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152 results about "Diimide" patented technology

Diimide, also called diazene or diimine, is a compound having the formula (NH)₂. It exists as two geometric isomers, E (trans) and Z (cis). The term diazene is more common for organic derivatives of diimide. Thus, azobenzene is an example of an organic diazene.

Preparation method and application of copper-based metal-organic framework catalytic material

The invention relates to the technical field of catalysts, and discloses a preparation method and application of a copper-based metal-organic framework catalytic material.The preparation method comprises the following steps that S1, cuprous salt, N, N '-bis (5-aminonicotinyl) naphthalimide and a solvent are mixed, and a mixture is obtained; s2, heating the mixture to a reaction temperature, carrying out a constant-temperature reaction, and cooling to obtain a crystal; and S3, washing and drying the crystal to obtain the copper-based metal-organic framework catalytic material. According to the preparation method of the copper-based metal-organic framework catalytic material provided by the invention, N, N '-bis (5-aminonicotinyl) naphthalimide is used as an organic ligand to prepare the copper-based metal framework Cu-PTD with N / O co-coordination, and the copper-based metal framework Cu-PTD has relatively strong electrocatalytic carbon dioxide reduction and electron transfer capabilities; and the catalyst has relatively high selectivity on electrocatalytic carbon dioxide reduction products.
Owner:JIANGXI UNIV OF SCI & TECH +1

Method for preparing polyimide fibers with different color systems based on in-situ coloring

The invention relates to the technical field of polyimide fibers, in particular to a method for preparing polyimide fibers of different color systems based on in-situ coloring, which comprises the following steps: carrying out condensation polymerization on perylene tetracarboxylic dianhydride compounds or perylene diimide, diamine monomers and dianhydride monomers to obtain a polyamide acid solution; adding acetic anhydride and pyridine into the polyamide acid solution for chemical ring-closure reaction to obtain a polyimide solution; and carrying out wet spinning on the obtained polyimide solution to obtain the colored polyimide fiber. The method for preparing the polyimide fibers of different color systems based on in-situ coloring is simple in process and environmentally friendly, and the prepared polyimide fibers of different color systems are high in color fastness and excellent in mechanical property.
Owner:DONGHUA UNIV

Double-state emission fluorescent dye and preparation method thereof

PendingCN120647659AOrganic chemistryNaphthalimide/phthalimide dyesQuantum yieldPtru catalyst
The preparation method comprises the following steps: carrying out reflux reaction on 4-bromo-1, 8-naphthalic anhydride and primary amine in an organic solvent to obtain an intermediate product, and carrying out C-N coupling reaction on the intermediate product, a compound containing a nitrogen secondary amine electron-donating group, alkali and a catalyst in the organic solvent to obtain the double-state emission fluorescent dye. The two-state emission dye is obtained. An amino auxochrome group of a bridge ring structure is modified in a 4-bromine-1, 8-naphthalimide parent, the fluorescence quantum yield of the dye in a polar solvent is improved through the characteristic that nitrogen atom lone pair electrons of the nitrogen-containing bridge ring structure are not easy to overturn, and pi-pi stacking, which is not beneficial to emission, of the dye is inhibited through the large steric hindrance effect of the bridge ring structure; the dye shows bright fluorescence emission in non-polar and polar solvents, also has a very strong fluorescence quantum yield in a solid state, and shows a quantum yield greater than 94% when the dye is dispersed in an EVA (Ethylene-Vinyl Acetate) film.
Owner:SUZHOU UNIV

Cellulose acetate based 1, 8-naphthalimide fluorescent probe for detecting Hg < 2 + > as well as preparation method and application of cellulose acetate based 1, 8-naphthalimide fluorescent probe

The invention discloses a cellulose acetate based 1, 8-naphthalimide fluorescent probe for detecting Hg < 2 + > as well as a preparation method and application of the cellulose acetate based 1, 8-naphthalimide fluorescent probe. The preparation method comprises the following steps: by taking 4-bromo-1, 8-naphthalic anhydride as a raw material, carrying out condensation reaction on the 4-bromo-1, 8-naphthalic anhydride and 4-aminobutyric acid to prepare 4-(4-bromo-1, 8-naphthalic diimide) butyric acid (BNA-B); the BNA-B and piperazine are subjected to a substitution reaction, and a compound PNA-B is prepared; the PNA-B and 4-(bromomethyl) pyridine hydrochloride are subjected to a substitution reaction, and a compound PNA-B is prepared; and the PNA-B and cellulose acetate (CA) are subjected to an esterification reaction, such that the cellulose acetate-based 1, 8-naphthalimide fluorescent probe PNA-CA is prepared. The compound can specifically recognize Hg < 2 + >, after Hg < 2 + > is added into a PNA-CA acetonitrile / PBS buffer solution under 365nm ultraviolet irradiation, the fluorescence color of the solution is changed from colorless to yellow, the response time is 20s, the detection limit reaches 9.3 * 10 <-8 > M, and the probe has a good application prospect.
Owner:NANJING FORESTRY UNIV

