122 results about "Bromide ions" patented technology

The invention provides a synthesis method of a bromide ion adsorbent for salt lake bromine extraction, and belongs to the technical field of adsorbent preparation, a mixed solution of strontium chloride and manganese chloride and a mixed solution of sodium phosphate and sodium hydroxide are subjected to precipitation reaction to obtain A-Sr4Mn6 (PO4) 6 (OH) 2; the preparation method comprises the following steps: reacting A-Sr4Mn6 (PO4) 6 (OH) 2 with a sodium bromide solution to obtain B-Sr4Mn6 (PO4) 6Br2; and reacting the B-Sr4Mn6 (PO4) 6Br2 with a sodium hydroxide solution to obtain Sr4Mn6 (PO4) 6 (OH) 2, namely the bromide ion adsorbent. The prepared adsorbent can selectively adsorb bromide ions from high-salt brine, and has the advantages of high adsorption capacity, high selectivity, high recyclability and the like; in brine with extremely high chloride ion concentration, low-concentration bromide ions can be selectively adsorbed without being influenced by high-concentration chloride ions; in a high-salt water body, the adsorption capacity on bromide ions is higher; the selective adsorption separation of the chloride ions and the bromide ions is realized.

The invention discloses a two-phase electrolyte, a preparation method thereof and a liquid energy storage battery system, and belongs to the technical field of electrochemical energy storage. According to the invention, a liquid-liquid double-phase electrolyte is composed of a water-phase electrolyte and an organic-phase electrolyte, wherein the organic-phase electrolyte contains a coupling system of 1-(methyl-decyl)-3-methylimidazolium bromide, tris (methyl-decyl) methyl ammonium bromide and (10-octadecyl) alkyl trimethyl ammonium bromide in a molar ratio of (5-7): (2-4): 1. During charging, positive electrode bromide ions are subjected to an oxidation reaction to generate a bromine simple substance, and meanwhile, the bromine simple substance and a coupling system of the quaternary ammonium bromide compound and the bromine complexing agent provided by the invention form a stable polybromine complex product, so that the polybromine complex product is prevented from being migrated into a water-phase electrolyte, and the purpose of improving the stability of the water-phase electrolyte in the absence of a diaphragm is achieved. The self-discharge reaction of bromine is significantly inhibited at a high temperature exceeding the boiling point temperature of bromine, the coulombic efficiency and energy efficiency of the liquid energy storage battery are improved, the system cost is reduced, and the long-term cycle stability of the liquid energy storage battery is improved.

The invention relates to an electrolyte for synergistically stabilizing positive electrode iodine multi-electron reaction through four-combination zinc salt and a high-surface-capacity zinc-iodine soft package battery. The electrolyte comprises the four-combination zinc salt and water, in the electrolyte, the total concentration of zinc ions in the four combinations of zinc salts is 2 + / -0.2 mol / L; the four-combination zinc salt is a four-combination zinc salt; the SO4 < 2-> in the electrolyte buffers the pH value of a system, so that side reaction of a negative electrode is reduced; cH3COO <-> can be cross-linked with I3 <->, so that shuttling of polyiodide is inhibited, and reversibility of a two-electron reaction is enhanced; bromide ions Br <-> in the electrolyte are chemically combined with I < + > through isohalogen to excite four-electron reaction; the trifluoromethanesulfonate OTf <-> with strong electronegativity surrounds the positive electricity I < + > by virtue of an ion atmosphere effect, so that active water molecule attack hydrolysis failure is avoided, a synergistic stable positive electrode iodine multi-electron reaction is realized, and the high-surface-capacity zinc-iodine soft package battery is beneficial to promoting the development of the zinc-iodine battery to practical application.

The invention discloses a method for removing bromine ions in a salt water body. The method comprises the steps of pretreatment before electrolytic oxidation, primary precise directional electrolysis, primary split-pole separated air real-time air stripping, secondary precise directional electrolysis, secondary split-pole separated air real-time air stripping, deep removal of bromine ions Br <-> by a reverse osmosis membrane, separation of bromine carrier airflow containing Br2 and the like. According to the method, the problems of environmental friendliness, economical efficiency, relatively good adaptability, directivity of a bromine ion Br <-> removal standard and how to deeply remove the bromine ion Br <-> in the prior art can be solved, and the Br <-> in the salt water body can be reduced to 10 ppm or below; the unit operation in the process path is basically conventional operation or universal operation, and has a good engineering feasibility foundation and an economic feasibility foundation.

