651 results about "Nickel ions" patented technology

The invention provides a precipitation method of a heavy metal solution. Cations in the heavy metal solution comprise nickel ions, cobalt ions, copper ions, zinc ions and manganese ions, and the precipitation method comprises the following steps: step S100, carrying out a manganese conversion reaction on an alkaline substance by adopting a solution containing manganese ions to obtain a converted manganese precipitate; s200, a stabilizing agent is adopted for carrying out a stabilizing reaction on the converted manganese precipitate, and a stable manganese precipitate is obtained; step S300, adding the stable manganese precipitate into a heavy metal solution for precipitation reaction to obtain precipitate slurry; step S400, continuously carrying out solid-liquid separation on the precipitate slurry to obtain a heavy metal precipitate and a manganese-containing solution; and S500, raw materials including the manganese-containing solution, an oxidizing agent and alkali liquor are subjected to an oxidation precipitation reaction, and a post-precipitation solution and a manganese product are obtained. The method solves the problems of poor sedimentation and filtration performance of a precipitation product, high moisture content of the precipitation product and low precipitation efficiency when heavy metals are precipitated in the heavy metal solution.

The invention discloses a nickel-containing etching wastewater treatment process, which belongs to the technical field of environmental protection, and comprises a raw water regulating tank, a pH pre-regulating tank, a heterogeneous catalytic oxidation tower, a neutralization coagulation tank, an inclined tube sedimentation tank and a clean water tank which are connected in sequence. According to the process, under the neutral condition, a catalyst loaded with cobalt manganese oxide is used for activating sodium hydrogen persulfate, high-activity sulfate free radicals are generated, a Ni-EDTA complex structure is fractured in a targeted mode, free nickel ions are released in situ, organic ligands are synchronously mineralized, and the adding amount of sodium hydrogen persulfate is dynamically adjusted through a clean water pool closed-loop control system; and high-purity nickel hydroxide precipitate is generated through alkaline precipitation and coagulation, so that efficient solid-liquid separation is realized. The treatment process disclosed by the invention is compact in flow and stable in operation, effectively solves the problems of difficult complex breaking, low nickel removal efficiency, high sludge toxicity, difficult resource recovery and the like when the EDTA complex nickel wastewater is treated by a traditional method, realizes closed-loop recovery of nickel resources, and has the remarkable advantages of low cost, high efficiency and environmental friendliness.

The invention discloses a foam iron-nickel surface in-situ growth platinum modified nickel-iron layered double hydroxide bifunctional material and a preparation method and application thereof.The preparation method comprises the steps that a foam iron-nickel substrate is immersed in an acid solution containing chloroplatinic acid, heating treatment is conducted for a certain period of time, and then the nickel-iron layered double hydroxide bifunctional material is obtained; and a nickel-iron layered double-metal hydroxide mixed material modified by platinum nanoparticles grows on the surface of the foam iron-nickel in situ. In the preparation process of the one-step method, nickel ions or / and iron ion salts and sacrificial agents do not need to be additionally added, atom economy is good, reaction conditions are mild, energy consumption is low, and meanwhile the problem that the catalyst is prone to falling off due to multiple times of operation and washing is solved. The platinum / ferronickel layered bimetal hydroxide / foam iron nickel electrode prepared by the method shows excellent hydrogen production and oxygen production activity in an alkaline water electrolysis reaction.

The invention relates to a preparation method of a nickel ion doped modified ferric sodium pyrophosphate positive electrode material, and belongs to the technical field of sodium ion battery positive electrode materials. The nickel ion doped modified ferric sodium pyrophosphate positive electrode material is prepared by adopting an integrated process system of liquid phase uniform mixing, spray granulation and precise segmented calcination. According to the process system, atomic-scale uniform doping of nickel ions and a specific microstructure of a precursor are realized through spray drying, and a plurality of inherent key technical problems of low electronic conductivity, low ion diffusion rate, impurity phase generation and the like of an NFPP material are solved together through a synergistic effect with a subsequent calcining process; furthermore, the discharge capacity of the ferric sodium phosphate pyrophosphate composite material at high rate is improved, so that the battery has relatively high cycling stability.

