396 results about "Acetylacetone" patented technology

The invention provides an acetylacetone-based composite thermal stabilizer which is a mixture obtained by mixing zinc acetylacetonate, calcium acetylacetonate or magnesium acetylacetonate and hydrotalcite pro rata. The composite thermal stabilizer is suitable for chloride-containing high polymer, such as polyvinyl chloride, chlorinated polyethylene, chlorinated polyvinyl chloride, copolymer of vinyl chloride-ethylene or copolymer of vinyl chloride-vinyl acetate, has better thermal stability, prolongs the thermal aging time of the chloride-containing high polymer, and overcomes the shortcomings of poor long-term performance of single stabilizer of zinc acetylacetonate, poor transparency of stabilizer of calcium acetylacetonate, and poor initial colorability of stabilizer of hydrotalcite. The composite thermal stabilizer has low cost, good initial colorability, excellent long-term performance and good transparency, and is an efficient composite thermal stabilizer.

The invention relates to the technical field of metal material hot working, and discloses a hot-rolled coiled plate production process which comprises the following steps: preparing a reaction type protective agent, the high-temperature-resistant coating is prepared from the following raw materials in parts by weight: 20 to 40 parts of tetraethoxysilane, 5 to 15 parts of triethyl phosphate, 1 to 5 parts of triethyl borate, 0.5 to 2.0 parts of cerous nitrate (III) hexahydrate, 0.1 to 1.0 part of lithium acetate and 0.01 to 0.05 part of vanadyl acetylacetonate (IV). Coating the surface of a hot-rolled plate blank with the protective agent; the coated plate blank is heated in a heating furnace, so that the protective agent forms a molten-state protective layer in situ; carrying out hot rolling on the plate blank with the molten protective layer; and cooling and coiling the hot-rolled steel strip. In the whole heating and hot rolling process, the molten protective layer isolates the contact between the steel and the oxidizing atmosphere, so that the generation of oxide scales is fundamentally inhibited, the production process is simplified, and the metal yield is increased.

The application discloses a preparation method of carbon aerogel material for light electromagnetic shielding, and comprises the following steps: adding resorcinol, phloroglucinol, a template agent and formaldehyde into pure water, stirring and dissolving to obtain a precursor solution; adding the precursor solution into white oil containing a surfactant, emulsifying, heating in an oil bath and fully reacting; centrifugal separation to obtain powder, high-temperature carbonization, dispersion in oleylamine, addition into a stock solution containing nickel acetylacetonate, triphenylphosphine and oleylamine, high-temperature reaction and cooling, addition of a mixture of hexane and ethanol to obtain a product; centrifugal separation and washing to obtain light high-electromagnetic-shielding carbon aerogel. The carbon aerogel material for light electromagnetic shielding prepared by the method has the advantages of small density, high efficiency, corrosion resistance, high electromagnetic shielding efficiency, high product yield and the like, and by controlling the nucleation and growth rate of Ni2P, the Ni2P nanoparticles can be uniformly grown on the carbon aerogel microspheres, and the method is suitable for application in large-scale industrial production.

The invention discloses a lightweight alumina foamed ceramic refractory material and a preparation method thereof, and relates to the technical field of ceramic materials. When the light aluminum oxide foamed ceramic refractory material is prepared, zirconium acetylacetonate, yttrium nitrate hexahydrate and aluminum nitrate nonahydrate are mixed to prepare a spinning solution for electrostatic spinning, nano aluminum titanate is loaded by using a nano spraying technology during spinning, and doped modified zirconium oxide fibers are prepared after high-temperature heat treatment and defibering and dispersing; mixing aluminum oxide micro powder, hollow aluminum oxide, a high-temperature foaming agent, doped modified zirconium oxide fibers and a sintering aid, and then performing ball milling and sieving to prepare aluminum oxide-based mixed powder; and carrying out mold pressing on the alumina-based mixed powder to prepare a green body, sintering, and cooling to prepare the lightweight alumina foamed ceramic refractory material. The light aluminum oxide foamed ceramic refractory material prepared by the invention has the advantages of light weight, low thermal conductivity, high compressive strength, high bending strength and good thermal shock resistance.