A cellulose acetate-based 1,8-naphthalimide fluorescent probe for the detection of hydrazine, its preparation method and application.

This invention discloses a cellulose acetate-based 1,8-naphthalenedimide fluorescent probe for detecting hydrazine, its preparation method, and its application. The invention uses 4-bromo-1,8-naphthalenedimide as a raw material, which undergoes a condensation reaction with 4-aminobutyric acid to obtain 4-(4-bromo-1,8-naphthalenedimide)butyric acid (BNA-B); BNA-B undergoes a coupling reaction with 4-formylphenylboronic acid to obtain 4-(4-(4-formylphenyl)-1,8-naphthalenedimide)butyric acid (FNA-B); compound FNA-B then undergoes an esterification reaction with cellulose acetate (CA) to obtain the cellulose acetate-based 1,8-naphthalenedimide fluorescent probe FNA-B-CA. This compound specifically recognizes hydrazine. Under 365 nm ultraviolet light irradiation, the addition of hydrazine to a DMF / H2O solution of FNA-B-CA changes the fluorescence color of the solution from bright blue to colorless, indicating a detection limit of 8.4 × 10⁻⁶ for hydrazine. ‑8 M has promising applications as a fluorescent probe for the detection of hydrazine.
Owner:NANJING FORESTRY UNIV

Polyglutamic acid granular fertilizer and preparation method thereof

The invention provides a polyglutamic acid granular fertilizer and a preparation method thereof, and the preparation method comprises the following steps: S1, dissolving lignin in an alkaline solution, and heating until the lignin is dissolved; adding epsilon-polylysine fermentation liquor, mixing, heating, adding a formaldehyde solution, and carrying out grafting reaction to obtain epsilon-polylysine grafted lignin; s2, mixing the epsilon-polylysine grafted lignin solution and the gamma-polyglutamic acid solution, adding N-hydroxysuccinimide, standing at a low temperature, adding 1-ethyl-(3-dimethylaminopropyl) carbodiimide hydrochloride, and mixing; carrying out gradient temperature reaction to obtain lignin grafted epsilon-polylysine / gamma-polyglutamic acid hydrogel; and S3, homogenizing the lignin-grafted epsilon-polylysine / gamma-polyglutamic acid hydrogel, carrying out normal-temperature high-pressure airflow crushing, and spraying the crushed hydrogel to the surfaces of particles obtained by granulating a basic material through high-pressure electrostatic spraying, so as to obtain the polyglutamic acid granular fertilizer. The obtained polyglutamic acid granular fertilizer has relatively strong water-retaining and slow-release (releasing water, urea and the like) effects.
Owner:HEILONGJIANG CHENGUANG BIO-ORGANIC FERTILIZER MFG CO LTD

Cellulose acetate 1, 8-naphthalimide fluorescent probe for detecting hydrazine as well as preparation method and application of cellulose acetate 1, 8-naphthalimide fluorescent probe

The invention discloses a cellulose acetate based 1, 8-naphthalimide fluorescent probe for detecting hydrazine as well as a preparation method and application of the cellulose acetate based 1, 8-naphthalimide fluorescent probe. The preparation method comprises the following steps: by taking 4-bromo-1, 8-naphthalic anhydride as a raw material, carrying out condensation reaction on the 4-bromo-1, 8-naphthalic anhydride and 4-aminobutyric acid to prepare 4-(4-bromo-1, 8-naphthalic diimide) butyric acid (BNA-B); the preparation method comprises the following steps: carrying out a coupling reaction on BNA-B and 4-formyl phenylboronic acid to prepare 4-(4-(4-formyl phenyl)-1, 8-naphthalimidoyl) butyric acid (FNA-B); and the compound FNA-B and cellulose acetate (CA) are subjected to an esterification reaction, such that the cellulose acetate-based 1, 8-naphthalimide fluorescent probe FNA-B-CA is prepared. The compound can specifically recognize hydrazine, after hydrazine is added into a DMF / H2O solution of FNA-B-CA under the irradiation of 365nm ultraviolet light, the fluorescence color of the solution is changed from bright blue to colorless, the detection limit of hydrazine reaches 8.4 * 10 <-8 > M, and the compound has a good application prospect as a fluorescent probe for detecting hydrazine.
Owner:NANJING FORESTRY UNIV

