1803 results about "Mass analyzer" patented technology

The invention relates to the technical field of cross-modal data fusion analysis of soil component detection and improvement agent preparation, in particular to a preparation method of a soil improvement agent based on component detection, which comprises the following steps: acquiring soil component data through a near infrared spectrometer, a high performance liquid chromatograph and an inductively coupled plasma mass spectrometer; an incremental principal component analysis algorithm is combined with an oscillation suppression function to update a covariance matrix in real time, a dynamic defect factor priority list is generated, a multi-objective optimization model improved based on NSGA-II is guided to integrate the soil pH value, humidity and organic matter content to construct a dose response curved surface, and a Pareto optimal solution set is solved. A sensor array collects environment feedback data, drives a transfer learning algorithm to calibrate parameters, a dynamic incidence matrix attenuation rate and optimal weight adaptive adjustment, iteratively outputs a modifier synergistic effect solution set through a closed-loop control mechanism, and solves the problems of difficult data fusion, principal component weight offset and component synergistic deviation. And the proportioning accuracy and stability are improved.

The invention discloses a standard volume-based mass spectrum signal calibration system and method, and belongs to the field of measurement, the standard volume-based mass spectrum signal calibration system comprises a standard flow generation system and a mass spectrum detection system.The standard flow generation system comprises a standard tank, a first valve, a fifth valve and a micro-leakage valve which are sequentially connected through a gas pipeline; a gas inlet pipeline, a film gauge and a first molecular pump set are connected to a gas pipeline connecting the first valve and the fifth valve in parallel, a second valve is installed on the gas inlet pipeline, and a fourth valve is installed at an inlet of the first molecular pump set. The mass spectrometry detection system comprises a vacuum chamber communicated with the micro-leakage valve through a gas pipeline, a mass spectrometer, a second molecular pump set and a full-scale gauge are connected to the vacuum chamber, and a gate valve is installed at an inlet of the second molecular pump set. The gas release rate can be calculated and continuously adjusted on the premise that a leak hole is not needed, and the problems that in the prior art, a standard leak hole is limited in application range, low-flux measurement is inaccurate, the nominal leak rate is prone to drifting, and cost is high are solved.

The invention belongs to the technical field of aircraft oil leakage monitoring, and relates to an aircraft oil leakage detection method based on a high-sensitivity mass spectrometry technology, and the method comprises the steps: obtaining a time-resolved mass spectrogram of aviation kerosene molecules in a sample testing stage, and storing the time-resolved mass spectrogram in a database; then oil gas molecules are captured at leakage-prone points of an aircraft pipeline system through a gas collection probe, the captured oil gas molecules are transmitted to an ion source end of a proton transfer reaction mass spectrometer through a negative pressure transmission system to be ionized to generate ions, and the ions are analyzed by a mass analysis system to obtain a mass spectrum; comparing the mass spectrogram obtained by analysis with a time-resolved mass spectrogram in a database, and judging whether leakage occurs or not; based on the method, the problems of insufficient anti-interference capability, difficulty in sample collection and the like of a high-sensitivity mass spectrum oil gas leak detection method can be solved in a targeted manner, and the functions of environmental interference suppression, efficient collection of oil gas molecules, improvement of spatial scanning resolution and the like can be realized at the same time.

The invention discloses an industrial gas production monitoring system based on data processing, and relates to the technical field of online monitoring, and the industrial gas production monitoring system comprises a data acquisition module which uses a plurality of sensors with determined positions to acquire real-time parameters in the industrial gas production process; the raw material gas detection module is used for acquiring raw material gas data through various sensors arranged at a raw material gas inlet and a raw material gas outlet and carrying out raw material quality detection on the raw material gas; the parameter monitoring module is used for detecting process parameters of gas production through a temperature sensor, a flow sensor and a pressure sensor; the safety detection module is used for carrying out leakage detection on the industrial gas production device and carrying out factory environment detection by using a multi-gas composite detector; the quality detection module is used for detecting the quality of the produced industrial gas by using a high-sensitivity sensor and a mass spectrometer; and the early warning module is used for carrying out fault detection on the industrial gas production based on all the obtained data and sending out safety early warning according to a fault detection result.

