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Lithium ion battery silicon-based composite anode material, preparation method thereof and battery

The invention relates to a lithium ion battery silicon-based composite anode material, a preparation method of the lithium ion battery silicon-based composite anode material, and a battery. The lithium ion battery silicon-based composite anode material adopts an embedded composite core-shell structure, a core has a structure formed by embedding nano silicon particles into a gap of an inner layer of hollowed graphite, and a shell is made from a non-graphite carbon material. According to the silicon-based composite anode material, mechanical grinding, mechanical fusing, isotropic compression processing and carbon coating technologies are combined, so that the nano silicon particles can be successfully embedded into the inner layer of the graphite and the surfaces of graphite particles are uniformly coated; the high-performance silicon-based composite anode material is obtained and is excellent in cycle performance (the 300-times cycle capacity retention ratio is more than 90%) and high in first efficiency (more than 90%); in addition, the silicon-based composite anode material is high in specific energy and compaction density, and can meet the requirements of a high-power density lithium ion battery; the preparation process is simple, the raw material cost is low, and the environment is protected.
Owner:BTR NEW MATERIAL GRP CO LTD

Live-working robot of transformer substation

ActiveCN103056866AGuaranteed isolationImprove the safety performance of live workingManipulatorTransformerHydraulic pump
The invention relates to a live-working robot of a transformer substation. All signals of a control system are wirelessly transmitted, so that the operational safety performance is improved for operation personnel. The live-working robot comprises a work machine and a remote-control command vehicle; the work machine mainly comprises a power system, an actuating mechanism, a hydraulic control system and an operating system, the actuating mechanism mainly comprises a traveling mechanism, a rotating platform, a lifting platform and a hydraulic mechanical arm with six degrees of freedom, the lifting platform comprises a plurality of insulating arms, the rotating platform is mounted on the traveling mechanism, the lifting platform is connected with the rotating platform, and the hydraulic mechanical arm with six degrees of freedom is connected with the lifting platform; and the hydraulic control system comprises a hydraulic pump and is connected with the power system, and the hydraulic pump is further connected with an oil tank on the traveling mechanism and is respectively connected with a lower electromagnetic reversing valve bank A, a central crossover coupling, an upper electromagnetic reversing valve bank B, a mechanical arm hydraulic servo valve bank C, driving cylinders of the various insulating arms and a rotating motor by a distributing valve.
Owner:STATE GRID INTELLIGENCE TECH CO LTD

Silicon-carbon composite material, lithium ion battery, and preparation method and application of silicon-carbon composite material

The invention discloses a silicon-carbon composite material, a lithium ion battery, and a preparation method and application of the silicon-carbon composite material. The preparation method of the silicon-carbon composite material comprises the steps: uniformly mixing silicon powder and silicon monoxide powder, then mixing with a solution containing an organic carbon source dispersant, and performing wet-process ball milling to obtain a slurry; uniformly mixing the slurry, graphite and a conductive agent, and performing spray drying to obtain spherical-like particles, wherein graphite is synthetic graphite and/or intermediate-phase graphite; mixing the spherical-like particles and asphalt, performing cladding processing under the inert atmosphere to obtain a cladded material; and then performing carbonizing processing to obtain the silicon-carbon composite material, wherein silicon powder, silicon monoxide powder, graphite and asphalt respectively accounts for 5-15%, 3-10%, 45-75% and 5-40% by weight of the sum of the above materials, and the organic carbon source dispersant and the conductive agent both accounts for 0.1-2% by weight of the sum of silicon powder, silicon monoxide powder and graphite. The silicon-carbon composite material has relatively good cycle performance, and can be directly used as a cathode material of the lithium ion battery. The preparation method is simple in technology, low in cost and applicable to industrial production.
Owner:SHANGHAI SHANSHAN TECH CO LTD

Electrolyte solution for high-capacity lithium-ion battery, preparation method and lithium-ion battery

The invention discloses an electrolyte solution for a high-capacity lithium-ion battery. The electrolyte solution includes non-aqueous solvent, lithium hexafluorophosphate, negative electrode film forming additive, positive electrode surface activity inhibiting additive and transition metal ion complexant; the negative electrode film forming additive includes organic ester negative electrode film forming additive of 1 to 10wt% of the total electrolyte solution and inorganic lithium salt negative electrode film forming additive of 0.5 to 2wt% of the total electrolyte solution; the positive electrode surface activity inhibiting additive includes fluorinated ether additive of 1 to 5wt% of the total electrolyte solution and nitrile additive of 0.1 to 5wt% of the total electrolyte solution; the transition metal ion complexant is of 0.1 to 1.0wt% of the total electrolyte solution. The electrolyte solution is adaptive to the high-capacity lithium-ion battery and is capable of optimizing the circulating performance and high-temperature storage performance of the lithium-ion battery. The invention further provides a preparation method of the electrolyte solution and the high-capacity lithium-ion battery adopting the electrolyte solution.
Owner:GUANGZHOU TINCI MATERIALS TECH