Interface modification layer material, perovskite solar cell and preparation method thereof

The invention relates to the technical field of perovskite solar cells, in particular to an interface modification layer material, a perovskite solar cell and a preparation method of the perovskite solar cell. The material of the interface modification layer comprises a sulfonic acid modified aromatic diimide compound. The perovskite solar cell comprises a transparent conductive substrate, a hole transport layer, a perovskite layer, an electron transport layer and an electrode layer, wherein an interface modification layer made of the interface modification layer material is arranged between the perovskite layer and the electron transport layer. The interface modification layer prepared from the sulfonic acid modified aromatic diimide compound is introduced between the perovskite layer and the electron transport layer, so that perovskite surface defect passivation and energy level matching can be realized at the same time, the electron extraction efficiency is remarkably improved, the compound loss is reduced, and the photoelectric conversion rate of the cell is improved.
Owner:CHUZHOU JIETAI NEW ENERGY TECH CO LTD

Gearbox oil and preparation method thereof

The invention belongs to the technical field of gearbox oil preparation, and particularly relates to gearbox oil and a preparation method thereof. The gearbox oil is prepared from the following raw materials: O, O '-diisoamyl dithiophosphate sodium salt, isooctyl acidic phosphate octadecylamine, 4, 4'-methylene bis (2, 2, 6-trimethyl-1, 3-pentanedione)-1, 2, 4-trimethyl-1, 3-pentanedione, 2, 4, 6-trimethyl-1, 3- The lubricating oil is prepared from 2, 6-di-tert-butylphenol), dialkyl dithiocarbamate, triethanolamine borate, methylbenzotriazole, a 2-butyl acrylate homopolymer, a hydrogenated styrene-diene copolymer, boronized polyisobutylene succinimide and the balance of base oil. The base oil is prepared from dipentaerythritol ester, poly-alpha-olefin, palm oil, 1-n-butyl naphthalene and dodecylphenol. According to the gearbox oil disclosed by the invention, the raw materials have a synergistic effect, so that the prepared gearbox oil has very good oxidation stability, corrosion resistance and wear resistance.
Owner:SHANDONG LONGHAI PETROCHEM CO LTD

Organic semiconductor heterojunction photoelectric adaptive memristor and preparation method thereof

The invention discloses an organic semiconductor heterojunction photoelectric self-adaptive memristor and a preparation method thereof, and belongs to the field of neuromorphic devices, and the memristor sequentially comprises a substrate, a bottom electrode, a lower active layer, an upper active layer and a top electrode from bottom to top; the upper active layer is prepared from an organic material zinc phthalocyanine, and the lower active layer is prepared from an organic material N, N-tricosylperylene-3, 4, 9, 10-tetracarboxylic diimide. The memristor prepared by the invention realizes simulation of desensitization behavior and retina light adaptation function, and adaptivity modes are switched according to a stimulation type time-sharing trigger mechanism to support multi-mode perception and adaptive information processing in a dynamic environment, so that the development of a neuromorphic device for simulating the adaptivity function of a biological sensory system is promoted.
Owner:NANJING UNIV OF POSTS & TELECOMM

Process for preparing a carbodiimide using a specific catalytic compound comprising a metal m and oxygen, wherein the metal m is one or more of mo and w

A process for preparing a carbodiimide includes (i) providing a mixture including one or more isocyanates and a catalytic compound, and (ii) subjecting the mixture obtained in (i) to reaction conditions in a gas atmosphere. The catalytic compound includes a metal and oxygen, wherein the metal is one or more of Mo and W. and at least a portion of the metal in the catalytic compound is bound to oxygen via one or more single bonds, via one or more double bonds, or via one or more single and double bonds. The reaction conditions in the gas atmosphere take place at a temperature in a range of from 45 to 220° C.
Owner:BASF SE

A polymer with alternating perylene diimide and naphthalene diimide, and its preparation method and application

