1980results about "Selective adsorption" patented technology

A process for upgrading plastic derived oil includes contacting the plastic derived oil with a mixed catalyst in a first reactor, where the mixed catalyst includes a decontamination catalyst and a cracking catalyst different from the decontamination catalyst. The first reactor reduces concentrations of halogen-containing compounds in the plastic derived oil. The process includes passing the first reactor effluent to a second reactor and contacting the first reactor effluent with the cracking catalyst to produce a second effluent comprising light olefins and naphtha range hydrocarbons. The process includes separating used mixed catalyst from the first reactor to produce a used decontamination catalyst and a second used cracking catalyst, and regenerating the decontamination catalyst and cracking catalyst in separate regenerators to reduce exposure of the cracking catalyst to halogen-containing compounds produced during regeneration of the used decontamination catalyst.

A process for upgrading plastic derived oil includes contacting a plastic derived oil stream with a decontamination catalyst in a first reactor, separating a first reactor effluent from a used decontamination catalyst, passing the first reactor effluent to a second reactor downstream of the first reactor, contacting the first reactor effluent with a cracking catalyst in the second reactor, and separating a second reactor effluent from a used cracking catalyst. The cracking catalyst is different from the decontamination catalyst. The process further includes regenerating the used decontamination catalyst in a decontamination catalyst regenerator to produce regenerated decontamination catalyst, and regenerating the used cracking catalyst in a cracking catalyst regenerator separate from the decontamination catalyst regenerator to produce regenerated cracking catalyst. Regenerating the used cracking catalyst separately reduces deactivation of the cracking catalyst by halogen-containing compounds produced during regeneration of the decontamination catalyst.

The invention discloses a double-site doped titanium lithium ion sieve adsorbent as well as a preparation method and application thereof. The adsorbent is a lithium removal product of a double-site doped titanium lithium ion sieve adsorbent precursor, the chemical general formula of the double-site doped titanium lithium ion sieve adsorbent precursor is Li (2-x) MxTi (1-y) NyOz, M is at least one of Na < + >, K < + >, Zn < 2 + >, Co < 2 + >, Ni < 2 + >, Mg < 2 + > and Al < 3 + > and occupies Li site, N is at least one of Cr < 3 + >, Fe < 3 + >, Zr < 4 + >, Nb < 5 + >, Ta < 5 + >, V < 5 + >, Mo < 6 + > and W < 6 + > and occupies Ti site, x is larger than or equal to 0.001 and smaller than or equal to 0.5, and y is larger than or equal to 0.001 and smaller than or equal to 0.5. Metal cations are introduced to replace Li sites and Ti sites at the same time, Li site substitution enlarges interlayer spacing and improves Li < + > diffusion rate, Ti site substitution regulates local chemical bond and electron distribution, stabilizes lattice structure and enhances electron conduction, and through double-site doping, 'ion-electron 'double channels are constructed, so that a collaborative optimization effect is achieved. The double-site doped titanium lithium ion sieve adsorbent disclosed by the invention is applied to adsorption and extraction of lithium in a Bayer process sodium aluminate solution, and the adsorbent shows excellent adsorption performance.

The invention relates to the field of sludge treatment, and particularly discloses a method for recycling phosphorus in sludge pyrolysis residues, a flocculant synthesis method and application. The invention discloses a method for recovering phosphorus in sludge pyrolysis residues. The method comprises the following steps: drying the sludge pyrolysis residues, grinding and sieving; the sludge pyrolysis residues are put into a hydrochloric acid solution to react, and solid-liquid separation is carried out after the reaction; treating the phosphorus-containing extracting solution through adsorption resin to obtain a phosphorus purification solution; adjusting the pH value of the phosphorus purification liquid to 9-11, and carrying out a crystallization reaction under the condition that the molar ratio of magnesium to nitrogen to phosphorus is (0.8-1.2): (1-1.6): 1 to obtain struvite; a synthetic method of the flocculating agent is as follows: the flocculating agent is prepared from residual sludge residues. The method for recycling phosphorus in the sludge pyrolysis residues has the advantages that phosphorus resources are recycled from the sludge pyrolysis residues, and the residues are secondarily utilized. The flocculating agent is applied to municipal sewage treatment.

