113 results about "Ferrocene" patented technology

The invention discloses an algae-based iron-carbon catalyst as well as a preparation method and application thereof, and relates to the technical field of new material research and development and sewage treatment. The preparation method comprises the following steps: mixing ferrocene, diatomite and a solvent to obtain a mixed solution; adding a hydrogen peroxide solution into the mixed solution, and then heating for reaction to obtain an intermediate; and roasting the intermediate to obtain the algae-based iron-carbon catalyst. According to the invention, ferrocene and diatomite are used as raw materials, and the high-performance algae-based iron-carbon catalyst is prepared through simple solvothermal reaction and roasting treatment. The obtained algae-based iron-carbon catalyst is stable in structure, high in activity and wide in applicable pH range in a persulfate oxidation system, and can be used for activating persulfate to degrade antibiotic pollutants in water.

The invention relates to a preparation method of a hydrolysis modified organic silicon high-temperature-resistant anticorrosive coating, and belongs to the technical field of anticorrosive coatings. The preparation method comprises the following steps: heating 1, 1 '-bis (dimethylsilyl) ferrocene, methylbenzene, chloroplatinic acid, 2, 2, 3, 3, 4, 4, 4-heptafluorobutyl acrylate and bis-(2-methylallyl) cyclooctyl-1, 5-diene ruthenium, and reacting to obtain an intermediate product 1; weighing methyltrimethoxysilane, phenyltrimethoxysilane and the intermediate product 1, uniformly stirring and mixing, slowly dropwise adding diluted hydrochloric acid, hydrolyzing, and heating to react, so as to obtain modified silicon resin; adding the modified silicon resin into petroleum ether, and adding silicone oil, an organic tin catalyst, a bis-ammonia coupling agent, filler and a curing agent to obtain the anticorrosive paint.

A group of inventions relates to the field of medical devices. A method for producing needles with adsorption properties is described by depositing an iron oxide coating onto the needle by atomic layer deposition. An acupuncture needle for reflex therapy, consisting of a handle and shaft made of metal material, is placed in a reactor where a vacuum is created at a pressure of approximately 10 mbar ± 0.1 mbar and a temperature of 150 ± 0.2 °C, then a ferrocenecarboxylic acid precursor in the form of vapor is delivered to the reactor, then nitrogen is added to the reactor and degassed to the initial pressure, and this process is repeated in pulse mode until a specific coating thickness is formed. The use of ferrocenecarboxylic acid as a precursor for producing an Fe3O4 coating is described. An acupuncture needle for adsorbing toxic heavy metal ions is described with a coating of Fe3O4 nanofilm thickness of 14 nm ± 0.1 nm, and the nanofilm has the appearance of a nanosieve as shown in Figure 1b. The use of acupuncture needles for adsorbing metal ions is described. The technical achievement of this invention is the development of a method for attaching a magnetic separation film of Fe3O4 to the surface of an acupuncture needle, which is simpler and less expensive in terms of methodology and technique, thereby imparting adsorption properties to the acupuncture needle. The needle of this invention makes it possible to adsorb toxic heavy metal ions such as cadmium, arsenic, manganese, cesium, aluminum, iron, cobalt, nickel, chromium, mercury, lead, copper, zinc, beryllium, antimony, thallium, bismuth, osmium, tin, molybdenum, zirconium, titanium, vanadium, molybdenum, and gallium.

The present application relates to a kind of radiotherapy sensitization microneedle and its preparation method and application, belong to biological medicine technical field.The radiotherapy sensitization microneedle of the present application includes hyaluronic acid and nano radiosensitizer;The radiotherapy sensitization microneedle is obtained by drying after hyaluronic acid and nano radiosensitizer solution are mixed;The nano radiosensitizer solution is prepared by the following method: hafnium salt, 1,1'-ferrocene dicarboxylic acid and benzoic acid are mixed in organic solvent and stirred, centrifugal;The supernatant obtained is dialyzed, extracted, and the liquid phase obtained after solid-liquid separation is nano radiosensitizer solution.The radiotherapy sensitization microneedle of the present application is applied to the growth inhibition and radiotherapy sensitization of mouse melanoma cell B16F10 cell, can fully play the role of radiotherapy sensitization while overcoming the limitation of prior art, and preparation route is simple, and have certain conversion prospect.

