc stannate. The organic phosphorus flame-retardant nylon composition has excellent flame-retardant performance and fire-resistant performance, and can also have high mechanical performance.

The invention discloses a preparation method and application of a Ni2P-loaded rare earth doped nickel-based micro-mesoporous material, and the method comprises the following steps: jointly dissolving hypophosphite, nickel salt and rare earth metal salt in a solvent for hydrothermal reaction, cleaning, drying and grinding the product to obtain rare earth metal doped nickel phosphite with a micro-mesoporous structure, and drying to obtain the Ni2P-loaded rare earth doped nickel-based micro-mesoporous material. And under the protection of inert atmosphere, co-calcining the Re-NiPO and phosphite in a non-mixing manner, and carrying out phosphating reaction to form nickel phosphide particles on the surface and in pores of the Re-NiPO, thereby obtaining the Ni2P-loaded rare earth doped nickel-based micro-mesoporous material. A series of Ni2P-coated Re-NiPO (Re = La, Ce, Sm) heterojunction materials are prepared through a hydrothermal-phosphating method, and the hard magnetic property and the catalytic activity can be improved at the same time.

The invention provides an iron nickel phosphide coated NiMoO4 nano array electrocatalyst as well as a preparation method and application thereof. The preparation method comprises the following steps: S1, dissolving a first nickel salt and a molybdenum source in water, carrying out first heating reaction together with foamed nickel, and carrying out heat preservation, so that a NiMoO4 nano array grows on the surface of the foamed nickel to obtain a product; s2, ammonium fluoride, urea, ferric salt and second nickel salt are dissolved in water and then mixed with a product obtained in the step S1, a second heating reaction is conducted, heat preservation is conducted, a FeNi-LDH shell layer grows on the surface of the NiMoO4 nano array, and a product is obtained; s3, hypophosphite and a product obtained in the step S2 are subjected to high-temperature phosphating treatment, FeNi-LDH is converted into a Fe3P / Ni3P heterojunction structure, and the NiMoO4 nano array electrocatalyst coated with the iron-nickel phosphide is obtained. The electrocatalyst has a relatively high active surface area, and has relatively good catalytic performance and stability when being used for electrolyzing seawater.

This invention proposes a boron-phosphorus co-doped multi-element alloy catalyst supported on a metal oxide substrate, its preparation method, and its application. It belongs to the technical field of sodium borohydride hydrolysis hydrogen production materials. The method involves loading cobalt salts (such as cobalt chloride or cobalt nitrate), iron salts (such as ferric chloride or ferric nitrate), and hypophosphite (such as sodium hypophosphite) onto a support (such as γ-alumina or titanium dioxide) using an initial wet impregnation method. Sodium borohydride solution is added for chemical reduction, and boron is added for doping. After washing the reduction product, the catalyst is dried to obtain the supported boron-phosphorus co-doped multi-element alloy catalyst. When used as a sodium borohydride hydrolysis hydrogen production catalyst, it provides a maximum hydrogen production rate of 12729.78 mL·g under optimal conditions. cat ‑1 ·min ‑1 It produces 100% of the theoretical hydrogen yield and features good catalytic performance, simple preparation method, abundant raw materials, and low cost.

The invention discloses a polypropylene composition and a preparation method and application thereof. The polypropylene composition comprises the following components by weight: 90-95 parts of polypropylene; 1-2 parts of hypophosphite; 0.5-2 parts of bromine flame retardant; 0.2-0.5 parts of flame retardant synergist; 0.1-0.4 parts of primary antioxidant; 0.1-0.4 parts of auxiliary antioxidant; 0.2-0.4 parts of hindered amine light stabilizer other than N-substituted alkoxy hindered amine; the flame retardant synergist is one or more of N-substituted alkoxy hindered amines. The polypropylene composition provided by the invention has the advantages of high temperature failure resistance, long powdering time and not easy to change color during processing.