The invention relates to a mass spectrometer ion detector micro-current multistage amplification circuit, which comprises a primary amplification circuit, a voltage following circuit, a secondary amplification circuit, a gain adjustment control circuit and an analog-to-digital conversion circuit, the gain adjustment control circuit can dynamically adjust the gain gears of the first-stage amplification circuit and the second-stage amplification circuit, 16 groups of different amplification gains can be achieved in total, and the application requirement for simultaneous detection of nine orders of magnitude of substances with different concentrations is met. The circuit is simple and reliable, is flexible and convenient to use, greatly widens the detection range of the mass spectrometer, and improves the automatic control level and detection efficiency of the mass spectrometer.

The invention discloses a mass spectrometer electrometer based on a capacitance integrator, and belongs to the technical field of electrometers. Comprising a capacitance integrator, the capacitance integrator is connected with a voltage holding circuit, the voltage holding circuit is connected with an acquisition control circuit and an amplification circuit, and the amplification circuit is connected with the acquisition control circuit; and the acquisition control circuit controls electric signals input into the capacitance integrator, the voltage holding circuit and the amplifying circuit through an I / V conversion control method, so that I / V conversion is completed. The capacitance integration is used for completing I / V conversion, the problem of high-resistance forbidding can be solved, meanwhile, compared with high-resistance conversion, the capacitance integration is adopted, the temperature stability of the electrometer is improved, and noise is reduced.

The invention belongs to the technical field of detection, relates to a free radical detection method, particularly provides a water free radical cation detection method, and aims to realize water free radical cation detection which is efficient, rapid, free of sample pretreatment and convenient to analyze. According to the invention, an LTQ-XL linear ion trap mass spectrometer is used as a detection tool, and a dielectric barrier corona discharge method is adopted to provide a water free radical cation detection method. The method comprises the following steps of: filling argon (Ar) between two discharge electrodes as a working gas, applying a certain voltage to two electrodes of a dielectric barrier discharge ionization source (DBDI), detecting water free radical cations to obtain a corresponding mass spectrum to represent the water free radical cations, and optimizing a target signal to obtain corresponding mass spectrum data. The method can be used for efficiently and quickly detecting the water free radical cations without sample pretreatment and the like, is convenient to analyze and apply, and has remarkable innovativeness and wide application prospects.

The invention relates to the technical field of vacuum measurement, in particular to a device for expanding the linear range of mass spectrometry measurement, which comprises a gas transmission pipeline, an electromagnetic valve, a small hole and a mass spectrometer, and is characterized in that the front end of the gas transmission pipeline is used for allowing a sample to be measured to enter, and the rear end of the gas transmission pipeline is connected with the mass spectrometer; the middle part of the gas transmission pipeline is divided into three channels, namely a first gas transmission pipeline, a second gas transmission pipeline and a third gas transmission pipeline; the first electromagnetic valve and the first small hole are sequentially arranged on the first gas transmission pipeline, the second electromagnetic valve and the second small hole are sequentially arranged on the second gas transmission pipeline, and the third electromagnetic valve and the third small hole are sequentially arranged on the third gas transmission pipeline. According to the method, manual dilution or segmented sample injection is not needed, a wide concentration range can be covered by single analysis, more than 60% of time cost is saved, and measurement in a dynamic range of 106 is realized.

The invention relates to the technical field of instruments and meters, in particular to an inductively coupled plasma mass spectrometer system for intelligent data processing and report generation. Comprising a sample introduction unit, a plasma excitation and ionization unit, a mass analyzer and detection unit, a vacuum system unit and an intelligent data processing and report generation unit. Efficient ionization is achieved through a bipolar radio frequency switching and AI optimized reaction gas plasma source, the AI optimization module monitors in real time and dynamically adjusts parameters so that the ionization efficiency can be stabilized at 92% + / -2%, and meanwhile a reaction gas control system can optimize plasma conditions to suppress interference ions. And the mass analyzer and the detection unit realize high-precision ion separation by utilizing AI interference correction and a QMS-TOF double analyzer mode, and an interference elimination module can automatically eliminate polyatomic ion interference, so that the ionization efficiency, the analysis precision and the accuracy are improved, the interference is effectively inhibited, and the analysis capability of the system on a complex sample is enhanced.