The present invention belongs to the technical field of semiconductor materials, and discloses a polymer with alternating arrangement of perylene diimide and naphthalene diimide, and its preparation method and application. The preparation method of the polymer includes the following steps: mixing naphthalic anhydride, alkanolamine and an organic solvent, and reacting to obtain naphthalene diimide-diol; mixing naphthalene diimide-diol, bromoacetic acid, 4-dimethylaminopyridine, 1-(3-dimethylaminopropyl)-3-ethylcarbodiimide hydrochloride and an organic solvent, and reacting to obtain naphthalene diimide-dibromide; mixing naphthalene diimide-dibromide, perylene diimide-diamine and an organic solvent, and reacting to obtain the polymer. The present invention takes naphthalene diimide and perylene diimide as the core structures, and through design and synthesis, obtains a polymer with good water and alcohol solubility. This polymer can integrate the physical and chemical properties of the above two structural units, providing a guarantee for its application as an electron transport layer material in solar cells.
Owner:ENERGY RES INST OF JIANGXI ACAD OF SCI

Anticoagulant biomaterials for blood purification and methods of making and using the same

ActiveCN117679978BMorpholineEthyl group
The application discloses an anticoagulant biomaterial for blood purification and a preparation method and application thereof, and comprises the following steps: providing an amphiphilic copolymer P(AA-MMA); blending polyethersulfone, P(AA-MMA) and a solvent, stirring at a set temperature to obtain a casting solution, and preparing a blending membrane from the casting solution; soaking the blending membrane in a 2-morpholine-4-yl ethanesulfonic acid buffer solution containing argatroban, 1-ethyl-(3-dimethylaminopropyl) carbonyl diimide and hydroxy succinimide, and reacting at room temperature to obtain an argatroban grafted blending membrane, namely the anticoagulant biomaterial. The method improves the hydrophilicity of the membrane, reduces the albumin adsorption of the membrane, reduces the adhesion of platelets on the membrane, prolongs the coagulation time APTT, PT and TT of the membrane, and is better in biocompatibility and enhanced in anticoagulation performance.
Owner:XIANGYA HOSPITAL CENT SOUTH UNIV

Wavelength selective photoresponse strontium-based metal organic framework eutectic material as well as preparation method and application thereof

PendingCN120535770ACrystal systemElectron donor
The invention discloses a wavelength selective photoresponse strontium-based metal organic framework eutectic material as well as a preparation method and application thereof. A metal node of the material is strontium ions, N, N '-bis (5-isophthalic acid) naphthalimide is used as a ligand, anthracene and a derivative thereof are used as objects, N, N-dimethylformamide is used as a solvent, and the material is obtained through solvothermal reaction. The material is composed of an electron donor (D) and an electron acceptor (A), and is a strontium-based MOF eutectic with an infinitely extended pi stacked A-D-D-A configuration. The MOF eutectic material has lattice characteristics of a tetragonal crystal system, a space group is I 41 / a, and cell parameters are a = b = 28.42240 (10), c = 13.71600 (10), and alpha = beta = gamma = 90 degrees. Sr-NDI at An has unique wavelength selective photoresponse property: ultraviolet light triggers [4 + 4] dimerization of an object anthracene, red light excites [4 + 2] reaction of anthracene and singlet oxygen, and near-infrared light induces generation of free radicals.
Owner:NANKAI UNIV

Siloxane d-a-d type perylene imide small molecule electron transport layer and preparation method thereof

The application discloses a siloxane D-A-D type perylene diimide small-molecule electronic transport layer and a preparation method thereof. Bromine perylene diimide is reacted with a primary amine containing a siloxane end group, and then is coupled with triphenylamine through a Suzuki coupling reaction to synthesize a small-molecule conjugated electrolyte. The siloxane D-A-D type perylene diimide small-molecule electronic transport layer has the following beneficial effects: first, the secondary amine in the side chain can form hydrogen bonds with F and H in the active layer, improve the interface compatibility, and improve the contact with the active layer; second, the D-A-D structure can realize intramolecular charge transfer, and excellent electron mobility can be exhibited; third, a good n-type self-doping is obtained, the work function of a high-stability metal Ag can be reduced, an ohmic contact is formed, and therefore the photovoltaic performance of a device is significantly improved; fourth, the stability can be improved due to the hydrophobicity of the siloxane; and finally, triphenylamine has a special non-planar molecular structure, and can inhibit excessive aggregation of the material.
Owner:NANCHANG HANGKONG UNIVERSITY