The organic phosphonate flame retardant prepared by the invention is obtained by reacting dialkyl hypophosphorous acid or dialkyl hypophosphite with halogenated alkyl phosphine oxide in a solvent and then separating and purifying, the synthesis method is simple, the use of high-pollution and high-toxicity substances is avoided, the synthesis structure is clear, and the temperature resistance is not influenced by residues of reactive hydrogen on phosphorus. Meanwhile, the synthesized ester group-containing organic phosphonate flame retardant provides better flame retardant property under the condition of lower additive amount, and the resin has higher retention rate of mechanical property and electrical property due to the low additive amount.

The present application relates to waste liquid treatment technical field, specifically to a kind of from chemical nickel plating waste liquid high-efficiency separation nickel, hypophosphorous acid and ammonia method, comprising the following steps: S1, nanofiltration: using roll nanofiltration membrane to chemical nickel plating waste water is nanofiltration separation, obtain containing nickel waste water, containing hypophosphorous acid and ammonia waste water;S2, bipolar membrane electrodialysis: the arrangement mode of bipolar membrane electrodialysis system is set to: the anode, first bipolar membrane, anion membrane, cation membrane, second bipolar membrane, cathode are sequentially arranged, containing hypophosphorous acid and ammonia waste water is passed into desalination room, deionized water is added in the acid room and base room, obtain hypophosphorous acid solution and ammonia gas;Then realize the separation of hypophosphorous acid and ammonia;The hypophosphite in the present application, ammonium in chemical nickel plating waste liquid is efficiently separated, and it is important to improve the phosphorus, ammonia resource utilization efficiency in chemical nickel plating waste liquid, reduce chemical nickel plating waste liquid processing difficulty and processing cost.

The invention relates to the technical field of hypophosphite synthesis, and provides a hypophosphite synthesis device and method.The hypophosphite synthesis device comprises a reaction tower body and further comprises a three-stage reaction mechanism, a liquid separation mechanism, a reaction prolonging mechanism, an anti-scaling mechanism and a bottom discharging mechanism; the liquid separation mechanism is mounted in the reaction tower body, the liquid separation mechanism is matched with the three-stage reaction mechanism and is used for uniformly distributing product liquid at a reaction position, the reaction extension mechanism is mounted in the reaction tower body and is used for delaying the time of a reaction product entering a next-stage reaction, and the anti-scaling mechanism is mounted in the reaction extension mechanism and is used for washing blocked yellow phosphorus particles. By means of the technical scheme, the problems that in the prior art, the maintenance process of a reaction tower is tedious, the tower needs to be disassembled for cleaning internal components, and the production efficiency is greatly influenced by frequent shutdown inspection and maintenance are solved.

The invention belongs to the field of flame retardant preparation and application, and discloses flame-retardant modified hypophosphite and a preparation method thereof.The flame-retardant modified hypophosphite is of a double-layer coating structure, the inner core is hypophosphite, the inner layer is phosphite, and the outer layer is cyanurate; the preparation method of the flame-retardant modified hypophosphite comprises the following steps: firstly, jointly adding the hypophosphite and the soluble metal salt into water, heating to 80-100 DEG C, stirring for 15-30 minutes, then adding the alkaline substance I into the water, keeping the temperature to react for 0.5-4 hours, adding the phosphorous acid, continuing to react for 0.5-4 hours, then adding the alkaline substance II into the water, stirring for 15-30 minutes, adding the cyanuric acid, keeping the temperature to react for 0.5-4 hours, and performing post-treatment to obtain the flame-retardant modified hypophosphite. The flame-retardant modified hypophosphite prepared by the method does not belong to inflammable solids, and is high in thermal decomposition temperature, better in safety, reasonable in preparation process, high in product yield, wide in raw material source and easy for industrial production.

The invention discloses a copper bar surface anti-oxidation treatment process, and belongs to the technical field of metal material surface protection and corrosion resistance evaluation, and the copper bar surface anti-oxidation treatment process comprises the following steps: carrying out film removal activation and micro roughening treatment on a copper bar; the copper bar is placed in an aqueous solution containing hypophosphite or phosphate and treated for 1-5 minutes at the temperature of 60-90 DEG C, so that a P-enriched interface layer is formed on the copper surface layer, and the P atomic fraction of the interface layer is 2%-8%; depositing an aluminum oxide or titanium oxide thin layer on the interface layer by adopting an atomic layer deposition process, wherein the substrate temperature is 80-120 DEG C and the total thickness is 5-30 nm; a phosphorus-rich interface layer is constructed in sequence, a compact inorganic thin layer is deposited, low-energy pulse laser sealing is implemented, and a silicon-oxygen sealing layer containing a two-dimensional sheet layer is formed, so that the oxygen blocking capability and the appearance stability can still be considered under the thin layer condition; the problem that electricity and color are difficult to stabilize at the same time when the thickness of a traditional single-layer or random laminated film is limited is solved.

