4375results about "Superimposed coating process" patented technology

Provided is a high-strength steel sheet having excellent member strength, ductility, stretch flangeability, bendability of a shear end surface, and low-temperature toughness. A high-strength steel sheet having a prescribed component composition and a steel structure in which the area ratio of martensite is 10%-80%, the area ratio of bainite is 2%-70%, the area ratio of ferrite is 80% or less, and the area ratio of retained austenite is 15% or less at a position at 1 / 4 of the sheet thickness. The ratio of the number of martensite blocks in which metastable carbides are present relative to the number of martensite blocks is 2% or more, and the standard deviation [sigma] n of the nano-hardness relative to the average value [Hn] ave of the nano-hardness is 0.60 x [Hn] ave or less when the nano-hardness at 225 points or more is measured at a position of 1 / 4 of the sheet thickness.

The invention relates to a multi-layer composite black film and a preparation method thereof. The multi-layer composite black film is formed by sequentially stacking a base material layer, a multi-layer film system and a top covering layer, the multi-layer film system is formed by alternately stacking a plurality of absorption layers and a plurality of oxide layers, the number of the layers is 7-30, an initial layer is an oxide layer, the refractive indexes of the oxide layers are the same (1.4-1.5), the thickness ratio of the oxide layers to the absorption layers is larger than 2, and the thickness ratio of the top covering layer to the absorption layers is larger than 1. And the thicknesses of the two layers are increased and then reduced from the substrate layer to the top covering layer. A buffer layer with gradually changed oxygen content is arranged between the oxide layer and the absorption layer, and both the oxide layer and the top covering layer are made of silicon dioxide. The preparation method comprises the following steps: providing the substrate layer, alternately depositing the absorption layer and the oxide layer by using a magnetron sputtering or electron beam evaporation process to form a multilayer film system, then forming the top covering layer, controlling parameters such as vacuum degree, power, temperature and the like during deposition, and forming the buffer layer in the same cavity. The multilayer composite black film has the inner surface reflectivity of less than 1% and the appearance surface reflectivity of less than 5%, and is simple in structure and low in preparation cost.

Vapor deposition processes for forming thin films comprising molybdenum on a substrate are provide. In some embodiments the processes comprise a plurality of deposition cycles in which the substrate is separately contacted with a vapor phase molybdenum precursor comprising a molybdenum halide, a first reactant comprising CO, and a second reactant comprising H2. In some embodiments the thin film comprises MoC, Mo2C, or MoOC. In some embodiments the substrate is additionally contacted with a nitrogen reactant and a thin film comprising molybdenum, carbon and nitrogen is deposited, such as MoCN or MoOCN.

The invention relates to the technical field of alloy coatings, and discloses a laser cladding high-entropy alloy coating and a preparation method thereof.The laser cladding high-entropy alloy coating is prepared from, by mass, 25%-45% of Fe, 15%-25% of Cr, 10%-20% of Ni, 5%-15% of Mn, 3%-10% of Al, 0%-5% of Ti, 1%-5% of a nanometer reinforcing phase and 0.1%-0.5% of a flow promoter. Lorentz force generated by an alternating electromagnetic field drives melt convection, so that the diffusion coefficient of segregation-prone elements such as Cr and Ni is increased, the ultrasonic cavitation effect is matched to crush dendritic crystals and promote dispersion of nanoparticles, the segregation index of the elements is reduced, a uniform nanocrystalline-amorphous composite structure is formed through the synergistic effect, and uniform distribution of elements in a molten pool is achieved.