The invention discloses a PbS quantum dot film which comprises a PbS-PbX2 quantum dot layer and a passivation layer covering the surface layer of the quantum dot layer. Wherein X is I and / or Br, and the passivation layer is made of iodine 3-aminopropionate and / or bromine 3-aminopropionate. Iodine 3-aminopropionate and / or bromine 3-aminopropionate are / is used as a passivator of the PbS-PbX2 quantum dot layer, amino (-NH2) and carboxylate radical (-COO-) in the iodine 3-aminopropionate and / or bromine 3-aminopropionate molecules can be used as bidentate ligands to be anchored on the surfaces of lead sulfide (PbS) quantum dots, the sulfur vacancy defect is filled, and the density of surface dangling bonds is reduced; and iodine or bromide ions are combined with Pb < 2 + > on the surfaces of the PbS quantum dots to form stable Pb-X bonds, so that non-radiative recombination can be inhibited, and the photoelectric conversion performance of the device is further optimized.

The invention relates to the technical field of organic synthesis, in particular to a method for synthesizing cyclopentane compounds through [3 + 2] cycloaddition reaction of aryl cyclopropane and olefin under the synergistic catalysis of bromide ions / visible light. The method comprises the following steps: in a nitrogen atmosphere, sequentially adding aryl cyclopropane, a benzyl malononitrile derivative, pyridine tribromide and a photocatalyst into a reaction solvent to obtain a mixture, stirring the mixture at the temperature of 40 DEG C under the irradiation of a 12W blue light LED lamp until the reaction is complete, and performing concentration and column chromatography purification to obtain the cyclopentane compound. The method has the advantages of mild reaction conditions, simple operation, simple and easily available raw materials and low cost.

The application discloses a vanadium-bromine flow battery electrolyte, a preparation method thereof and a flow battery. The electrolyte comprises a positive electrolyte and a negative electrolyte. The positive electrolyte contains water, bromine ions and an additive. The additive is a pyridine derivative and / or an imidazole derivative. The negative electrolyte contains an acid, vanadium ions and water. The preparation method comprises the following steps: mixing a bromine source with water, and then adding the pyridine derivative and / or the imidazole derivative to obtain the positive electrolyte; dissolving a vanadium source with an acid, and then filtering to obtain a filtrate; adding water to the filtrate, and then adjusting the concentration of vanadium ions to a target final concentration to obtain the negative electrolyte. The flow battery comprises the above-mentioned vanadium-bromine flow battery electrolyte, a positive electrode, an ion-conducting membrane and a negative electrode. The application solves the problems of low energy density, high price and cost, zinc dendrite and positive bromine volatilization of the current flow battery by introducing the coupling of a vanadium-based energy storage medium and a bromine oxygen reduction-oxidation couple.

The application discloses polylactic acid polyol as well as a preparation method and application thereof, and the preparation method comprises the following steps: preparing an in-situ catalyst by heating reaction of a zinc salt, an organic ammonium salt and bis(ethylene carbonate) ether; the anion of the organic ammonium salt is selected from any one of bromide, chloride and iodide; and a lactide monomer is added to obtain polylactic acid polyol through a polymerization reaction. The polylactic acid polyol prepared by the application has a flexible chain segment, can provide better flexibility, and can be applied to preparation of polyurethane materials.

The invention belongs to the technical field of organic electrochemical synthesis, and particularly relates to an electrochemical preparation method of 3, 4-dibromo pyrazole. 3, 4, 5-tribromopyrazole is adopted as a substrate, the problems that pyrazole is low in stability and prone to ring opening are effectively solved by adjusting the concentration of the substrate, cathode and anode electrode materials and the electrolytic potential, the yield of the prepared 3, 4-dibromopyrazole is higher than 60% and far exceeds the synthesis yield of an existing 3, 4-dibromopyrazole debromination synthesis method in the background technology, and the method is suitable for industrial production. And the preparation process is simpler. According to the application, 3-bromo pyrazole and 3, 4, 5-tribromo pyrazole are added and subjected to electrochemical reduction debromination at a cathode to generate 3, 4-dibromo pyrazole and bromide ions, the bromide ions lose electrons at an anode and are electrically oxidized into bromine, and the bromine reacts with the 3-bromo pyrazole to generate the 3, 4-dibromo pyrazole.

