Coatings for enhancement of properties and performance of substrate articles and apparatus

Abstract

Coatings applicable to a variety of substrate articles, structures, materials, and equipment are described. In various applications, the substrate includes metal surface susceptible to formation of oxide, nitride, fluoride, or chloride of such metal thereon, wherein the metal surface is configured to be contacted in use with gas, solid, or liquid that is reactive therewith to form a reaction product that is deleterious to the substrate article, structure, material, or equipment. The metal surface is coated with a protective coating preventing reaction of the coated surface with the reactive gas, and/or otherwise improving the electrical, chemical, thermal, or structural properties of the substrate article or equipment. Various methods of coating the metal surface are described, and for selecting the coating material that is utilized.

Description

CROSS-REFERENCE TO RELATED APPLICATIONS[0001]This application claims priority to International Application No. PCT / US2016 / 017910, filed Feb. 13, 2016, which in turn claims the benefit under the provisions of 35 U.S. C. §119 of the following U.S. provisional patent applications: U.S. Provisional Patent Application No. 62 / 116,181 filed Feb. 13, 2015 in the names of Carlo Waldfried, et al. for “THIN FILM ATOMIC LAYER DEPOSITION COATINGS”; U.S. Provisional Patent Application No. 62 / 167,890 filed May 28, 2015 in the names of Bryan C. Hendrix, et al. for “COATINGS TO PREVENT TRANSPORT OF TRACE METALS BY AL2CL6 VAPOR”; U.S. Provisional Patent Application No. 62 / 188,333 filed Jul. 2, 2015 in the names of Bryan C. Hendrix, et al. for “COATINGS FOR ENHANCEMENT OF PROPERTIES AND PERFORMANCE OF SUBSTRATE ARTICLES AND APPARATUS”; and U.S. Provisional Patent Application No. 62 / 221,594 filed Sep. 21, 2015 in the names of Bryan C. Hendrix, et al. for “COATINGS FOR ENHANCEMENT OF PROPERTIES AND PERF...

AI Technical Summary

Benefits of technology

[0013]A further aspect of the disclosure relates to a method of improving performance of a structure, material, or apparatus comprising metal surface susceptible to formation of oxide, nitride, or halide of said metal thereon, wherein the metal surface is configured to be contacted in use or operation of said structure, material, or apparatus with gas, solid, or liquid that is reactive with said metal oxide, nitride, or halide to form a reaction product that is deleterious to said structure, material, or apparatus and its use or operation, said method comprising coating the metal surface with a protective coating preventing reaction of the coated surface with the reactive gas.

[0014]In another aspect, the disclosure relates to a method of improving performance of a semiconductor manufacturing apparatus comprising metal surface susceptible to formation of oxide, nitride, or halide of said metal thereon, wherein the metal surface is configured to be contacted in operation of said apparatus with gas, solid, or liquid that is reactive with the metal oxide, nitride, or halide to form a reaction product that is deleterious to said apparatus and its operation, such method comprising coating the metal surface with a protective coating preventing reaction of the coated surface with the reactive gas.

[0015]In another aspect, the disclosure relates to improving the performance of a semiconductor manufacturing apparatus in contact with a reactive solid.

Problems solved by technology

In many fields of endeavor, structures, materials, and apparatus are encountered that include surface susceptible to formation of contaminant species, such as surfaces of aluminum, anodized aluminum, quartz, stainless steel, etc. that are susceptible to formation of undesired oxide, nitride, and halide (e.g., fluoride and / or chloride) contaminant species thereon, which interfere with the use, utility, or function of the associated products, equipment, or materials.

Although Al2O3 is widely deposited by ALD using trimethyl aluminum as a source reagent, trimethyl aluminum nonetheless is a pyrophoric liquid subject to significant safety and regulatory costs.

As a result, when dialuminum hexachloride encounters such metal oxides, the metal oxides react with the dialuminum hexachloride to form corresponding vapor phase metalloaluminum chloride compounds which can transport to wafers and semiconductor devices or device precursor structures and may deposit the trace metals or otherwise damage the products being manufactured in the equipment.

Alternatively, the metal oxide can react with Al2Cl6 vapor to form Al2O3 and particulate metal chlorides that can transport to the device structure and cause damage.

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