The invention relates to a method for co-processing low-flash-point low-calorific-value waste liquid in a cement kiln, and belongs to the technical field of environmental protection. The low-flash-point low-calorific-value waste liquid is conveyed to a pressure-stabilizing and flow-stabilizing tank and then is stably output to a low-pressure gasification preheater; the low-pressure gasification preheater is used for heating the waste liquid by utilizing low-grade waste heat of the cement kiln system and gasifying the waste liquid; the gas-liquid mixed phase is conveyed to a kiln head cover nozzle and a decomposing furnace nozzle through a special conveying pipeline, and heat energy is released and thoroughly decomposed; the inner wall of the special conveying pipeline is coated with a malonyl urea-epoxy resin composite coating; the malonyl urea-epoxy resin composite coating is prepared from epoxy resin, malonyl urea, methylbenzene, amino ferrocene and additional amino ferrocene; after the flue gas is co-treated by the cement kiln disclosed by the invention, the concentration of benzene and chlorobenzene in the flue gas is remarkably reduced, and the requirements of environment-friendly emission are met.

The application discloses a triphenylmethane polyether dye and a preparation method thereof, and the preparation method comprises the following steps: (1) adding an organic catalyst and an oxidant into a triphenylmethane polyether dye leucoaqueous solution in the interval of 40-60 DEG C, adding an acid-binding agent to maintain a proper pH, and completing oxidation; the organic catalyst is a ferrocene-rotene iron compound; (2) adjusting the pH with an acid-binding agent aqueous solution, removing the organic catalyst by hot filtration, removing water through vacuum distillation of the filtrate, and performing pressure filtration to obtain the triphenylmethane polyether dye. The improved rotene iron catalyst is used in the application, the catalytic effect is obviously improved, the reaction temperature and activation energy are reduced, the defects of excessive hydrogen peroxide oxidation are overcome, and the obtained product meets the EN71-3 standard.

The application provides an in-situ oriented carbon nanotube / silicon nitride nanobelt composite material and a preparation method thereof, and comprises the following steps: uniformly mixing methyltrimethoxysilane, dimethyldimethoxysilane, ethanol, water and nitric acid according to a certain proportion, and obtaining a siloxane xerogel precursor after stirring and drying; obtaining a silicon nitride nanomaterial by a carbothermal reduction reaction method under high-temperature conditions; injecting a mixed solution of ethanol, ethylenediamine and ferrocene into a tube furnace by a floating CVD method under high-temperature conditions, and growing carbon nanotubes on the surface of the silicon nitride nanobelt to obtain the in-situ oriented carbon nanotube / silicon nitride nanobelt composite material; and the application grows the carbon nanotubes on the surface of the silicon nitride nanobelt material by the floating CVD method to improve the electromagnetic shielding performance of the silicon nitride nanocomposite material, and finally, the carbon nanotube / silicon nitride nanobelt composite material with light weight, flexibility and good electromagnetic shielding performance is prepared.

The invention discloses a phosphorus-containing oxynitride compound based on a cycloarane skeleton and a ferrocene skeleton and a preparation method and application thereof, the phosphorus-containing oxynitride compound based on the cycloarane skeleton and the ferrocene skeleton is selected from at least one of compounds with structural formulas as shown in a formula I and a formula II, wherein Ar is independently selected from phenyl and C7-C15 substituted aryl; the substituent group of the substituted aryl group is selected from one of C1-C4 alkyl groups and methoxyl groups. According to the invention, a class of novel phosphorus-nitrogen-oxygen-containing compounds which have two planar chirality and are based on the cycloarane skeleton and the ferrocene skeleton can be effectively synthesized; as a ligand, the compound shows excellent catalytic activity and enantioselective control ability in asymmetric hydrogenation of an iridium-catalyzed N-aryl indolone compound or a heterobiaryl ketone compound.

The application relates to a method for synthesizing ferrocene phosphine oxide compounds. Specifically, a ferrocene-substituted compound, diaryl phosphine oxide is used as raw material to realize C-H phosphine oxide reaction of ferrocene under the promotion of electricity. The application has the following advantages: the ferrocene-substituted compound is directly used as a C-H donor without guidance, no additional oxidant and metal catalyst are needed, the condition is mild, the substrate range is wide, and the yield is good.