The invention discloses a helium detection device and method for the airtightness of a bonding interface and a bonding microcavity, and belongs to the field of the airtightness of MEMS devices. The device comprises a sample holder, a mass spectrometer, a molecular pump, a mechanical pump and other components, helium is used as detection gas, and the helium is leaked only through a bonding interface through a customized and processed test sample and sample holder structure, so that the interference of other leaks in a non-bonding area on a test result is avoided. The testing method comprises the steps of sample introduction, vacuum pumping, helium filling, signal detection, dynamic and steady state testing and the like, the helium leak rate is monitored in real time by combining with a helium mass spectrometer, and the minimum leak detection rate is that high-sensitivity air tightness detection is ensured. According to the method, the airtightness of the bonding interface can be independently evaluated, and a reliable basis is provided for development of a novel bonding process. The method is suitable for air tightness detection and evaluation of the bonding process in MEMS device processing and manufacturing.

A method of mass spectrometry comprising: a) providing a mass spectrometer having a time of flight (TOP) mass analyser: b) performing a survey scan comprising separating a packet of precursor ion species and mass analysing ions so as to obtain first mass spectral data: c) determining a time window over which one of the precursor ion species. or fragment or product ions derived therefrom, were mass analysed: d) separating another packet of precursor ion species and mass analysing ions so as to obtain second mass spectral data. wherein the pusher of the TOP mass analyser is pulsed according to a plurality of consecutive pulse sequences during a plurality of respective pulse sequence time periods. wherein each pulse sequence consists of consecutive pushes that are arranged such that the duration between any pair of pushes in the pulse sequence is different to the duration between any other pair of pushes within the pulse sequence: f) selecting mass spectral data, from the second mass spectral data, that was obtained during a time period corresponding to said time window of the survey scan, so as to obtain selected data; g) repeating steps d) to f) at least one further time such that multiple sets of said selected data are obtained; combining said multiple sets of selected data and decoding the combined data to obtain mass spectral data representative of the mass to charge ratios of the ions detected by the TOP mass analyser.

The invention provides a mass spectrometer operation state monitoring method, system and device and a medium, and relates to the technical field of fault monitoring, and the method comprises the steps: collecting environment parameters in a mass spectrometer operation environment, carrying out the vacuum degree influence analysis of a mass spectrometer according to the environment parameters, and obtaining vacuum degree influence parameters; analyzing the mass axis offset influence of the mass spectrometer according to the environmental parameters to obtain mass axis offset parameters; testing to obtain an actual vacuum degree influence parameter and an actual mass error parameter of the mass spectrometer, performing state influence verification by combining the vacuum degree influence parameter and the mass axis offset parameter, and processing to obtain a vacuum verification coefficient and a mass verification coefficient; and according to the vacuum verification coefficient and the quality verification coefficient, performing fusion state anomaly analysis on the vacuum degree influence parameter and the quality axis offset parameter to obtain a state anomaly coefficient, and performing fault judgment and early warning. The technical problem that fault early warning is not timely in the monitoring process of the operation state of the mass spectrometer in the prior art is solved.

The invention discloses an atomization mechanism for a plasma mass spectrometer, and relates to the technical field of atomizers, the atomization mechanism comprises an atomization cup, an atomization head and a sample introduction hopper which are respectively arranged at two openings of the atomization cup, a transmission mechanism arranged in the atomization cup, and an atomization nozzle communicated with the interior of the atomization cup, the sample feeding hopper is rotationally connected with the inner wall of the atomizing cup, and the transmission mechanism is in transmission connection with the sample feeding hopper; to-be-atomized liquid flows into the sample feeding hopper through the atomizing head; atomized airflow flows into the atomizing cup through the sample injection hopper and can be blown to liquid in the sample injection hopper; the transmission mechanism can drive the sample feeding hopper to rotate under the action of atomized airflow; and the liquid is atomized in the atomizing cup and then is discharged through the atomizing nozzle. In the atomization process, the transmission mechanism can drive the sample feeding hopper to rotate under the action of atomization airflow, powder and particles in liquid raw materials can be well decomposed through rotation of the sample feeding hopper, the stability of the concentration of liquid fed into a plasma light source is guaranteed, and meanwhile the atomizer can be prevented from being blocked.