The invention relates to an optical fiber hydrogen sensor based on a silver film-nanowire hole array structure and a preparation method thereof in the field of photochemical sensors. The optical fiber hydrogen sensor comprises a multimode optical fiber, and a sensing area is formed on the multimode optical fiber; the sensing area is formed by stripping a coating layer with a preset length from the multimode optical fiber, thinning the optical fiber in the area, plating a silver film on the surface of the thinned optical fiber, and adsorbing a nanowire hole array structure which is sequentially and vertically arranged on the surface of the silver film in a liquid level self-assembly manner; the nanowire hole array is of a metal-medium-metal (MIM) structure, a gold-palladium nanowire array is arranged at the bottom, an intermediate medium layer is made of aluminum oxide, and a silver film with a hole array in any shape is arranged at the top. When light is transmitted to a sensing area from a fiber core of the multimode optical fiber, the light and a metal silver film can excite a surface plasmon resonance (SPR) effect, meanwhile, an MIM structure formed by a gold-palladium nanowire, an aluminum oxide dielectric layer and a porous silver film serves as an optical coupling antenna through a local surface plasmon resonance (LSPR) effect at the edge of a top hole, and the optical coupling antenna is used for transmitting the light to the sensing area. Light energy is efficiently converged and excited in an extremely bound gap plasmon (Gap Plasmon) in an aluminum oxide dielectric layer, so that far-unconventional electromagnetic field enhancement is generated in a sensing core area, and the sensitivity of the sensor is greatly improved.

The invention relates to the technical field of metal surface protection, and discloses a corrosion-resistant self-repairing metal fastener and a preparation method thereof.The corrosion-resistant self-repairing metal fastener comprises a zinc alloy matrix, a nanometer passivation layer, a slow-release corrosion-resistant layer and a self-repairing functional layer, and the nanometer passivation layer, the slow-release corrosion-resistant layer and the self-repairing functional layer sequentially wrap the zinc alloy matrix; the zinc alloy matrix consists of Al, Cu, Mg, Ce and Zn; the nano passivation layer adopts zinc phosphate / silane composite sol to construct a Si-O-P covalent bond network, and plasma is combined to graft epoxy groups to enhance the interface bonding strength; the slow-release anti-corrosion layer is used for loading a pH response type benzotriazole derivative through gradient aperture mesoporous silica, so that the dynamic controlled release of a corrosion inhibitor is realized; the self-repairing functional layer adopts a synergistic effect of a mechanical triggering type sulfydryl siloxane microcapsule and a pH triggering type EDTA chelating agent microcapsule to form a physical plugging-chemical passivation dual-mode repairing mechanism. Through four-stage cooperation of matrix modification, interface strengthening, slow-release regulation and control and intelligent repair, the corrosion resistance of the corrosion-resistant self-repairing metal fastener in a complex environment is remarkably enhanced.

The invention relates to the technical field of motor rotors, and discloses a motor rotor and a machining method thereof.The method comprises the steps that hot forging is conducted on an alloy steel base material based on the preset forging and pressing temperature, and multi-layer gradient cutting is conducted on a rotor initial blank; the method comprises the following steps: performing composite deposition treatment on a cylindrical blank based on a magnetic material, placing the magnetic composite blank in a vacuum environment for dynamic heat treatment, performing dynamic balance finishing on the heat treatment blank based on a preset alloy, performing surface strengthening treatment on a balance rotor in a nitrogen atmosphere, and coating the balance rotor subjected to surface strengthening with a preset coating, the motor rotor with the optimized surface is obtained; and dynamic balance trimming is combined with preset alloy characteristics for microstructure regulation and control, and it is ensured that the rotor has excellent operation stability in a high-rotation-speed environment. And finally, surface strengthening treatment is carried out in a nitrogen atmosphere, and a functional coating is used for covering, so that the wear resistance and corrosion resistance of the surface layer are remarkably improved, and the requirements of a motor system on a high-performance rotor under complex working conditions are met.

The invention discloses a multi-layer plating process for optimizing surface characteristics of a base material, which is characterized by comprising the following steps of: pretreating the surface of a plated base material, improving the surface smoothness of the base material, and removing dirt on the surface of the base material; electroplating the base material by using the nickel pre-plating solution; chemical plating: the base material subjected to pre-plating treatment is placed in a chemical composite plating solution for chemical plating; the chemical composite plating solution comprises a basic plating solution and second-phase particles, the second-phase particles are nano niobium carbide, and the second-phase particles are wrapped and embedded into an alloy plating layer in the chemical plating process, so that the second-phase particles are distributed in plating layer matrix metal in a discrete mode to form a discontinuous phase. The hard particles niobium carbide are added and are dispersed and distributed in a coating substrate (Ni-P alloy), the hard particles can effectively refine the substrate metal, so that the hardness of the substrate metal is improved, and the niobium carbide hard phase particles are high in hardness, excellent in wear resistance, large in yield limit and high in pressure resistance.