The hypophosphite is used for inhibiting a syntrophic methanogenesis effect or the growth of hydrogen nutritional methanogens, and a plant gene is modified to contain and express a heterologous hypophosphite / 2-oxoglutarate dioxygenase htxa gene, so that reduced phosphorus, such as hypophosphite, can be used as a phosphorus source; and hypophosphite and phosphite fertilizer modifiers are used as phosphorus sources for soil microorganisms to increase carbon storage in deep deposits.

The invention discloses an oxygen-vacancy-rich Nb2O5 material and a preparation method thereof, a negative pole piece and a zinc ion battery, and belongs to the technical field of batteries. The preparation method comprises the following steps: S1, mixing a niobium source, quaternary ammonium base and a solvent to obtain initial gel; s2, heating the initial gel, and carrying out a reaction so as to obtain an Nb2O5 precursor; and S3, calcining the Nb2O5 precursor and hypophosphite in an inactive atmosphere to obtain the oxygen vacancy-enriched Nb2O5 material. The Nb2O5 negative electrode material for the zinc ion battery is developed for the first time, and the oxygen-vacancy-rich Nb2O5 material prepared by adopting a solvothermal and reduction dual-regulation mode has high oxygen vacancy density and good structural stability; the prepared rocking chair type battery structure avoids the problems of dendritic crystals, rusting, hydrogen precipitation and the like caused by a traditional metal zinc negative electrode, and is high in safety and long in cycle life.

The foamed polypropylene resin particles contain an inorganic hypophosphite and a melamine flame retardant. The amount of the inorganic hypophosphite blended in the foamed particles is 0.5% by mass or more, the amount of the melamine-based flame retardant blended in the foamed particles is 0.05% by mass or more, and the total of the amount of the inorganic hypophosphite blended in the foamed particles and the amount of the melamine-based flame retardant blended in the foamed particles is 5% by mass or less. The foamed particles further comprise a first antioxidant comprising a phenolic antioxidant and a second antioxidant comprising a phosphorus-based antioxidant and / or a sulfur-based antioxidant. The total of the blending amount of the first antioxidant and the blending amount of the second antioxidant in the foamed particles is 0.05% by mass or more and 0.6% by mass or less, and the ratio of the blending amount of the second antioxidant to the blending amount of the first antioxidant is 0.5-10.

The application belongs to the technical field of aluminum diethyl hypophosphite synthesis, and particularly relates to a preparation method and application of aluminum diethyl hypophosphite. The preparation method of the aluminum diethyl hypophosphite comprises the following steps: mixing soluble hypophosphite and a first solvent in a reactor to obtain a soluble hypophosphite solution; replacing air in the reactor with nitrogen and heating; introducing ethylene into the soluble hypophosphite solution to obtain a reaction solution; mixing an initiator, a catalyst and the reaction solution, reacting, obtaining a diethyl hypophosphite solution, adding a second solvent to obtain a diluted diethyl hypophosphite solution; adjusting the pH of the diluted diethyl hypophosphite solution to be acidic, adding an aluminum sulfate aqueous solution, and reacting to obtain the aluminum diethyl hypophosphite. The initiator comprises an oxidizing agent and a reducing agent. The application can reduce the reaction temperature to 22-50 DEG C, reduce energy consumption, improve the reaction efficiency, and obtain the aluminum diethyl hypophosphite with high purity and high yield.