The invention relates to the technical field of mass spectrometers, and discloses a mass spectrometer tuning method and device, electronic equipment, a storage medium and a program product, and the method comprises the steps: obtaining a tuning parameter data set of a target mass spectrometer, the tuning parameter data set comprising a plurality of tuning parameters and a parameter range corresponding to each tuning parameter; obtaining an optimization target of the target mass spectrometer; based on the tuning parameter data set, the optimization target and a pre-constructed constrained multi-target Bayesian optimization framework, predicting an optimal tuning parameter combination of the optimization target, the optimal tuning parameter combination being used for tuning the target mass spectrometer; the constrained multi-objective Bayesian optimization framework combines Bayesian optimization and multi-objective optimization. According to the invention, multi-objective optimization is carried out based on the constrained multi-objective Bayesian optimization framework, the optimal tuning parameter combination can be automatically generated, simultaneous tuning of multiple parameters of the mass spectrometer is realized, and the tuning performance and precision of the mass spectrometer are improved.

The invention relates to the technical field of molecular simulation, and provides a method for constructing a heavy component average molecular structure of thickened oil, which comprises the following steps: inputting parameters, generating a core aromatic ring unit, constructing an inner-layer aliphatic ring unit, constructing an outer-layer aliphatic ring unit, generating a side chain unit, and storing and outputting structural information. A plurality of molecular structures meeting experimental data are generated at a time through a traversal algorithm thought, composition characteristics of a heavy oil complex mixture are met, more available molecular structures are provided for molecular simulation, the accuracy and efficiency of molecular modeling are improved, the molecular structures completely meeting the experimental data can be rapidly generated, and the method is suitable for large-scale popularization and application. And only the mass spectrometer, the elemental analyzer, the nuclear magnetic resonance hydrogen spectrum and the infrared spectrum data need to be input, so that the experiment cost is reduced.

The utility model discloses an ionization sample injection platform device for a mass spectrometer. The ionization sample injection platform device comprises a base, and a rotary sample frame, a swing arm grabbing mechanism, a turnover sample injection port mechanism and a high-voltage applying mechanism which are arranged on the base, the rotary sample frame is used for loading a plurality of to-be-tested samples; a sample to be detected is arranged in the suction head; the swing arm grabbing mechanism is used for taking and placing a to-be-tested sample through lifting and rotating actions of an electric gripper; the overturning sample inlet mechanism is arranged at the detection port of the mass spectrometer and is used for controlling the to-be-detected sample to execute an overturning action, so that the to-be-detected sample is aligned with the tip part of the detection port of the mass spectrometer; the high-voltage electricity applying mechanism is used for releasing high-voltage electricity to the tip end of the suction head. The ionization sample introduction platform device structure for the mass spectrometer enters a field, and the detection efficiency can be remarkably improved.

The application discloses a testing device and testing method for hydrogen isotope permeation parameters of fusion reactor application materials, relates to material testing technology in the hydrogen field, and belongs to the field of material testing technology in the hydrogen field. The testing device for hydrogen isotope permeation parameters of fusion reactor application materials comprises the following: a membrane sample is installed in a membrane testing cavity to divide the membrane testing cavity into a gas inlet sub-cavity and a permeation sub-cavity; a gas inlet tank is selectively communicated with the gas inlet sub-cavity to supply testing gas; a collecting tank is selectively communicated with the permeation sub-cavity to collect outflowing gas; a vacuum pumping structure is used for pumping the gas inlet sub-cavity and the permeation sub-cavity; a heating structure is used for heating the gas inlet sub-cavity and the permeation sub-cavity; a high-resolution mass spectrometer is selectively communicated with the permeation sub-cavity, and gas selectively flows into the high-resolution mass spectrometer. The testing device for hydrogen isotope permeation parameters of fusion reactor application materials can control the gas pressure and temperature in the two sub-cavities respectively, thereby accurately determining the hydrogen isotope permeation parameters of the materials, and the precision is high, and the data resolution is excellent.

