1755 results about "Adsorption separation" patented technology

An apparatus is presented for separating chemicals using adsorption separation methods. The apparatus uses a plurality of adsorption units holding adsorbent, where the adsorption units positioned in a cylindrical spool, are serially connected and the spool is rotated to shift the relative position of the feeds and drawoffs to the apparatus.

The invention discloses a full-temperature-range pressure swing adsorption gas separation, refinement and purification method.By means of the difference of the temperatures and pressures of different raw material gases and the difference of the adsorption separation coefficients and physical chemistry properties of all components in the raw material gases in the temperature range of 80-200 DEG C and the pressure range of 0.03-4.0 MPa, the adsorption or desorption regeneration operation of the pressure swing adsorption circulation process is adjusted by coupling all separation methods, the adsorption theory that the pressure or temperature swing adsorption separation process is only limited to the adsorption and desorption regeneration circulation operation through pressure or temperature changes is expanded, and therefore all raw material gases are separated, refined and purified by achieving the energy gradient utilization in the gas separation, refinement and purification process and achieving the circulation operation, where adsorption, desorption and regeneration are easily matched and balanced, in the moderate to low cold and moderate to high temperature pressure swing adsorption separation process, and it is changed that a traditional adsorption method is only limited to the auxiliary effect of refinement and purification, and adsorption becomes the basic separation unit operation just as important as refinement, absorption and extraction separation.

The invention provides a method for continuous production of polyformaldehyde dimethyl ether. The method is characterized by comprising the following steps: a) feeding dimethoxymethane and hot-melted paraformaldehyde into a fixed bed reactor and adopting an acidic resin catalyst, so as to prepare polyformaldehyde dimethyl ether (DMM3-8), wherein the reaction temperature is 120-180 DEG C and the pressure is 0.1-10 MPa; b) cooling the reaction product, and then performing adsorptive separation through a dehydrating tower, so as to obtain polyformaldehyde dimethyl ether of which most water, cytidine glycol and hemiacetal are desorbed; c) feeding the polyformaldehyde dimethyl ether subjected to desorption into a distillation tower for separation, wherein most of a low-boiling component (dimethoxymethane (DMM)), poly-di-formaldehyde dimethyl ether (DMM2), a by-product (methanol) and triformol are extracted first, and then the materials in a tower kettle are fed into a rectifying tower in the next step, so as to extract the rest of the DMM2 and the triformol; and d) returning the low-boiling component (dimethoxymethane (DMM)), the methanol, the DMM2 and the triformol, which are evaporated out by the distillation tower and the rectifying tower in the last step, into the fixed bed reactor to continue to react to prepare polyformaldehyde dimethyl ether.

The invention provides a nano-size layered double hydroxide and a step-by-step precipitation preparation method thereof. The preparation method comprises the following steps: based on a soluble salt of a metal and an alkali as raw materials, respectively precipitating metal ions constituting an LDH (layered double hydroxide) layer plate through step-by-step precipitation reaction and generating the LDH during the second-step precipitation process. As the activity of the hydroxide prepared by the first-step precipitation reaction is high, the LDH can fast nucleate and grow during the second-step precipitation, an obtained LDH sheet is thinner, the thickness of the layer plate is 5-15nm, the length of the layer plate is 50-150nm, and the specific surface area of a BET (Brunauer-Emmett-Teller) is 140-280m<2> / g, which is much larger than the specific surface area of the common LDH. By adopting the method, the shortcoming of small specific surface area during the preparation of the LDH through a co-precipitation method can be overcome. The preparation method adopted by the invention is simple and convenient, high temperature and high pressure are not required, special equipment is not required, sources of the raw materials are rich, and the cost is low. The layered double hydroxide can be widely applied to the fields of adsorption separation, catalysis, high polymer materials and the like.

