2040results about "Ion-exchange process apparatus" patented technology

The invention relates to catalytically coated anion exchange membranes and their production. The catalytically active coated anion exchange membranes are used in electrochemical cells, in particular for water electrolysis. The object of the invention was to provide a process for producing an electrocatalytically active coated anion exchange membrane whose coating is porous and thus the electrocatalytically active centers located in the coating are easily accessible to the reactants. A basic idea of the process according to the invention is to incorporate particulate inorganic material into the catalyst coating as a placeholder, to solidify the coating, and then to leach the inorganic material out of the coating. The leaching converts the inorganic material into a water-soluble product that can be easily washed out of the coating.What remains are voids (pores) where the particulate inorganic material was previously located within the coating. The inorganic material therefore assumes the function of a structure-imparting agent within the coating composition, which is lost during the catalytically active coating process.

The invention discloses a double-site doped titanium lithium ion sieve adsorbent as well as a preparation method and application thereof. The adsorbent is a lithium removal product of a double-site doped titanium lithium ion sieve adsorbent precursor, the chemical general formula of the double-site doped titanium lithium ion sieve adsorbent precursor is Li (2-x) MxTi (1-y) NyOz, M is at least one of Na < + >, K < + >, Zn < 2 + >, Co < 2 + >, Ni < 2 + >, Mg < 2 + > and Al < 3 + > and occupies Li site, N is at least one of Cr < 3 + >, Fe < 3 + >, Zr < 4 + >, Nb < 5 + >, Ta < 5 + >, V < 5 + >, Mo < 6 + > and W < 6 + > and occupies Ti site, x is larger than or equal to 0.001 and smaller than or equal to 0.5, and y is larger than or equal to 0.001 and smaller than or equal to 0.5. Metal cations are introduced to replace Li sites and Ti sites at the same time, Li site substitution enlarges interlayer spacing and improves Li < + > diffusion rate, Ti site substitution regulates local chemical bond and electron distribution, stabilizes lattice structure and enhances electron conduction, and through double-site doping, 'ion-electron 'double channels are constructed, so that a collaborative optimization effect is achieved. The double-site doped titanium lithium ion sieve adsorbent disclosed by the invention is applied to adsorption and extraction of lithium in a Bayer process sodium aluminate solution, and the adsorbent shows excellent adsorption performance.

The invention relates to the technical field of chemical separation, in particular to a cyclohexanone rectification and purification method based on high-tower segmented packing, which comprises the following steps: step 1, filtering a cyclohexanone raw material containing impurities to remove solid particles, and dynamically adjusting the filtering precision according to the viscosity of the raw material; 2, arranging a bottom section, a middle section and a top section in the vertical high tower; the temperature gradient of each section is regulated and controlled through an independent temperature control unit, so that the temperature gradient of the middle section is matched with the relative volatility of the cyclohexanone-light component; 3, dynamically adjusting the reflux ratio based on the real-time detection result of the purity of the tower top distillate, and controlling an intermittent discharge valve according to the density change of the tower bottom heavy component enrichment liquid so as to continuously remove the heavy components; and 4, recycling the waste heat of the steam at the top of the tower for preheating the raw materials, and inhibiting the tower pressure fluctuation through a buffer tank. Through the innovative design of sectional packing of the high tower, the separation efficiency is improved, the energy consumption is reduced, and meanwhile, the equipment reliability is improved.

The invention discloses a method for extracting and purifying flavone in litsea coreana through an ultrasonic-assisted eutectic solvent, and belongs to the technical field of green processing of natural products. The invention provides a method for efficiently preparing litsea coreana flavone by integrating computer prediction, green solvent extraction and resin purification technologies. The method comprises the following steps: firstly, calculating and screening a deep eutectic solvent system with the highest affinity with the litsea coreana flavone on the basis of a COSMO-RS theoretical model, then coupling the optimized DES with an ultrasonic-assisted extraction (UAE) technology, and through the synergistic effect of the DES and the UAE technology, remarkably improving the extraction rate of the litsea coreana flavone and furthest keeping the biological activity of a target component; then, a macroporous resin dynamic adsorption-desorption purification process is linked, so that high-selectivity enrichment and impurity removal of the flavonoid compounds in the crude extract are realized, a high-purity product is obtained, and a complete process route from intelligent screening, efficient extraction to precise purification is finally formed.