The invention provides a modified porous chitosan gel bead, a preparation method thereof and application of the modified porous chitosan gel bead in cobalt-nickel separation, and belongs to the technical field of chitosan preparation. The preparation method comprises the following steps: firstly, modifying chitosan by using polyethylene glycol and glutaraldehyde to obtain a porous chitosan gel bead with a cross-linked structure, and then grafting by using epichlorohydrin, ethylenediamine and 2-chloromethylpyridine hydrochloride to obtain the modified porous chitosan gel bead containing an aminomethylpyridine functional group. The modified porous chitosan gel bead has excellent selective adsorption on nickel ions in a cobalt-nickel solution with the pH value range of 2-5, and nickel-cobalt separation can be achieved. In addition, the modified porous chitosan gel bead also has a good nickel-cobalt separation effect in a salt-containing system. The preparation method of the modified porous chitosan gel bead provided by the invention is simple in process, and the raw material chitosan is wide in source, non-toxic and environment-friendly.

To provide a positive electrode active material for a lithium ion secondary battery, having high capacity and being excellent in charging and discharging cycle characteristic.SOLUTION: A positive electrode active material contains lithium, cobalt, nickel, aluminum, and oxygen. The spin density due to any one or more of divalent nickel ions, trivalent nickel ions, divalent cobalt ions, and tetravalent cobalt ions is in a predetermined range. The positive electrode active material further contains magnesium. The suitable magnesium concentration is expressed by the concentration relative to cobalt. The positive electrode active material preferably contains fluorine additionally.SELECTED DRAWING: Figure 1

The invention discloses a method for controlling ion concentration and volume balance in an electrolyte by using nickel hydroxide. The method comprises the following steps: preparing a reaction base solution containing a first complexing agent and a first alkali; the first anolyte, a second complexing agent solution and a second alkali solution are simultaneously added to the bottom of the reaction base solution for stirring reaction, solid-liquid separation is performed after nickel hydroxide reaches the target particle size, and filtrate and a filter cake are obtained; washing the filter cake, and slurrying the filter cake by using a second anolyte to obtain a nickel hydroxide slurrying material; and adjusting the sodium ion concentration, pH and nickel ion concentration of the third anolyte by adopting a sodium hydroxide solution, a nickel hydroxide slurrying material and a nickel sulfate solution to obtain the catholyte. According to the invention, a feeding mode of feeding at the bottom is adopted, and a complexing agent is matched, so that crystals can stably grow and are convenient to filter; in the preparation process, aging and too high pH conditions are not needed, operation is simpler, labor intensity is small, the reaction rate is higher, and continuous treatment of the anolyte can be achieved.

The invention provides a preparation method of a nickel-based composite oxygen evolution anode for alkalescent electrolyte. According to the invention, nickel-based alloy is used as substrates, two same substrates are respectively used as a working electrode and an auxiliary electrode, two-electrode system electrochemical oxidation reduction treatment at room temperature is carried out in a mixed solution of phosphate, carbonate and chloride, and two reconstructed nickel-based composite oxygen evolution electrodes are obtained at the same time. In the electrochemical oxidation process, nickel ions and other metal (Fe, Co, Cr and Mn) ions are dissolved out from the nickel-based alloy under the etching assistance of chloride ions; in the electrochemical reduction process, water on the electrode is reduced to form hydroxyl. Under continuous oxidation reduction, substance reconstruction is carried out to generate a composite catalyst layer of phosphate, carbonate and hydroxide of nickel and other metals, so that not only can the oxygen evolution activity be improved, but also metal dissolution and corrosion passivation when the catalyst is used in a weakly alkaline solution can be inhibited, and the durability of the electrode is greatly improved.

