The invention relates to a conjugate PI bridge connected
furan based n-type conjugated
polymer and an application thereof in organic photoelectric devices. The conjugated
polymer consists of two parts, i.e., naphthalimide and a conjugate PI bridge connected
furan structure. The conjugated
polymer has a relatively wide absorption spectrum, a relatively great absorption coefficient and relatively
high electron mobility and can be applied to efficient organic solar cells as an efficient
electron acceptor. According to the conjugate PI bridge connected
furan based n-type conjugated polymer and theapplication thereof in the organic photoelectric devices, the D-A copolymerized n-
semiconductor conjugated polymer is designed, thus, the absorption coefficient of the polymer can be greatly increased, the absorption spectrum is widened, the
photocurrent of
cell devices and the efficiency of the
cell devices can be greatly improved; and the novel n-type conjugated polymer can achieve the equilibrium of short-circuit current, open-circuit
voltage and packing factor as the
electron acceptor, full-polymer solar cells with the
energy conversion efficiency exceeding 10% are prepared, and the performance of the full-polymer solar cells is far superior to that of cells based on the existing acceptors.