The invention provides an adsorbent capable of simultaneously adsorbing bilirubin and cytokines and a preparation method and application thereof, and the preparation method comprises the following steps: carrying out suspension polymerization reaction on a styrene monomer and a polyvinyl cross-linking agent in a dispersion medium under the action of a continuous multi-component pore-foaming agent and an initiator to prepare polystyrene-based macroporous resin; carrying out chloromethylation reaction on the polystyrene-based macroporous resin to prepare chlorine balls; carrying out post-crosslinking reaction on the chloromethylated beads to prepare the adsorbent capable of adsorbing bilirubin and cytokines at the same time; the continuous multi-component pore-foaming agent comprises a first pore-foaming agent, a second pore-foaming agent and a third pore-foaming agent of which the solubility parameters are gradually increased in sequence; the temperature of the suspension polymerization reaction is adjusted according to the mass fraction of the polyvinyl cross-linking agent in the monomer mixture and the solubility parameter of the continuous multi-component pore-foaming agent, and the monomer mixture is composed of styrene monomers and the polyvinyl cross-linking agent. The bilirubin and cell factors can be adsorbed at the same time, and the safety of blood purification is improved.

The invention provides a high-molecular adsorption material with high selectivity on platinum group metals as well as a preparation method and application of the high-molecular adsorption material, and belongs to the technical field of material science. Comprising the following steps: (1) preparing a methanol solution containing platinum group metal ions, and adding a functional monomer mixture and modified graphene oxide to form a pre-assembled compound; (2) adding a cross-linking agent and an initiator, removing oxygen, and polymerizing to obtain a polymer; and (3) grinding the polymer, eluting metal ions, washing to be neutral, and drying. The high-molecular adsorption material provided by the invention takes modified graphene oxide as a support body, template molecules and specific functional monomers (4-vinylpyridine and 2-mercaptobenzimidazole) are combined to form a pre-assembled compound, then a cross-linking agent and an initiator are added, recognition sites are fixed through cross-linking polymerization, and finally, the high-molecular adsorption material is obtained after the template molecules are eluted. The adsorbent is high in adsorption rate, capable of specifically adsorbing platinum group metal, good in stability and reproducibility and capable of being repeatedly used.

The invention relates to an aromatic hydrocarbon isomer adsorbent containing a modified X-type molecular sieve. The outer surface area of the modified X-type molecular sieve is 9.5-19m < 2 > / g, and the sum of the pore volume of mesopores and the pore volume of macropores is 6%-18% of the total pore volume. The p-xylene adsorbent comprises 88-95% by mass of a modified X-type molecular sieve, 4-11% by mass of a crystal transformation X-type molecular sieve and 1-3% by mass of a matrix. The invention also relates to a preparation method of the adsorbent and application of the adsorbent in adsorption separation of p-xylene from mixed C8 aromatic hydrocarbons.

The present application relates to the technical field of water treatment devices, and provides a water softener. The water softener comprises a water softening valve, a connection assembly, a water path assembly, and resin tanks. The water softening valve comprises a valve body, a valve element assembly, a driving part, and a transmission mechanism. Both the valve element assembly and the driving part are disposed within the valve body, and the driving part is in transmission connection with the valve element via the transmission mechanism. The connection assembly is in communication with the water softening valve and is located at one side of the water softening valve. The connection assembly is provided with a drain passage. The driving part is configured to drive the transmission mechanism to act, so as to control opening of the drain passage. The water path assembly is in communication with the connection assembly, and is used to guide the flow of water. The resin tanks are used to soften water flowing therethrough. In the present application, a driving apparatus is employed to drive the transmission mechanism to act, so that the transmission mechanism can control the valve element to control water-path switching, and can control the opening of passages within the connection assembly, thereby enabling full control of the entire water path, simplifying control logic, improving control efficiency, reducing the number of control devices, and lowering the failure rate of the water path control assembly.