Low-temperature refrigeration air conditioner and wind speed control method thereof

The invention discloses a low-temperature refrigeration air conditioner and a wind speed control method thereof. The low-temperature refrigeration air conditioner comprises a wind speed control deviceof an outdoor unit fan. The wind speed fan control device comprises a temperature detection unit, a fan control unit and the outdoor unit fan, wherein the temperature detection unit detects the temperature of a condenser of the air conditioner so as to obtain a simulated condensation temperature; the fan control unit generates control signals of the rotation speed change and on-off of the fan according to the simulated condensation temperature; and the outdoor unit fan responds to the control signals of the fan control unit and generates corresponding outdoor unit wind speed. The method for controlling the wind speed of the low-temperature refrigeration air conditioner controls the rotation speed change and on-off of the fan by simulating the condensation temperature of the condenser so as to provide different wind speeds for an outdoor unit. Because of simulating a pressure signal by detecting a temperature signal, the air conditioner and the method avoid direct contact between a wind speed control system and a refrigerant system so as to avoid leakage.
Owner:HAIER GRP CORP +1

Method for preparing bimetal composite plate by stirring friction braze welding

The invention discloses a method for preparing a bimetal composite plate by stirring friction braze welding. The method comprises that: a plate with small hardness is used as a covering layer metal plate; a plate with high hardness is used as a base layer metal plate; the covering layer metal plate and the base layer metal plate are horizontally fixed on a working platform surface in a lap joint mode; solders which can generate eutectic reaction with one of the upper/base layer metal plates are preset between the upper/base layer metal plates; a non-needle type cylinder friction device is arranged over the covering layer metal plate; the non-needle type cylindrical friction device is made to rotate and be pressed to be closely contacted with the surface layer of the covering layer metal plate, but not penetrate the covering layer metal plate, and the non-needle type cylindrical friction device rotates in the original position or moves forward along the surface of the covering layer metal plate while rotating; by utilizing frictional heat to melt the solders, the upper/base layer metal plates are both quickly melted in the solders, thereby achieving excellent interface combination; and the excessive solders are squeezed out, and a thin and dense soldering seam is formed, so that the bimetal composite plate is prepared. Compared with the braze welding in a furnace, the method has the advantages of high efficiency, energy conservation, pressure lead-in, unnecessary soldering flux and gas protection and short holding time at a high temperature.
Owner:XI AN JIAOTONG UNIV

Silicon dioxide composite anode material for lithium ion battery, as well as preparation method and application of silicon dioxide composite anode material

The invention discloses a silicon dioxide composite anode material for a lithium ion battery, as well as a preparation method and an application of the silicon dioxide composite anode material. The silicon dioxide composite anode material is prepared from the components of silicon dioxide powder and a conductive carbon layer with the surface of the silicon dioxide powder is uniformly and densely coated. With the adoption of the silicon dioxide composite anode material, the original component structure of an SiO material system is kept, so that the lower volume effect is ensured; the silicon dioxide dense carbon layer coating structure is successfully realized by adopting the technologies of mixing kneading, sheet rolling, press forming and the like, and thus the first coulombic efficiency of the silicon dioxide composite anode material is remarkably increased, and can reach a theoretical value being larger than 77 percent, and the cycle performance and the conductive characteristic are also remarkably improved, so that the silicon dioxide composite anode material is suitable for being charged and discharged with the large rate and can be applied to the power market.
Owner:BTR NEW MATERIAL GRP CO LTD +1

Surface Raman and infrared spectroscopy double-enhanced detecting method based on graphene and nanogold compounding

Provided is a surface Raman and infrared spectroscopy double-enhanced detecting method based on graphene and nanogold compounding.According to the method, light sources, a lens, a graphene nanobelt and gold nanoparticle composite substrate, an infrared Fourier spectrograph and a Raman spectrometer are included.Infrared light waves and visible light waves emitted by the infrared light source and the laser light source respectively pass through a beam combiner and then irradiate the graphene nanobelt and gold nanoparticle composite substrate, after the light waves and trace molecules adsorbed on the substrate interact, reflected light is gathered by the focusing lens to enter the infrared Fourier spectrograph, and meanwhile scattered light is gathered into the Raman spectrometer.Raman scattering signals of the trace molecules can be enhanced through the local area plasma effect of the gold nanoparticles, and meanwhile infrared absorption spectrum signals of the trace molecules can be dynamically enhanced through the graphene surface plasma effect within the broadband range.According to the method, double enhancement of surface Raman and broadband infrared spectroscopy signals is achieved on the same substrate, and the advantages of being wide in enhancement wave band, high in detecting sensitivity, wide in detected matter variety range, good in stability and the like are achieved.
Owner:CHONGQING UNIV