The invention relates to the technical field of chemical separation, in particular to a cyclohexanone rectification and purification method based on high-tower segmented packing, which comprises the following steps: step 1, filtering a cyclohexanone raw material containing impurities to remove solid particles, and dynamically adjusting the filtering precision according to the viscosity of the raw material; 2, arranging a bottom section, a middle section and a top section in the vertical high tower; the temperature gradient of each section is regulated and controlled through an independent temperature control unit, so that the temperature gradient of the middle section is matched with the relative volatility of the cyclohexanone-light component; 3, dynamically adjusting the reflux ratio based on the real-time detection result of the purity of the tower top distillate, and controlling an intermittent discharge valve according to the density change of the tower bottom heavy component enrichment liquid so as to continuously remove the heavy components; and 4, recycling the waste heat of the steam at the top of the tower for preheating the raw materials, and inhibiting the tower pressure fluctuation through a buffer tank. Through the innovative design of sectional packing of the high tower, the separation efficiency is improved, the energy consumption is reduced, and meanwhile, the equipment reliability is improved.

The present invention relates to the extraction of lithium from liquid resources such as natural and synthetic brines, leachate solutions from clays and minerals, and recycled products.

The invention relates to a glabridin purification process for low-glabridin, which comprises the following steps: removing glabridin in a glabridin product by using a metal organic framework material (MOFs); the purification process comprises the following steps: extracting glycyrrhiza glabra roots with ethanol or methanol, and filtering to remove medicine residues to obtain an extracting solution; concentrating the extracting solution under reduced pressure to a certain volume, and then adsorbing and removing the glabriol through a filler column filled with an MOFs material; or enabling the extract liquor in the purification process of the glabridin to flow through a filler column filled with the MOFs material to adsorb and remove the glabriol; or adding the MOFs material into other fillers in a glabridin column chromatography purification process to adsorb and remove the glabridin, so as to obtain a glabridin product with low glabridin content. According to the method disclosed by the invention, the glabriol in the glabridin is simply and effectively removed, the content of the glabriol in the prepared glabridin product is lower than 0.1%, the safety of the product is improved, and the method has a strong market competitive advantage. The adsorption material can be recycled after being heated and desorbed, and has potential application prospect and wide application value.

The invention discloses a method for extracting and purifying flavone in litsea coreana through an ultrasonic-assisted eutectic solvent, and belongs to the technical field of green processing of natural products. The invention provides a method for efficiently preparing litsea coreana flavone by integrating computer prediction, green solvent extraction and resin purification technologies. The method comprises the following steps: firstly, calculating and screening a deep eutectic solvent system with the highest affinity with the litsea coreana flavone on the basis of a COSMO-RS theoretical model, then coupling the optimized DES with an ultrasonic-assisted extraction (UAE) technology, and through the synergistic effect of the DES and the UAE technology, remarkably improving the extraction rate of the litsea coreana flavone and furthest keeping the biological activity of a target component; then, a macroporous resin dynamic adsorption-desorption purification process is linked, so that high-selectivity enrichment and impurity removal of the flavonoid compounds in the crude extract are realized, a high-purity product is obtained, and a complete process route from intelligent screening, efficient extraction to precise purification is finally formed.

The invention provides an adsorbent capable of simultaneously adsorbing bilirubin and cytokines and a preparation method and application thereof, and the preparation method comprises the following steps: carrying out suspension polymerization reaction on a styrene monomer and a polyvinyl cross-linking agent in a dispersion medium under the action of a continuous multi-component pore-foaming agent and an initiator to prepare polystyrene-based macroporous resin; carrying out chloromethylation reaction on the polystyrene-based macroporous resin to prepare chlorine balls; carrying out post-crosslinking reaction on the chloromethylated beads to prepare the adsorbent capable of adsorbing bilirubin and cytokines at the same time; the continuous multi-component pore-foaming agent comprises a first pore-foaming agent, a second pore-foaming agent and a third pore-foaming agent of which the solubility parameters are gradually increased in sequence; the temperature of the suspension polymerization reaction is adjusted according to the mass fraction of the polyvinyl cross-linking agent in the monomer mixture and the solubility parameter of the continuous multi-component pore-foaming agent, and the monomer mixture is composed of styrene monomers and the polyvinyl cross-linking agent. The bilirubin and cell factors can be adsorbed at the same time, and the safety of blood purification is improved.

