1556 results about "Acid etching" patented technology

A porous silicon based material comprising porous crystalline elemental silicon formed by reducing silicon dioxide with a reducing metal in a heating process followed by acid etching is used to construct negative electrode used in lithium ion batteries. Gradual temperature heating ramp(s) with optional temperature steps can be used to perform the heating process. The porous silicon formed has a high surface area from about 10 m²/g to about 200 m²/g and is substantially free of carbon. The negative electrode formed can have a discharge specific capacity of at least 1800 mAh/g at rate of C/3 discharged from 1.5V to 0.005V against lithium with in some embodiments loading levels ranging from about 1.4 mg/cm² to about 3.5 mg/cm². In some embodiments, the porous silicon can be coated with a carbon coating or blended with carbon nanofibers or other conductive carbon material.

The present invention provides methods of forming graphene films on various non-catalyst surfaces by applying a carbon source and a catalyst to the surface and initiating graphene film formation. In some embodiments, graphene film formation may be initiated by induction heating. In some embodiments, the carbon source is applied to the non-catalyst surface before the catalyst is applied to the surface. In other embodiments, the catalyst is applied to the non-catalyst surface before the carbon source is applied to the surface. In further embodiments, the catalyst and the carbon source are applied to the non-catalyst surface at the same time. Further embodiments of the present invention may also include a step of separating the catalyst from the formed graphene film, such as by acid etching.

Methods for forming vias in glass substrates by laser drilling and acid etching are disclosed. In one embodiment, a method forming a via in a glass substrate includes laser drilling the via through at least a portion of a thickness of the glass substrate from an incident surface of the glass substrate. The method further includes etching the glass substrate for an etching duration to increase a diameter of an incident opening of the via and applying ultrasonic energy to the glass substrate during at least a portion of the etching duration. The applied ultrasonic energy has a frequency between 40 kHz and 192 kHz.

The invention relates to a test device and a method for simulating acid etching crack flow guide capability. The test device consists of a liquid storage tank, a diaphragm pump, a pipeline electric heating sleeve, a flow meter, a flat plate clamping device, a pressure return valve, a condensing pipe, a waste liquid tank, a data collection and control panel and the like, wherein the inner side of the clamping device is provided with a temperature sensor and a pressure sensor, both ends of the lamping device are provided with small liquid inlet holes and small liquid outlet holes, the inside of the clamping device is provided with a liquid inlet piston and a liquid outlet piston, a rock core chamber is arranged between the liquid inlet piston and the liquid outlet piston, the clamping device is connected with a pressure machine, and the diaphragm pump, the pipeline electric heating sleeve, the flow meter, the temperature sensor and the pressure sensor are all connected with the data collection and control panel and a computer. The test method comprises the following steps; cutting the rock into rock core samples conforming to the standard flow guide chamber, and sealing and curing the rock core samples; placing the rock core samples into the rock core chamber; adopting a gasket for simulating the crack width; sequentially opening a clear water storage tank and an acid liquid storage tank; starting the computer, and inputting experiment parameters; and calculating the flow guide capability of the acid etching cracks of the rock core samples. The invention can simulate the real conditions of the underground acid etching crack forms, and can meet the requirements of the acid etching crack flow guide capability test under different environment conditions.

The invention relates to a novel titanium substrate lead dioxide electrode and a preparation method thereof, which belong to the field of water treatment technology application. The titanium substrate lead dioxide electrode adopts titanium material as a carrier; after the titanium substrate undergoes acid etching, pyrolytic process is adopted to plate a tin-stibium oxide bottom layer; alkaline solution is then used for electroplating an alpha-PbO2 intermediate layer; acidic composite electroplating solution is used for preparing a fluorine-containing beta-PbO2 surface layer doped with an active metal (such as bismuth, nickel, lanthanum, cerium and erbium) and a particle with high absorption performance (such as powdered activated carbon and chitosan), thus obtaining a novel titanium substrate lead dioxide electrode. The titanium substrate lead dioxide electrode prepared by the method has low cost and long service life. Using the electrode as an anode and applying certain applied voltage can realize efficient removal and mineralization to the organic contaminants in the water. With simple operation and convenient management, the method is applicable to small-scale and dispersible wastewater and feed water treatment.