The invention belongs to the technical field of conductive microsphere preparation, and particularly relates to a surface-roughened nickel-plated conductive microsphere and a preparation method and application thereof. The preparation method comprises the following steps: carrying out pretreatment to enable the surfaces of the polymer microspheres to contain nickel ions, reducing the nickel ions into nickel nanoparticles, activating the microspheres and carrying out chemical plating. According to the invention, the specific surface area of the conductive microspheres is increased by reducing the nickel nanoparticles on the surfaces of the microspheres, a large amount of impurities cannot be generated among the microspheres, and adhesion among the microspheres can be effectively prevented. According to the prepared conductive microspheres, the plating layer and the polystyrene microspheres are firmly combined, and the risk that the conductivity is reduced due to the fact that the surface of the plating layer falls off is reduced. The preparation method is safe, environment-friendly, simple, convenient and suitable for industrial production requirements.

The invention discloses a NiCrAl structured catalyst as well as a preparation method and an application method thereof. The catalyst contains NiCrAl layered double hydroxides (NiCrAl-LDHs) and a metal substrate, the NiCrAl-LDHs vertically grow on the surface of the metal substrate in situ, nickel ions, chromium ions and aluminum ions in the NiCrAl-LDHs structure come from the metal substrate, and the preparation method comprises the following steps: dissolving urea in water to prepare a urea aqueous solution; and putting the metal substrate into the urea aqueous solution, and carrying out hydrothermal reaction to obtain the composite material. The application method of the catalyst comprises the following steps: introducing current into the catalyst in a reaction atmosphere, and driving the catalytic reaction by using Joule heat generated by the current. The NiCrAl structured catalyst provided by the invention has the characteristics of simple preparation method, less chemical reagent dosage, excellent catalytic performance, easiness in batch production and the like, and is very suitable for application of electrothermal catalysis.

The invention provides a nickel-tungsten alloy electroplating solution, a preparation method thereof and a preparation method of a solar cell metal electrode, and particularly relates to the technical field of solar cell preparation. The nickel-tungsten alloy electroplating solution provided by the invention comprises nickel salt, tungstate, a complexing agent, a wetting agent and water. In the nickel-tungsten alloy electroplating solution provided by the invention, on the basis of nickel salt and tungstate, a uniform and compact nickel-tungsten alloy layer can be formed on the surface of a plated part, and the layer of alloy combines the electrical conductivity of nickel and the corrosion resistance and high hardness characteristics of tungsten, so that the comprehensive performance of the plated part is remarkably improved. And the complexing agent is added, so that the activity of nickel ions and tungsten ions and the electrodeposition process are effectively controlled, and the quality and the production efficiency of a plating layer are optimized. And the wetting agent is used, so that the wettability of the plating solution on the surface of a plating piece is improved, uniform deposition of an alloy layer is promoted, pores and defects are reduced, and the binding force and durability of a plating layer are enhanced.

The invention discloses an alkaline electrolyzed water diaphragm based on nickel oxyhydroxide and a preparation method and application of the alkaline electrolyzed water diaphragm, and relates to the technical field of composite diaphragms.The alkaline electrolyzed water diaphragm is prepared through a phase inversion method, and nanometer nickel oxyhydroxide NiOOH particles are selected as inorganic nanometer filler; the mass percent of the nickel oxyhydroxide in the membrane casting solution is 15-30%. A strong chemical bond formed by nickel ions and hydroxyl in the hydroxyl nickel oxide crystal endows the material with excellent structural stability, and the material shows excellent solubility resistance, hydrolysis resistance and structural collapse resistance in a strong alkaline electrolysis environment and can tolerate high-concentration OH <-> erosion for a long time; meanwhile, the intrinsic high-oxidation-resistance characteristic is achieved.