Water stable thermoplastic composition

The invention relates to a thermoplastic composition comprising, based on the weight of the composition, (A) 40 to 70% by weight of an aromatic polycarbonate, (B) 20 to 40% by weight of a polyester, (C) 1 to 15% by weight of an impact modifier, (D) 0.1 to 10% by weight of a hydrolysis stabilizer composition comprising at least one compound containing a diimide function, (E) 0 to 5% by weight of further components, the total amount of (A) to (E) is 100% by weight, and wherein the composition is selected to have a combination of at least 50 kJ / m2 of an initial notched Izod impact, determined according to ISO 180-1A at a temperature of 23 DEG C, at least 70% of a notched Izod impact retention, determined according to the method described in the specification, a heat distortion temperature of at least 90 DEG C as determined according to ISO 75A lay-flat mode under a load of 1.8 MPa.
Owner:SABIC GLOBAL TECHNOLOGIES BV

Preparation method of buspirone hydrochloride

The invention belongs to the technical field of medicine synthesis processes, and particularly relates to a preparation method of high-yield and high-purity buspirone hydrochloride. According to the method, 8-(2-pyrimidinyl)-8-aza-5-5-azonium spiro [4.5] decane hydrobromide (pyrimidino piperazine quaternary ammonium salt for short) and 3, 3-tetramethylene glutarimide are taken as raw materials, a mixed solvent of methylbenzene and n-amyl alcohol and / or n-hexanol is taken as a solvent, buspirone can be generated in the presence of sodium carbonate without adding a phase transfer catalyst, and buspirone can be obtained through acid adjustment and extraction. After toluene reverse phase impurity removal, a water phase is adjusted to be alkaline, an ethanol solution of hydrogen chloride is added after toluene extraction, and buspirone hydrochloride solid is directly separated out. The preparation process has a very good cleaning effect on impurities, and the obtained buspirone hydrochloride is high in purity, high in process yield, good in atom economy and low in output of three wastes.
Owner:YANGTAI PHARMA SHANDONG

Perylene diimide derivative-based COF material for photocatalysis of OER

The invention provides a perylene diimide derivative based covalent organic framework material and a covalent organic framework compound which can be used for photocatalysis. The synthesis method of the compound is simple and green, raw materials are cheap and easy to obtain, the whole synthesis process is simple, and the compound is expected to be put into industrial production. In addition, the compound has excellent photocatalytic performance.
Owner:FUJIAN INST OF RES ON THE STRUCTURE OF MATTER CHINESE ACAD OF SCI

Gasoline engine lubricating oil composition

The present invention provides a gasoline engine lubricating oil composition comprising the following components: (A) an organophosphorus compound, accounting for 0.05% to 10% of the total mass of the composition; (B) an alkyldiphenylamine, accounting for 0.05% to 5% of the total mass of the composition; (C) polyisobutylene succinimide, accounting for 2% to 30% of the total mass of the composition; (D) a sulfonate and / or a sulfurized alkylphenol, accounting for 0.2% to 10% of the total mass of the composition; (E) a zinc dialkyl dithiophosphate, accounting for 0.2% to 10% of the total mass of the composition; (F) an organomolybdenum, accounting for 0.05% to 5% of the total mass of the composition; (G) an ethylene-propylene copolymer, accounting for 2% to 30% of the total mass of the composition; and (H) a major amount of a lubricating oil base oil. The structure of the organophosphorus compound is described in the specification. The gasoline engine lubricating oil composition of the present invention has excellent anti-wear, friction-reducing, antioxidant, and detergency properties, and can inhibit the formation of deposits in turbochargers.
Owner:CHINA PETROLEUM & CHEMICAL CORP +1

Hair coloring composition comprising at least one (poly)carbodiimide compound and at least one compound comprising at least one hydroxy function

The present invention relates to a hair coloring composition, particularly for hair, comprising: - at least one (poly)carbodiimide compound; - at least 4% by weight of at least one compound having at least one hydroxyl group, relative to the total weight of the composition; and - optionally at least one coloring agent selected from pigments, direct dyes, and mixtures thereof. The present invention also relates to a method for coloring hair keratin fibers and a device for coloring hair keratin fibers.
Owner:LOREAL SA