The present invention relates to a nitrogen adsorbent having nitrogen selective adsorptivity by including an organic-inorganic hybrid nanoporous material having a coordinatively unsaturated metal site with density of 0.2 mmol / g to 10 mmol / g in a skeleton, surface or pore; and use thereof, such as a device separating nitrogen from a gas mixture containing nitrogen and methane, a pressure swing adsorption separation device and a temperature swing adsorption separation device for separating nitrogen provided, a method for separating nitrogen and methane from a gas mixture containing nitrogen and methane, a device for separating nitrogen, oxygen or argon, a method for separating nitrogen, oxygen or argon from a gas mixture containing nitrogen, oxygen or argon, and a method for preparing nitrogen or high purity inert gas all separated from a gas mixture containing nitrogen and inert gas.

The invention discloses a preparation method and application of a nitrogen-doped starch-based activated carbon microsphere material. The nitrogen-doped starch-based activated carbon microsphere material is prepared by taking starch as the carbon source and taking a nitrogen-containing compound as the nitrogen source through the steps of gelatinization, hydrothermal treatment, carbonization, activation and the like. The diameters of prepared carbon microspheres range from 0.5 micrometer to 10 micrometers, the particle size is controllable, the dispersity is good, the specific surface area ranges from 1,000 m<2> / g to 3,000 m<2> / g, and the nitrogen content ranges from 0.2% to 15%. The prepared material relates to the application fields of electrochemical energy storage, adsorption separation, catalyst carriers, drug carriers and the like and is particularly applicable to electrochemical energy storage. Green biomass is adopted as the carbon source, sources are wide, the price is low, and the preparation technology is simple, easy to control, environmentally friendly and suitable for large-scale production.

The invention provides a polymeric hydrogel grafted on fibers by calcium ion crosslinking and a preparation method thereof. The polymeric hydrogel comprises the following components in percentage by mass: 3-8% of sodium polyacrylate grafted fiber, 0.96-4% of sodium alginate, 0-2% of water-solubility polymeric additive, 0.96-8% of calcium chloride and 75-95% of deionized water. The preparation method comprises the following steps: grafting polyacrylic acid on fibers by ultraviolet radiation; neutralizing with sodium hydroxide to obtain sodium polyacrylate-grafted fibers; soaking sodium polyacrylate-grafted fibers in an aqueous sodium alginate solution; taking out and scraping off the superabundant adherent viscous solution; and crosslinking in an aqueous calcium chloride solution to obtain the calcium alginate hydrogel grafted on the fibers. The preparation method is simple to operate, and the prepared polymeric hydrogel grafted on fibers has application prospects in the fields of adsorption separation, drug control and release, immobilized enzyme, tissue engineering and the like.

The invention discloses a method for extracting active sites of iridoid, and extracting monomer geniposidic acid (GPA), geniposide(GP) and aucubin(AU) from eucommia, wherein raw materials are extracted by taking the eucommia(husk, leaf or seed) as materials and utilizing the conventional leaching method, the ultrasonic extraction method or the microwave extraction method, and an extracting solution is preliminarily purified by methods such as the solvent extraction and the adsorption separation of special adsorbents, etc., and thus the active sites of the iridoid(the total content of the iridoid is no less than 50 percent) is obtained, and GPA, GP and AU undergo the separation, low temperature condensation, refrigeration and drying by using the preparation high pass filter technique and taking an alcohol-water solution as the mobile phase to obtain monomers of GPA, GP and AU, contents of which are all no less than 90 percent. The preparation method disclosed by the invention utilizes novel process of the extraction and separation, and can simultaneously prepare a plurality of monomer products of the eucommia, and provides scientific foundations for the comprehensive development and utilization of the eucommia; moreover, the whole process does not use solvents harmful to human bodies, thereby realizing the green preparation.