The invention discloses a process for treating nickel wastewater containing nickel acetate cleaning water and nickel acetate concentrated water, which comprises the following steps: S1, filtering nickel wastewater, S2, carrying out primary concentration treatment, S3, carrying out secondary concentration treatment, S4, treating by a sodium metaaluminate method, S5, carrying out collaborative filtration treatment, and S6, discharging RO (Reverse Osmosis) produced water up to the standard. The method comprises the following steps: primarily enriching nickel ions by adopting primary nickel concentration treatment and secondary nickel concentration treatment, adding a sodium metaaluminate solution into a mixed solution, enabling the pH value of the mixed solution to be 8-12, enabling the nickel ions to react with hydroxyl ions to generate a nickel hydroxide precipitate, adding a sulfuric acid solution to adjust the pH value of the mixed solution back to 6.5-7.5, hydrolyzing sodium metaaluminate to generate an aluminum hydroxide precipitate, and carrying out secondary nickel concentration treatment on the aluminum hydroxide precipitate; aluminum hydroxide adsorbs nickel hydroxide to form a composite precipitate, aluminum ions and nickel ions are subjected to a competitive complexation reaction, and a flocculating agent is added into a mixed solution to form a flocculent precipitate, so that the reaction time is short, the nickel content in the nickel sludge can be greatly increased, the treatment period can be shortened, and the operation cost can be reduced.

The invention discloses a method for preparing a conductive ceramic with controllable resistivity, and relates to the technical field of conductive ceramics. The invention adopts three different particle sizes of aluminum oxide, titanium nitride, and silicon dioxide to form a ceramic slurry, which reduces the possibility of deformation, and adjusts the amount of titanium nitride added to adjust the ceramic resistivity, thereby realizing the controllable resistivity of the ceramic; the invention adopts methacrylic acid glycidyl ether and starch to form a gel skeleton, and uses amino-treated nanographite sheets as a support to ensure the mechanical strength of the ceramic; the ceramic slurry is used as a core material, and then a layer of gel is wrapped around the outer layer of the core material, and a three-stage high-temperature sintering treatment is performed to optimize the strength of the ceramic, while making the zirconium ions and nickel ions doped with the gel combine with the lanthanum ions in the atomized liquid, and form a zirconium-nickel-lanthanum-carbon crystal structure under a H2O / O2 atmosphere, which greatly improves the conductivity of the gel layer, thereby forming a uniform and continuous conductive path on the surface and inside of the ceramic.

The invention discloses a method for recycling iron phosphate from chemical nickel-plating waste liquid, which belongs to the technical field of industrial wastewater treatment and recycling, and comprises the following steps: S1, chemical nickel-plating waste liquid pretreatment: putting the chemical nickel-plating waste liquid into an electrolytic bath for electrolytic treatment, adding calcium salt into the electrolyzed waste liquid to remove sulfate ions, adding a sodium hydroxide solution to further remove nickel ions to obtain nickel-removed waste liquid; s2, Fenton oxidation: adding hydrogen peroxide and a surface-modified coated nano zero-valent iron Fenton catalyst into the nickel-removed waste liquid, and carrying out Fenton oxidation to obtain iron phosphate precipitate; s3, separating the iron phosphate precipitate from the wastewater; s4, electro-Fenton oxidation: finally, carrying out electro-Fenton oxidation on the cleaning wastewater and the wastewater subjected to filter pressing to obtain iron phosphate precipitate. The efficiency and purity of recovering iron phosphate from the chemical nickel-plating waste liquid are improved, and the problems of low iron phosphate recovery rate and insufficient catalyst stability in the prior art are solved.