The invention relates to the technical field of rare earth metal electrolysis cathode protection coatings, in particular to a high-temperature-corrosion-resistant yttrium-stabilized zirconia gradient coating on the surface of a tungsten cathode. A metallurgically bonded strong bonding bottom layer is constructed on a tungsten substrate through surface pretreatment and reactive sintering, then an atmosphere plasma technology is adopted to spray a creep-resistant gradient layer with continuous components to buffer thermal stress, and finally a sol-gel technology is utilized to construct an extremely compact corrosion-resistant surface layer in a superposition mode. The high-temperature-corrosion-resistant yttrium-stabilized zirconia gradient coating is constructed through a multi-scale and multi-mechanism synergistic effect, the problems that a tungsten cathode coating is insufficient in binding force and poor in thermal shock resistance are fundamentally solved, molten salt permeation can be blocked, and the service life of a tungsten cathode in a severe environment is remarkably prolonged.

The invention discloses a corrosion-resistant coating for a gas turbine compressor blade and a preparation method of the corrosion-resistant coating, and belongs to the technical field of coatings. Rare earth elements are added into a traditional inorganic salt aluminum coating, and the corrosion resistance and oxidation resistance of the inorganic salt aluminum coating are improved. A corrosion product of the prepared Zn-Al-Mg-rare earth alloy coating is extremely compact, a corrosion channel is blocked, the self-sealing effect of the coating is improved, and the corrosion resistance of the coating is greatly improved; and meanwhile, the Zn-Al-Mg-rare earth alloy coating obtained through electric arc spraying is high in density and good in comprehensive mechanical property.

The invention discloses a cyanide-free cadmium-iron alloy plating process for high-strength structural steel. The cyanide-free cadmium-iron alloy plating process comprises the step that a nickel-titanium alloy plating layer, a cyanide-free cadmium-iron alloy plating layer and a hexavalent chromium passivation film are sequentially prepared on a high-strength structural steel substrate from inside to outside. The prepared sample piece is subjected to a hydrogen brittleness test according to HB 5067.1-2005 Part 1 of hydrogen brittleness test of plating process: Mechanical Method, and the test result meets the standard requirement; the surface of a plated part is free of white rust after being subjected to an acetate mist test for 400h according to GB / T 10125-2021 Artificial Atmosphere Corrosion Test Salt Spray Test, and a plating layer of the plated part has excellent corrosion resistance; according to GB / T 5270-2005 < GB / T 5270-2005 < GB / T > 5270-2005 < GB / T > 5270-2005 > < GB / T > 5270-2005 > < GB / T > 5270-2005 > < GB / T > 5270-2005 > < GB /

The invention relates to the technical field of anti-oxidation coatings, and particularly discloses a tantalum-tungsten alloy anti-oxidation coating and a preparation process thereof. The tantalum-tungsten alloy anti-oxidation coating comprises a transition layer, an inner layer, a barrier layer and an outer layer which are stacked in sequence, the transition layer is prepared from the following raw materials: an Ir target, a Ta target and an Re target are adopted for co-sputtering; the inner layer is prepared from the following raw materials in parts by mass: Si, MoSi2, Y and Ta-W alloy powder; the barrier layer is prepared from the following raw materials in parts by mass: Al2O3, Yb2O3 and 3YZrO2; the outer layer is prepared from the following raw materials in parts by mass: a compound: Yb2O3, La2O3, Gd2O3, SiC and B4C; and the multi-element borides comprise ZrB2 and HfB2. The tantalum-tungsten alloy anti-oxidation coating prepared in the invention has relatively good high-temperature oxidation resistance.

The invention relates to the technical field of structures and preparation of hydrogen sensor chips, in particular to a preparation method of a vehicle-mounted catalytic combustion type hydrogen sensor chip based on an MEMS (micro-electromechanical system), which comprises the following steps: step 1, growing a layer of SiO2 with low thermal conductivity and insulativity on the front and back surfaces of a Si wafer by adopting a plasma enhanced chemical vapor deposition technology; 2, continuing to grow a SiNX structural layer on the front surface of the Si wafer to form a composite supporting layer with the SiO2 / SiNX micron thickness; 3, patterning is conducted on the surface of the composite film through the photoetching technology, a layer of metal platinum is prepared on the surface of the composite film through the magnetron sputtering technology to serve as a heating electrode and a testing electrode, and the two electrodes are arranged in parallel to form a double-snake-shaped structure which comprises a working area and a welding disc. The catalytic combustion type hydrogen sensor has the advantages of being simple in technological process, low in power consumption and high in response speed, and the response time is 1t; 2s.

