The invention relates to a photovoltaic
cell piece and a preparation method, the preparation method comprises the steps that a laminated structure is formed on a
silicon substrate, the laminated structure comprises a first tunneling layer, a second tunneling layer, a first
doping layer, a third tunneling layer and a second
doping layer which are arranged in a laminated mode, the first tunneling layer is adjacent to the
silicon substrate, and the second tunneling layer is adjacent to the third tunneling layer; a
mask layer is formed on the side, away from the third tunneling layer, of the second
doping layer, the part, located in the non-metallization area, of the
mask layer is removed through
laser to form a patterned
mask layer, and at least part, located in the non-metallization area, of the laminated structure is removed through
laser to form a patterned laminated structure, and removing the patterned
mask layer by using an acid solution, and depositing a
passivation layer on the patterned laminated structure to form a
metal electrode in
ohmic contact with a doping layer included in the patterned laminated structure. The photovoltaic
cell prepared according to the preparation method provided by the invention can have relatively high
photoelectric conversion efficiency and
fill factor.