A process for separating a product from a multicomponent feedstream to an adsorption apparatus or system. The apparatus or system may comprise a moving-bed or a simulated moving-bed adsorption means. The product comprises at least one organic compound, such as an aryl compound with alkyl substitutes. In embodiments the conduits used to supply the feedstream to the apparatus or system are flushed with media of multiple grades. In embodiments the process achieves improvements in one or more of efficiency of adsorption separation, capacity of adsorption apparatus systems, and purity of product attainable by adsorption process.

The invention relates to a preparation method of a mesoporous X-type molecular sieve and a method for preparing an adsorbent by using the molecular sieve as an active component. The prepared adsorbent based on the mesoporous X-type molecular sieve is used as a paraxylene adsorptive separation adsorbent. The method for preparing the mesoporous X-type molecular sieve comprises the following steps: by using water glass as a silicon source and aluminum hydroxide as an aluminum source, adding a template, and carrying out hydrothermal synthesis to obtain the mesoporous X-type molecular sieve. The mesoporous molecular sieve and kaolin are proportionally molded to obtain 0.3-0.8mm granules, and the granules are subjected to barium ion or (and) potassium ion exchange until the exchange degree is greater than 99%, thereby obtaining the adsorbent which has excellent adsorptive separation capacity for paraxylene in C8 aromatic hydrocarbons. Compared with the prior art, the active component mesoporous X-type molecular sieve of the adsorbent, which is prepared by using the template, has the crystal form structure of the X-type molecular sieve and the pore distribution of the mesoporous and microporous dual models; the mesoporous pore size distribution is 2nm or so; and thus, the problem of overlow mass transfer rate in the adsorbent can be solved.

The invention discloses an acidified zeolite. The technical scheme is as follows: the acidified zeolite is composed of zeolite, attapulgite clay, magnesia, hydrochloric acid, instant sodium silicate, polyvinyl alcohol, hydroxypropyl methylcellulose and sodium carbonate. The acidified zeolite materials are input into a mill and milled, and the milled powder is the acidified zeolite. The production method of acidified red mud adopts acidification before composite proportioning, thereby avoiding the chemical reaction between the sulfuric acid and the instant sodium silicate, polyvinyl alcohol, hydroxypropyl methylcellulose and sodium carbonate; and the acidified zeolite can effectively remove ammonia, iron, fluorine, phosphides and micro pollutants in domestic sewage, and can be used for removing or recovering heavy metal ions and treating radioactive waste. The acidified rear has the characteristics of favorable thixotropy, favorable heat stability, favorable plasticity and favorable binding property, and is suitable for producing drying agents, adsorptive separation agents, molecular sieves, catalysts, defluorination soil improvers, deodorizers and firefighting products.

The invention discloses a porous metal organic framework material reinforcing methane adsorption separation and preparation and application thereof, the porous metal organic framework material is a supramolecular porous network structural compound prepared from metal ions at least containing CuII and at least one organic compound which can be coordinated with the CuII and at least is provided with two teeth. The CuII-containing porous metal organic framework material can be synthesized by co precipitation, hydrothermal, microwave, ball milling and other different methods, the biggest feature of the porous metal organic framework material is to improve the methane adsorption separation performance by use of effect of weakly polar or nonpolar solvents on the surface in the preparation process of. The CuII-containing porous metal organic framework material has excellent CH4 adsorption selectivity in the separation process of CH4 and N2, the equilibrium adsorption selectivity can reach more than 6, and the material is particularly suitable for use in oil field gas, shale gas, coal seam gas and biogas development and utilization process.

The invention discloses a technology for preparing liquefied natural gas and liquid ammonia by using coke oven gas. The coke oven gas is subjected to the steps of compression, purification, methanation, cryogenic separation and liquefaction of synthetic natural gas, variable pressure adsorptive separation and liquid ammonia preparation with hydrogen rich gas, so that the liquefied natural gas (LNG) of which methane purity is more than 99 percent and the liquid ammonia reaching national first level standard are obtained. By the technology, the hydrogen byproduct of the coke oven gas for preparing the LNG is fully utilized; effective ingredients of the coke oven gas such as H2, N2, CH4, CO and CO2 are furthest utilized; the CO and the CO2 are methanated, so that the yield of the CH4 is improved by about 1 / 3; the liquefied CH4 is used as the LNG and sold; and the rest nitrogen-containing hydrogen-rich gas is used as a raw material for synthesizing ammonia, so that the additional value of the coke oven gas is improved, and reliable raw material guarantee is provided for developing downstream products with high additional values and prolonging the product chain.