The present disclosure is directed to methods and systems of purifying solvents. The purified solvents can be used for cleaning a semiconductor substrate in a multistep semiconductor manufacturing process.

The invention discloses a strong-hydrophobicity chromatographic stationary phase modified by a covalent triazine skeleton containing an octyl chain as well as a preparation method and application of the strong-hydrophobicity chromatographic stationary phase. Activated silica gel is modified by utilizing a silane coupling agent, so that gamma-glycidyl ether oxypropyl trimethoxy is introduced into the surface of the silica gel; and performing in-situ growth of a covalent triazine skeleton layer containing an octyl chain through a Schiff base condensation reaction to prepare the strong-hydrophobicity chromatographic stationary phase. A covalent triazine skeleton containing a hydrophobic octyl chain in the structure is used for modifying the surface of silica gel, and a bonding phase contains a triazine ring, a benzene ring, an octyl chain and an amino group. According to the stationary phase, a hydrophobic long octyl chain is introduced into a bonding unit of CTF, so that the structure, morphology and performance of the CTF are changed, a'flower-on-sphere 'morphology is formed, and the stationary phase has a rigid porous structure, adjustable hydrophilicity / hydrophobicity, a rich pi electron system, strong hydrophobicity and good separation selectivity for non-polar compounds, and can be widely applied to separation of various samples.

An ion exchange filter (100) comprising: an outer housing (1) comprising a coolant inlet (2) and a coolant outlet (12); and an ion exchange device (11) configured to be disposed within the outer housing (1). The ion exchange device (11) comprises: an inner housing (5) configured to be inserted within the outer housing (1), the ion exchange filter (100) further comprising an inlet chamber (16) defined between a bottom portion of the inner housing (5) and a bottom portion of the outer housing (1); an ion exchange element (6) disposed within the inner housing (5) and configured to adsorb conductive ions in a coolant liquid; and an upper cover (10) removably connected to the inner housing (5) and to the outer housing (1), the ion exchange filter (100) further comprising an outlet chamber (73) defined between a top portion of the inner housing (5) and the ion exchange element (6).

The invention relates to the field of polymer grading, and discloses a polyethylene grading method, polyethylene obtained through the polyethylene grading method, a system for polyethylene grading and application of the system. According to the polyethylene grading method, on the basis of preparing a high-temperature liquid chromatographic column, two-time flow division is adopted, and the flow ratio of second flow division is controlled, so that accurate and directional grading of a polyethylene raw material is realized, and the purposes of accurate and directional regulation and control of the average molecular weight, the molecular weight distribution curve and the branched structure of polyethylene, especially low-density polyethylene, are realized.

The invention relates to the technical field of pharmaceutical separation, and discloses a device, method and application of ursodeoxycholic acid preparation and purification. The device comprises a separation tank, wherein a batching center cylinder is rotatably installed inside the separation tank, and a plurality of elution tubes are arranged around the batching center cylinder. The batching center cylinder rotates forward, and centrifugal force is used to load adsorption resin into each elution tube. Then, the batching center cylinder rotates reversely, and the volume of each elution tube is poured out by anti-centrifugal force, so as to achieve a more convenient effect of replacing the adsorption resin. The replaced adsorption resin is cleaned outside the device and reused. The purification method and application thereof realize column loading, sample loading and elution in the separation tank in sequence without stopping the machine for operation, and simplify the column loading and column replacement operations, so as to solve the problem that the separation and purification process in the prior art is complicated and not suitable for batch production, so as to meet the industrial production requirements of solvent recycling.