The utility model relates to the technical field of sewage treatment, and provides a multistage capacitive deionization device for electroplating wastewater, which comprises a box body, a quick dismounting mechanism is arranged in the box body, and the quick dismounting mechanism comprises five groups of sliding strips which are in sliding connection with preformed grooves in the inner wall of the box body; a cation filtering layer, an anion filtering layer, a nickel ion adsorption layer, a medium filtering layer and an activated carbon filtering layer are fixedly connected to the side surfaces, close to each other, of each group of sliding strips respectively. By means of the technical scheme, the problem that in the prior art, by arranging the sliding strips, use can be conducted by changing the installation positions of all the laminates is solved, and by arranging the fixing frames, the fixing rods, the L-shaped clamping strips and the clamping blocks, rapid self-locking can be conducted after the laminates are installed, so that nickel ions can be rapidly treated after being adsorbed, and the service life of the nickel ions is prolonged. And each laminate can be conveniently cleaned and replaced, and the problem that the subsequent use effect is affected by much dirt adhered to the surfaces of the laminates is avoided.

The application provides a preparation method of an octene aldehyde liquid-phase hydrogenation catalyst, and steps of the method comprise the following: (1) preparing a salt solution containing nickel ions, copper ions and aluminum ions, heating to 40-80 DEG C, adding a basic precipitator to react, and aging after the reaction is completed; (2) uniformly mixing the precipitate obtained after aging in step (1) with silica sol to obtain slurry; (3) washing and filtering the slurry, then adding alkali metal carbonate powder and boron nitride solid, uniformly mixing, and then shaping, drying and calcining to obtain the octene aldehyde liquid-phase hydrogenation catalyst. The preparation method is simple, green, environmentally friendly and easy to industrialize, the conversion rate and selectivity of the obtained octene aldehyde liquid-phase hydrogenation catalyst are high, and the catalyst is stable in performance and durable.

The invention relates to the field of resin synthesis, in particular to functionalized hierarchical pore adsorption chelating resin as well as a preparation method and application thereof. According to the functionalized hierarchical pore adsorption chelating resin, the particle size is 0.65-1.2 mm, the specific surface area is 550-1500 m < 2 > / g, the pore volume is 0.4-1.8 cm < 3 > / g, the proportion of micropores is 15-35%, the proportion of mesopores is 25-40%, and the proportion of macropores is 25-60%. Micropores, mesopores and macropores of the functionalized hierarchical pore adsorption chelating resin are uniformly distributed, the particle size is moderate, the specific surface area and pore volume are relatively large, and the functionalized hierarchical pore adsorption chelating resin has relatively large adsorption capacity on copper ions, nickel ions and lead ions.

The invention provides a preparation method of nickel-carbon conductive shielding foam, which comprises the following steps: S1, mixing carbon nanotubes and cerium oxide in proportion, and adding nano nickel powder to form a suspension; adding a reducing agent to carry out reduction reaction so as to deposit nickel ions on the surfaces of the carbon nanotubes and the cerium oxide particles; s2, mixing the nickel-carbon nanotube-cerium oxide composite powder with an ionic liquid dispersant, mixing organic silicone oil and silicone rubber to serve as a matrix, then adding polyfuran and maleimide, and adding a silane coupling agent to be fully combined; adding the dispersed composite powder into an organic silicon matrix, continuously stirring until the materials are uniformly mixed, then adding a platinum catalyst and a cross-linking agent, pouring the mixture into a mold, and curing to form foam; s3, pasting a conductive layer; S4, setting a bonding layer; and S5, setting an isolation layer. By adopting the nickel-carbon nanotube-cerium oxide composite material, the electromagnetic shielding performance of the foam is greatly improved. The ultra-thin self-repairing function is also realized.