The invention provides a high-molecular adsorption material with high selectivity on platinum group metals as well as a preparation method and application of the high-molecular adsorption material, and belongs to the technical field of material science. Comprising the following steps: (1) preparing a methanol solution containing platinum group metal ions, and adding a functional monomer mixture and modified graphene oxide to form a pre-assembled compound; (2) adding a cross-linking agent and an initiator, removing oxygen, and polymerizing to obtain a polymer; and (3) grinding the polymer, eluting metal ions, washing to be neutral, and drying. The high-molecular adsorption material provided by the invention takes modified graphene oxide as a support body, template molecules and specific functional monomers (4-vinylpyridine and 2-mercaptobenzimidazole) are combined to form a pre-assembled compound, then a cross-linking agent and an initiator are added, recognition sites are fixed through cross-linking polymerization, and finally, the high-molecular adsorption material is obtained after the template molecules are eluted. The adsorbent is high in adsorption rate, capable of specifically adsorbing platinum group metal, good in stability and reproducibility and capable of being repeatedly used.

The present invention relates to a method for preparing a attapulgite / molecular sieve composite adsorbent, comprising the following steps: (1) using NaX molecular sieve powder as a raw material, adding purified attapulgite, grinding, adding an aluminum source for crystallization, filtering, washing to a pH of 7 to 8, and drying to obtain a attapulgite / molecular sieve composite adsorbent precursor; (2) exchanging the composite adsorbent precursor obtained in step (1) with metal cations, and then filtering, washing, drying, molding, and activating to obtain the composite adsorbent. The composite adsorbent has a simple preparation method, a large adsorption capacity, and good selectivity. It can effectively adsorb and separate liquid mixtures, and has broad application prospects in selectively adsorbing and separating p-xylene from C8 aromatic isomers. The present invention also relates to a attapulgite / molecular sieve composite adsorbent and its application in adsorbing and separating p-xylene in mixed xylene.

The invention relates to an aromatic hydrocarbon isomer adsorbent containing a modified X-type molecular sieve. The outer surface area of the modified X-type molecular sieve is 9.5-19m < 2 > / g, and the sum of the pore volume of mesopores and the pore volume of macropores is 6%-18% of the total pore volume. The p-xylene adsorbent comprises 88-95% by mass of a modified X-type molecular sieve, 4-11% by mass of a crystal transformation X-type molecular sieve and 1-3% by mass of a matrix. The invention also relates to a preparation method of the adsorbent and application of the adsorbent in adsorption separation of p-xylene from mixed C8 aromatic hydrocarbons.

The invention discloses a phosphate functionalized silicon-based solid adsorbent and application thereof, and belongs to the technical field of yttrium separation and purification, a preparation method comprises the following steps: step 1, synthesizing silicon-based resin particles SiO2-P by using spherical porous silicon dioxide as a solid-phase carrier and styrene as a raw material through an in-situ polymerization technology, and 2, synthesizing the phosphate-functionalized silicon-based solid adsorbent HDEHP / SiO2-P by using di (2-ethylhexyl) phosphate HDEHP as a raw material and utilizing a vacuum impregnation technology. Therefore, the phosphate functionalized silicon-based solid adsorbent and the application thereof are adopted in the invention. The phosphate can specifically and selectively extract trivalent yttrium ions, so that efficient separation of yttrium and strontium is realized, high-purity yttrium can be obtained through separation and purification after elution, and a solid adsorbent can be recycled.

The invention discloses phenolic resin-based spherical activated carbon and a preparation method and application thereof.The preparation method comprises the steps that raw materials containing linear phenolic resin, a curing agent and an organic solvent are mixed to obtain a mixed solution, the mixed solution is dropped into a hot oil column, and thermosetting phenolic resin balls are obtained through crosslinking, curing, balling and drying; and further performing high-temperature carbonization to obtain the phenolic resin-based spherical activated carbon. The preparation method disclosed by the invention is simple and can be continuously operated. The obtained spherical activated carbon is uniform in size, and the size can be controlled and adjusted within the range of 0.5-2.5 mm.

