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1200 results about "Perovskite solar cell" patented technology

A perovskite solar cell (PSC) is a type of solar cell which includes a perovskite structured compound, most commonly a hybrid organic-inorganic lead or tin halide-based material, as the light-harvesting active layer. Perovskite materials, such as methylammonium lead halides and all-inorganic cesium lead halide, are cheap to produce and simple to manufacture.

Organic and inorganic hybrid perovskite-based solar cell and method for manufacturing same

The invention relates to an organic and inorganic hybrid perovskite-based solar cell and a method for manufacturing the same. The organic and inorganic hybrid perovskite-based solar cell comprises a substrate, a transparent electrode, an electron transport layer, an ultrathin orientation layer, a perovskite light absorption layer, a hole transport layer and a counter electrode. The transparent electrode, the electron transport layer, the ultrathin orientation layer, the perovskite light absorption layer, the hole transport layer and the counter electrode are sequentially stacked on the substrate. The method includes modifying micro-nano structures on the surfaces of the electron transport layer or the hole transport layer to form the ultrathin orientation layer before the perovskite light absorption layer is manufactured by the aid of a liquid phase process. The organic and inorganic hybrid perovskite-based solar cell and the method have the advantages that orientated growth of crystals of perovskite is controlled under large-ring structural effects of molecules in the ultrathin orientation layer, accordingly, the crystallization regularity can be improved, and internal defects can be reduced; the diffusion lengths of current carriers inside the perovskite light absorption layer can be effectively increased, accordingly, recombination of electron-hole pairs on the inside and interfaces of the perovskite light absorption layer can be prevented, and the photoelectric conversion efficiency and the stability of the cell can be obviously improved; the crystallization quality of the perovskite light absorption layer cannot be easily affected by film forming conditions under the orientation mold plate effects of the ultrathin orientation layer, accordingly, the device manufacturing repeatability can be improved, and the low-temperature solution method is applicable to industrially producing large-area perovskite solar cells.
Owner:CHINA LUCKY FILM CORP

Perovskite solar cell and preparation method thereof

The invention belongs to the field of a solar cell, and discloses a perovskite solar cell. The perovskite solar cell sequentially comprises a transparent conductive substrate, an electron transmission layer, an interface modification layer, a modified perovskite active layer, a hole transmission layer and a positive electrode, wherein the electron transmission layer is a nanometer TiO2 particle layer, and the interface modification layer is a fullerene derivative layer. A sol-gel method is employed, high-crystallization TiO2 nanoparticles are synthesized by taking titanium tetrachloride is used as a precursor, the TiO2 nanoparticles are applied to the perovskite solar cell by employing a low-temperature annealing process, a fullerene derivative is directly spin-coated on a surface of the obtained nanometer TiO2 particle layer for modification, the defects in TiO2 and perovskite are passivated, a novel perovskite synthesis path is employed, the obtained perovskite solar cell has high efficiency and does not have hysteresis effect under a low-temperature preparation process, and the device can be used for stable transmission; and moreover, the related preparation method is simple, is low in energy consumption and is suitable for promotion and application.
Owner:WUHAN UNIV OF TECH

Perovskite solar cell with interface modification layers and preparation method of perovskite solar cell

The invention relates to a perovskite solar cell with interface modification layers. The cross-sectional structure of the perovskite solar cell includes a transparent conductive substrate, a first transmission layer, a perovskite active layer, a second transmission layer and a back electrode; at least one first interface modification layer is disposed between the perovskite active layer and the first transmission layer; and no or at least one second interface modification layer is disposed between the perovskite active layer and the second transmission layer. The invention also discloses a preparation method of the perovskite solar cell. According to the method, the interface modification layers are additionally arranged between the perovskite active layer and transmission layers of a perovskite solar cell, so that the perovskite solar cell with the interface modification layers can be prepared; the surfaces of the transmission layers are passivated; the crystal structure of the perovskite is optimized; ion migration in the perovskite active layer is suppressed to a certain extent; and therefore, the photoelectric conversion efficiency and long-term stability of the perovskite cellare improved.
Owner:HANGZHOU MICROQUANTA SEMICON CO LTD