The invention provides metal-organic framework materials with magnetic cores and preparation and application thereof, and belongs to the technical field of magnetic metal-organic framework materials. FeCl3 6H2O is adopted for preparing superparamagnetic Fe3O4 cores, cetyl trimethyl ammonium bromide is used as a template agent, sodium silicate is used as silicon sources of SiO2 shell layers, mesoporous SiO2 shell layers are formed on the surfaces of the Fe3O4 cores by adopting an ultrasonic wave method, the template agent is removed by roasting under protection of N2 after drying, and magnetic SiO2@Fe3O4 nanospheres are prepared. The SiO2@Fe3O4 nanospheres are used as cores, an in-situ self-assembly mesh structure IRMOFs is carried out on the surfaces of the SiO2@Fe3O4 cores through Zn metal ions and organic carboxylic acid ligands by adopting the ultrasonic wave method. The novel MOFs materials can be used as catalysts of liquid phase catalysis reaction, and also have application values in the aspects of adsorption, separation, biological medicine and the like.

The invention relates to a MoFs adsorbent and application thereof. The adsorbent is prepared by the following steps: as the weight of metal organic framework material raw powder is used as the base, adding a binder accounting for 2-50% of the metal organic framework material raw powder in weight, an extrusion aid accounting for 3-60% of the metal organic framework material raw powder in weight, and water accounting for 1-30% of the metal organic framework material raw powder in weight into the metal organic framework material raw powder, stirring and kneading uniformly, and forming; and stoving, and roasting so as to obtain the formed MoFs adsorbent. A metal organic framework material is selected from one of ZIF-76, UiO-66, UiO-67 or MIL-125; the MoFs adsorbent is used for adsorbing isoparaffins from an alkane mixture in a back-shape-selective manner; the MoFs adsorbent has relatively high adsorption capacity or relatively high adsorption acting force on one or more kinds of isoparaffins, so that the isoparaffins are more preferentially adsorbed as compared with n-alkanes in an adsorption separation process; meanwhile, as the metal organic framework material has large specific surface area and pore volume, the adsorption capacity on alkanes is large, and the high-efficiency separation on n-alkanes and isoparaffins can be realized.

The invention relates to a preparation process of a metal-organic framework porous adsorption material for C4-C8 normal paraffin and isoparaffin adsorption separation. According to the preparation method of the synthesized metal-organic framework porous adsorption material, metal ion nitrate and an organic ligand are dissolved according to the mass ratio of 1:1-15 in a mixed solution of N,N-dimethylformamide and N,N-diethyl formamide; stirring is carried out for 0.5-12 h; reaction temperature is controlled to 80-250 DEG C, and reaction time is 12-120 h; and by a hydrothermal synthesis method, the metal-organic framework porous adsorption material is prepared. The material has characteristics as follows: specific surface area is large; pore structure height is ordered; pore size is controllable; surface potential energy is controllable; and adsorption capacity of normal paraffin is large. The material can selectively adsorb normal paraffin from mixed materials of normal paraffin and isoparaffin, has high selectivity and has a wide practical application prospect in normal paraffin and isoparaffin separation.

