The invention relates to an
electrophoresis codeposition-in-situ thermal conversion short-process preparation method of a multi-element doped Co-Mn
spinel protective
coating. According to the method,
spinel precursor
powder does not need to be prefabricated, commercial Co3O4, Mn3O4, a
rare earth oxide R2O3 (R is Y, Ce or La) and a
doped oxide XxOy (X is Cu, Ni or Fe) are directly dispersed in an organic mixed
solvent in proportion to form a stable suspension, and after
electrophoresis codeposition, the stable (Co, Mn, R, X) 3O4
spinel coating is formed in situ through three-stage heat treatment of
impurity removal, conversion and structure homogenization. Compared with a traditional
sol-
gel method for synthesizing a precursor and then performing
electrophoresis, the method has the advantages that the process is remarkably simplified, the period is shortened, the cost is reduced, thermal mismatch caused by Cr volatilization and Fe phase
precipitation is effectively inhibited, and the compactness and high-temperature stability of the
coating are improved. The method has the advantages of being short in process, low in
equipment requirement, high in
doping flexibility and the like, and is suitable for interface anti-oxidation protection of an SOFC
metal connector and surface protection of other high-temperature electrochemical
system metal parts.