A hybrid inductively coupled plasma mass spectrometer (ICP-MS) system is disclosed for simultaneous elemental and molecular analysis in positive and negative polarities. It includes an ICP torch that generates plasma with a buffer gas, producing both positively and negatively charged ions from a sample. Positioned between the sampler and skimmer, an insert with a defined geometry forms a reaction chamber. Various embodiments feature multiple apertures for pressure control, a rotatable disk for aperture regulation, a slider gate for pressure adjustment, a circular gate with adjustable radial apertures, and an inlet for introducing gases, reagents, dopants, or analytes. These components enable precise pressure modulation, optimizing performance for dual-polarity mass spectrometry. The system enhances analytical flexibility by facilitating controlled ion reactions, improving sensitivity and specificity for both elemental and molecular applications. This innovation expands ICP-MS functionality, supporting diverse scientific and industrial applications requiring high-precision mass analysis.

A power supply device applies a voltage to a quadrupole mass filter. The power supply device has a main substrate and a wave-detection substrate. The main substrate includes a detector. The wave-detection substrate includes a wave detector and an identifier. The wave detector detects an AC component of a voltage to be applied to the quadrupole mass filter as a wave-detection voltage. The identifier outputs identification information of the wave detector defined in correspondence with the configuration of a rectifying device of the wave detector. The detector detects identification information output by the identifier, and supplies the detected identification information to a corrector that corrects a deviation of voltage caused by a leakage current of the rectifying device.

The invention relates to the technical field of plasma concentration monitoring methods, in particular to a method for rapidly detecting the content of tacrolimus in plasma through paper spray mass spectrometry. The method provided by the invention comprises the following steps: adding a to-be-detected plasma sample into a precipitation solution, vortex, taking supernate, and dropwise adding the supernate onto a paper base; spraying voltage is applied to the paper base, the paper base generates electrospray, and the electrospray enters a mass spectrometer for detection; preparing a gradient matrix matched tacrolimus standard solution, replacing the to-be-detected plasma sample with the gradient matrix matched tacrolimus standard solution, repeating the operation, recording a detection result, and drawing a standard curve by taking the matrix matched tacrolimus concentration as an abscissa and taking peak area data acquired by a mass spectrometer as an ordinate; and comparing the recorded detection result with the drawn standard curve, and quantitatively analyzing the content of tacrolimus in the to-be-detected plasma sample. The method disclosed by the invention is simple to operate and high in analysis speed, has relatively good precision and accuracy and also has high sensitivity and high selectivity.

The invention discloses a device and a method for testing hydrogen isotope permeation parameters of a fusion reactor application material, and relates to a material testing technology in the field of hydrogen, and the device for testing the hydrogen isotope permeation parameters of the fusion reactor application material is characterized in that a membrane sample is mounted in a membrane testing cavity to divide the membrane testing cavity into a gas inlet sub-cavity and a permeation sub-cavity; the gas inlet tank is selectively communicated with the gas inlet sub-cavity so as to supply test gas, and the collecting tank is selectively communicated with the permeation sub-cavity so as to collect flowing-out gas; the vacuumizing structure is used for vacuumizing the air inlet sub-cavity and the permeation sub-cavity, and the heating structure is used for heating the air inlet sub-cavity and the permeation sub-cavity; the high-resolution mass spectrometer is selectively communicated with the permeation sub-cavity, and gas selectively flows into the high-resolution mass spectrometer. According to the device for testing the hydrogen isotope permeation parameters of the fusion reactor application material, the air pressure and the temperature in the two sub-cavities can be controlled respectively, so that the hydrogen isotope permeation parameters of the material can be accurately measured, the accuracy is high, and the data resolution is excellent.