The invention relates to the technical field of lead frame coarsening, in particular to a nickel coarsening process of a lead frame. A nickel coarsening process of a lead frame comprises the following procedures of oil removal, acid pickling, nickel electroplating coarsening and acid pickling, the nickel electroplating coarsening refers to that an electroplating coarse nickel layer is obtained in an electroplating bath loaded with nickel electroplating coarsening liquid in an electroplating mode, and the nickel electroplating coarsening liquid comprises 90-130 g / L of nickel aminosulfonate, 40-50 g / L of boric acid and 0.1-0.3 g / L of an additive. According to the nickel roughening process of the lead frame, the rough nickel layer can be directly obtained, and the copper substrate does not need to be treated, namely additional electroplating pretreatment is not needed. According to the nickel coarsening process, crystallization of nickel ions on the surface of the lead frame is remarkably affected in the nickel electroplating deposition process through the additive in the nickel electroplating coarsening liquid, the limiting current density of the nickel electroplating coarsening liquid is reduced, deposition of a high-current-density area is restrained, nearly-spherical round grains are formed, and the nickel electroplating quality is improved. Meanwhile, the process of electron deposition of nickel ions is accelerated, cathodic polarization is reduced, growth of nickel crystal nucleuses is promoted instead of nucleation, large-size particles are formed, the surface roughness is improved, an electroplating coarse nickel layer with certain roughness is finally formed, the content of nickel metal in an electroplating nickel coarsening solution cannot be continuously increased, wastewater discharge is reduced, and the production cost is reduced. The environment is protected.

The invention discloses an extracting agent for extracting and separating nickel cobalt and lithium magnesium, which relates to the technical field of extracting agents and is a composite extracting agent consisting of an extracting agent A and a synergistic extracting agent B, the extraction agent A is tertiary carbon carboxylic acid and salt thereof, the synergistic extraction agent B is composed of a synergistic extraction agent a and a synergistic extraction agent b, the synergistic extraction agent a is naphthalene sulfonic acid and salt thereof, and the synergistic extraction agent b is alcohol R5OH. The invention provides a synergistic extraction system of nickel and cobalt. Tertiary-carbon carboxylic acid with the carbon atom number of 10-20, tertiary-carbon sulfonic acid with the carbon atom number of 10-20 and fatty alcohol with the carbon atom number of 8-16 cooperate with each other. The tertiary carbon carboxylic acid, the tertiary carbon sulfonic acid and the fatty alcohol are matched, so that the tertiary carbon carboxylic acid, the tertiary carbon sulfonic acid and the fatty alcohol have very good selectivity and relatively strong extraction capacity on nickel ions and cobalt ions; and the defects that the water solubility of an existing extraction system is high and strong acid enters a water phase when the strong acid is used for reverse extraction are effectively overcome.

The invention relates to a modified molecular sieve and a preparation method and application thereof, and the preparation method comprises the following steps: alkali modification: obtaining an alkali modified ultra-stable Y molecular sieve; performing nickel ion exchange for many times to obtain a nickel ion loaded ultra-stable Y molecular sieve; and carrying out cerium ion exchange to obtain the nickel-cerium double-loaded ultra-stable Y molecular sieve. On the basis of an ultra-stable Y-type molecular sieve, a novel modified molecular sieve is prepared through further modification treatment, so that the adsorption performance of the novel modified molecular sieve on organic sulfides such as mercaptan and thioether in oily sewage and oily waste gas is improved, and a more efficient, economical and environment-friendly technical solution is provided for VOCs emission treatment in the petrochemical industry; the method has important application value and market prospect.

The invention provides a copper-nickel alloy friction film based wind power gear oil additive composition and a preparation method thereof, belongs to the technical field of lubricating oil, and aims to solve the technical problems of low bearing capacity and poor antifriction effect of a friction film formed by wind power gear oil. The wind power gear lubricating oil comprises the following components in percentage by mass: 0.8%-1.4% of a sulfur-containing extreme pressure agent, 0.4%-1.0% of a phosphorus-containing anti-wear agent, 0.5%-1.5% of copper nanoparticles, 0.5%-1.0% of nickel acetylacetonate, 0.15%-0.25% of an antioxidant, 0.1%-0.20% of an anti-rust agent, 0.015%-0.025% of an anti-foaming agent, 0.04%-0.05% of a demulsifying agent, 0.4%-0.8% of a dispersing agent and 93.8%-97.1% of synthetic base oil, and the sum of the percentages of the components is 100%. Nickel acetylacetonate forms high-activity nickel ions under friction induction, the high-activity nickel ions react with a friction pair substrate to form an alloy interface layer, and meanwhile the alloy interface layer and copper nanoparticles form a high-strength copper-nickel alloy friction film through interface alloy.