The invention discloses a flexible lanthanum zirconate-alumina fiber membrane as well as a preparation method and application thereof, and belongs to the technical field of inorganic nonmetal ceramic fiber materials. The preparation method comprises the following steps: dissolving zirconium oxychloride octahydrate, lanthanum chloride heptahydrate and aluminum chloride hexahydrate into absolute methanol, sequentially adding acetylacetone and triethylamine, stirring, and drying under reduced pressure to obtain a zirconium-lanthanum-aluminum polymer precursor containing triethylamine hydrochloride; soaking the zirconium-lanthanum-aluminum polymer precursor containing triethylamine hydrochloride in acetone, standing, filtering, concentrating under reduced pressure, and drying to obtain a zirconium-lanthanum-aluminum acetylacetone polymer precursor; the preparation method comprises the following steps: preparing a spinning solution from a zirconium-lanthanum-aluminum acetylacetone polymer precursor, absolute methanol serving as a solvent and polyoxyethylene serving as a spinning aid, and carrying out electrostatic spinning on the spinning solution to obtain a lanthanum zirconate-aluminum oxide precursor fiber membrane; and performing heat treatment on the lanthanum zirconate-aluminum oxide precursor fiber membrane to obtain the flexible lanthanum zirconate-aluminum oxide fiber membrane. According to the preparation method, acetylacetone is added into zirconium oxychloride, lanthanum chloride and aluminum chloride for coordination to form a linear zirconium-lanthanum-aluminum acetylacetone polymer, so that the technical problem that lanthanum zirconate long fibers with high strength and good flexibility are difficult to obtain is solved.

The invention relates to the technical field of energetic materials, in particular to a laser response type high-entropy alloy-based initiating explosive material and a preparation method thereof. The initiating explosive material is mainly formed by uniformly loading a heat-sensitive high-energy compound (such as lead stilbeneate or hexa (4-amino-3, 5-dinitropyrazole) copper) on high-entropy alloy nanoparticles containing five or more metal elements, wherein the heat-sensitive high-energy compound is such as lead stilbeneate or hexa (4-amino-3, 5-dinitropyrazole) copper. The preparation method comprises the following steps: mixing acetylacetone metal salt, a surfactant and a reducing agent in an organic solvent, and stirring and reacting at 180-220 DEG C to prepare high-entropy alloy nanoparticles; the nano particles and a high-energy compound are co-dispersed in a mixed solvent containing a dispersing agent, ultrasonic treatment is carried out to form suspension liquid, and freeze drying is carried out to obtain the nano particles. The method is characterized in that the excellent photo-thermal conversion performance of the high-entropy alloy is utilized, under low laser energy irradiation, a high-energy compound can be effectively excited, and stable detonation of secondary charge CL-20 is successfully achieved. According to the invention, the problems of high response threshold and low output energy of the existing laser initiating explosive material are solved.

The invention discloses a FeNi-C-CNTs-carbon fiber composite material and a preparation method and application thereof, and the preparation method comprises the following steps: (1) cutting carbon fibers into short fibers, dispersing the short fibers into fiber bundles, fixing the fiber bundles, and carrying out electrostatic dispersion; (2) spraying an adhesive on the surface of the dispersed carbon fiber to form an adhesive layer on the surface of the carbon fiber, and then pre-curing the adhesive; and (3) carrying out chemical vapor deposition by adopting a horizontal tube furnace and taking a mixture of ferric acetylacetonate and nickel acetylacetonate as a metal precursor. In the FeNi-C-CNTs-carbon fiber composite material, the FeNi alloy nanoparticles and the carbon nanotubes cooperatively construct a three-dimensional conductive network, wave absorbing mechanisms such as magnetic loss, dielectric loss and multiple scattering are strengthened by means of the unique structure, the wave absorbing performance is remarkably improved, the effective frequency band is widened, and the composite material has excellent microwave absorbing performance and structural stability.