The invention discloses a modified mesoporous silica adsorbent as well as a preparation method and application thereof, and relates to the technical field of porous material preparation. The preparation method of the modified mesoporous silica adsorbent provided by the invention comprises the following steps: hydrolyzing a silicon source in a solution containing a template agent to form a preliminary framework of silica, then adding a silane coupling agent containing at least one of sulfydryl, sulfonyl and amino, carrying out a hydrothermal reaction at 60-120 DEG C, and removing the template agent to obtain the modified mesoporous silica adsorbent. The modified mesoporous silica adsorbent capable of selectively adsorbing zirconium and hafnium can be obtained. The modified mesoporous silica adsorbent prepared by the method is used for adsorbing and enriching zirconium and hafnium ions, the adsorption capacities of 6.23 mg / g and 5.95 mg / g or above can be obtained respectively, the adsorption capacity is excellent, and the adsorbent can reach adsorption equilibrium within 10 min and is excellent in adsorption rate.

The invention relates to the technical field of preparation of solid-phase microextraction devices, and particularly discloses a pretreatment method and analysis application of a quinolone antibiotic sample, a conjugated microporous polymer (CMP) is successfully prepared by adopting a SonogashiraHagihara cross-coupling reaction, and a cationic conjugated microporous polymer CMP-I is obtained by further carrying out methylation treatment on the CMP by using CH3I. According to the present invention, the cationic CMP-I is adopted as the solid phase extraction adsorption material to construct the solid phase microextraction-liquid chromatography-tandem mass spectrometry (SPE-LC-MS / MS) analysis method, and the method has characteristics of high sensitivity and low detection limit in the QA detection aspect, and can meet the accurate determination requirement of the trace QA in meat and water.

Methods and systems for monitoring and / or controlling production units used at various stages of biological product development and manufacturing are presented herein. In particular, in certain embodiments, the biological production monitoring and control techniques described herein utilize a mid-infrared (mid-IR) analyzer that is capable of obtaining mid-infrared spectral data from an aqueous sample in substantially real time. The techniques described herein can utilize this mid-infrared spectroscopic data to measure sample quality metrics, such as protein content, titer, secondary structure, aggregation, and the like, as well as viral and / or nucleic acid characteristics. Thus, sample quality metrics can be measured substantially in real time and / or continuously to assess, for example, the production quality of protein and gene therapeutic agents, and can be used by a control system to adjust and / or control process parameters to improve product quality, etc.

The present disclosure is directed to methods and systems of purifying solvents. The purified solvents can be used for cleaning a semiconductor substrate in a multistep semiconductor manufacturing process.

The invention provides a purification technology for regenerated DMT in a chemical recovery process of waste polyester, which comprises the following steps: S1) mixing divalent metal salt, trivalent metal salt, an alkaline reagent and water, and carrying out vacuum drying on the reaction product to obtain a layered double-metal hydroxide precursor; s2) mixing the precursor with a solution containing functional anions, and carrying out vacuum drying on a product obtained after intercalation modification to obtain functional anion modified layered double hydroxide; s3) carrying out electrostatic self-assembly on the hydroxylated hexagonal boron nitride and the layered double-metal hydroxide, carrying out suction filtration on the obtained mixed solution on a carrier, and drying to obtain an adsorption film; s4, the waste polyester alcoholysis solution is adsorbed through the adsorption film.According to the pretreatment technology for purification of the waste polyester alcoholysis solution, the purified alcoholysis solution has higher purity, and meanwhile the difficulty of follow-up reduced pressure distillation purification of regenerated DMT is effectively reduced.

The utility model relates to the technical field of polycrystalline silicon production equipment, in particular to a trichlorosilane purification system in a polycrystalline silicon production process, which is characterized in that a coarse distillation primary tower is communicated with a cold hydrogenation primary separation tower; the low-boiling-point recovery tower is communicated with the primary crude distillation tower; the crude distillation secondary tower is communicated with the crude distillation primary tower; the rectification primary tower is communicated with the crude distillation secondary tower; the high-boiling recovery tower is communicated with the rectification primary tower; the rectifying secondary tower is communicated with the rectifying primary tower; the rectification secondary tower is communicated with the crude distillation primary tower; the third-stage rectification tower is communicated with the second-stage rectification tower; a tower kettle of the third-stage rectification tower is communicated with the first-stage rectification tower; the light component removal tower is communicated with the low-boiling-point recovery tower and the high-boiling-point recovery tower; the heavy component removal tower is communicated with the light component removal tower; the high-boiling recovery tower is communicated with the tower kettle of the de-heavy tower; a gas phase outlet of the heavy component removal tower is sequentially connected with a gas phase adsorption device and a light component tower; a reflux inlet of the light component tower is communicated with the light component removal tower; and the heavy separation tower is communicated with the light separation tower. According to the utility model, the stability and reliability of large-load operation of the rectification system can be improved.