The invention discloses a wide-temperature-range ultrahigh vacuum system gas component testing device and method, the device comprises an inner vacuum cavity, an outer vacuum cavity, a sample supporting plate, a quadrupole mass spectrometer, a vacuum system, a vacuum coupling sample transfer rod and a control device, the outer vacuum cavity is used for loading, unloading and transferring a sample, and the inner vacuum cavity is used for maintaining and testing the ultrahigh vacuum system. The vacuum system adopts a mechanical pump, a molecular pump, an ion pump and other multi-stage vacuum pumps to vacuumize, and adopts multiple groups of vacuum gauges to measure different vacuum degrees. A quadrupole mass spectrometer is adopted to analyze and detect gas components generated by the parts.

The invention relates to the field of mass spectrum equipment, in particular to a low-noise and high-sensitivity mass spectrometer Faraday cup. The Faraday cup comprises a rectangular housing, one side of which is open; the suppression grid is arranged in the shell and is close to the opening; the collector is arranged in the shell and is adjacent to the suppression grid; a slit baffle is arranged at the opening of the shell; the collector is fixed through the insulating lining, insulated from the shell, and used for receiving the ion beam and generating current; the suppression grid electrode is fixed through an insulating lining and a metal positioning block, and negative bias voltage is applied to suppress escape of secondary electrons; the top cover is assembled on the shell to form a sealed whole; the collector connecting piece is arranged on the lower portion of the collector, one end of the Faraday cup outgoing line is welded to the collector connecting piece, and the other end of the Faraday cup outgoing line is led out of the shell. Noise is remarkably reduced, and the detection sensitivity of a mass spectrometer is improved.

The invention discloses a gas mass spectrometer ion source performance testing device, and belongs to the technical field of mass spectrometer testing, the ion source performance testing device comprises an ion source testing assembly, the ion source testing assembly is used for fixing and testing a to-be-tested ion source and converting ions into ion beams, and the ion source testing assembly is connected with an adjustable flight tube assembly. The adjustable flight tube assembly provides a flight channel for the ion beam, the adjustable flight tube assembly can stretch and retract relative to the ion source test assembly to adjust the flight distance of the ion beam, one end, far away from the ion source test assembly, of the adjustable flight tube assembly is connected with an adjustable observation assembly, and the adjustable observation assembly can slide relative to the ion source test assembly. Therefore, the observation position and the ion beam flight distance are adjusted. According to the invention, the installed to-be-detected ion source can be rapidly detected in a high-vacuum environment, the detection time is shortened from two days to half an hour aiming at complex operation of an existing ion source on an instrument, and the installation and detection efficiency of the ion source is greatly improved.

The invention relates to a continuous ion beam screening and enriching system and method and a mass spectrograph, and the continuous ion beam screening and enriching system comprises a vacuum differential unit, a first ion focusing unit, a mass screening unit, a second ion focusing unit, an enriching and releasing unit and a third ion focusing unit which are sequentially arranged from upstream to downstream. The enrichment and release unit is provided with a shell and a plurality of annular electrode plates which are arranged in parallel and located in a cavity of the shell, a resistor and a capacitor are connected between every two adjacent annular electrode plates to form a gradient electric field, and center holes of the annular electrode plates are concentrically arranged to jointly form an ion channel penetrating between an inlet and an outlet of the enrichment and release unit. According to the invention, continuous ion beam low-energy-consumption enrichment and pulse release can be realized, and strict requirements of scientific and industrial fields on mass spectrum detection and ion control precision are met.

The utility model discloses a high-efficiency sampling device of an ultra-high performance liquid chromatography tandem mass spectrometer, which comprises a support, and a linkage adjusting mechanism is mounted in the middle of the top end of the support. The device has the beneficial effects that the linkage adjusting mechanism consisting of the racks, the sliding strips, the test tube placing seats, the clamping holes, the motor and the gear is mounted on the support, so that after a sample test tube on one test tube placing seat is used, the gear rotates under the action of the motor, and the gear can be matched with the corresponding rack after rotating; therefore, the used test tube placing seat slides out of the support, and the other test tube placing seat on which the sample test tube is placed is moved into the support, so that the sample test tube on the other test tube placing seat can be continuously fed when the sample test tube on one test tube placing seat is replaced, and the sample test tube on the other test tube placing seat can be conveniently replaced. The interruption of the sample introduction process of the ultra-high performance liquid chromatography tandem mass spectrometer is avoided, and the sample introduction efficiency of the ultra-high performance liquid chromatography tandem mass spectrometer is higher.