The invention provides a method for recycling battery-grade manganese sulfate from manganese-containing feed liquid. The method comprises the following steps: (1) carrying out resin adsorption on a manganese-containing feed liquid to obtain a nickel-cobalt adsorbate and an adsorbed feed liquid; (2) sequentially carrying out extraction treatment and reverse extraction treatment on the adsorbed feed liquid to obtain a solution containing manganese sulfate and an organic phase after reverse extraction; (3) carrying out evaporative crystallization on the solution containing manganese sulfate to obtain battery-grade manganese sulfate; positive ions in the manganese-containing feed liquid comprise manganese ions, nickel ions, cobalt ions, calcium ions and magnesium ions, and negative ions in the manganese-containing feed liquid comprise sulfate ions; an extraction agent adopted in the extraction treatment process comprises an HBL116 extraction agent. According to the method disclosed by the invention, metal oxidation hydrolysis cannot be caused to generate a third phase, the extraction process is stable, enrichment of a high-concentration manganese sulfate solution is realized, high-purity manganese sulfate crystals with qualified impurities are obtained, and efficient recovery of manganese in a high-calcium-magnesium feed liquid system can be realized; and a complicated recovery process is not needed, so that the cost is lower.

The invention belongs to the technical field of hydrometallurgy, and particularly relates to a method for separating nickel and cobalt from a nickel-containing solution and preparing nickel salt, which comprises the following steps: 1) chelating and precipitating impurity metal ions in the nickel-containing solution by using ammonium polyphosphate with the polymerization degree of more than 1000 as an impurity removal agent, thereby removing copper, iron, zinc and aluminum to obtain an impurity-removed solution; 2) extracting the impurity-removed solution by using a diluent, alpha-hydroxyoxime, carboxylic acid and alkyl alcohol as an extraction organic phase to obtain a nickel-loaded organic phase; 3) washing the nickel-loaded organic phase by using nickel-containing washing water; and (4) reverse extraction is conducted on the washed nickel-loaded organic phase through reverse extraction liquid containing acid and nickel ions, nickel-rich liquid is obtained after reverse extraction is completed, nickel salt in the nickel-rich liquid is crystallized, and nickel salt solids are obtained after phase separation. According to the method, nickel is selectively extracted through the compound extraction system after impurity removal, the extraction rate of nickel reaches up to 99.8%, nickel is separated from metal ions such as cobalt and lithium, and the method is simple in process, low in equipment manufacturing cost and low in manufacturing cost.

The invention discloses a nanorod-shaped Ni / Ni3S2 / VN electro-catalytic material and a preparation method and application thereof.The preparation method comprises the steps that firstly, a nickel source is loaded on the surface of bacterial cellulose, and a Ni / Ni3S2 / VN electro-catalytic hydrogen evolution material with the nanorod-shaped morphology is prepared through a solid-phase sintering method; the bacterial cellulose is a pure natural biomass element, has no pollution to the environment, is green and environment-friendly, has a large number of carboxyl functional groups on the surface, can effectively complex free nickel ions in a solution as a template agent, and keeps good catalytic stability after being carbonized into carbon nanofibers, and Ni3S2 and VN are compounded, so that the catalytic performance of the carbon nanofibers is improved. According to the preparation method, a nanorod-shaped heterostructure is formed, part of Ni metal is reduced, all the components have a synergistic effect, the excellent electro-catalytic hydrogen evolution performance is shown in an alkaline environment, the preparation process is green, simple and convenient, and reaction conditions are easy to control.