The invention discloses a preparation method of a low-pore-number composite lining, and belongs to the technical field of textiles. The preparation method of the low-hole-number composite lining comprises the following steps: (1) weaving polyester yarns into gray fabric; (2) shaping and preshrinking the gray fabric; (3) dyeing the set and pre-shrunk gray fabric; (4) shaping and finishing the dyed gray fabric to obtain a composite lining; wherein the dye for dyeing is obtained by reacting N-amino-4-N, N-dimethyl-1, 8-naphthalimide with ferrocene dicarboxaldehyde, and the dye for dyeing is obtained by reacting N-amino-4-N, N-dimethyl-1, 8-naphthalimide with ferrocene The setting agent for setting and finishing contains a hydrophilic softening agent, the hydrophilic softening agent is obtained by mixing polyether phenyl silicone oil with a compound emulsifier and deionized water, and the polyether phenyl silicone oil is obtained by reacting side chain hydrogen-containing silicone oil, allyl alcohol polyoxyalkyl ether, vinyltriethoxysilane and 1-(4-vinyl-phenyl)-ethanone; the prepared low-hole-number composite lining is good in hydrophilicity, color fastness and softness.

The present invention relates to the technical field of wood-plastic composites, and provides a PVC wood-plastic material having strong smoke suppression and flame retardancy, and a preparation method therefor. The PVC wood-plastic material comprises the following components in parts by weight: 70-100 parts of a PVC resin, 20-30 parts of wood powder, 20-30 parts of calcium carbonate, 15-20 parts of a smoke suppression material, 10-15 parts of a flame retardant, 1-6 parts of a foaming agent, 5-10 parts of a stabilizer, 1-2 parts of a coupling agent, 5-10 parts of a processing aid, and 1-4 parts of a lubricant, wherein the smoke suppression material comprises a molybdenum compound, ferrocene and an oxalate dihydrate in a mass ratio of 1:(0.5-1.5):(5-10). The preparation method comprises the end-capping modification of the wood powder and the preparation of the PVC wood-plastic material. The prepared PVC wood-plastic material has excellent flame retardancy and smoke suppression properties.

The application relates to a Faraday cage type aptamer sensor based on a MOF nanofilm and a method for detecting Staphylococcus aureus. A 1,1'-ferrocene carboxylic acid is used as a ligand, zirconium / hafnium is used as a central atom, and a Zr-based MOF nanofilm with different hafnium doping ratios is synthesized by using a bottom-up method. A Zr / Hf-MOF nanofilm with large size and excellent conductivity is selected as a two-dimensional signal probe, and is used for constructing an aptamer sensor of a Faraday cage. When Staphylococcus aureus exists, the Zr / Hf-MOF nanofilm is attached to the surface of an electrode to form a Faraday cage sensing interface, the interface expands an outer Helmholtz plane layer, leads to direct electron transmission between the electrode and the signal probe, and thus Staphylococcus aureus can be detected through an electrochemical workstation. The detection method of the application can realize detection of a large target by requiring the size and conductivity of the MOF nanofilm, and effectively amplifies the electrical signal through the Faraday cage structure, and has excellent detection specificity and sensitivity.

The invention relates to the technical field of nano material preparation and electrochemical energy storage, in particular to a single-walled carbon nanotube and a preparation method thereof. According to the preparation method, a floating catalyst chemical vapor deposition (FCCVD) method is adopted, a compound of ferrocene and sublimed sulfur is used as a catalyst precursor, a horizontal tube furnace with at least three independent temperature zones is adopted, and a specific staged programmed heating strategy is adopted, so that the high-temperature-resistant and high-temperature-resistant catalyst is obtained. And the temperatures of the precursor sublimation area, the catalyst formation and activation area and the main growth area are accurately controlled in sequence. Wherein the temperature of the main growth region is accurately controlled at an optimal window of 1000 DEG C. The method effectively inhibits the generation of multi-walled carbon nanotubes and defect structures, and can stably prepare single-walled carbon nanotubes with high graphitization degree and less metal residues. The method is high in process controllability, and a reliable scheme is provided for large-scale preparation of the high-performance single-walled carbon nanotubes.