The invention discloses a device and a detection method for online oxidation-enrichment-reduction determination of nanogram-level nitrogen isotopes in a solid, and belongs to the technical field of nitrogen isotope analysis. The device comprises an oxidation system, a nitrogen oxide enrichment system, a nitrogen reduction system, a mass spectrum interface system, a stable isotope ratio mass spectrometer and pipelines for connecting all parts of the device. The device provided by the invention greatly reduces the quantitation limit of the nitrogen isotope in the solid sample, can realize high-precision determination of the nanogram-level nitrogen isotope in the solid sample, and has the advantages of simplicity and convenience in operation, high accuracy and the like.

The invention relates to the technical field of mass spectrometer sampling, in particular to a sampling device of an inductively coupled plasma mass spectrometer, which comprises a bottom plate, and an inductively coupled plasma mass spectrometer body is fixedly mounted at the top of the bottom plate. During application, the sample introduction mechanism adopts a first motor to drive a turntable to carry a sample during use, power is amplified through transmission of a large belt wheel and a small belt wheel, and a non-contact magnetic coupling drives a pumping spiral driving blade to rotate to generate negative pressure, so that automatic sample extraction, negative pressure control of opening and closing of a plugging plate and accurate control of a sample conveying channel are realized; by means of the design, carrying power is converted into pumping power, the equipment structure is simplified, the number of parts and energy consumption are reduced, the equipment operation and maintenance cost is reduced, an automatic continuous sample injection process replaces traditional single-pipe extraction, the sample injection time is greatly shortened, and the sample treatment efficiency is improved.

In a mass spectrometer (10) for gas analysis, comprising: a mass spectrometer housing (12) evacuated by a vacuum pump; an ion source (16) for ionizing gas atoms or molecules entering the mass spectrometer enclosure (12) and accelerating ions in the mass spectrometer enclosure (12); an ion trap (22) made of an electrically conductive material for collecting ions generated by the ion source (16); an electrical measurement device (24) for measuring the potential or current of the ion trap (22) and connected to the ion trap (22) for inferring the ions collected by the ion trap (22) from the measured potential or current; a magnetic or electromagnetic deflection device configured to deflect or map ions having a specific mass-to-charge ratio to the ion trap (22); an electron barrier (30) made of an electrically conductive material is provided at the ion trap (22), the electron barrier having a lower potential than the ion trap (22) and being configured to generate a reverse electric field to return electrons released from the ion trap (22) onto the ion trap (22).

According to the dioxin closed-loop control method based on real-time detection and dynamic optimization, an online monitoring system is deployed, a tunable laser ionization time-of-flight mass spectrometer is arranged at an incineration flue gas discharge outlet to detect the concentration of trichlorobenzene serving as a dioxin indicator in real time, and a sensor is combined to detect working condition parameters; polynomial regression is used for real-time conversion of dioxin toxicity equivalent concentration, and an on-line monitoring-toxicity evaluation integrated system is formed. And a double-layer random forest-eagle mixed optimization model is constructed, the first layer is based on historical working condition data to train a random forest model to predict the dioxin emission trend and the potential standard exceeding risk, and the second layer is used for dynamically optimizing the incineration parameter combination through an improved eagle optimization algorithm and issuing the incineration parameter combination to an incineration system in real time. And meanwhile, a calcium-based retardant directional spraying device is deployed in a flue gas purification section, so that uniform covering and accurate dosage control of the retardant are realized, and the low-temperature resynthesis reaction of dioxin is inhibited. And finally, parameters of the double-layer optimization model are dynamically updated based on the error of an actual detection value and a predicted value, the adaptability of the model to working condition fluctuation is improved, therefore, dioxin emission is effectively reduced, and the environmental protection property and stability of the incineration process are improved.