The invention discloses a method and a device for rapidly measuring the concentration of various inorganic anions in water. According to the method, rapid and high-precision colorimetric detection of eight ions such as fluorine ions, chloride ions, nitrite ions, bromide ions, nitrate ions, phosphate radicals, sulfite radicals and sulfate radicals is realized by adopting a reaction strategy of adding a color developing auxiliary agent and a specific color developing agent step by step and combining with step-by-step uniform mixing and optimizing a reagent combination, a concentration ratio and a reaction time sequence aiming at different target ions. The device comprises a sample groove, a multi-cavity color developing agent bin, a color developing auxiliary bin, a reaction tank, a liquid path conveying module, an image acquisition module and a control module which are integrated in a shell. Through deep integration of a chemical system and an automatic process, the problems of cross interference, poor color development stability, complicated operation and the like in multi-index detection of portable equipment are solved, and the method has the advantages of high detection speed, high accuracy, strong anti-interference performance, easiness in carrying and simplicity and convenience in operation.

The invention belongs to the field of post-treatment of organic chemical synthesis methods, and relates to a post-treatment method for propiconazole synthesis. A crude propiconazole product is used as a raw material and is subjected to an isomerization reaction under the combined action of a bromine-containing ionic liquid and sodium alkoxide to generate cis-propiconazole. The bromine-containing ionic liquid is imidazolium bromine salt: [CnH2n + 1-MIM] + Br <-> (n = 2-4) or pyridinium bromine salt: [CmH2m + 1-Py] + Br <-> (m = 2-4). The method is mild in process condition, low in reaction temperature, short in process path, simple to operate and high in safety, efficient conversion of low-efficiency trans-propiconazole and ineffective isomers is achieved, the content of cis-propiconazole in a treated sample is as high as 99%, the yield is as high as 97%, the economical efficiency of the process is improved, and the method is suitable for industrial production. And the ionic liquid used in the reaction can be further recycled, so that the atom utilization rate is increased.

The invention belongs to the technical field of nylon 66 polymer performance testing, and particularly relates to a method for simultaneously testing the content of iodide ions and bromide ions in a nylon 66 polymer, which comprises the following steps of: extracting the iodide ions and the bromide ions in the polymer by using weak acid salt (sub-carbonate or bicarbonate) instead of potassium nitrate as an ionic strength regulator; the acid environment in the extracted solution is adjusted with formic acid, silver nitrate is adopted as a titrant, iodide ions and bromide ions in the extract liquor are detected at the same time through potentiometric titration, and the problem that the iodide ions and the bromide ions cannot be detected at the same time is solved.

The invention belongs to the field of photovoltaic materials, and provides a flexible perovskite photovoltaic material and a preparation method thereof. The flexible film comprises a flexible substrate layer which is composed of polyethylene glycol terephthalate, and the surface of the flexible substrate layer is modified with nanoscale silicon dioxide particles; the chemical formula of the perovskite active layer is ABX3, A is mixed positive ions of formamidine ions and cesium ions, B is lead ions, and X is mixed halogen of iodide ions and bromide ions; a flexible packaging layer, wherein the flexible packaging layer is formed by compounding polydimethylsiloxane and graphene; according to the invention, by adopting the collaborative design of the flexible substrate (polyethylene glycol terephthalate) with the surface modified by nano silicon dioxide particles and the polydimethylsiloxane and graphene composite packaging layer, the photovoltaic material can bear more than 1000 times of 180-degree bending circulation, and the efficiency attenuation is less than 5%; the perovskite material is obviously superior to a traditional rigid perovskite material (fracture failure can be achieved after 100 times of bending).

The present invention relates to the preparation and use of high-entropy nanozymes with multi-pathway synergistic antibacterial effects, belonging to the field of nanozyme catalytic materials. The present invention, for the first time, utilizes a hydrothermal method and high-temperature calcination method to synthesize oxygen-vacancy-rich high-entropy oxides with haloperoxidase-like, peroxidase-like, and glutathione oxidase-like activities. These oxides can catalyze bromide ions and hydrogen peroxide to generate hypobromous acid, which interferes with bacterial quorum sensing, and hydroxyl radicals, which disrupt structure and function. Furthermore, these oxides consume glutathione, which maintains the internal redox balance of bacteria. This allows for multi-pathway synergistic and efficient bacterial damage and inactivation, helping to address the problems of existing antifouling nanozyme materials, which suffer from a single catalytic pathway and poor component adjustability. This allows for the practical expansion of high-entropy nanozyme coatings, and has potential application prospects in the field of marine biofouling.