The invention belongs to the field of microelectronics, and particularly relates to a full-transparent HfO2-based ferroelectric capacitor and a preparation method and application thereof, and the full-transparent HfO2-based ferroelectric capacitor comprises a substrate, a bottom electrode, a ferroelectric medium layer and a top electrode which are sequentially stacked from bottom to top. Insertion layers are respectively arranged between the ferroelectric medium layer and the bottom electrode and between the ferroelectric medium layer and the top electrode. And the intercalation layer is a TiOx intercalation layer. Compared with the prior art, the defects that in the prior art, the ferroelectric performance of a transparent ferroelectric device is poor, a high annealing temperature is needed, and then the thermal budget requirement of a back-end process is not met are overcome; the TiOx intercalation layers are introduced to the two sides of the ferroelectric dielectric layer, so that the grain orientation is improved, the annealing temperature can be reduced to 400 DEG C, and the method can be compatible with a back-end process.

The invention discloses a lead zirconate titanate film material with an ultrahigh voltage coefficient as well as a preparation method and application of the lead zirconate titanate film material, and belongs to the technical field of electronic material development and film materials. The preparation of the lead zirconate titanate film material is realized by adopting a sol-gel spin-coating method and controlling the annealing times. The piezoelectric film material provided by the invention can be directly deposited on a Si substrate coated with metal Pt, does not need to introduce an additional buffer layer or dope any element, is short in annealing time and simple in preparation process, all required raw materials are cheap and easy to obtain, and the piezoelectric film material particularly has high orientation degree, low coercive voltage and excellent ferroelectric and piezoelectric properties, is suitable for preparing large-size (2-4 inches) wafers, and has a wide application prospect. And huge application potential is shown in the field of piezoelectric micro-electro-mechanical system (MEMS) devices.

The present invention relates to a coated cutting tool (1) for metal machining comprising a cemented carbide substrate body (5) and a coating (6) comprising a layer of a metal nitride, there is an uppermost part of the cemented carbide substrate body (5) wherein there are uppermost WC grains adjacent to the coating (6), there is an intermediate zone between an uppermost part of said WC grains and the coating (6) comprising a peak of Me3 intensity in an EDX line scan made from within the coating (6) into a WC grain perpendicular to the surface plane of the WC grain, Me3 is one of Ti, Cr, Zr, Mo, Nb and V, the average content of Me3 within + / - 10 nm from the Me3 max peak position is from 2 to 30 at%, the Me3 within + / - 1.0 nm from the Me3 max peak position in the EDX line scan is present as a metal nitride or carbonitride, the average content of any noble gas element or combination of noble gas elements, within + / - 1.0 nm from the Me3 max peak position in the EDX line scan, is ≤0.6 at%.

The invention relates to the technical field of optical materials and nano structures, in particular to an ultraviolet broadband light absorber based on graphene and a multi-layer periodic structure. The structure of the ultraviolet broadband light absorber sequentially comprises a graphene layer, a distributed Bragg reflection grating structure layer and a SiO2 substrate at the bottom from top to bottom. The preparation process of the ultraviolet broadband light absorber comprises the following steps: preparing the graphene layer; a SiO2 layer is deposited; depositing a TiO2 layer; carrying out multi-layer superposition; adding a graphene layer; and completing the device. The light absorption efficiency of graphene in the ultraviolet band is greatly improved, broadband efficient absorption within the wavelength range of 240-370 nm is achieved, the highest absorption rate can reach 99.75%, the absorber is not sensitive to polarization, the preparation process is simple, and technical support is provided for design of the efficient ultraviolet absorber.

A cutting tool comprising a base material and a coating disposed on the base material, wherein the coating comprises a hard particle layer; the hard particle layer is formed from a plurality of hard particles including titanium, silicon, carbon, and nitrogen; in the hard particles, a concentration of the silicon periodically changes along a first direction set in the hard particles; and an orientation of the hard particle layer is a (311) orientation.