The invention discloses a Fe-modified TiO2 hollow microsphere photo-Fenton catalyst as well as a preparation method and application thereof, and relates to the technical field of catalyst preparation, and the preparation method comprises the following steps: preparing TiO2 microspheres with hollow structures from hexadecyl trimethyl ammonium bromide, absolute methanol, deionized water and tetrabutyl titanate; the method comprises the following steps: mixing ferrocene and 0.25 C-TiO2 powder, putting the mixture into a quartz tube, putting the quartz tube into a muffle furnace, heating and pyrolyzing according to a two-stage program, alternately washing black powder with absolute ethyl alcohol and deionized water after the pyrolysis is finished, and drying to obtain a sample CT-5Fe; the preparation method comprises the following steps: dispersing CT-5Fe in an H2O2 solution, carrying out a water bath reaction, collecting a gray product, carrying out centrifugal operation, washing, and drying to obtain the Fe-modified TiO2 hollow microsphere photo-Fenton catalyst, namely CT-5Fe-HO. According to the invention, a photocatalysis-Fenton-like coupling system for phenol degradation is constructed, the PMS adsorption and activation capability is enhanced, high activity and good cycle stability are maintained in a wide pH range and in a complex water body, and a solution is provided for water body pollution treatment.

A preparation method of a three-dimensional self-supporting phenolic resin derived carbon (at) carbon nanotube sponge comprises the following steps: step 1, injecting a ferrocene and dichlorobenzene carbon source solution into a reaction furnace in a hydrogen / argon mixed atmosphere to obtain a carbon nanotube sponge; step 2, dissolving resorcinol and hexamethylenetetramine in the deionized water; cutting a carbon nanotube sponge into proper small blocks, putting the small blocks into the mixed solution, transferring the small blocks into an oil bath pan, carrying out stirring heat treatment / autoclave heat treatment for a period of time, standing overnight, and cooling to room temperature, so as to obtain resorcinol and hexamethylenetetramine prepolymer coated carbon nanotube sponge; step 3, taking out the resorcinol and hexamethylenetetramine prepolymer coated carbon nanotube sponge, washing, and then freeze-drying to maintain the three-dimensional porous network structure; and finally, carrying out high-temperature annealing treatment to obtain the three-dimensional self-supporting phenolic resin derived carbon-coated carbon nanotube sponge. The integrated self-supporting composite electrode is successfully constructed through a three-dimensional network in-situ synthesis process.

The application provides a preparation method and application of a novel ferrocene pyridine hydrazine manganese complex. The manganese complex has multiple advantages such as low cost, simple synthesis and air stability. Meanwhile, the provided manganese complex can be applied to an asymmetric hydrogenation reaction and has certain industrial application prospect.

The present application relates to the technical fields of organic metal compound synthesis, and discloses a production process method for synthesizing ferrocene based on one-pot method, which takes sodium, anhydrous ferrous chloride and dicyclopentadiene as raw materials, and completes the whole process of dicyclopentadiene depolymerization, sodium cyclopentadiene generation and ferrocene coordination synthesis in a non-protic solvent through gradient temperature control in one-pot method.The present application discards the disadvantages of multi-step reaction in traditional process, and does not need to prepare cyclopentadiene by pre-depolymerizing dicyclopentadiene, thus greatly simplifying the production process, reducing energy consumption and raw material loss, and achieving the product conversion rate of up to 85%, the purity of up to 99%, simple and controllable operation, adaptation to industrialized continuous production, and good economic and environmental benefits.

The invention belongs to the technical field of photocatalyst materials, and particularly relates to a three-dimensional graphene aerogel photo-self-Fenton catalyst as well as a preparation method and application thereof. The preparation method comprises the following steps: mixing graphene dispersion liquid containing ethylenediamine with phenolic resin prepolymerization liquid containing ferrocene aldehyde, phenols and a basic catalyst, and performing one-step hydrothermal reaction, washing and freeze-drying to prepare the three-dimensional graphene aerogel photo-self-Fenton catalyst. The catalyst can be used for degrading organic pollutants in water under the irradiation of visible light.

The invention belongs to the field of film-wrapped stranded conductors, and particularly provides a low-dielectric-loss paint film composition and a preparation method thereof and a film-wrapped stranded conductor. The preparation method of the low-dielectric-loss paint film composition comprises the following steps that S01, ferrocenecarboxylic acid, octaaniline propyl cage-shaped polysilsesquioxane and diethylene glycol are taken and mixed, N, N-dimethylformamide is used for dispersion, and a mixture is obtained; stirring and reacting at room temperature to obtain a precursor liquid, then supplementing octaaniline propyl cage-shaped polysilsesquioxane, continuously reacting, then supplementing N, N-dimethylformamide, re-dispersing, and recording as a liquid A for later use; s02, dihydric alcohol and diisocyanate are taken and mixed, the mixture is heated for a reaction, then N, N-dimethylformamide is added for dispersion, and after continuous treatment, a polyurethane prepolymer dispersion liquid is obtained and marked as a liquid B for standby application; and S03, mixing the solution A with the solution B, and concentrating to obtain the paint film composition. The paint film composition prepared by the invention has the advantages of low dielectric loss and good mechanical properties.