The invention discloses an adsorbent used for efficiently separating formaldehyde from air and a preparation method thereof. An adsorbent carrier is active carbon, the surface of which is attached with one or more of -NH, -NH2 and -NH3. The precursor of -NH, -NH2 and -NH3 is one of salvolatile, ammonium bicarbonate, ammonium sulfate, ammonium nitrate, ammonium chloride, ethene diamine, hexamethylenediamine, aniline and urea. The adsorbent can absorb and separate formaldehyde in air when space velocity is 20000-80000h<-1> at room temperature. Especially when the formaldehyde and benzene seriesin the air coexist, the adsorbent not only can absorb and separate formaldehyde but also can absorb and separate the benzene series. Therefore, the adsorbent can be widely applied to the purifying treatment of air in hermetic and semi-hermetic limited spaces, such as building interiors, spacecrafts, submarines, undergrounds and the like.

The invention discloses a nanometer material with controllable particle sizes and silicon dioxide hollow spheres and a method for preparing nanometer material. TEOS (tetraethyl orthosilicate) is used as an organic silicon source, CTAB (cetyl trimethyl ammonium bromide) is used as a structure directing agent, water, ethyl alcohol and cyclohexane are used as solvents, and PVP (polyvinyl pyrrolidone) is used as a stabilizer. The method includes carrying out heat reaction by the aid of the solvents to form precursors of the SiO2 hollow spheres; calcining the precursors and removing organic matters so as to obtain the SiO2 hollow spheres. The nanometer material and the method have the advantages that the silicon dioxide hollow spheres prepared by the aid of the method are excellent in dispersibility and have the adjustable particle sizes (of 220-430 nm), large pore diameters (of 10-12 nm) and uniform shell thicknesses, and cavities are large and can be used for storing large quantities of guest molecules; the nanometer material is high in chemical stability and packaging capacity and can be widely applied to the fields of enzymatic catalysis, substance adsorptive separation and the like; the method includes simple synthesis processes, is clean and is free of pollution and low in cost, and preparation procedures are good in repeatability.

The invention discloses a preparation method of a magnetic metal organic framework material and an application of the magnetic metal organic framework material. The preparation method comprises the steps of synthesizing a nano magnetic material Fe3O4 by adopting a coprecipitation method, adding the nano magnetic material Fe3O4, FeCI3.6H2O and terephthalic acid into DMF, carrying out ultrasonic mixing, and synthesizing Fe3O4 / MIL-101(Fe) by adopting a hydrothermal method; separating a product by utilizing a magnetic field, washing with hot ethyl alcohol, and drying overnight so as to obtain the Fe3O4 / MIL-101(Fe). The Fe3O4 / MIL-101(Fe) obtained by the method is applied to separating and enriching organophosphorus in urine. The magnetic metal organic framework material is uniform in particle size, is relatively strong in magnetism, and is good in dispersibility; MIL-101(Fe) formed by the coordination of oxygen bearing carboxylate ligand and a metal ion F3<3+> is adopted as an adsorption separation medium and is combined with a magnetic solid phase extraction technique for being combined with chromatography so as to determine trace organophosphorus residues in urea, and the magnetic metal organic framework material is relatively high in flexibility.

The invention concerns a simulated moving bed adsorption separation device comprising a limited number of valves. According to the invention, the device comprises a column with a plurality of sectors Sk with 2 superimposed plates Pi with a single distribution network, each sector Sk comprising an external principal bypass line Lk connected to each plate Pi of Sk via a plate valve Vi. Each line Lk comprises a flow limitation means and is connected to each of the fluid networks via a single valve.Further, the connectors of lines Lk onto the column are offset by at most 20° inside Sk to limit the volume of lines Lk, and are offset by a mean angle in the range 70° to 110° between two neighbouring sectors Sk and Sk+1 so as not to weaken the column mechanically. The plates preferably comprise panels DMEi,j with parallel segments the direction of which varies from plate to plate or per group of 2 plates.The invention also concerns a separation process using said device, in particular to separate para-xylene or meta-xylene from an aromatic C8 cut.