The invention belongs to the technical field of rhenium alloy materials, and particularly relates to a high-strength rhenium alloy material and a preparation method thereof. The rhenium alloy material is prepared from the following raw materials in percentage by mass: 12 to 24 weight percent of molybdenum, 6 to 9 weight percent of niobium, 2 to 5 weight percent of cobalt, 1 to 3 weight percent of tungsten, 0.5 to 1.2 weight percent of modified tantalum carbide, 3 to 6 weight percent of high-entropy rare earth and the balance of rhenium and other inevitable impurities. The modified tantalum carbide is prepared by the following preparation process: adding tantalum chloride, zirconium oxychloride and phenolic resin into a mixed solution of acetylacetone and n-butyl alcohol, stirring for 1-2 hours under a heating condition, dropwise adding ammonia water, continuously stirring for 0.5-1 hour, and drying to obtain a precursor; calcining the precursor, and cooling to obtain the modified tantalum carbide. The rhenium alloy prepared through the method has high hardness, good bending strength and excellent high-temperature mechanical property.

The invention relates to the technical field of electroplating, in particular to a nickel stripping agent, a preparation method of the nickel stripping agent and a nickel plating layer stripping method. The nickel stripping agent comprises the following raw materials: an oxidizing agent, a complexing agent, a dissolution promoter, a surfactant and a corrosion inhibitor, wherein the mass ratio of the oxidizing agent to the complexing agent to the dissolution promoter to the surfactant to the corrosion inhibitor is (4-15): (3-25): (1-11): (0.01-1): (0.01-5); wherein the oxidizing agent is nitrobenzoic acid; the complexing agent is one or more of 2-amino-2-methyl-1-propyl alcohol, acetylacetone, nitrilotriacetic acid, nitrilotriacetic acid sodium salt, acrylate, sodium gluconate and ethylenediamine hydrochloride; the dissolution promoter is an alcohol ether solvent. According to the nickel stripping agent, the oxidizing agent with relatively low toxicity and a non-toxic or low-toxicity non-volatile complexing system are adopted, nickel can be completely removed, a base material cannot be eroded, and the threat to the health of operators can be remarkably reduced.

The invention discloses a preparation method of a bifunctional heterojunction catalyst for AEM electrolyzed water. The method comprises the following steps: step 1, mixing multi-walled carbon nanotubes, deionized water, absolute ethyl alcohol and inorganic acid; step 2, putting the mixed solution in the step 1 into an ultrasonic machine to form a porous structure and more active adsorption sites; step 3, carrying out freeze drying treatment on the mixed solution treated in the step 2; step 4, mixing the dried multi-walled carbon nanotubes with acetylacetone salt, and uniformly grinding the mixed powder; and step 5, putting the powder obtained in the step 4 into a tubular furnace, and carrying out heat treatment in the atmosphere of H2 / Ar to obtain the PtFeCoNiMoZr / ZrO heterojunction catalyst. The catalyst has a remarkable catalytic effect on HER and OER reactions, and meanwhile, stable electrolysis which stably runs for 200 hours in an AEM electrolytic cell under the current density of 1200 mA / cm < 2 > is successfully realized.

The application relates to the technical field of fireproof cables, and discloses an aluminum alloy core fireproof cable and a preparation process thereof. The aluminum alloy core fireproof cable comprises, from inside to outside, a conductor, an insulation layer, a filling layer, a bundling heat insulation layer, an isolation layer, a fireproof layer and a sheath layer. The sheath layer comprises the following components by weight: 100 parts of polyvinyl chloride, 10 to 15 parts of a plasticizer, 10 to 15 parts of ethylene-vinyl acetate copolymer, 25 to 30 parts of a flame retardant, 0.5 to 1.5 parts of an antioxidant, 10 to 20 parts of a filler, and 0.5 to 1 part of a lubricant. The preparation method of the flame retardant comprises the following steps: mixing calcium oxide, magnesium oxide and zinc oxide, and obtaining a solid solution after solid solution annealing; mixing the solid solution with aluminum hydroxide, ammonium polyphosphate and a metal acetylacetone complex to obtain the flame retardant. Through the technical scheme, the problem of insufficient fire resistance of the fireproof cable in the related art is solved.