The invention relates to the technical field of preparation of high-purity boron oxide, and discloses a purification method of high-purity boron oxide and a device thereof, and the purification method comprises the following steps: step 1, mixing crude boron oxide with a liquid metal alloy, and dissolving metal impurities through gradient temperature control; 2, applying ultrasonic treatment to the mixed system, introducing a vortex field, and stripping impurities on the surface of the boron oxide; 3, a liquid metal phase and a boron oxide solid phase are separated through cooperation of a magnetic field and a pulse high-voltage electrostatic field; 4, non-metal ion impurities are removed through a gradient porous ceramic adsorption bed; and step 5, melting boron oxide in vacuum and carrying out gradient cooling crystallization. By adopting the technical scheme of a Ga-I n-Bi-Er quaternary liquid alloy system, the technical effect of selective targeted removal of metal impurities is achieved, and compared with a liquid metal system depending on single phase solubility difference in the prior art, the defect that efficient chelating and dynamic settling separation of the impurities cannot be achieved at the same time is overcome.

The utility model belongs to the technical field of semiconductor silicon wafer processing, and discloses semiconductor silicon wafer grinding waste liquid filtering equipment, which comprises a processing box, and is characterized in that the processing box is arranged on a bottom frame, bearings are arranged at the upper end and the lower end of the processing box, and a bearing frame is arranged at the top of the processing box; a primary filtering structure and a driving structure are arranged on the bearing frame, the primary filtering structure is communicated with the treatment box, a stirring structure and a liquid discharging structure are arranged in the treatment box, and the stirring structure and the liquid discharging structure are both connected with the driving structure. According to the utility model, the used semiconductor silicon wafer grinding waste liquid is conveyed into the primary filtering box, and large-particle impurities in the grinding waste liquid are filtered by the primary filtering box, so that the grinding waste liquid can be filtered for multiple times, the difficulty of primary filtering treatment can be reduced, the filtering effect of the grinding waste liquid is improved, and the recycling of the grinding liquid is facilitated.

The present invention relates to a container (10) for extracting lithium or lithium salts from a brine with a brine inlet port (20) for receiving the brine arranged at a first portion of the container (10); a multiple-use port (30) arranged at a second portion of the container (10); a sorbent bed volume (40) for holding a sorbent material, arranged between the brine inlet port (20) and the multiple-use port (30); and a mixing chamber (50) arranged inside the container (10) between the brine inlet port (20) and the sorbent bed volume (40), for mixing the brine before entering the sorbent bed volume (40). The present invention further relates to a process for extracting lithium or lithium salts from the brine and to a process for extracting lithium or lithium salts from a loaded sorbent material and to a process for cleaning the container (10).

The invention discloses a processing technology of a quinoa seedling bud green juice bubble functional beverage, and belongs to the technical field of beverage processing. Comprising the steps of raw material pretreatment, crushing and juicing, filtration treatment, enzyme deactivation treatment, blending, sterilization treatment and carbonation treatment. In the filtering process, a product obtained after juicing is filtered through a 200-400-mesh filter screen and then filtered through a filter material; the filter material comprises modified PVDF (polyvinylidene fluoride), modified chitosan, modified MOFs (metal organic frameworks) and modified titanium dioxide. The modified MOFs are obtained by acetylating MOFs and then modifying the MOFs with a silane coupling agent; the modified PVDF is obtained by sequentially grafting sulfobetaine metacrylic acid ester, polyethylene glycol metacrylic acid ester and alkyl acrylate on PVDF; the modified chitosan is obtained by sequentially grafting PEG-acrylic acid and methyl methacrylate to chitosan; the modified titanium dioxide is obtained by modifying titanium dioxide through a silane coupling agent. The chenopodium quinoa seedling buds are made into the bubble functional beverage, so that the beverage is endowed with good taste; the filter material can reduce loss of protein and polyphenol and effectively retain nutritional ingredients.