The invention relates to a chemical nickel plating wastewater treatment agent and a treatment method. The treatment agent comprises the following components: 1-5 wt% of sodium tungstate, 50-60 wt% of ferrous sulfate, 15-20 wt% of aluminum sulfate, 10-15 wt% of magnesium sulfate and 10-15 wt% of calcium chloride. The treatment method comprises the following steps: S1, adjusting the pH value of the chemical nickel plating wastewater to be treated to 2-3; s2, carrying out iron-carbon micro-electrolysis on the chemical nickel-plating wastewater treated in the step S1; s3, adding the chemical nickel-plating wastewater treatment agent according to any one of claims 1-3 into the chemical nickel-plating wastewater treated in the step S2, uniformly stirring, and adding an oxidizing agent for oxidation; and S4, adjusting the pH value of the chemical nickel-plating wastewater treated in the step S3 to 4.5-6, then adding a flocculating agent for flocculation, and carrying out solid-liquid separation. According to the method, hypophosphite and heavy metal in the chemical nickel-plating wastewater can be efficiently removed at low cost.

The invention discloses a low-consumption and environment-friendly hypophosphite purification process, and belongs to the technical field of hypophosphite purification. Comprising the following steps: S1, heating and dissolving hypophosphite raw material powder and ultrapure water according to a certain proportion, mixing, and filtering by adopting a microfiltration membrane to remove particulate matters; s2, adding a proper amount of chelating agent into the filtrate of the hypophosphite, conveying the filtrate into a dynamic crystallization kettle, and slowly cooling and crystallizing; s3, separating hypophosphite mother liquor from crystals, and drying the hypophosphite crystals; and S4, purifying the hypophosphite mother liquor by using macroporous adsorption resin so that the hypophosphite mother liquor is used for the crystallization process of a new batch of materials again.

The present invention relates to a histidine hypophosphite inorganic-organic hybrid nonlinear optical crystal and its preparation and application. The chemical formula of the optical crystal is A(H2PO2), wherein A is L-C6H 10 N3O2 or D‑C6H 10 N3O2; belongs to the monoclinic system, space group is P21, unit cell parameters are α=γ=90°, β=99.0~99.4°, Z=2. The crystal of the present invention (L-C6H 10 N3O2)(H2PO2) and (D‑C6H 10 The birefringence of N3O2 (H2PO2) at 546nm is 0.084 and 0.058. Under 1064nm laser irradiation, its powder SHG coefficient is 1 and 2 times that of KH2PO4 (KDP), and phase matching is achieved under 1064nm laser irradiation. Furthermore, the ultraviolet absorption cutoff edges of this crystal material are 233nm and 234nm, corresponding to optical band gaps of 5.32eV and 5.30eV, respectively, showing broad application prospects in the field of ultraviolet lasers.

The invention discloses a nickel-based catalyst as well as a preparation method and application thereof. The preparation method of the nickel-based catalyst comprises the following steps: S1, carrying out electro-deposition on a deposition solution in a three-electrode system taking foamed nickel as a working electrode; a precursor material is obtained; the deposition liquid comprises nickel salt, cobalt salt, thiourea and a phosphorus source; the phosphorus source comprises hypophosphite and / or phosphite; and S2, carrying out annealing treatment on the precursor material. The nickel-based catalyst prepared by the preparation method disclosed by the invention is applied to a urea oxidation reaction and has relatively good catalytic activity and stability.

The application discloses a water-based fire-retardant coating special fire-retardant agent and a preparation method thereof. The application firstly prepares a melamine cyanurate microencapsulated hypophosphite phosphorus-nitrogen synergistic fire-retardant system through chemical bonds and hydrogen bonds, then carries out hyperbranched silane modification, and finally forms a firm dendritic structure on the surface of the hyperbranched phosphorus-nitrogen synergistic fire-retardant system through post-chain extension crosslinking in a water-based coating polycondensation reaction and emulsification reaction, so as to obtain the water-based fire-retardant coating special fire-retardant agent. The fire-retardant agent has good fire-retardant effect when applied in the water-based coating, low system viscosity, good compatibility with a matrix, good dispersibility and good migration and precipitation resistance, and the hyperbranched silane modification has a certain crosslinking degree, so that the contact angle and the mechanical properties of the matrix are improved.