The invention discloses a photovoltaic cable sheath material with ultraviolet aging resistance and long service life. Comprising the following components in parts by weight: 100 to 120 parts of high-density polyethylene, 0.3 to 0.5 part of a benzotriazole ultraviolet light absorber, 0.5 to 0.8 part of a hindered amine light stabilizer, 0.2 to 0.5 part of an antioxidant, 3 to 5 parts of salicylate intercalated magnesium aluminum hydrotalcite, 0.02 to 0.05 part of cerium acetylacetonate, 2 to 4 parts of rutile type nano titanium dioxide, 3 to 5 parts of a compatilizer and 0.5 to 1 part of a dispersant. The photovoltaic cable is prepared from the anti-ultraviolet aging long-life photovoltaic cable sheath material, an insulating layer material and a conductor, so that the obtained photovoltaic cable sheath material and the photovoltaic cable have excellent anti-ultraviolet capability and thermal aging resistance, and have relatively long service life.

The application discloses a preparation method of Fe single-atom and Cu cluster co-doped nitrogen-carbon material and application of the material in full-pH oxygen reduction electrocatalysis. The ZIF-8 with a three-dimensional and rich pore structure is used as a framework, and Fe@ZIF-8 is prepared by using a solvothermal method. Then, copper acetylacetonate is used as a copper source, and the copper acetylacetonate molecules dispersed in the gas phase are adsorbed on the surface of the ZIF-8 by using the rich pore structure of the ZIF-8 and the low sublimation temperature of the metal acetylacetonate salt. Finally, pyrolysis is carried out under nitrogen or inert atmosphere, so as to form the Fe single-atom and Cu cluster co-doped nitrogen-carbon material. The material is subjected to electrochemical test under acidic, neutral and alkaline conditions, and the material exhibits high oxygen reduction electrocatalysis performance in the full-pH range and has good stability. The material has good performance as a cathode catalyst in a fuel cell, an alkaline / neutral zinc-air battery, and has high application value.

The invention discloses a method for extracting lithium from lithium precipitation mother liquor to obtain lithium phosphate, which specifically comprises the following steps of: performing preliminary extraction on the lithium precipitation mother liquor, performing reverse extraction by adopting a composite reverse extraction agent consisting of phosphoric acid and acetylacetone in a molar ratio of (5-15): 1, controlling the pH value of a reverse extraction system to be 5-7, and performing phase splitting to obtain a lithium phosphate wet product; and finally, adding the lithium phosphate wet product into lithium hydroxide for reaction, and filtering to obtain lithium phosphate. According to the method, efficient enrichment of lithium ions in the lithium precipitation mother liquor is achieved through the extraction and reverse extraction processes, meanwhile, through optimization of a reverse extraction system in the reverse extraction process, formation of calcium phosphate impurities is reduced, the extraction purity of lithium is improved, the morphology of lithium phosphate can be regulated and controlled in the reverse extraction process, batch stability is achieved, and the product quality is improved.

The invention discloses a synergistic aqueous zinc ion battery electrolyte additive and a preparation method thereof, and also provides a high-performance aqueous zinc ion battery adopting the additive. The electrolyte additive is composed of a solvent, a water-soluble zinc salt and cerium acetylacetonate (Ce (AcAc) 3), and the preparation method of the additive comprises the following steps: completely dissolving cerium acetylacetonate in water to form a homogeneous solution, then adding the water-soluble zinc salt, and fully stirring and mixing to obtain the target additive. The aqueous zinc ion battery system comprises a zinc metal negative electrode, a positive electrode, a diaphragm and an electrolyte containing the additive. An acetylacetone ligand (AcAc-) in the additive inhibits the activity of water molecules by regulating and controlling a zinc ion solvation structure, so that water-induced side reactions are reduced; meanwhile, cerium ions (Ce < 3 + >) induce zinc ions to be uniformly deposited through an electrostatic shielding effect and surface energy regulation and control, so that the growth of zinc dendrites is effectively inhibited. AcAc <-> and Ce < 3 + > form a dynamic protection layer through coordination, and the protection layer has a double synergistic effect mechanism, so that the cycle life of the zinc anode is remarkably prolonged.