The invention discloses a preparation method of an acid-resistant chlorine-resistant selective palladium adsorbent, and relates to a preparation method of a selective palladium adsorbent. The invention aims to solve the technical problems of poor structural stability, low adsorption capacity, poor selectivity and difficulty in cyclic regeneration of the existing palladium adsorbent in strong acid and high chlorine systems. According to the preparation method, fumarinonitrile is taken as a cyanogen-containing monomer, zinc chloride is taken as a catalyst, a triazine skeleton network is constructed through an ionothermal trimerization reaction, no organic solvent or expensive catalyst is needed in the process, the reaction condition is mild, the process is simple and convenient, and good environmental compatibility is achieved; the PdCl4 < 2->-doped porous carbon material provides abundant coordination sites, has a relatively large specific surface area and a developed porous structure, can effectively promote mass transfer and adsorption of metal ions, can form stable complexation with PdCl4 < 2->, shows extremely high palladium adsorption capacity and selectivity, and can still keep structural integrity and adsorption activity under strong acid and high chlorine conditions.

Provided is a cation exchange membrane in which when a hydroxide aqueous solution showing strong alkalinity is produced by using an electrodialyzer, significant swelling in the cation exchange membrane in contact with the hydroxide aqueous solution is suppressed, destruction of a cation exchange resin due to polyvalent cations contained as impurities in a raw material inorganic salt is suppressed, and the capacity of the cation exchange membrane is hardly lowered.　This cation exchange membrane is characterized by having an electric resistance of 2.0-5.0 (Ω∙cm2), as measured at 25ºC in 0.5 mol / L of a NaCl aqueous solution, and a dimensional change rate of at most 1.2%.

The invention provides a percolation device and a preparation method of a phyllanthus emblica extract. The percolation device comprises a percolation tank, a pressing device and a plurality of separation structures, the preparation method of the emblic leafflower fruit extract comprises the following steps: firstly, coarsely crushing and soaking an emblic leafflower fruit medicinal material, then percolating the emblic leafflower fruit medicinal material in a percolating device, and collecting percolate; the preparation method comprises the following steps: extracting a percolate, adsorbing the percolate through macroporous resin, eluting with water and ethanol in sequence, combining an obtained lower column liquid and a water washing liquid, separating through a ceramic membrane and an ultrafiltration membrane in sequence to obtain a micromolecular functional sugar part, decolorizing with activated carbon, eluting with an ethanol solution, concentrating and drying to obtain a polyphenol part, and proportioning to obtain a target product. According to the technical scheme provided by the invention, active micromolecular functional sugar and polyphenol components in the phyllanthus emblica can be extracted and enriched at one time. The extract is light in color and good in solubility, so that the problems of single extracted component and inconvenience in application due to poor color and solubility in the traditional process are effectively solved.

The invention relates to a method for extracting lithium from a salt lake and synchronously removing silicon and boron. The method comprises the following steps: pre-treating and filtering lithium-containing brine; carrying out reverse osmosis concentration treatment to concentrate lithium to be more than 2.5 g / L; carrying out nanofiltration treatment to remove magnesium, calcium and sulfate ions; treating by adopting an electrodialysis system to obtain a high-silicon and high-boron desalted solution and a low-silicon and low-boron lithium concentrated solution; the low-silicon and low-boron lithium concentrated solution is treated with chelating resin and boron removal resin, so that magnesium and calcium ions are smaller than or equal to 2 mg / L, boron is smaller than or equal to 20 mg / L, and the refined lithium concentrated solution is obtained; concentrating by an evaporation system, adding a precipitant, precipitating, filtering, washing, crushing and demagnetizing to obtain a low-silicon low-boron battery-grade lithium carbonate product. The invention further discloses a system for extracting lithium from the salt lake and synchronously removing silicon and boron, the complex and low-efficiency boron removal and silicon removal nanofiltration process is adopted, and concentration of lithium and efficient removal of silicon and boron are synchronously achieved; silicon scaling pollution caused by membrane separation and heat exchanger tube nests is avoided, and deep removal of silicon and boron is realized.