The invention relates to the technical field of water treatment, and discloses a method and a device for recycling bromine triions based on irradiation coupling electronic control ion exchange and application, the method comprises the following steps: placing a bromine-containing stock solution in an electronic control ion exchange device which is a single-chamber device, irradiating the bromine-containing stock solution by using gamma rays, bromine ions in the bromine-containing stock solution are oxidized and react to form bromine triions; and then switching on a circuit and applying an oxidation potential to the working electrode to drive the bromine triions to directionally move towards the membrane and adsorb the bromine triions, and selectively recovering the bromine triions. The device comprises a single-chamber reactor, a liquid path system, a gamma-ray irradiation source for the single-chamber reactor, an electrochemical driving system, a two-electrode system with electrodes immersed in a bromine-containing stock solution, and a potential control system.

Disclosed is an alkali metal ion conductor which behaves as a liquid at a low temperature. The alkali metal ion conductor of the present disclosure is an alkali metal ion conductor comprising a salt, wherein the salt comprises a first cation, a second cation, and a first anion, the first cation is a tetraalkylammonium ion having an alkyl chain length of 5 or more, the second cation is an alkali metal ion, and the first anion is at least one anion selected from the group consisting of a bromine ion, a chlorine ion, and a hydrogen sulfate ion.

Methods and systems are provided for selectively extracting lithium from lithium ion batteries while avoiding the extraction of other metals from such batteries. The method involves contacting a sample including a lithium ion battery with an aqueous mixture of Br2 and a bromide reagent that dissociates in water to provide a bromide ion, and allowing the aqueous mixture to leach lithium ion from the sample as an aqueous solution of LiBr. LiBr is then recycled. For embodiments wherein the bromide reagent is HBr, hydrogen and bromine can be recovered as gases.

The preparation method comprises the following steps: after a micro electrode is prepared through 3D printing, iodine is loaded on the surface of the micro electrode to form an iodine positive electrode; preparing a zinc negative electrode matched with the iodine positive electrode in shape through laser engraving; uniformly mixing water, hyaluronic acid, hydrophilic silicon dioxide, zinc perchlorate and zinc bromide to form a gel electrolyte; and sequentially laminating the iodine positive electrode, the gel electrolyte and the zinc negative electrode on the substrate, and packaging to obtain the wide-temperature-range micro zinc-iodine battery. According to the gel electrolyte disclosed by the invention, hyaluronic acid and hydrophilic silicon dioxide lock water through hydrogen bonds formed between hyaluronic acid and hydrophilic silicon dioxide and water molecules, evaporation of water at a high temperature is inhibited, perchlorate inhibits solidification of water at a low temperature by destroying hydrogen bond structures between water molecules in a gel network, and a wide temperature range of a miniature battery is realized; meanwhile, bromide ions in the electrolyte are transmitted to a positive electrode through an interface to excite a four-electron reaction of iodine, so that the energy density of the micro zinc-iodine battery is improved.

The invention relates to a confinement structure composite membrane electrode and a preparation method and application thereof, the confinement structure composite membrane electrode is composed of a microporous ceramic substrate and a membrane electrode main body, and the membrane electrode main body is mainly composed of a conductive carrier, a BiOBr nanosheet, a carbon nanotube and a binder. The invention also comprises a preparation method of the confinement structure composite membrane electrode and a method for efficiently extracting bromine from brine of an oil and gas field by using the confinement structure composite membrane electrode. By utilizing the method, efficient selective electrooxidation bromine extraction from the brine of the oil and gas field can be realized without using noble metal, and the bromine ion conversion rate is up to 94.6%. The confinement structure composite membrane electrode can also be popularized and applied to various electrooxidation fields.

