The present application relates to the technical field of
nuclear fuel cycle and
radioactive waste treatment, in particular to a method and
system for treating
uranium-containing organic phase, the
system comprises pretreatment washing tank,
pyrolysis reactor, phase separation tank,
uranium recovery device,
vacuum distillation device,
tail gas treatment device and solidification device connected in sequence; the method first removes acid by
water washing pretreatment of
uranium-containing organic phase at 40-50 DEG C, then adds
phosphoric acid to catalyze
pyrolysis to decompose TBP and transfer uranium to
phosphoric acid phase, recovers uranium and n-
dodecane after phase separation, simultaneously treats
tail gas and solidifies residual waste, and further provides online
monitoring and control subsystem to realize
automatic control and safety
interlocking; the present application has mild reaction condition, avoids strong
corrosive substance generation, total uranium
recovery rate reaches more than 90%, about 80% of n-
dodecane can be recycled, greatly reduces
radioactive waste production amount, is safe and reliable in operation, and is suitable for
radioactive waste organic extractant reduction and resourceful treatment in
nuclear fuel cycle.