A high purity isobutane adsorption separation and purification apparatus is provided including a pressure regulator which regulates the pressure of an isobutane-containing gas; the at least one adsorption bed packed with zeolite 5A and carbon molecular sieve arranged downstream of and operatively associated with the pressure regulator; a flow control valve disposed between the pressure regulator and the at least one adsorption bed; a surge tank operatively associated with and for receiving a purified isobutane product from the at least one adsorption bed; a vacuum pump operatively associated with and for removal of impurities from the at least one adsorption bed; and valves disposed between the pressure regulator and the at least one adsorption bed, between the at least one adsorption bed and the surge tank, and between the at least one adsorption bed and the vacuum pump. An adsorptive separation and isobutane purification process is also provided which may be used with the apparatus of the invention.

The invention discloses an adsorbent for adsorbing heavy metal ions, and the preparation method of the adsorbent. The invention is characterized in that a silane coupling agent and acid anhydride are in epoxy ring cleavage reaction in inert atmosphere or air at the temperature of minus 78 to 200 DEG C, wherein the mol ratio of the silane coupling agent to the acid anhydride is 1 : 2 to 20; after the reaction product is dissolved by a solvent, halogenated alkane is added to the solution according to the mol ratio of two to ten times of the silane coupling agent, the amination reaction is carried out at the temperature of 0 to 200 DEG C, and then, the product generated by the amination reaction is cleaned with water or ethanol and is dried to obtain the adsorbent for adsorbing the heavy metal ions. In the adsorbent, acidic groups are arranged on both sides of a molecular backbone, and basic groups are positioned on the molecular backbone. The adsorbent has stronger capability for adsorbing heavy metal ions, such as Pb2+, Cu2+ and the like in the solution, and can be used for adsorption separation and purification treatment of waste water containing heavy metal ions.

The invention discloses a highly-graphitized carbon nanowire ball material and a preparation method thereof. An activated carbon material is prepared from carbohydrate used as a carbon source through hydrothermal and carbonization activation, the prepared activated carbon material is dipped in a metal salt catalyst solution and dried, a prepared dipped sample is treated at the high temperature under the protection of inert gas, and a graphitized carbon and metal composite is obtained; the obtained composite is treated with an acidic solution, washed, subjected to solid-liquid separation and dried, and the highly-graphitized carbon nanowire ball material is prepared. The wire ball is formed by winding carbon nanowires with the diameters of 10-100 nm, the diameter of the wire ball is 0.2-5 mu m, and the graphitization degree is 0.7-1. The highly-graphitized carbon nanowire ball material has the advantages of uniform dispersion, high graphitization degree, large specific surface area, low cost of raw materials, simple process, no pollution, easiness in industrial production and the like and has wide application prospect in the fields of electrochemical energy storage, adsorption separation, catalyst carriers, medicines and the like.

The invention discloses a preparation method and application of a porous active carbon material with a radix puerariae-based interconnected hierarchical aperture structure. The method comprises the following steps: carrying out clean washing, slicing, drying and other pretreatment on radix puerariae, and then adopting hydrothermal, carbonization and activation treatment processes to prepare the porous active carbon material with the radix puerariae-based interconnected hierarchical aperture structure. The obtained material having the interconnected hierarchical aperture structure, and has the micropore volume of 0.2-0.8 m<3> / g, the mesopore volume of 0.02-0.6 m<3> / g, the total pore volume of 0.3-1.3 m<3> / g and the total specific surface area of 500-3000 m<2> / g. The prepared material relates to the electrochemical energy storage, adsorption separation, catalyst carrier, drug carrier and other fields, and particularly is suitable for application in super capacitors. The green biomass is adopted as a carbon source and is wide in source and low in price, and the preparation method has the advantages of simple process, easily controlled process and environmental friendliness, and is suitable for large-scale production.