The present invention discloses a magnetic nanocomposite material, a preparation method thereof, and an application thereof in the enrichment of low-abundance proteins. The magnetic nanocomposite material proposed by the present invention is Fe3O4@TS-1. Its preparation method is simple to operate. The sol-gel hydrothermal method is adopted, and the preparation is stable. The magnetic composite material Fe3O4@TS-1 is successfully synthesized. While ensuring the material properties of the TS-1 molecular sieve material, this material not only guarantees excellent protein adsorption performance but also endows it with magnetism, providing a simpler, faster, and more efficient technical method for large-scale sample processing. The enrichment of low-abundance proteins based on the magnetic nanocomposite material proposed by the present invention can be applied to almost all sample types, effectively solving the interference caused by high-abundance proteins to the identification of low-abundance proteins during mass spectrometry detection, and the number of protein identifications can be increased by 100% - 700%.

A bipolar membrane in which a cation-exchange membrane and an anion-exchange membrane are joined to each other, wherein a leakage ratio of gluconic acid at 60° C. is not more than 1.0%, and the cation-exchange membrane is supported by a polyolefin reinforcing member and, further, contains a polyvinyl chloride.

The invention discloses a binder-free granular carbon molecular sieve and application thereof in C4 olefin mixture separation, and belongs to the technical field of C4 olefin adsorption and separation. The granular carbon molecular sieve for C4 olefin mixture component separation is obtained by crushing a precursor, screening particles with a proper particle size as a carbon source, and then performing carbonization and pyrolysis in a tubular furnace. The granular carbon molecular sieve disclosed by the invention is high in adsorption capacity, high in selectivity, good in stability, high in particle strength and easy to recycle and regenerate, and can be directly used for industrial devices. Compared with the traditional solvent absorption, extractive distillation and low-temperature distillation technologies, the separation method provided by the invention has the advantages of low energy consumption, small equipment investment, environmental friendliness and the like, and has a wide application prospect in the field of C4 olefin component separation.

The invention discloses equipment and a method for preparing an electronic-grade salicylic acid solution. The equipment comprises an acidification tank, an alkali tank, a micron filter, an anion filter, a cation adsorption column and a nano filter. The acidification tank is used for loading a salicylic acid solution and an acidic substance, and the alkali tank is used for loading an eluent. The method comprises the following steps: firstly, removing large impurities from a salicylic acid solution and acidic substances through a micron filter, then conveying the salicylic acid solution and acidic substances to an anion filter, adsorbing salicylic acid through anion adsorption resin to obtain phenol, removing the phenol, then introducing an eluent, washing off the salicylic acid solution, conveying the salicylic acid solution to a cation adsorption column to remove metal ions, and finally conveying the salicylic acid solution and the acidic substances to a nano filter to obtain the purified salicylic acid. And reducing the granularity of the salicylic acid solution to obtain the electronic-grade salicylic acid solution. The electronic-grade salicylic acid solution has the advantage of strong selective complexing ability to metals, and has a good wet etching effect in the integrated circuit manufacturing process.

The invention discloses a parameter differential separation process, and relates to the technical field of separation. The defects in the prior art are overcome. The method specifically comprises the following steps: carrying out a generalized separation process by using a parameter differential moving bed, and operating the generalized separation process to eliminate a displacement zone in chromatographic sequential operation; the method comprises the following steps: contacting a mobile-phase liquid feeding solution with solid-phase resin / adsorbent filler through a novel mass transfer equilibrium contact method, and starting to obtain a characteristic separation curve; the multiple components contained in the mobile phase liquid feed solution are separated by a new mass transfer equilibrium contact process such that at least one component contained in the mobile phase liquid feed solution can be adsorbed onto the resin / adsorbent. The method realizes final separation of a large-scale production separation system, improves the maximum mass transfer efficiency, can also be used for a binary separation system in the separation process of glucose and fructose, reduces the consumption of washing liquid, and reduces the final power consumption.