Protein transport material

This protein transport material contains a polycyclic compound having, in the main skeleton, one or two structures represented by general formula (1) (In the formula, Ar1 represents a condensed aromatic ring optionally having a substituent with the proviso that when R is a group having a primary, secondary or tertiary amino group or R is a group having a nitrogen cation-containing group, Ar1 is a condensed aromatic ring that is other than a perylene diimide ring and optionally has a substituent; R represents an anionic group or a cationic group; n represents an integer of 1 or more; and when n is an integer of 2 or more, the n number of Rs may be the same or different.) or general formula (5) (In the formula, R17 and R18 are the same or different and each represent an aryl group optionally having a substituent.). The protein transport material uses precisely synthesizable small molecules, has excellent protein transport efficiency, and is capable of transporting a protein into cells.
Owner:NAT UNIV CORP TOKAI NAT HIGHER EDUCATION & RES SYST

Aromatic dipeptide functionalized mercapto compounds, methods of making and using the same

The application relates to the technical field of compound synthesis, and discloses an aromatic dipeptide functionalized mercapto compound, 3,5-di(triphenylmethylthio)benzoic acid is obtained by adding 3,5-di(methylmercapto)benzoic acid and pyridine into a solution of chloromethyl triphenylphosphonium, purifying after sufficient reaction; then the 3,5-di(triphenylmethylthio)benzoic acid is mixed with N-hydroxysuccinimide and dissolved in an organic solvent, EDC.HCl is added, purifying after sufficient reaction; then 2,5-dioxopyrrolidin-1-yl 3,5-bis(triphenylmethylthiomethyl)benzoate is obtained; then phenylalanine-tryptophan and triethylamine are added, purifying after sufficient reaction; then (3,5-bis(triphenylmethylthiomethyl)benzoyl)tryptophylphenylalanine is obtained; then trifluoroacetic acid and triethylsilane are added, purifying after sufficient reaction; and finally the aromatic dipeptide functionalized mercapto compound is obtained. The aromatic dipeptide functionalized mercapto compound can quickly and effectively identify sodium and potassium ions, and has relatively low detection limit and relatively loose detection condition.
Owner:HUANENG WUHAN POWER GENERATION CO LTD

Antistatic semiconductor UV (ultraviolet) visbreaking layer and protective film and preparation method of antistatic semiconductor UV visbreaking layer and protective film

The invention relates to the technical field of polyurethane adhesives, and discloses an antistatic semiconductor UV visbreaking adhesive layer, a protective film and a preparation method of the antistatic semiconductor UV visbreaking adhesive layer, and the antistatic semiconductor UV visbreaking adhesive layer is prepared by adding a perylene diimide modified carbon nanotube solution, a reactive diluent and a photoinitiator into a UV polyurethane solution. UV-polymerizable alkenyl is introduced into a polyurethane molecular chain, so that the peel strength is reduced after photocuring, and the viscosity-reducing and easy-to-peel effects are shown. A high-temperature-resistant perylene diimide condensed ring is introduced into a polyurethane main chain, so that the high-temperature resistance of an adhesive layer is improved. The carbon nano tube is subjected to non-covalent surface modification, so that the interfacial force with a polyurethane molecular chain is improved, the dispersity of the carbon nano tube in the viscosity-reducing glue becomes good, the carbon nano tube can be promoted to form a continuous conductive path, and the antistatic performance is improved. The viscosity-reducing adhesive has good practical application in the aspects of semiconductor chip wafer processing, high-temperature-resistant adhesives, antistatic adhesives and the like.
Owner:东莞市华达新材料有限公司

A compound and uses thereof

ActiveCN117126133BImidePyridazine
This invention belongs to the field of pharmaceutical chemistry technology, and discloses a compound and its uses. Specifically, it relates to a CRBN small molecule ligand compound based on a pyridazine-glutarimide core skeleton (PDG), its composition, and its application. It also relates to a protein degrading agent based on a CRBN small molecule ligand compound based on a pyridazine-glutarimide core skeleton (PDG) and its application. Specifically, the CRBN small molecule ligand compound is shown in (Ⅰ): wherein R... 1 and R 2 Selected from one or more of the following: fused rings attached to a pyridazine core, H, alkyl, OR, F, CN, CF3, NR2, Ph, 4-Py; Y selected from one or more of CH, CD, CF, and N; R 3 Selected from one or more of OR, NR2, CHR2, and C≡CR; R 4 Selected from H or alkyl.
Owner:OCEAN UNIV OF CHINA

Methane derivative-containing compound and organic electroluminescent device thereof