The invention discloses a (Fe (OH) 2) ((OH) 0.25 (H2O) 0.5) / W18O49 composite material as well as a preparation method and application thereof, and belongs to the technical field of functional materials. The preparation method comprises the following steps: uniformly mixing and stirring cyclohexanol, acetylacetone and absolute ethyl alcohol, adding tungsten hexachloride, uniformly stirring at room temperature, then adding ferric trichloride, uniformly stirring at room temperature, carrying out hydrothermal reaction, washing and drying to obtain the (Fe (OH) 2) ((OH) 0.25 (H2O) 0.5) / W18O49 composite material. A mixed system of cyclohexanol, acetylacetone and absolute ethyl alcohol is utilized to synergistically solve the problems of advanced hydrolysis and agglomeration of metal ions; the oxygen vacancy of the W18O49 accelerates the conversion of the sodium polysulfide, and the Fe (OH) 2 derivative strengthens the chemical anchoring of the sodium polysulfide, thereby realizing the synergy of the anchoring and rapid conversion of the NaPSs. When being used as a sodium-sulfur battery positive electrode material catalyst, the catalyst shows excellent catalytic performance and rate capability, and still has the capacity of 420 mAh g <-1 > after circulating for 25000 circles under the large current density of 10 A g <-1 >. The strong adsorption characteristic of the hydroxylated iron-based component and the high catalytic activity of W18O49 are utilized to form a synergistic effect, and a new scheme is provided for breaking through the technical bottleneck of an RT Na-S battery.

The invention provides an electrolyte composition, an electrochemical in-situ etching method of non-metallic inclusions for heavy rail steel and application of the electrochemical in-situ etching method. The electrolyte composition comprises the following components in parts by weight: 1.6 to 2.3 parts of lithium chloride, 10 to 13.5 parts of acetylacetone, 45 to 84 parts of methanol and 2 to 43 parts of a reagent A, the reagent A is a mixed aqueous solution of ethylenediamine tetraacetic acid and sodium citrate. The lithium chloride, the acetylacetone, the methanol and the reagent A in specific parts are matched for use, the obtained electrolyte composition is used for in-situ electrochemical etching of the heavy rail steel, and three-dimensional in-situ etching of the non-metallic inclusions in the heavy rail steel can be successfully achieved. The in-situ information of the non-metallic inclusions in the hypereutectoid heavy rail steel is reserved, and the three-dimensional morphology of the non-metallic inclusions can be presented more comprehensively.

The application discloses a preparation method of vanadium-doped and high-hydrated mangan-chromian spinel monocrystal under high temperature and high pressure. The cylindrical mangan-chromian spinel sample is prepared by taking solid rose triangular rhombic manganese carbonate crystal, solid chromium (III) acetate hydroxide crystalline powder, solid vanadium (IV) acetylacetonate oxide powder, solid oxalic acid powder, solid bixbyite powder, solid chromium hydroxide powder and liquid dilute nitric acid as starting raw materials; two pieces of water source sheets are made from the bixbyite powder and the chromium hydroxide powder with a weight ratio of 4:1; the two pieces of water source sheets are placed at two ends of the cylindrical mangan-chromian spinel sample and then are placed into a double-capsule structure experimental sample bin with an inner layer sleeve being a graphite tube and an outer layer sleeve being a gold-palladium alloy tube; the high temperature and high pressure reaction is carried out to obtain the mangan-chromian spinel monocrystal; and the preparation technology blank of the vanadium-doped and high-hydrated mangan-chromian spinel large-particle monocrystal under the current high temperature and high pressure conditions is solved.

The invention belongs to the technical field of lithium ion battery negative electrode materials, and particularly relates to a method for preparing a silicon-carbon composite negative electrode material by using porous carbon jet powder fine powder, which comprises the following steps: (S1) mixing the porous carbon jet powder fine powder and a binder according to a mass ratio of 100: (12-18), and then carrying out curing reaction to obtain a precursor; the binder comprises the following raw materials: petroleum asphalt, a polyamide acid solution, cellulose nanofibers, an epoxy silane coupling agent alcohol-water solution, nickelocene and / or nickel acetylacetonate, and toluene. (S2) after crushing and screening the precursor, performing pyrolysis carbonization in an inert atmosphere to obtain pyrolytic carbon; (S3) activating the pyrolytic carbon under an activation atmosphere condition to obtain a porous carbon material; and (S4) carrying out silane deposition on the porous carbon to obtain the silicon-carbon composite negative electrode material. According to the preparation method, the binder with specific components is adopted, so that the porous carbon airflow fine powder is recycled, and the silicon-carbon composite negative electrode material with excellent electrochemical performance is prepared.