The invention relates to a monovalent ion selective cation exchange membrane and a preparation method and application thereof, and the preparation method comprises the following steps: mixing polyethyleneimine and a cross-linking agent to obtain a pre-polymerized solution; coating the surface of a cationic base membrane with the pre-polymerized solution, and then heating to carry out a cross-linking reaction, so as to obtain a base membrane after surface cross-linking; and soaking the base membrane subjected to surface crosslinking in an oil phase solution of acyl chloride monomers, and carrying out interfacial polymerization reaction to obtain the monovalent ion selective cation exchange membrane. Through the synergistic effect of a three-dimensional network structure constructed through cross-linking reaction and a selective separation layer constructed through interfacial polymerization, the Li < + > / Mg < 2 + > separation coefficient can be increased, and long-acting and stable operation is achieved.

The invention discloses a feed additive for synergistically improving oxidative stress resistance of broiler chickens based on oleuropein-luteoloside-maslinic acid ternary combination and application of the feed additive, the feed additive is the olea europaea leaf extract, the total polyphenol content of the feed additive is about 52%, the total flavone content is 7%, and the total flavone content is 5%. The feed is mainly composed of oleuropein, luteolin-7-beta-glucoside and maslinic acid, the oleuropein, the luteolin-7-beta-glucoside and the maslinic acid are sequentially added in a molar ratio of 6: 1: 1 to generate a synergistic anti-oxidative stress effect, and when the feed is applied to breeding on the basis of corn-soybean daily ration of broilers, the daily gain of the broilers can be obviously increased, the feed conversion ratio is reduced, and the feed conversion rate is increased. The intestinal micro-ecological health, the anti-oxidative stress effect and the organism immunity are improved, and the infection rate and the death rate of intestinal diseases such as diarrhea of broilers are reduced. The product has the advantages of being simple and convenient to prepare and use, free of toxic and side effects, beneficial to broiler chicken growth and human health, free of the problems of drug resistance, drug residues and the like, and capable of promoting chicken meat quality improvement and the like.

The invention discloses a method for separating lithium and boron in a solution with a high boron-lithium ratio. The separation method comprises the following steps: carrying out primary homogeneous electrodialysis concentration separation on a solution with a high boron-lithium ratio under an alkaline condition to prepare primary lithium-rich concentrated water; diluting the first-stage lithium-rich concentrated water to prepare first-stage diluted lithium-rich concentrated water; performing high-pressure RO concentration on the primary diluted lithium-rich concentrated water under an acidic condition to prepare lithium-rich RO concentrated water; performing first-stage homogeneous phase electrodialysis concentration separation on the lithium-rich RO concentrated water under an acidic condition to prepare first-stage lithium-rich concentrated water; carrying out adsorption boron removal and desorption treatment on the first-stage lithium-rich concentrated water by adopting boron removal adsorption resin under an alkaline condition to prepare mixed lithium-rich concentrated water and boron-containing desorption liquid; carrying out MVR (mechanical vapor recompression) evaporation on the mixed lithium-rich concentrated water for preparing battery-grade lithium carbonate; and mixing the secondary boron-rich fresh water with the boron-containing desorption solution, and carrying out MVR evaporation to obtain a boric acid product. According to the method, a reasonable boron removal process combination is adopted, and boron in the solution with the high boron-lithium ratio is removed.

The invention relates to the technical field of rare earth element separation methods, in particular to a method for separating ytterbium and lutetium by using a phosphate adsorbent, which comprises the following steps: loading a phosphate solution on a porous solid-phase carrier by using a vacuum impregnation method, and carrying out reduced pressure evaporation and drying to obtain a phosphate solid adsorbent; filling an exchange column with the solid adsorbent to obtain the exchange column filled with the solid adsorbent; enabling a nitric acid solution containing ytterbium and lutetium to flow through an exchange column filled with a solid adsorbent to complete a column adsorption process; and performing elution, performing desorption by using a desorption solution to obtain the regenerated exchange column filled with the solid adsorbent, respectively collecting the ytterbium solution and the lutetium solution, completing the separation process, and repeating the steps. By adopting the steps, the separation of ytterbium and lutetium is directly realized from the nitric acid solution containing ytterbium Yb and lutetium Lu through column adsorption separation, leaching and desorption processes, and high-purity ytterbium and lutetium products are prepared.