The invention relates to a method for extracting copper of a PCB acid etching waste liquid and preparing polyferric chloride, which comprises the following steps: the PCB acid etching waste liquid is electrolyzed directly and copper powder precipitated by electrolysis is reclaimed; reduced iron is added into a mixed solution after the electrolysis and copper sponge precipitated by replacement reaction is reclaimed; claimed crude copper is purified and prepared into copper powder products; the mixed solution after replacement reaction is added with ferric oxide or a substance containing Fe irons; the mixed solution mingled with the Fe irons is added respectively with a polymeric antioxidant and a stabilizer and simultaneously, the pH value of which is regulated with acid or alkali; and finally, the PFC is prepared. The method of the invention completely realizes reclamation and recycling of wastes and water environment treatment and finally 'zero' emission and has good environmental protection, simple preparation process, high economic benefit and wide application scope.

The invention relates to the field of recovery, in particular to a copper recovery system of printed board acid etching waste solution and an etching solution regeneration method. The system comprises a set of solid-liquid separation device, a current control device and an electrolytic bath, wherein the electrolytic bath is divided into a cathode chamber and an anode chamber by an ion membrane; the insides of the cathode chamber and the anode chamber are respectively provided with a cathode plate and an anode plate; the cathode plate and the anode plate are respectively connected with the current control device; all the bathes are connected with the electrolytic bath by pipelines to form a closed loop, through arranging the ion membrane in the electrolytic bath to divide the electrolytic bath into the cathode chamber and the anode chamber, when waste solution enters the electrolytic bath, the liquid in each chamber has electrolysis reaction under the action of respective polar plate to precipitate copper in the cathode chamber, the copper is recovered by a filter unit, and the bath solution enters a mixing bath for regeneration and reuse. The system reaches the goal of the regeneration of etching solution and recovery of copper.

The invention discloses a nano loaded titanium-based electric catalytic film comprising a conductive microporous separating titanium film matrix and a catalytic coating. Furthermore, the invention also discloses a preparation method of the nano loaded titanium-based electric catalytic film, which comprises the following steps of: (1) preprocessing the titanium film matrix by sand blasting, alkali washing, and acid etching: soaking the matrix after sand blasting in an NaOH solution for 0.5 to 2h, then processing for 1 to 2h in an oxalic acid solution with the mass percent concentration of 10 percent after washing to a neutral state, washing with water and drying at 100 to 120 DEG C; and (2) preparing and loading a catalytic coating: preparing the catalytic coating by adopting a sol-gel method, a thermal decomposition method, an electrodeposition method or a chemical vapor deposition method and loading at the surface of the titanium film matrix and in a hole. Furthermore, the invention also discloses a film reactor comprising the nano loaded titanium-based electric catalytic film. According to the nano loaded titanium-based electric catalytic film, the defects on material strength, range limitation of working voltage, catalytic oxidation efficacy and the like in the prior art are solved.

The invention provides an aluminum alloy surface treatment method which comprises the steps of sequentially carrying out pretreatment, chemical plating and electroplating on an aluminum alloy matrix, wherein the pretreatment comprises the steps of sequentially carrying out anode oxidation, laser etching, erosion and acid etching on the aluminum alloy matrix. By using the method for forming electroplating texture on the surface of an aluminum alloy, the obtained product has natural texture, is not subject to skip plating, bubbling and discoloration phenomena and has a good decorative effect. Besides, the method has the advantage of simple operation, realizes the unshaded treatment and the convenient maintenance by using the technology of anode oxidation plus electroplating, and facilitates the mass production.

A transparent touch panel substrate comprising a transparent substrate and deposited thereon a transparent conductive metal oxide film which contains zinc, indium, and tin as metallic elements and is soluble in acids. The transparent conductive metal oxide film preferably contains zinc in an amount of from 40 to 65 atomic % based on all metals and contains indium in an amount of from 0.25 to 1.3 times the amount of tin on an atomic basis. The film preferably has a thickness of from 100 to 160 nm. Unlike the conventional substrate for resistive film type transparent touch panels which comprises a glass plate coated with a transparent conductive ITO film, the touch panel substrate of the invention combines three properties: high light transmittance; ease of processing in forming a transparent electrode by acid etching; and the transparent conductive film has a moderate sheet resistance of from 500 to 5,000 OMEGA. It therefore realizes a touch panel which combines the three functions of having satisfactory display quality, being of the power-saving type, and enabling touch switch operations to be conducted without fail.