The invention provides a method for preparing chiral amine by catalyzing asymmetric hydrogenation of aromatic imine through a manganese / chiral ferrocene P, N, N ligand. The manganese precursor and ligand adopted by the method are easy to obtain, the reaction condition is mild, the operation is simple, the target chiral amine compound can be obtained with high yield and high stereoselectivity, and continuous large-scale preparation can be realized. The catalyst system is high in activity, the molar ratio of imine to the catalyst can reach 100000: 1, and the catalyst has a very good industrial application prospect.

This invention relates to a method for preparing a graphene-based coated iron catalyst for the deep removal of trace amounts of acetylene and ethylene impurities from electronic-grade hydrogen chloride, belonging to the field of catalyst technology. The method involves dispersing phenolic resin and graphene quantum dots in toluene, adding allyltrimethylammonium bromide, ferrocene methylamine, and sodium ethoxide, heating and stirring the reaction, and adjusting the pH with acetic acid. Citric acid and ferric acetylacetone are then added, and the mixture is stirred. Sodium borohydride is added in two stages, and the reaction is continued with stirring to obtain a gel precursor. The gel precursor is then ultrasonically dispersed, dried, and subjected to staged heating in a nitrogen-hydrogen atmosphere to obtain the resin-based coated iron catalyst. The catalyst prepared by this invention can effectively remove trace amounts of acetylene and ethylene impurities from electronic-grade hydrogen chloride, improving the purity of electronic-grade hydrogen chloride.

The invention relates to the technical field of membrane separation, and discloses a high-protein milk concentration process based on a membrane filtration technology, the process adopts an electric response membrane grafted with an electric response polymer brush on the surface, and an electric control zymogen modified by genetic engineering is added into milk feed liquid to be treated. The zymogen is modified with an electric field responsive anchoring group and an electric signal activated ferrocene protecting group. In the filtering stage, a first electric field is applied to stretch the polymer brush, so that anti-pollution filtering is realized; and in the cleaning stage, switching to a second electric field to enable the polymer brush to shrink and drive the zymogen to be anchored on the surface of the membrane, and applying an activation pulse to trigger the activity of the zymogen so as to degrade pollutants in situ. On the premise of not interrupting production, not adding chemical cleaning agents and not damaging target product protein, milk concentration is efficiently and continuously carried out, and long-term stable high permeation flux is maintained.

This invention discloses an ultra-low friction lubricating material system with self-catalytic effect and its preparation method, belonging to the field of lubricant technology. The ultra-low friction lubricating material system is composed of a base oil, an organometallic catalyst, and organic additives. The organometallic catalyst is at least one selected from ferrocene, cobalt carbonate, cobalt oxalate, copper acetate, and nickel oxalate. The organic additives are at least one selected from o-xylene, ethylene glycol, dodecanol, oleic acid, and tetraethyl orthosilicate. During friction, the organometallic catalyst releases metal ions, which, under the action of frictional heat and contact pressure, catalyze the base oil components to form a carbonaceous lubricating film in situ on the surface of the friction pair. The organic additives provide an additional carbon source during friction, working together with the organometallic catalyst to reduce the break-in time for the friction pair to reach a stable state. This lubricating material system not only significantly reduces the coefficient of friction and wear rate but also significantly shortens the break-in time.

This disclosure provides a redox flow battery with long operating time or long life for energy storage applications. A water-soluble perylenediimide molecule can be used as an energy storage material in the anode chamber, and a water-soluble ferrocene molecule can be used as an energy storage material in the cathode chamber. This redox flow battery has a substantially negligible crossover rate across the membrane.

The application belongs to the field of aquaculture, and particularly relates to an ammonia-nitrogen removing agent for aquaculture and a preparation method thereof. The ammonia-nitrogen removing agent is composed of the following components in parts by weight: organic chlorine 8-10 parts, peroxide 6-8 parts, oxygen supplier 0.2-0.5 parts, catalyst 0.5-1 part, pH regulator 2 parts, and stabilizer 4-5 parts. The organic chlorine is sodium dichloroisocyanurate and cyanuric chloride, or cyanuric chloride. The catalyst is ferrocene. The pH regulator is sodium bisulfate and phosphate, or phosphate. The stabilizer is anhydrous sodium sulfate and anhydrous magnesium sulfate, or anhydrous sodium sulfate and anhydrous magnesium chloride. The application slowly releases hypochlorous acid through organic precursors, and degrades ammonia-nitrogen in water by combining with the ammonium magnesium phosphate method, so that the concentration is controllable and the effective period is long. While the ammonia-nitrogen removing agent of the application efficiently degrades ammonia-nitrogen, the problem of excessively high initial effective chlorine concentration is avoided, and the safety and stability of the treatment process are significantly improved.