The invention relates to the technical field of automobile glass surface treatment, in particular to heat management coated glass and a preparation method thereof, and the heat management coated glass is prepared by compounding two pieces of composite glass through an adhesive film; the composite glass sequentially comprises a glass substrate, an ultraviolet absorption functional layer and an infrared reflection functional layer, the preparation raw materials of the ultraviolet absorption functional layer at least comprise a SiO2 sol matrix and an inorganic ultraviolet absorbent; the preparation raw materials of the infrared reflection functional layer at least comprise tetraethoxysilane, acetylacetone, hydrochloric acid and antimony-doped tin oxide nanoparticles. The surface of the glass is coated with the optimized ultraviolet absorption functional layer and the infrared reflection functional layer, so that the barrier rate to ultraviolet (UV) of 99% or above and the reflectivity to infrared (IR) of 80-90% are achieved, and meanwhile, the glass has the characteristics of low cost and high weather resistance.

The invention belongs to the technical field of a lithium battery solid electrolyte, and particularly provides a cross-linked PEO-based composite solid electrolyte and a preparation method thereof, which are used for improving the mechanical strength and electrochemical performance of the PEO-based solid electrolyte. The cross-linked PEO-based composite solid electrolyte comprises poly (ethylene oxide) (PEO), lithium bis (trifluoromethylsulfonyl) imide (LiTFSI) and bis (acetylacetonate) diisopropyl titanate, the bis (acetylacetonate) diisopropyl titanate is used as a cross-linking agent, and the mass of the poly (ethylene oxide) (PEO) is used as a reference, so that the mass of the poly (ethylene oxide) (PEO) and the mass of the lithium bis (trifluoromethylsulfonyl) imide (LiTFSI) are uniformly distributed, and the mass of the lithium bis (trifluoromethylsulfonyl) imide (LiTFSI) is uniformly distributed on the basis of the mass of the poly (ethylene oxide) (PEO). The content of the bis (acetylacetonate) diisopropyl titanate is 3 to 5 weight percent of that of the polyethylene oxide. According to the invention, bis (acetylacetonate) diisopropyl titanate (TAA) is creatively provided as a cross-linking agent of the PEO-based composite solid electrolyte, and the introduction of the cross-linking agent can significantly increase the mechanical strength of PEO and increase the stability of the PEO-based solid electrolyte to lithium metal, so that the cycle life is prolonged, and the electrochemical performance is improved.

The present application relates to a kind of by in-situ oxygen removal carbon improves high temperature wave-transparent performance of organic silicon composite material and preparation method thereof, select methyl organosilicon resin (i.e. silicon-oxygen bond (Si-O) is main chain, methyl (CH3) is side chain high molecular compound) as precursor, select toluene and ethanol according to (4-5):1 Proportion mixed as solvent, by mixing preparation resin solution, and in resin solution according to certain proportion mixed addition cerium salt with acetylacetone cerium salt;Resin solution is compounded with fiber preform by vacuum impregnation process, by impregnation-curing, obtain the organic silicon composite material with good dielectric property.Compared with prior art, the composite material of the present application has the function of stable dielectric property at high temperature, and can be applied to missile radar antenna cover material.

The application discloses a polyester synthesis method and application thereof. The polyester synthesis method comprises the following steps: preparing a sol containing cellulose nanocrystals, and an alcohol solution containing an aluminum alkoxide; adding the alcohol solution into the sol to react; separating a solid phase to obtain a composite catalyst; and synthesizing polyester under the co-catalysis of the composite catalyst and diisopropyl bis(acetylacetonyl) titanate. The polyester synthesized by the method has low carboxyl content, high light transmittance, high mechanical property and hydrolysis resistance, and can be used for preparing a polyester film. The application also provides application of the polyester prepared by the method.