The invention provides a fractural diverting acid-fracturing method for carbonate oil-gas reservoirs. The method includes the steps of 1, injecting 50-5000 cubic meters of fracturing fluid into a stratum at a displacement speed of 2.0-15.0 m<3>/min; 2, injecting 5-100 cubic meters of material fluid into the stratum at a displacement speed of 1.0-15.0 m<3>/min, and allowing pumping at a displacement speed of 0.5-4.0 m<3>/min after the material fluid enters a preset intra-fracture bridge plug; 3, injecting 50-500 cubic meters of fracturing fluid into the stratum at a displacement speed of 3.0-15.0 m<3>/min to allow forced fractural diverting; 4, injecting 20-300 cubic meters of acid fluid at a speed of 2.0-15.0 m<3>/min to allow modification by acid etching; performing at least one operation of steps from 2 to 4. The method has the advantages that multiple diverted acid-fracturing fractures can be formed after repeated multiple of temporary plugging and fracture forming, temporary plugging material degrades after acid-fracturing construction is complete, low pollution is caused to reservoirs, and the method helps improve acid-fracturing efficiency.

The invention provides a method for manufacturing a high-AR (aspect ratio) and fine-line PCB (printed circuit board), which comprises the following steps: (1) preparing a PCB substrate; (2) carrying out PTH (plating through hole) process; (3) carrying out primary electroplating process; (4) carrying out primary pattern transfer; (5) carrying out pattern electroplating process; (6) removing dry film; (7) abrading the PCB substrate by an abrasive belt; (8) carrying out secondary electroplating process; (9) carrying out secondary pattern transfer; and (10) carrying out the acid etching process. By adopting the primary electroplating process and the secondary electroplating process and adopting the step for plating holes instead of surfaces with copper, the method of the invention can meet the requirements for the thickness of the hole copper, reduce the thickness of the surface copper and make the etching process easier at the same time, thus favoring for the production of fine-line and small-gap PCBs, being helpful for the fine-line manufacture and meeting the requirements of quality for the reliability of the PCBs.

The invention discloses a method for experimentally determining carbonate rock oil and gas reservoir acid fracturing fracture conductivity distribution. The method comprises the steps that an acid fracturing simulator FracproPT is adopted for simulating the down-hole acid fracturing fracture extending and acid etching process during acid fracturing, and fracture width distribution, fracture height distribution, temperature distribution and acid liquor mass concentration distribution data in the hydraulic fracture length direction are obtained; in the hydraulic fracture length direction, fracture width, fracture height and temperature data of total 10 feature points with the acid liquor mass concentration being 100%, 90%, 80%, 70%, 60%, 50%, 40%, 30%, 20%, 10% of the initial mass concentration are selected; acid injection displacement of the oil field site scale is converted into acid injection displacement of the laboratory scale; according to the acid liquor mass concentration data of the 10 feature points, acid liquor used for an experiment is prepared; and the acid etching process is simulated, the conductivity under the condition of reservoir closed pressure is tested experimentally, and a distribution diagram of the acid etching fracture conductivity in the fracture length direction under the reservoir condition is drawn. The method is reliable in principle and simple and convenient to operate and has wide market prospects.

