The invention relates to the technical field of electrophoretic display, in particular to a preparation method of black electrophoretic particles with low
reflectivity and high charge quantity. The method comprises the following steps: S1, mixing pre-dried black electrophoretic particles with
ethanol, water and
zirconium beads, adjusting the pH value by using
ammonia water, and carrying out ball milling; transferring to a four-neck flask, adding a
silane coupling agent, adjusting the pH value again, reacting at 80 DEG C, washing, centrifuging and
drying to obtain modified particles; s2, carrying out ball milling on the modified particles, a
monomer 1, a
monomer 2 and a
solvent, transferring into a four-neck flask, heating to 50 DEG C under the protection of
nitrogen, adding an initiator, and reacting at 70-85 DEG C; after cooling, adding 3-5 parts of monomers and a
solvent, repeatedly heating, adding an initiator, and reacting at 70-85 DEG C; and cooling again, supplementing the
monomer 2 or 3, reacting under the same condition, and finally centrifuging, washing and
drying to obtain the modified electrophoretic particle with the controllable shell structure. According to the invention, controllable regulation and control of low
reflectivity and high charge quantity of the black electrophoretic particles are realized.