The disclosure relates to the purification and treatment of oil produced from the liquefaction of waste polymer like for instance the pyrolysis of waste plastics via the polymerization of dienes prior to further treatments.

The invention discloses a strong-hydrophobicity chromatographic stationary phase modified by a covalent triazine skeleton containing an octyl chain as well as a preparation method and application of the strong-hydrophobicity chromatographic stationary phase. Activated silica gel is modified by utilizing a silane coupling agent, so that gamma-glycidyl ether oxypropyl trimethoxy is introduced into the surface of the silica gel; and performing in-situ growth of a covalent triazine skeleton layer containing an octyl chain through a Schiff base condensation reaction to prepare the strong-hydrophobicity chromatographic stationary phase. A covalent triazine skeleton containing a hydrophobic octyl chain in the structure is used for modifying the surface of silica gel, and a bonding phase contains a triazine ring, a benzene ring, an octyl chain and an amino group. According to the stationary phase, a hydrophobic long octyl chain is introduced into a bonding unit of CTF, so that the structure, morphology and performance of the CTF are changed, a'flower-on-sphere 'morphology is formed, and the stationary phase has a rigid porous structure, adjustable hydrophilicity / hydrophobicity, a rich pi electron system, strong hydrophobicity and good separation selectivity for non-polar compounds, and can be widely applied to separation of various samples.

The invention provides a method for producing berberine hydrochloride, berbamine and jatrorrhizine hydrochloride by using berberis poiretii schneid. The method comprises the following steps: by taking berberis poiretii schneid as a raw material, carrying out crushing, acid extraction, heat-preservation filtration clarification and membrane separation to obtain a membrane refined solution; then, the berberine hydrochloride is produced through crystallization and recrystallization; performing decoloration and fractional crystallization through alkaline anion exchange resin to produce berbamine; and carrying out macroporous adsorption resin chromatography to produce jatrorrhizine hydrochloride. The berberine hydrochloride, the berbamine and the jateorhizine hydrochloride are continuously produced and prepared, and comprehensive utilization of the berberis poiretii schneid raw material is achieved; the problem that the salt wastewater pollutes the environment can be solved, and step-by-step separation and purification of alkaloid are achieved; the membrane separation and the resin are combined, so that repeated crystallization and activated carbon decoloration are avoided, and the yield and the quality of the berbamine can be remarkably improved; the high-content jateorhizine is prepared without using an organic solvent except ethanol, and the application prospect in industry is wide.

The invention belongs to the technical field of waste PET (Polyethylene Terephthalate) recovery, and particularly relates to a continuous production system and process for efficiently recovering and refining PTA (Purified Terephthalic Acid) from waste PET and application. According to the continuous production system and process for efficiently recovering and refining the PTA from the waste PET, through mutual cooperation of the enzymolysis unit, the first solid-liquid separation unit, the filter cake dissolving and decolorizing unit, the electrolysis unit, the second solid-liquid separation unit and the recrystallization unit, continuous production of'obtaining the refined PTA by taking the waste PET as a raw material 'is realized; besides, by adjusting the runner structure in the electrolysis assembly of the electrolysis unit, the situation of electrolysis interruption caused by the fact that TA generated by electrolysis is prone to being deposited on the surface of the anode plate is avoided, guarantee is provided for continuous proceeding of the whole degradation and recovery process, and the system and the process have important significance on efficient degradation and recovery of waste PET.

The disclosure relates to the purification and treatment of oil produced from the liquefaction of waste polymer like for instance the pyrolysis of waste plastics via the polymerization of dienes prior to further treatments.