The invention provides a novel urchin-shaped ordered carbon-iron composite material as well as a preparation method and application thereof, and belongs to the technical field of carbon nanomaterials. The preparation method comprises the following steps: by taking triethanolamine, cetyltrimethylammonium bromide, sodium salicylate and tetraethyl silicate as raw materials, mixing and stirring, carrying out hydrothermal reaction, washing and centrifuging, drying and calcining in an air atmosphere to obtain an urchin-shaped silicon template; then compounding the silicon template and dopamine in a Tris solution, and carrying out stirring ultrasonic treatment, standing in a dark place and centrifugal drying to obtain mesoporous silicon filled with polydopamine; and mixing the product with ferrocene in acetone, adding a hydrogen peroxide solution, carrying out oil bath stirring until the solvent is volatilized, drying, calcining in an inert atmosphere, and finally, carrying out alkaline solution reflux and centrifugal drying treatment to obtain the novel urchin-shaped ordered carbon-iron composite material. The obtained novel urchin-shaped ordered carbon-iron composite material has excellent catalytic activity, and has a good application prospect in the fields of electro-catalysis, engineering materials, energy storage and conversion and the like.

The application relates to the field of liquid crystal polymer materials, and particularly discloses a liquid crystal polymer monomer containing ferrocene, a polymer and a preparation method thereof. A protecting agent is introduced into n-bromo-1-n-alkanol, and reacts with vinyl terephthalic acid to obtain a vinyl terephthalic acid derivative; the protecting agent of the vinyl terephthalic acid derivative is removed, and esterification is carried out with ferrocene formic acid to obtain a liquid crystal polymer monomer containing ferrocene, and then polymerization is carried out to obtain a liquid crystal polymer polymer containing ferrocene. The polymer has the advantages of complete monomer polymerization, good liquid crystal property, heat stability and electrochemical performance, high conversion rate, relatively narrow dispersity, suitability for industrial production and applicability to preparation of electrode materials.

The invention discloses a preparation method for electrocatalytic synthesis of polyfluorinated biaryl, and belongs to the field of organic synthesis. The invention solves the problem that the existing method for synthesizing the complex polyfluorinated aryl compound by using polyfluorinated aromatic hydrocarbon mostly depends on the use of a metal nucleophilic reagent or the redox capacity of a photocatalyst. The method comprises the following steps: uniformly mixing polyfluorinated aromatic hydrocarbon, aromatic hydrocarbon, tetrabutylammonium bromide, ferrocene, potassium hydroxide and an organic solvent, and then carrying out electrochemical reaction. The method is used for preparing the polyfluorinated biaryl through electro-catalytic synthesis.

This invention provides a ferrocene-amine-based bidentate phosphine ligand compound, its preparation method, and its application. The structure of the ferrocene-amine-based bidentate phosphine ligand compound is shown below: wherein R 1 Selected from any one of isopropyl, tert-butyl, n-butyl, dimethyltert-butylsilyl, or triisopropylsilyl; R 2 R 3 R 4 R 5 The ligands are independently selected from any one of phenyl, tert-butyl, pyridyl, cyclohexyl, N-methylpyrroleyl, N-methylimidazolyl, quinolinyl, furanyl, thiofuranyl, or adamantyl. The novel ferroceneamine-based bidentate phosphine ligands provided by this invention have the advantages of high activity and high selectivity.

The invention relates to a chiral ferrocene skeleton PNNO tetradentate ligand and application thereof in asymmetric hydrogenation reaction. The ligand has the advantages of simple synthesis, good stability, high selectivity and the like. A metal complex of the ligand shows very excellent catalytic activity and extremely high enantioselectivity in an asymmetric hydrogenation reaction of ketone, can efficiently catalyze reduction of prochiral ketones such as aryl alkyl ketone, heteroaryl alkyl ketone, aryl (hetero) aryl ketone, aliphatic ketone and the like into corresponding chiral alcohol, and has huge industrial application potential.