The invention relates to a quantum dot material, a preparation method and a quantum dot film and a backlight module applying the quantum dot material. The quantum dot material comprises a core layer, a ligand layer and a coating layer. The ligand layer is formed and covers at least a partial region of the surface of the core layer and forms a bond with the core layer. And the coating layer is formed and covers at least partial area of the surface of the ligand layer and is bonded with the ligand layer. The ligand layer is formed by at least three ligand compounds, and the at least three ligand compounds comprise a first type of ligand compound and a second type of ligand compound; the first type of ligand compound has a first coordination group to form a bond with the core layer, and the second type of ligand compound has a second coordination group to form a bond with the coating layer. The core layer has an ABX3 crystal structure, the A site is occupied by formamidine ions, the B site is occupied by lead ions, and the X site is occupied by one of chloride ions, bromide ions and iodide ions. When the wavelength of incident light is 450 nm, the highest emission wavelength of the quantum dot material responding to the incident light is 450-760 nm.

The invention discloses a trigonelline metformin salt and a preparation method thereof, and the preparation method comprises the following steps: providing a resin column filled with anion exchange resin, treating the resin column with a salt solution for ion replacement activation to obtain an activated resin column, anions of the salt are chloride ions, bromide ions, acetate ions, malate ions, lactate ions, tartrate ions or citrate ions; enabling the trigonelline metformin iodized salt solution to pass through an activated resin column, and selectively collecting the exchanged solution; and carrying out concentration treatment on the collected exchanged solution to obtain the trigonelline metformin salt. In combination with a specific embodiment, compared with a trigonelline metformin iodate, the solubility of the trigonelline metformin salt prepared by the preparation method of the trigonelline metformin salt provided by the invention in water is greatly improved, so that the application range of the trigonelline metformin salt is greatly expanded.

The invention relates to the technical field of waste recycling, in particular to a harmless treatment and resource recycling method for bromine in bromine-containing waste, which comprises the following steps: putting the bromine-containing waste into a reaction solution, and heating for reaction to obtain debrominated waste and filtrate containing bromine ions; the reaction liquid comprises an alkaline substance, a copper compound precursor, a ligand and a solvent; the ligand is selected from at least one of a bidentate ligand containing two nitrogen sites, a polydentate ligand containing two nitrogen sites, a bidentate ligand containing two oxygen sites, a polydentate ligand containing two oxygen sites, a bidentate ligand containing one nitrogen and one oxygen site and a polydentate ligand containing one nitrogen and one oxygen site; the temperature of the heating reaction is not higher than 150 DEG C. The invention solves the problems of environmental pollution and bromine resource waste caused by organic bromine pollutants (such as highly toxic brominated dioxin) due to landfill, incineration and other traditional treatments after the brominated flame retardant (such as tetrabromobisphenol A, polybrominated diphenyl ether and the like)-containing plastic or resin is abandoned.

The application discloses a method for degrading brominated organic pollutants in water by using UV / H2O2, and first establishes a high-level oxidation treatment method for brominated pollutants in water by combining UV and H2O2, determines the initial concentration of the brominated pollutants and the adding proportion of the oxidant H2O2 by using absorbance, Lambert-Beer law and the principle of absorbance additivity, and verifies the rationality of the concentration settings of the brominated pollutants and the oxidant in the kinetics evaluation, and further establishes a detection method for bromide ions, which, compared with the traditional ion chromatography method, does not need an additional pretreatment process, avoids the matrix interference of coexisting organic matters, and greatly saves the experimental and instrument use costs; for the identification of degradation products, the method established by the application accurately detects the evolution trend of more than twenty structural molecules in the examples along with the treatment process, and the method can be widely applied to the wastewater treatment of brominated flame retardants, brominated phenols and other bromine-containing organic matters in the environment.

The invention provides a high-air-stability sulfide electrolyte and a preparation method thereof, and belongs to the technical field of energy storage batteries, LiI is selected as a raw material, LiBr is used as an additive to replace part or all of LiI, through bromine ion doping, crystal slight compression is caused, crystal lattice channels more beneficial to migration are formed, an energy barrier of lithium ion migration is reduced, and the air stability of the sulfide electrolyte is improved. The ionic conductivity of the material is obviously improved; the sulfide electrolyte structure has no free-state S < 2->, and the main structural unit is that the sensitivity of the material to moisture in air is reduced; meanwhile, bromide ions have high chemical stability, are difficult to oxidize by moisture or oxygen in the air, play a chemical passivation role in a crystal structure, can effectively prevent the moisture in the air from permeating and hydrolysis reaction, reduce the release of toxic byproduct gases and greatly improve the air stability.