Preparation method for cesium lead bromide inorganic perovskite thin film and photovoltaic device based on cesium lead bromide inorganic perovskite thin film

ActiveCN107564978ASolve the preparation of CsPbBr <sub>3</sub> many disadvantages ofImprove film qualityFinal product manufacturePhotovoltaic energy generationSolubilityPerovskite solar cell
The invention discloses a preparation method for a cesium lead bromide inorganic perovskite thin film and a photovoltaic device based on the cesium lead bromide inorganic perovskite thin film. An unstable yellow oblique-phase CsPbI3 thin film is prepared by employing a one-step solution method and then is converted to a stable black cubic-phase CsPbBr3 thin film by employing a Br2 steam thermal injection gas-phase deposition method. Gas-phase exchange reaction of halide ions is utilized, I<-> in CsPbI3 is substituted by Br<-> with smaller radius, the purpose of lattice shrinkage, phase changesuppression and stability improvement are achieved, the bottleneck problem that Br solubility of a traditional one-step solution method is limited can be effectively solved, and the problems that thethin film is easy to fall during immersion of a two-step solution method also can be prevented; and meanwhile, the prepared CsPbBr3 thin film is also used as a light absorption layer to prepare an FTO/c-TiO2/m-TiO2/CsPbBr3/C perovskite solar cell with an all-inorganic structure, the photoelectric efficiency of a battery in initial batch reaches 3.23%, and the battery shows favorable long-term stability.
Owner:HEFEI UNIV OF TECH

Method for manufacturing high-efficiency perovskite type solar cell through large crystal grain forming

The invention discloses a method for manufacturing a high-efficiency perovskite type solar cell through large crystal grain forming. The method for manufacturing the high-efficiency perovskite type solar cell through large crystal grain forming at least sequentially comprises the steps that hole (or electron) transport layer materials, perovskite type materials, electron (or hole) transport layer materials and electrode materials are grown on a conducting substrate. The performance of the cell can be improved greatly by improving crystal grain forming of the perovskite type materials. During manufacturing, two kinds of precursor materials need to be dissolved in a solvent, so that a yellow mixing solution is obtained, the temperature of the yellow solution needs to be kept between 65 DEG C and 80 DEG C all the time before spin coating, the temperature of the substrate is kept between 170 DEG C and 200 DEG C, spin coating needs to be conducted at the spinning speed of 3500-5000 rpm for about one to three seconds instantly after the yellow solution is dripped on the substrate, then rapid cooling is conducted for about three to five seconds till the temperature reaches 50 DEG C, then natural cooling is conducted till the temperature reaches an indoor temperature, in this way, a yellow film can be changed into a dark brown film, and large crystal grain forming can be observed at the same time.
Owner:朱熹

Method for preparing perovskite thin film in perovskite solar cell via solution air extraction and ventilation method

The invention provides a method for preparing a perovskite thin film in a perovskite solar cell via a solution air extraction and ventilation method. The method comprises the following steps: a perovskite liquid film coated on a surface of a base body is subjected to air extracting and drying operation in an environment where the partial pressure of the solvent is lower than 99% saturated vapor pressure of the solvent at current temperature; during drying processes or after the perovskite liquid film is completely dries, a gas which does not react chemically with a perovskite is let in, and therefore a process that the solvent is evaporated or solvent molecules leave the environment can be accelerated via solvent molecule concentration dilution. Heterogeneous nucleation and growth of the surface of the base body can be realized via control over drying process conditions, and therefore a uniform and compact perovskite thin film can be formed. The method can be used for accelerating liquid film drying processes, making solvent steam molecules leave a surface of the thin film quickly, and obtaining the uniform-structured and compact perovskite thin film; thus current leakage caused by perovskite thin film loopholes can be prevented and the method can help make high-efficiency solar cells; the method is advantaged by simple operation, easy-to-implement property, low cost, high repetition accuracy, convenience for industrialization and the like.
Owner:杨冠军

