The invention provides a preparation method of a bipolar
current collector based on a selective double-sided modified masking film. The preparation method comprises the following steps: depositing a Ni-Cr
alloy layer on a single side surface of an
aluminum substrate; one side of the masking film is etched to form a roughened surface, and the other side of the masking film is hydrophobic to form a hydrophobic surface; the roughened surface of the masking film and the surface, without the Ni-Cr
alloy layer, of the aluminum matrix are pressed, and the edge is coated with curing glue; and placing the pressed and glued sample in an
electroplating solution to electroplate a
copper layer, finally
cutting off an edge glue sealing area, and stripping the masking film. According to the preparation method, the masking film used for protecting the back surface of the
aluminum substrate is subjected to double-sided differential treatment, the edge sealing technology is matched, and the Ni-Cr
alloy is adopted for bottoming, so that the
adhesive force between the
copper plating layer and the
aluminum substrate is improved, the risk of causing
corrosion of a
primary battery is reduced, the bipolar
current collector which is firmly combined and has a pure interface can be prepared, and the service life of the bipolar
current collector is prolonged. And a feasible solution is provided for realizing light-weight and high-performance current collectors for electronic devices such as
lithium batteries and the like.