The invention relates to an improved photoelectric coupler packaging electroplating technology which comprises the following steps that S10, self-repairing microcapsules are dispersed into electroplating liquid, the microcapsules comprise wall materials and core materials, and the core materials comprise vinyl siloxane and chloroplatinic acid catalysts; s20, sequentially forming a nano gradient composite coating structure on the surface of the substrate, wherein the composite coating structure comprises a substrate layer, a transition layer, a main functional layer and a packaging layer; and S30, carrying out micro-area deposition by adopting a light-induced selective electroplating process, wherein the micro-area deposition comprises laser micro-area activation, pulse electroplating deposition and in-situ ultraviolet curing. According to the electroplating process, through the nanometer gradient composite coating structure, the interface stress concentration is reduced through layer-by-layer transition of the material and the thickness, the thermal cycle resistance of the coating is improved, and meanwhile the balance among conductivity, mechanical strength and thermal stability is achieved.

The invention provides a thermal barrier coating with an interface three-dimensional bionic structure and a preparation method and application of the thermal barrier coating, and belongs to the technical field of thermal barrier coatings. By means of 3D printing, preparation of a complex, special and arrangement-distribution-controllable three-dimensional texture component with a complex geometrical shape and an internal structure can be achieved, and therefore the coating interface residual stress, the contact area and the pinning effect are improved; 3D printing can avoid internal oxidation of the bonding layer, and meanwhile it is ensured that the structure of the multi-level interface is uniform and stable; and then the ceramic layer is prepared by combining the spraying technology, preparation of the interface three-dimensional bionic structure thermal barrier coating is achieved, interface mechanical engagement of the bonding layer and the ceramic layer can be increased through the structure, an interlocking mechanism is achieved, the coating interface structure and residual stress are improved, and therefore the service life of the coating is greatly prolonged, and the bonding strength of the coating is greatly improved.

The invention relates to the technical field of lamps, in particular to a plating forming process of a lamp. The problems that the interface bonding force of the coating and the matrix is insufficient and the corrosion resistance of the coating is poor are solved. According to the method, micro-arc oxidation is carried out in the pretreatment stage, a compact Al-Si-O ceramic layer is generated on the surface of a high-aluminum matrix in situ, and in combination with deep diffusion of plasma siliconizing, a transition area with gradient Si distribution is constructed; the pitting corrosion resistance of the coating is optimized through the component gradient design of the inner-layer coating, the middle-layer coating and the outer-layer coating; the surface of the coating lamp is subjected to checkerboard scanning by using short pulse laser, so that the porosity and microdefects of the surface of the coating are improved, and the corrosion resistance of the coating is enhanced; a uniform oxynitride passivation film is generated on the surface of the coating in situ through low-temperature plasma post-oxidation-nitridation treatment, the defect that a film layer is easy to strip in a traditional passivation process is avoided, and the corrosion resistance of the material in long-term service can be stably maintained.

The invention relates to the technical field of titanium-steel composite plates, and particularly discloses a high-thermal-conductivity titanium-steel cold-rolled composite plate and a preparation method thereof.The preparation method comprises the steps that plasma etching treatment is conducted on a titanium plate, a TiB2-graphene heat conduction layer is arranged on the etched surface in a laser cladding mode, and an aluminum oxide whisker layer is deposited on a stainless steel plate through plasma electrolysis; the preparation method comprises the following steps: spraying nano-copper slurry on the surface of aluminum oxide whiskers, curing, carrying out composite rolling on a modified titanium plate and a stainless steel plate, and carrying out annealing and tempering treatment after rolling to obtain the high-thermal-conductivity titanium steel cold-rolled composite plate.

The invention relates to the technical field of metal material coatings, in particular to a PVD composite coating and a preparation method thereof. The preparation method comprises the following steps: pretreating a metal matrix to obtain a pretreated matrix; carrying out magnetron sputtering deposition on the surface of the pretreated matrix by using a composite target material, carrying out plasma spraying and laser texturing for multiple times, and repeating the process to form a composite coating crude product containing a third rare earth doped high-entropy alloy coating; the composite coating crude product is subjected to post-treatment, and the composite coating is obtained; wherein the composite target material is AlCoCrFeNi-Y, and the composite oxide comprises aluminum oxide, titanium oxide and cerium oxide. According to the preparation method, the bonding strength, hardness and strength of the composite coating can be remarkably improved through magnetron sputtering deposition of the rare earth doped high-entropy alloy coating, plasma spraying formation of the composite ceramic coating with the gradient content, laser texturing treatment, alternate construction of multiple layers of coatings and the like in combination with elaborately selected materials with low expansion coefficients.