Flexile and large-area perovskite solar cell module and preparation method thereof

The invention relates to a flexile and large-area perovskite solar cell module and a preparation method thereof. The perovskite solar cell module comprises a metal back reflection layer, an electron transmission layer, a perovskite absorption layer, a cavity transmission layer, a transparent conductive front electrode, transparent packaging glue and a flexible and transparent plastic cover plate, which are stacked on a flexible substrate in sequence; light enters from a direction of the flexible and transparent plastic cover plate; the metal back reflection layer, the electron transmission layer, the perovskite absorption layer, the cavity transmission layer and the transparent conductive front electrode are separated by pre-set separation grooves to form a plurality of sub-cells which are connected in series. The flexile and large-area perovskite solar cell module has no requirements on permeability and conductivity of the substrate and the common and cheap flexible substrate can be adopted, so that the cost is remarkably reduced; the preparation method is simple in process, the rate of finished products is high and large-scale production is easy to realize; on the basis of not influencing performances of a perovskite solar cell, adverse effects on the perovskite solar cell, caused by external factors including water vapor, chemical corrosion, external stress and the like, can be avoided, and the reliability of the cell is improved.
Owner:TIANJIN POLYTECHNIC UNIV

Mesoscopic perovskite photovoltaic cell with tin-oxide electron-transporting layer and preparation method thereof

The invention relates to a perovskite photovoltaic cell with bilayer nanometer mesoporous electron-transporting layer and preparation method thereof. The cell comprises a conducting substrate, an electron-transporting layer with double-layer structure, a perovskite light absorption layer, a hole-transporting layer and metal electrodes. The perovskite photovoltaic cell with bilayer nanometer mesoporous electron-transporting layer has the advantages that the SnO2 with one step method low-temperature growth, is used as the electron-transporting layer in the photovoltaic cell, replaces the TiO2 electron-transporting layer with two steps method high temperature sintering, and the preparation process is simplified. The mesoporous perovskite photovoltaic cell prepared with one step low-temperature growth method obtains 13.82% of highlight electricity transfer efficiency, and reduces the manufacturing cost effectively at the same time. Compared with a planer construction, the mesoporous structure used in the perovskite photovoltaic cell is liable for the adherence of the perovskite light absorption material. SnO2 conducts a smaller dissimilation on the perovskite light absorption layer than the TiO2 does, the performance and stability of the cell are improved in this way. The perovskite photovoltaic cell with bilayer nanometer mesoporous electron-transporting layer and preparation method thereof plays a great promoting role in the development and popularization on the flexible solar cell, and further promotes the industrialized application on the perovskite solar cell.
Owner:WUHAN UNIV

Novel method for improving uniformity and crystallinity of organic-inorganic perovskite thin film

The invention relates to a novel process for preparing an organic-inorganic perovskite thin film through adopting an experimental scheme in which two kinds of metal compounds are adopted as precursors. With the novel process adopted, an efficient solar battery device with a planar structure can be prepared. According to the novel process, the two kinds of metal compound precursors are compounded, and therefore, a pinhole defect of the perovskite thin film can be effectively avoided, and compound of electrons and holes can be alleviated, and short-circuiting risks of the perovskite thin film can be decreased. The novel process of the invention belongs to the photoelectric material field and is characterized in that the two kinds of metal compounds are selected as a source of metal ions in a perovskite material, wherein the general formula of the organic-inorganic perovskite material is ABX3, wherein A is CH3NH3 or NH2-CH=NH2, B is Pb or Sn, and X is I or Br. With the preparation method adopted, the thickness of the perovskite thin film is uniform, and the crystallinity of the perovskite thin film is high, the perovskite thin film can have high electron and hole transport ability. The preparation method is suitable for large-area preparation of organic-inorganic perovskite solar battery devices with planar structures.
Owner:QINGDAO INST OF BIOENERGY & BIOPROCESS TECH CHINESE ACADEMY OF SCI
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