Composite silicon negative electrode material, and preparation method and application thereof

The invention relates to a composite silicon negative electrode material. The composite silicon negative electrode material comprises nanometer silicon, a nanometer composite layer coating the surface of nanometer silicon and a conductive carbon layer uniformly coating the nanometer composite layer, wherein the nanometer composite layer is silicon oxide and metal alloy. According to the composite silicon negative electrode material with a three-layer structure, the nanometer composite layer composed of the silicon oxide and the metal alloy coating the surface of the silicon oxide effectively reduces volume expansion of the nanometer silicon, maintains the characteristic of high conductivity of the silicon material, improves mobility of lithium ions, prevents direct contact between a silicon negative electrode and an electrolyte, and can form a hard SEI film on the surface of the composite silicon negative electrode material, thereby allowing the cycle performance of the material to be substantially enhanced. The composite silicon negative electrode material has the characteristics of high capacity (greater than 1500 mAh / g), long cycle life (with a capacity retention ratio of more than 90% after 300 cycles) and high conductivity. The preparation method for the composite silicon negative electrode material is simple, easily controllable, and applicable to industrial production.
Owner:DINGYUAN NEW ENERGY TECH CO LTD

Silicon-carbon composite negative pole material preparation method and lithium ion battery

The invention relates to a silicon-carbon composite negative pole material preparation method and a lithium ion battery. The preparation method comprises putting nanometer silicon and graphite micro-powder into a ball mill, carrying out ball milling uniform dispersion in an organic solvent environment, carrying out vacuum drying, putting the dried mixture and asphalt into a cone-type mixer, carrying out coarse mixing, putting the mixed powder subjected to coarse mixing into a mechanical fusion machine, carrying out mechanical fusion, carrying out heat treatment in an inert gas protective atmosphere and carrying out cooling to obtain the silicon-carbon composite negative pole material. The preparation method carries out asphalt softening coating on nanometer silicon so that silicon particle and electrolyte direct contact is avoided, a capacity reduction rate is delayed, a lithium ion diffusion path is shortened, an electrode material electron conduction loss is avoided, and first charge-discharge efficiency, a charge-discharge electric capacity and cycle performances are improved. Before coating, nanometer silicon is dispersed through graphite micro-powder so that it is avoided that in asphalt coating, nanometer silicon aggregation causes local capacity excess and nanometer silicon is uniformly dispersed.
Owner:浙江超恒动力科技有限公司

Fast ion conductor modified lithium ion battery cathode material lithium cobalt oxide with fast ion conductor and preparation method

The invention discloses a fast ion conductor modified lithium ion battery anode material lithium cobalt oxide comprising lithium cobalt oxide and a lithium fast ion conductor layer coating the outer surface of the lithium cobalt oxide. The lithium fast ion conductor layer comprises the components of Li1+x+yAxB2-xSiyP3-yO12-eN, wherein A is one or more than one of Al, Sc, La, Cr, Fe, Tl, Eu and In, B is one or more than one of Ti, Zr and Hf, N is one or more than one of Li2O, MgO and Y2O3, and x, y and e are all not less than 0 and not more than 2. The preparation method of the fast ion conductor modified lithium ion battery anode material lithium cobalt oxide comprises the following steps of: evenly mixing A, B an N sources, lithium salt, a silicon source, a phosphorus source and a lithium ion battery anode material to be modified, carrying out the processes of drying, roasting, crushing, screening and the like to prepare the lithium ion battery anode material coated with a phosphate system on the surface. The modified anode material lithium cobalt oxide not only can work under a higher voltage and greatly improve the battery capacity, but also greatly improves the cycle performance, the multiplying power performance, the overcharging performance and the safety performance thereof.
Owner:TIANJIN B&M SCI & TECH

Composite porous current collector, and preparation method and application thereof

The invention provides a composite porous current collector, and a preparation method and an application thereof. The composite porous current collector comprises a porous electron conducting layer with through holes and an electron insulating layer with through holes, wherein the porosity of the through holes of porous electron conducting layer is not less than the porosity of the through holes of the electron insulating layer, a position of the porous electron conducting layer corresponding to the position of the through hole of the electron insulating layer is a through hole, and a position of the porous electron conducting layer corresponding to the position of the non-through hole of the electron insulating layer can be a through hole, and also can be a blind hole or a rough surface. The electron insulating layer is adjacent to an isolation layer, so puncture of precipitated lithium dendrite to a diaphragm is prevented, direct contact of the electron conducting layer is avoided, and the safety of a battery is improved; the above corresponding through hole structure is in favor of transferring lithium ions, so the internal resistance of the battery is reduced; the hole structure of the porous electron conducting layer and the homogeneous rough surface are in favor of full contact of an electrode active substance with the current collector, the current is uniformly distributed, and the current collection effect is improved; and the preparation method adopting airflow punching has the advantages of simplicity, easy implementation, cleanness, energy saving, combination of other various enforcement modes, and convenience for production and application.
Owner:南京竞予能源有限公司