The invention belongs to the technical field of electro-catalytic materials, and particularly relates to a metal cation doped polymetallic sulfide nanosphere as well as a preparation method and application thereof. The metal cation doped polymetallic sulfide nanosphere is formed by polymetallic sulfide nanosheets, and polymetallic sulfide comprises molybdenum sulfide and metal cation doped cobalt sulfide; the metal cations comprise nickel ions and / or manganese ions. The material has excellent bifunctional catalytic performance of hydrogen evolution reaction (HER) and oxygen evolution reaction (OER), shows excellent water electrolysis performance, and can effectively improve the catalytic efficiency of water electrolysis.

The invention relates to the field of hydrometallurgy, in particular to a method for preparing nickel sulfate from nickel raw material leachate. The trend of the washing liquid in the traditional process is changed in the technological process, so that the amount of the washing liquid entering the nickel sulfate solution is reduced, the concentration of nickel ions in the nickel sulfate solution before evaporation is improved, and the unit cost of evaporative crystallization of nickel sulfate is reduced. P507 cobalt extraction washing liquid enters a P204 impurity extraction and soap conversion section, P507 magnesium extraction washing liquid enters a P507 cobalt extraction and soap conversion section and / or the P204 impurity extraction and soap conversion section, Cy272 magnesium extraction washing liquid enters a P507 magnesium extraction and soap conversion section, the P507 cobalt extraction and soap conversion section and / or the P204 impurity extraction and soap conversion section, and the washing liquid is transferred to the previous procedure and enters the soap conversion section instead of entering an extraction system; washing liquid is discharged out of the system in the form of sodium sulfate wastewater, so that the water phase amount of the system is reduced, and the nickel ion concentration in the nickel sulfate solution is improved.

The invention belongs to the technical field of electromagnetic shielding materials and conductive polymer-based composite materials, and particularly relates to a flexible aramid nanofiber conductive film and a preparation method and application thereof. The preparation method comprises the following steps: firstly, preparing an aramid nanofiber membrane through vacuum-assisted filtration, and then immersing the aramid nanofiber membrane into a nickel ion-containing solution for ultrasonic pretreatment and activation treatment by a sodium borohydride solution to obtain a modified aramid nanofiber membrane; and mixing with a chemical nickel plating solution under an external magnetic field, drying, and dip-coating with a polydimethylsiloxane packaging solution to obtain the flexible aramid nanofiber membrane. The finally obtained flexible aramid nanofiber conductive film has excellent flexibility, heat resistance and corrosion resistance. The method is easy to operate, economical and environmentally friendly, the material has excellent electromagnetic shielding performance due to the porous layered structure of the formed nanofiber membrane and the nickel coating on the surface, and the problem of mutual interference between electronic elements can be solved.

The invention discloses a hollow carbon sphere loaded Ni / NiO heterojunction material, which is prepared by the following steps: firstly preparing a solid carbon sphere loaded Ni / NiO heterojunction material SiO2-NC-Ni / NiO by a template sacrifice method, and then removing a SiO2 template by an alkaline etching method to obtain the hollow carbon sphere loaded Ni / NiO heterojunction material NC-Ni / NiO. The preparation method comprises the following steps: 1, preparing PDA coated silicon dioxide solid spheres; 2, preparing PDA coated silicon dioxide solid sphere loaded nickel ions; 3, preparing a carbon-coated silicon dioxide solid sphere loaded nickel-nickel oxide heterojunction; and 4, preparing the hollow carbon sphere loaded nickel-nickel oxide heterojunction. The invention relates to a preparation method of an NC-Ni / NiO doped lithium aluminum hydride hydrogen storage material, which comprises the following steps of: mixing NC-Ni / NiO serving as a catalyst and lithium aluminum hydride under an argon condition, and performing ball milling to obtain LiAlH4-NC-Ni / NiO. When the material is used as a hydrogen storage material, the initial dehydrogenation temperature is 60-70 DEG C, and the hydrogen desorption amount is 7.0-7.2 wt.%.