To provide a transformant exhibiting a containment effect independent of phosphorous acid.SOLUTION: The transformant is deficient in functions of a gene encoding a phosphate transporter protein and a gene encoding a phosphate ester transporter protein, and has a gene encoding a hypophosphite-specific transporter protein introduced thereinto.SELECTED DRAWING: Figure 1

The invention relates to a preparation method and application of hypophosphorous acid double salt, and the preparation method comprises the following steps: I, adding water and various metal salts into an ultrasonic grinding reactor, and starting the ultrasonic grinding reactor to obtain metal salt slurry; iI, adding sodium hypophosphite and water into a reaction kettle for dissolving and clarifying, heating to 70-90 DEG C, adding the first batch of metal salt slurry, uniformly stirring, adding the sol, and continuously stirring and reacting for 1-2 hours; and III, after the reaction is completed, heating to 90-110 DEG C, adding a second batch of metal salt slurry, regulating the pH value of the system by using a pH buffer reagent, controlling the pH value to be 4.0-8.0, and stirring to react for 1-3 hours. According to the invention, the problems in the prior art that particles formed by agglomeration of hypophosphite crystals produced by an inorganic double decomposition synthesis method are irregular and large in particle size, so that the product is large in particle size and wide in distribution, and the flame retardance, the mechanical property and the like of the product are unfavorably influenced are solved.

The application is a kind of O3 type sodium ion battery positive electrode material of reducing method induced residual base conversion. The chemical formula of the positive electrode material is Na 1+x Ni 0.33 Fe 0.33 Mn 0.33 P x O 2+2x In the preparation, the selected reducing acid salt, including but not limited to hypophosphite or bisulfite, is used as a residual base eliminator and a reducing agent, and through grinding and calcination, the mechanism of acid-base neutralization reaction and redox reaction is used to realize the functions of residual base conversion coating and surface coordination environment adjustment. The first coulombic efficiency of the battery obtained by the application is as high as 94%, the voltage hysteresis is greatly reduced, the capacity retention rate after 300 cycles at 1C is increased from 38% to 84%, and a new generation of coating scheme with great potential for scaling is provided for layered positive electrode materials.

To provide a method of manufacturing a printed wiring board which is excellent in formation accuracy even with a small L / S, can form a circuit pattern having high adhesion, and is excellent in working environment.SOLUTION: A method for producing a printed wiring board, comprising the following steps 1 to 7 in this order: Step 1: A step of attaching a first catalyst to a surface of an insulating material. Step 2: a step of adhering a second catalyst containing at least nickel to the surface of the insulating material by bringing the insulating material into contact with an electroless nickel plating solution containing hypophosphite as a reducing agent. Step 3: a step of forming a seed layer by contact with an electroless copper plating solution containing hypophosphite as a reducing agent. Step 4: a step of forming a resist pattern on the surface of the seed layer. Step 5: a step of forming a copper layer by electrolytic copper plating in a region exposed from the resist pattern. Step 6: Step of removing the resist pattern. Step 7: a step of removing the exposed seed layer and the first catalyst and the second catalyst between the seed layer and the insulating material to obtain a circuit pattern.SELECTED DRAWING: Figure 1

The invention relates to the field of zinc ion batteries, in particular to a zinc ion battery manganese dioxide-manganese phosphide heterojunction material and a preparation method thereof.The preparation method comprises the steps that potassium peroxydisulfate, potassium sulfate and divalent manganese salt are dissolved in deionized water and added into a concentrated sulfuric acid solution, and a first reaction solution is obtained; keeping the temperature at 140 DEG C for 12-24 hours to obtain a second reaction solution; washing and drying to obtain first powder; adding deionized water, stirring and uniformly dispersing to obtain a third reaction solution; performing ultrasonic dispersion on the graphene slurry in ethanol to obtain a fourth reaction solution; uniformly stirring the third reaction solution and the fourth reaction solution, and washing and drying a second solid precipitate obtained by filtering to obtain second powder; carrying out heat preservation on the second powder and hypophosphite in a nitrogen atmosphere at 450 DEG C for 2-4 hours, and washing and drying an obtained third solid precipitate; the manganese dioxide-manganese phosphide heterojunction material for the zinc ion battery can improve the electron transmission efficiency of manganese dioxide.