The invention provides a preparation method of a high-performance titanium anode. The preparation method comprises the following steps: pretreating a titanium substrate; the preparation method comprises the following steps: coating a tantalum-containing solution on a titanium substrate, and carrying out drying, pre-sintering and oxidation treatment to form a Ta2O5 bottom layer; wherein the drying temperature ranges from 80 DEG C to 110 DEG C, and the drying time ranges from 8 min to 12 min; the presintering temperature is 450-550 DEG C, and the presintering time is 8-15 minutes; the oxidation treatment temperature ranges from 600 DEG C to 680 DEG C, and the oxidation treatment time ranges from 1.5 h to 2.5 h; the surface of the Ta2O5 bottom layer is coated with a Pt-Ti alloy solution, then sintering is conducted for 10-20 min at the temperature of 500-550 DEG C, and a middle layer is formed; the surface of the middle layer is coated with an Ir-Ta-Sn-Co-Mn solution for 3-5 times, sintering is conducted for 10-15 min at the temperature of 500-600 DEG C after each time of coating, and a surface active layer is formed; wherein the molar ratio of all metal components in the Ir-Ta-Sn-Co-Mn solution is as follows: Ir: Ta: Sn: Co: Mn is equal to 7.16: 4.5: 0.8: 0.8: (0.5-1.2). According to the preparation method of the high-performance titanium anode, through staged sintering, multi-layer component regulation and control and process optimization, the problems of insufficient coating compactness, matrix passivation and low Ir utilization rate are solved, and the technical effects that the strengthening life is larger than or equal to 20 days (40000 A / m), and the bath voltage reduction is larger than or equal to 10% are achieved. The invention further provides the high-performance titanium anode and application thereof.

The invention provides a preparation method of a bipolar current collector based on a selective double-sided modified masking film. The preparation method comprises the following steps: depositing a Ni-Cr alloy layer on a single side surface of an aluminum substrate; one side of the masking film is etched to form a roughened surface, and the other side of the masking film is hydrophobic to form a hydrophobic surface; the roughened surface of the masking film and the surface, without the Ni-Cr alloy layer, of the aluminum matrix are pressed, and the edge is coated with curing glue; and placing the pressed and glued sample in an electroplating solution to electroplate a copper layer, finally cutting off an edge glue sealing area, and stripping the masking film. According to the preparation method, the masking film used for protecting the back surface of the aluminum substrate is subjected to double-sided differential treatment, the edge sealing technology is matched, and the Ni-Cr alloy is adopted for bottoming, so that the adhesive force between the copper plating layer and the aluminum substrate is improved, the risk of causing corrosion of a primary battery is reduced, the bipolar current collector which is firmly combined and has a pure interface can be prepared, and the service life of the bipolar current collector is prolonged. And a feasible solution is provided for realizing light-weight and high-performance current collectors for electronic devices such as lithium batteries and the like.

The invention discloses an anti-deformation industrial furnace water beam structure made of a gradient composite material and a preparation method. The water beam structure sequentially comprises a high-temperature-resistant gradient layer, a thermal stress buffer layer and a heat conduction base body layer from outside to inside. Wherein the high-temperature-resistant gradient layer is composed of a ceramic and / or metal ceramic material, and the components of the high-temperature-resistant gradient layer are in continuous or stepped transition from the outer surface to the inside in the thickness direction to form a metal material for resisting high-temperature oxidation and hot corrosion; the thermal stress buffer layer is composed of a metal-based composite material, the coefficient of thermal expansion (CTE) of the thermal stress buffer layer is between that of the high-temperature-resistant gradient layer and that of the heat-conducting matrix layer, and the thermal stress buffer layer is used for relieving And the heat-conducting matrix layer is made of a high-heat-conductivity metal material and is used for rapidly conducting out heat. Through collaborative optimization of materials and structures, the problems that a traditional water beam is concentrated in thermal stress and poor in thermal shock resistance are solved, and the water beam is suitable for long-term stable operation of a high-temperature industrial furnace.