A TPC-OTBS n-hexane solution is added to a mixture of TPC-OSO2F, DMF, and DBU and allowed to stand to produce a crosslinked solvent gel; the crosslinked solvent gel is added to methanol, stirred, and dried to produce the porous crosslinked material. The gel acquired can be prepared into a pore-rich solid porous organic polymer material by means of solvent exchange. SEM and TEM are used to characterize the surface and internal morphologies of the solid material, and the porous morphology thereof is discovered, with large pores being the majority. Infrared and nuclear magnetic resonance are used to characterize the structure of a crosslinked polysulfate; the complete reaction of a sulfuryl fluoride group is proven by means of solid-state fluorine nuclear magnetic resonance spectroscopy and XPS element analysis; and the porous structure of the crosslinked polysulfate allows same to be provided with improved application prospect in terms of adsorption.

The invention relates to the field of polymer grading, and discloses a polyethylene grading method, polyethylene obtained through the polyethylene grading method, a system for polyethylene grading and application of the system. According to the polyethylene grading method, on the basis of preparing a high-temperature liquid chromatographic column, two-time flow division is adopted, and the flow ratio of second flow division is controlled, so that accurate and directional grading of a polyethylene raw material is realized, and the purposes of accurate and directional regulation and control of the average molecular weight, the molecular weight distribution curve and the branched structure of polyethylene, especially low-density polyethylene, are realized.

The invention relates to a hydrophilic core-shell type chromatographic stationary phase material and application thereof. The hydrophilic core-shell type chromatographic stationary phase material comprises spherical silicon dioxide and a mesoporous layer which coats the spherical silicon dioxide, contains an amide group and is compounded with silicon dioxide. The preparation method comprises the following steps: firstly preparing solid silicon dioxide microspheres, then coating the surfaces of the silicon dioxide microspheres with mesoporous silicon dioxide shell layers through surface in-situ growth, and finally modifying the mesoporous shell layers through grafting and polymerization reaction to obtain the hydrophilic core-shell material containing the amide groups. The aperture of the material is mesoporous 2-20 nanometers, hydrophilic oligosaccharide substances can be separated, radix morindae officinalis oligosaccharide can be separated, and compared with a traditional chromatographic column, the separation degree is better, the column efficiency is higher, and the good separation performance is achieved. The preparation steps are simple, the reaction conditions are mild, and the method is simple.

The invention relates to the technical field of pharmaceutical separation, and discloses a device, method and application of ursodeoxycholic acid preparation and purification. The device comprises a separation tank, wherein a batching center cylinder is rotatably installed inside the separation tank, and a plurality of elution tubes are arranged around the batching center cylinder. The batching center cylinder rotates forward, and centrifugal force is used to load adsorption resin into each elution tube. Then, the batching center cylinder rotates reversely, and the volume of each elution tube is poured out by anti-centrifugal force, so as to achieve a more convenient effect of replacing the adsorption resin. The replaced adsorption resin is cleaned outside the device and reused. The purification method and application thereof realize column loading, sample loading and elution in the separation tank in sequence without stopping the machine for operation, and simplify the column loading and column replacement operations, so as to solve the problem that the separation and purification process in the prior art is complicated and not suitable for batch production, so as to meet the industrial production requirements of solvent recycling.

The invention relates to the technical field of preparation of high-purity boron oxide, and discloses a purification method of high-purity boron oxide and a device thereof, and the purification method comprises the following steps: step 1, mixing crude boron oxide with a liquid metal alloy, and dissolving metal impurities through gradient temperature control; 2, applying ultrasonic treatment to the mixed system, introducing a vortex field, and stripping impurities on the surface of the boron oxide; 3, a liquid metal phase and a boron oxide solid phase are separated through cooperation of a magnetic field and a pulse high-voltage electrostatic field; 4, non-metal ion impurities are removed through a gradient porous ceramic adsorption bed; and step 5, melting boron oxide in vacuum and carrying out gradient cooling crystallization. By adopting the technical scheme of a Ga-I n-Bi-Er quaternary liquid alloy system, the technical effect of selective targeted removal of metal impurities is achieved, and compared with a liquid metal system depending on single phase solubility difference in the prior art, the defect that efficient chelating and dynamic settling separation of the impurities cannot be achieved at the same time is overcome.