The invention discloses a method for improving the peel strength of an AlN
copper-clad plate through Zn < 2 + > pretreatment and the AlN
copper-clad plate, and the method comprises the following steps: pretreatment of an AlN
ceramic substrate:
coating the surface of the AlN
ceramic substrate with a Zn < 2 + >-containing solution for activation treatment, and carrying out high-temperature oxidation treatment after activation treatment to form an
oxide layer on the surface of the AlN
ceramic substrate;
copper sheet pretreatment: preparing a Cu2O film on the surface of the copper sheet, and
drying for later use; and preparing the AlN copper-clad plate: tightly attaching the surface of the copper sheet with the Cu2O film to the surface of the AlN
ceramic substrate with the
oxide layer, and then performing high-temperature cladding. The composition of the oxidation layer on the surface of the oxidized AlN substrate is effectively changed, the
surface roughness of the oxidation layer is improved, the surface area of the oxidation layer is increased, the
wetting ability of Cu-O eutectic liquid in the
bonding process is improved, the peel strength of the AlN copper-clad plate is enhanced, the peel strength is improved by about 14%, the bonding performance is further improved, the
operation mode is simple, and the cost is low. The method is easy to implement and has good popularization and application value.