The invention provides a gradient self-repairing sealing coating and a preparation method thereof, and relates to a high-temperature protection material. The gradient self-repairing sealing coating comprises a bonding layer, a gradient middle layer, a transition layer and an abradable surface layer which are sequentially arranged from a base body to the surface. A bonding layer in the gradient self-repairing sealing coating contains silicate, so that the bonding strength and the heat-resistant stability of a matrix are improved; rare earth silicate and Ir elements are introduced into the gradient intermediate layer, so that high-temperature corrosion resistance is enhanced, and thermal stress is relieved; the transition layer contains zirconium oxide and graphene and has the functions of thermal isolation and stress regulation; the abradable surface layer is formed by combining rare earth silicate and graphite, low friction and preferential abrasion are achieved, and effective sacrifice protection is provided. The overall structure can have multiple properties of heat, corrosion resistance and abrasion resistance, and is suitable for the surface protection requirement under the complex hot end working condition.

The invention discloses a multi-layer flexible radiation cooling composite diaphragm which structurally comprises a flexible base layer film, and a SiO2 inorganic coating, a first layer of polyvinylidene fluoride (PVDF), a nano-silver layer deposited by magnetron sputtering and a second layer of PVDF which are sequentially coated to form a base layer film / SiO2 / PVDF / Ag / PVDF sandwich structure. The SiO2 layer is prepared through a sol-gel method, the surface roughness is smaller than 2 nm, and the visible light transmittance is larger than 95%; the thickness of the silver layer is 50 + / -5 nm, and the total thickness of SiO2 / PVDF / Ag does not exceed 150 nm. According to the composite diaphragm, ultraviolet reflection, visible light high transmission (greater than 92%) and near-infrared high reflection (greater than 88%) are realized through spectrum selective regulation and control, and meanwhile, SiO2 and PVDF synergistically enhance the infrared emissivity of an atmospheric window wave band (8-13 [mu] m). The flexible PET base material is combined with the PVDF interlayer design to restrain silver layer oxidation and interface stripping, the recovery rate is larger than 95% after 1000 times of bending circulation, and the NIR reflectivity attenuation is smaller than or equal to 5%. The composite diaphragm disclosed by the invention has the advantages of high light transmission, efficient cooling, excellent flexibility and long-term stability, and is suitable for flexible scenes such as agricultural greenhouses and the like.

The invention discloses an AlCrN / TiSiN / AlCrTiSiON pre-oxidation multilayer composite coating and a preparation process thereof, belonging to the technical field of coatings. The bottom layer of the composite coating is an AlCrN transition layer, and an AlCrN / TiSiN nano multilayer film and a TiSiN high-hardness layer are sequentially stacked for 1-4 times on the transition layer; The outermost layer is a compact AlCrTiSiON pre-oxidation coating, wherein the AlCrTiSiON pre-oxidation coating has excellent wear resistance and heat resistance. The coating is prepared by adopting an arc ion plating technology. The invention prepares the pre-oxidation coating with high hardness, high wear resistance and high heat resistance through process design and optimization of coating structure and pre-oxidation layer process parameters.

The invention relates to the technical field of copper foil production, in particular to a production process of strippable copper foil. The preparation method comprises the following steps: by taking an HTE copper foil as a base material, completing pretreatment of the copper foil by adopting a vapor deposition process; after the pretreated copper foil is washed, high voltage is applied to the cathode and the anode in an inert gas environment, so that a metal isolation layer is formed on the surface of the pretreated copper foil, and a carrier copper foil is obtained; the obtained carrier copper foil is put into an electrolyte containing cerous nitrate, gluconic acid and tetradecanoic acid, a compact organic cerium protective film layer is generated on the surface of the carrier copper foil after electro-deposition, and the organic cerium protective film layer and the metal isolation layer are mutually cooperated and matched, so that the corrosion resistance and the oxidation resistance of the strippable copper foil are further improved; the strippable copper foil produced by the invention not only has excellent corrosion resistance, oxidation resistance and mechanical properties, but also has excellent stripping performance, so that the service life of the strippable copper foil is prolonged, and the quality of the strippable copper foil is effectively ensured.