Provided is a semiconductor etching solution having a large etching ratio of SiGe relative to Si when an object containing Si and SiGe is treated and having excellent storage stability. The semiconductor etching solution includes: a fluoride ion source; a carboxylic acid; a percarboxylic acid; hydrogen peroxide; and bromide ions, and a content of the bromide ions is less than 500 mass ppm with respect to a total mass of the semiconductor etching solution.

This invention discloses a high-efficiency sodium bromide recovery process for PTA wastewater, belonging to the technical field of wastewater treatment and bromine resource recovery and utilization in the production of purified terephthalic acid. The process includes the following steps: Pretreatment softening: A stream of bromine-containing wastewater generated during the production of purified terephthalic acid is provided. The bromine-containing wastewater is introduced into a chelating resin unit at a volume hourly space velocity (VHSV) to remove calcium and magnesium ions from the bromine-containing wastewater, resulting in softened water. Through a re-filtration enhanced salt separation step, the physical washing effect of the dialysis water is utilized to effectively wash the retained bromide ions into the product water side, overcoming the Donnan effect at high concentrations. Through an acidification and decarbonation step, the wastewater is transformed from a complex ternary system of carbonates, bromides, and sulfates into a simple binary system of sulfates and bromides, eliminating the interference of carbonate ions on the membrane system.

The present invention refers to a controlled method for depositing a chromium or chromium alloy layer on at least one substrate, the method comprising the steps (a) providing an aqueous deposition bath, wherein the bath comprises - trivalent chromium ions, - bromide ions, - alkali metal cations in a total amount of 0 mol / L to 1 mol / L, based on the total volume of the deposition bath, and the bath has - a target pH within the range from 4.1 to 7.0, (b) providing the at least one substrate and at least one anode, (c) immersing the at least one substrate in the aqueous deposition bath and applying an electrical direct current such that the chromium or chromium alloy layer is deposited on the substrate, the substrate being the cathode, wherein during or after step (c) the pH of the deposition bath is lower than the target p H, (d) adding NH4OH and / or NH3 during or after step (c) to the deposition bath such that the target pH of the deposition bath is recovered.

The application provides a light conversion agent, a preparation method and application thereof, and a light conversion film, and belongs to the technical field of chemical synthesis. The light conversion agent is an organic salt ion-rare earth Eu (III) anion type, is an ion pair type light conversion agent, has absorption of organic and inorganic complexes, has stronger ultraviolet absorption capacity, and is synthesized by introducing an electron-donating group N,N-dimethyl into a para position of a pyridine nitrogen and introducing a bromohexyl group to form a corresponding electron-withdrawing pyridine group to synthesize a pyridine salt, and is synthesized by taking 2-thiophene formyl trifluoroacetylacetone as a ligand to synthesize a rare earth anion complex Eu (HTTA) 4 ‑ By ion exchange, bromine ions in the pyridine salt are replaced by the complex anions, and by electrostatic interaction between the pyridine cation and the anion complex, sensitization of rare earth luminescence is realized, and the ultraviolet absorption capacity is improved. Moreover, the light conversion agent has a long alkyl flexible chain, can be better blended with LLDPE, and enhances the stability and dispersibility of the light conversion agent in resin.

A halogenated polymer has excellent heat resistance and whiteness as compared with a conventional halogen-containing polymer. A halogenated polymer represented by the following formula (1), contains bromide ions, which has a bromide ion content of 1 to 2,000 ppm:wherein R is a C1-C6 alkylene group, —S— or —SO2—, and n is a real number.

The invention discloses a three-phase catalytic oxidation treatment system for printing and dyeing wastewater, belongs to the technical field of sewage treatment, and solves the problems of treatment of wastewater by ozone catalysis, monitoring of missing of trace toxic by-products and metal leaching, poison of effluent and ozone consumption, acidification inactivation circulation and silent collapse of the system. Comprising a pulse electrolysis pretreatment unit used for decomposing pollutants through pulse electrolysis oxidation and adjusting current and duty ratio according to catalyst health degree and bromide ion concentration; the invention discloses a heterogeneous catalytic oxidation main reactor. Bromide ions are reduced through pulse electrolysis, a reaction environment is dynamically regulated and controlled through online metal monitoring to prevent catalyst collapse, and real-time biotoxicity early warning is combined as a final judgment, so that the whole treatment process can sense and break vicious cycles of toxicity generation and catalyst failure in advance, and long-term safety and stability of effluent are ensured.