Presently disclosed are methods and apparatus for separation of reaction products from reaction mixtures in an ionic liquid catalysis process, particularly in conversion of biomass, cellulose, and sugars into chemical intermediates such as 5-hydroxymethylfurfural (HMF). In one embodiment an ion exclusion adsorption mechanism is used for the separation process. The process comprises (i) mixing the ionic liquid-containing reaction mixture with de-ionized water, (ii) flowing the water solution mixture into an adsorption column, (iii) eluting the column with a water- and / or alcohol-based fluid, and (iv) collecting separated fractions at different elution times.

A method for gas separation, purification and clarification by FTrPSA uses the temperature and pressure of different raw gases as well as the differences in adsorption separation coefficients and physicochemical properties among all components in the raw gases at a temperature range of −80-200° C. and a pressure range of 0.03-4.0 Mpa, regulates the adsorption or desorption regeneration operation in the PSA cycle process by coupling various separation methods, and expands the adsorption theory that the PSA or TSA separation process is limited to the cyclic operation of adsorption and desorption regeneration through pressure or temperature changes, thus realizing the gradient utilization of energy in the process of gas separation, purification and clarification as well as the easy-to-match and easy-to-balance cyclic operation of adsorption and desorption regeneration in the process of intercooling & shallow-cooling and medium & high-temperature PSA separation to separate, purify and clarify various raw gases.

The invention discloses a preparation method of a metal-organic framework material for adsorbing separation of carbon dioxide / methane. The preparation method comprises the following steps of: (1) mixing 0.46-1.16mol / L cupric nitrate water solution and 0.23-0.58mol / L trimesic acid ethanol solution, fully stirring, then adding into a stainless steel reaction kettle provided with a polytetrafluoroethylene inner liner for sealing, and carrying out solvent thermal reaction while controlling the crystallization temperature to be 60-150 DEG C and the crystallization time at 12-24h; (2) opening the stainless steel reaction kettle, filtering, sequentially washing by methyl alcohol and deionized water, and drying at the temperature of 80-105 DEG C to obtain blue crystal; and (3) vacuumizing the blue crystal at the temperature of 150-200 DEG C to obtain the Cu-containing metal-organic framework material.

The in situ active carbon regenerating method and apparatus with medium blocking discharge plasma belongs to the field of chemical adsorbing separation and pollutant controlling technology. Under atmospheric pressure, low temperature unbalanced plasma generated through medium blocking discharge is used to in situ regenerate active carbon with adsorbate filled between the discharge electrodes under the action of high activity matter, ultraviolet and high energy electron bombardment, etc. The in situ active carbon regenerating apparatus consists of high voltage AC source, reactor and auxiliary device mainly. The present invention has the advantages of high regeneration efficiency, short regeneration period, no secondary pollution, no need of post-treatment, low active carbon loss, etc; and is suitable for active carbon regeneration mainly.

This invention relates to a method of efficiently producing a high-purity para-substituted aromatic hydrocarbon while suppressing caulking without requiring isomerization-adsorption separation steps, and more particularly to a method of producing a para-substituted aromatic hydrocarbon, characterized in that a methylating agent and an aromatic hydrocarbon are reacted in the presence of a catalyst formed by coating MFI type zeolite having a particle size of not more than 100 μm with a crystalline silicate.

The invention provides a novel method for absorption and separation of high-purity chlorogenic acid, comprising an absorption process, an impurity cleaning process and an elution process. The method is characterized in that: after chlorogenic acid stock solution is dynamically absorbed by at least dual tandem absorption column which is filled with macroporous resins until penetration, impurity removal solution is added for impurity removal; and finally eluent is used for elution until no chlorogenic acid flows out, and effluent is collected. The purity of the pure chlorogenic acid solution obtained by the method can reach over 92 percent as shown by HPLC detection, and the concentration can reach between 0.1 and 0.8 milligram per milliliter; and the pure chlorogenic acid solution can be widely applied in the fields such as foodstuff, medicines, cosmetics and so on. Solid, namely dried chlorogenic acid powder, obtained after direct drying of the pure chlorogenic acid solution prepared by the method, does not require reprocessing, can be directly applied, and is convenient for conveying.