The invention belongs to the technical field of organic electroluminescent materials, and particularly relates to a compound containing a methane derivative and an organic electroluminescent device.The central methane derivative of the series of compounds has certain flexibility, molecules are matched more tightly in the evaporation process, and the film-forming property of the material is good; meanwhile, substituent groups such as electron-withdrawing CF3, diimide and trimethylsilane are introduced into outer side groups of the series of compounds, so that the action of an external electric field on electrons can be inhibited, the electron polarizability is reduced, and the low refractive index requirement of the material is met.
Owner:JILIN YUANHE ELECTRONICS MATERIALS CO LTD

Preparation method of lithium-enriched material precursor

The invention belongs to the field of inorganic enrichment materials, and discloses a preparation method of a lithium enrichment material precursor, which comprises the following steps: mixing a lithium-containing solution with an AlCl3 solution, adding an alkaline reagent for reaction to generate a chloride of lithium-aluminum double hydroxide, cleaning the chloride of lithium-aluminum double hydroxide, and carrying out preliminary crushing to obtain a lithium-aluminum double hydroxide precursor; and carrying out ball milling on the crushed product to obtain precursor powder, carrying out heat treatment on the precursor powder, adding a naphthalimide solution, and removing the solvent to obtain the lithium-enriched material precursor. According to the preparation method of the lithium-enriched material precursor, the precursor with better adhesion with the resin matrix can be manufactured, so that the adsorbability and the mechanical property of the final product lithium-enriched material are integrally improved.
Owner:SHENZHEN JUNENG YONGTUO LITHIUM TECHNOLOGY DEVELOPMENT CO LTD

Polycarbodiimide compound, aqueous resin composition and food packaging container

Provided are a polycarbodiimide compound that enables an aqueous resin composition capable of forming a coating (layer) having water resistance and adhesion that can withstand use for food packaging to be obtained, an aqueous resin composition containing the polycarbodiimide compound, and a food packaging having a layer formed of the aqueous resin composition. A polycarbodiimide compound (A) represented by formula (1) below,wherein R1 represents a residue obtained by removing a functional group capable of reacting with isocyanate from a hydrophilic compound having the functional group capable of reacting with isocyanate, R2 represents a divalent residue obtained by removing an isocyanate group from an aliphatic diisocyanate compound, and R3 represents a divalent residue obtained by removing a hydroxyl group from a glycol compound having 2 or 3 carbon atoms; X represents a group that is formed by reaction between the hydrophilic compound and the aliphatic diisocyanate compound; n1 represents a number of 1 to 10, n2 represents a number of 1 to 10, and p represents a number of 2 to 4; and a plurality of R1 and R2 each may be the same or different.
Owner:NISSHINBO CHEM

Construction of donor-acceptor type perylene diimide-based porous conjugated polymer probes and methods for detecting methamphetamine and amphetamine solutions

PendingCN122325723AImideElectron donor
This invention provides a method for constructing a donor-acceptor type perylene diimide-based porous conjugated polymer probe and detecting methamphetamine and amphetamine solutions. The method synthesizes donor-acceptor type perylene diimide-based porous conjugated polymer probes with different topologies by combining an electron acceptor perylene diimide derivative and an electron donor aggregation-induced emission fluorophore via a succinate coupling reaction. When used for the detection of methamphetamine and amphetamine, this system exhibits a clear ratiometric fluorescence response, with the fluorescence color gradually changing from yellow-green to orange and orange-red, demonstrating a significant ratiometric fluorescence response. It features fast response speed, high detection sensitivity, good selectivity, and no interference from other common structurally and property-similar substances, enabling the differentiation and identification of methamphetamine and amphetamine.
Owner:XINJIANG TECH INST OF PHYSICS & CHEM CHINESE ACAD OF SCI

Process for preparing water-stable thermoplastic composition

The present invention relates to a process for the preparation of a thermoplastic composition comprising an aromatic polycarbonate, a polyester, a hydrolysis stabilizer composition, optionally an impact modifier and optionally further components, comprising the steps of: a) combining the polyester with the hydrolysis stabilizer composition in a first melt mixing device to form a stabilized polyester, b) combining the stabilized polyester with an aromatic polycarbonate and optionally an impact modifier in a second melt mixing device, wherein the hydrolytic stabilizer composition comprises at least one compound containing diimide and / or epoxy functional groups.
Owner:SABIC GLOBAL TECHNOLOGIES BV