The invention relates to a normalization-free high-magnetic induction low-iron loss acid etching-resistant non-oriented silicon steel and a production method thereof. The normalization-free high-magnetic induction low-iron loss acid etching-resistant non-oriented silicon steel comprises the following components in percentage by weight: C less than or equal to 0.0050%, 0.30-2.50% of Si, 0.15%-0.80% of Mn, 0.25-0.80% of Al, P less than or equal to 0.050%, S less than or equal to 0.0050%, N less than or equal to 0.0050%, Ti less than or equal to 0.0050% and 0.20-0.45% of Sn+Cu, wherein Sn and Cu are not equal to 0.The production method comprises the following steps of: smelting and casting into a blank; heating and soaking the cast blank to 1080-1150 DEG C; carrying out conventional hot rolling; rolling; pickling; carrying out one-time cold rolling to the thickness of a finished product; and annealing. The normalization-free high-magnetic induction low-iron loss acid etching-resistant non-oriented silicon steel disclosed by the invention is low in Si alloying degree, achieves the P 1.5/50 to the level of medium-high grade non-oriented silicon steels and the magnetic induction B 5000 higher than that of common non-oriented silicon steels by more than 0.08 T and equivalent to that of high-magnetic induction non-oriented silicon steels with same iron loss grades, is very conductive to enhancing the stability of a motor operated in a harsh environment for a long time and prolonging the service life of the motor and can also reduce the rusting loss in producing, storing, transporting and using processes.

The invention discloses a cross-linked acid and sand-carrying acid-fracturing method for a ground with argillaceous dolomites. Cross-linked acid-fracturing for the ground is combined with cross-linked acid sand-carrying acid-fracturing for the ground in the method, and in other words, the cross-linked acid and sand-carrying acid-fracturing method includes performing the cross-linked acid-fracturing in a prepad fluid stage; and performing the cross-linked acid sand-carrying acid-fracturing for the ground in a main sand feeding stage. The cross-linked acid and sand-carrying acid-fracturing method has the advantages that the process is simple, operation is facilitated, and a construction effect is obvious; the method can be widely applied to transformation construction for complex lithologic oil and gas reservoirs with argillaceous dolomites and the like; a deep-penetration prop fracture with durable flow conductivity can be formed to the greatest extent under the combined effect of acid-fracturing and sand-feeding acid-fracturing technologies, acid etching and propping effects are played for the fracture, and the flow conductivity of the artificial fracture and the productivity of an oil well are greatly improved.

The invention discloses a preparation method of a super-hydrophobic coating layer on an aluminum surface. The preparation method mainly comprises the following steps: (1) an aluminum piece is polished by an abrasive paper, is ultrasonically cleaned for 10 minutes by acetone and ethanol, is washed by distilled water to remove oil stains on the surface, and is dried in an oven; (2) the aluminum piece is dip in an acid etching agent for etching to obtain the aluminum surface with a micron rough structure; (3) the micron rough aluminum piece is dip in nanometer TiO2 particle solution, and is treated at high temperature to obtain the aluminum surface with a micron-nanometer composite rough structure; and (4) the aluminum surface with the micron-nanometer composite rough structure is treated by fluorine silane with low surface energy to obtain the aluminum surface with super-hydrophobic performance. The prepared super-hydrophobic aluminum piece is excellent in self-cleaning performance, fog resistance and ice covering resistance, and can be applied to field of ice covering prevention.

The invention discloses a clean viscous acid for acid fracturing of a carbonate reservoir, which is applied to the technical fields of acidification and acid fracturing of petroleum carbonate reservoirs. The clean viscous acid consists of the following components in percentage by weight: 3-7 percent of hexadecyl trimethyl ammonium bromide, 0.3-0.7 percent of sodium salicylate, 15-28 percent of hydrochloric acid, 0.125-0.25 percent of citric acid or 0.05-0.1 percent of CX-301 or 0.3-0.5 percent of TW-1 serving as an iron ion stabilizing agent, 0.2-0.25 percent of a diimidazoline quaternary ammonium salt and the balance of water. The clean viscous acid has high retardative property, the retarding rate can reach 42-56 percent, the fresh acid viscosity is 25-40 mPa.S, and the acid liquor viscosity rises during acid fracturing of the carbonate reservoir. When the hydrogen ion concentration falls till the pH is more than or equal to 2, the acid liquor viscosity rises for forming viscoelastic gel, the permeation resistance of an acid liquor in a high permeation layer is increased, and the length of an acid etching crack is prolonged. Reacted residual acid gel can undergo gel breaking automatically, is free from residues, is easy for discharging, and has small damage to stratums.