The invention discloses a surface ruthenium-nitrogen coordinated Ru nano-particle catalyst, a preparation method and application of the surface ruthenium-nitrogen coordinated Ru nano-particle catalyst in bisphenol A hydrogenation reaction. Ruthenium acetylacetonate and a nitrogen-containing ligand form a porous precursor by adopting a sol-gel method, and then the porous precursor is subjected to inert gas pyrolysis and H2 / NH3 activation treatment. In an XPS (X-ray polystyrene) N1s spectrogram of the prepared Ru nano-particle catalyst, Ru-N coordination nitrogen at 399.0-399.5 eV accounts for 30%-60% of the total nitrogen atom. When the catalyst is applied to bisphenol A hydrogenation reaction, the sulfur content of the raw material is less than 100ppm, and the yield of hydrogenated bisphenol A can reach 94%; the attenuation is less than 5% after 5 cycles, and the sulfur adsorption capacity of the Ru nano-particle catalyst is less than 0.1 wt%. The surface ruthenium-nitrogen coordinated Ru nano-particle catalyst is high in activity, good in selectivity and excellent in sulfur tolerance, can stably play a role in a sulfur-containing environment, is simple and controllable in preparation process, and is beneficial to industrial production.

The invention discloses a preparation method of a superfine PtIr nanowire catalyst for ammoxidation. The preparation method comprises the following steps: firstly, fully dissolving platinum acetylacetonate, iridium acetylacetonate, tungsten hexacarbonyl and dodecyl trimethyl ammonium bromide in oleylamine to obtain a light yellow solution; carrying out ultrasonic treatment on the obtained light yellow solution until the solution is fully dissolved; and heating the obtained uniform light yellow solution to 190 DEG C in an oil bath, keeping the temperature for 5 hours, centrifuging, washing and drying to obtain the superfine PtIr nanowire catalyst. The nanowire structure has a high specific surface area and abundant active sites, and is beneficial to effective quality and electron transmission. Through alloying of Ir and Pt, the electronic structure on the surface of the catalyst is changed, and the poisoning probability is effectively reduced. Meanwhile, the adsorption and activation process of ammonia molecules is optimized through the synergistic effect between Pt and Ir, the reaction activation energy is reduced, and the reaction rate is remarkably increased. The catalyst not only has remarkable ammonia oxidation catalytic performance, but also is good in stability and simple in preparation process.

The application relates to the technical field of chemical energy and electric energy conversion, and particularly discloses a zinc-nickel battery electrolyte additive based on dynamic interface modification and a preparation method thereof. The additive is composed of an interface film former composed of sodium phytate and sodium dodecyl sulfonate, a cerium acetylacetone electric field regulator and a double-end amino polyethylene glycol bridging component in a specific mass ratio. Through the multiple synergistic mechanisms of interface film formation, electric field regulation and molecular bridging, the additive can construct an intelligent dynamic interface layer on the surface of a zinc negative electrode, and can synchronously and efficiently inhibit zinc dendrite growth and zinc self-corrosion. The microspherical additive prepared by using a high-speed shearing and spray drying process has good dispersibility and high stability. When the additive is applied to a zinc-nickel battery electrolyte, the cycle life, rate performance and high and low temperature performance of the battery can be remarkably improved, and the additive has important practical value.

The invention discloses a starch composite adhesive for synthesizing zinc acetylacetonate based on a self-polarized ceramic solid phase as well as a preparation method and application of the starch composite adhesive, and belongs to the technical field of wood adhesives. (1) solid-phase synthesis of zinc acetylacetonate; (2) preparation of starch grafted acrylamide; (3) cross-linking modification of starch grafted acrylamide; and (4) compounding phenolic resin. The preparation method comprises the following steps: initiating acrylamide to be grafted to starch by using ammonium persulfate, then adding zinc acetylacetonate which is synthesized based on a self-polarization ceramic reactor solid phase as a cross-linking agent to obtain cross-linked modified starch grafted acrylamide, and then compounding the cross-linked modified starch grafted acrylamide with water-soluble phenolic resin, thereby realizing the preparation of the high-strength, water-resistant, aging-resistant and environment-friendly adhesive. The adhesive can effectively solve the problem that the strength of a traditional starch adhesive is quickly attenuated in a humid environment, and is suitable for high-humidity application scenes such as ships and ocean platforms.