Hardware system for cloud development and testing

InactiveCN103067502ADevelopment and testing are safe, efficient and fastMeet different project needsSoftware testing/debuggingTransmissionComputer hardwareSoftware development
The invention discloses a hardware system for cloud development and testing. The hardware system for the cloud development and testing is characterized in that after software development or testing software requirements or hardware requirements are finished customizing by a terminal, a server can automatically found a virtual machine of conducting software development or testing for the terminal; after a user of the virtual machine pays for purchases, a running environment, functional components, data, tools or systems corresponding to the virtual machine are uniformly stored and installed, and run on an independent hardware device, and are offered to the user; after the independent hardware device is accessed to the server through a network, the software development and testing data on the independent hardware device of the user can be automatically synchronized to the virtual machine; after the independent hardware device is accessed to the server through the network, the software development and the testing data generated by the virtual machine in the independent hardware device can also be automatically synchronized to the independent hardware device. According to the hardware system for the cloud development and testing, the software development and test work can be placed and conducted on a cloud platform uniformly. In addition, equipment is ordered through a remote custom software and hardware configuration, so that the sale model of integrated equipment of software and hardware such as a computer, a mobile phone, a tablet computer, a mobile television, a smart television and a game machine can be thoroughly changed.
Owner:BEYONDSOFT SHANGHAI CO LTD

Leg and wheel hybrid type hydraulic mechanical leg

The invention discloses a leg and wheel hybrid type hydraulic mechanical leg. The leg and wheel hybrid type hydraulic mechanical leg comprises a thigh hydraulic cylinder, a shank hydraulic cylinder, thigh rod plates installed in parallel, shank rod plates installed in parallel, main body connecting plates installed in parallel and thigh hydraulic cylinder connecting plates installed in parallel. A main body cylinder connecting pillar is arranged between a square main body fixing block of the main body connecting plates and a square main body fixing block of the thigh hydraulic cylinder connecting plates. The two main body connecting plates are hinged to the two thigh rod plates respectively. The two thigh rod plates are hinged to the two shank rod plates respectively. A thigh tail end rod parallel to the shank rod plates is fixed between the two shank rod plates through a square shank fixing block. The two ends of the thigh hydraulic cylinder are hinged to the position between the upper portions of the two thigh rod plates and the position between the bottoms of the two thigh hydraulic cylinder connecting plates. The two ends of the shank hydraulic cylinder are hinged to the position between the middles of the two shank rod plates and a side arm plate extending from the two thigh rod plates. According to the leg and wheel hybrid type hydraulic mechanical leg, the structure is simple, control is convenient due to the two hydraulic cylinders, quick switching between two proceeding modes can be guaranteed due to a wheel installed at the knee joint position, and the leg and wheel hybrid type hydraulic mechanical leg can be applied to a four-foot or six-foot robot.
Owner:ZHEJIANG UNIV

Preparation method of nano-network conductive polymer coated lithium iron phosphate anode material

The invention discloses a preparation method of a nano-network conductive polymer coated lithium iron phosphate anode material. The preparation method is characterized in that: a surfactant is used as a template; and a conductive polymer monomer is subjected to in-situ polymerization on a lithium iron phosphate surface in a low-temperature acid solution medium and a nano-network structure is grown; and thus, the nano-network conductive polymer coated lithium iron phosphate anode material is formed. The special shape of the nano-network conductive polymer is favorable for a current carrier to be conducted among polymer aggregate particles; and the nano-network conductive polymer has high current carrier mobility ratio, and can effectively connect surfaces among lithium iron phosphate particles when coated on the lithium iron phosphate surface to form an effective conductive network, so the lithium iron phosphate conductivity is significantly improved, and the contact resistance and electrode polarization among the particles are reduced to ensure that the electrochemical performance of an electrode material is greatly improved. The preparation method has a simple process and readily-available raw materials, and is suitable for carrying out industrial large-scale production.
Owner:ZHONGKE LITHIUM BATTERY NEW ENERGY CO LTD

Autonomous navigation and man-machine coordination catching operating system of benthic organism catching robot

The invention relates to an autonomous navigation and man-machine coordination catching operating system of a benthic organism catching robot, which comprises a catching robot, a computer used for carrying out comprehensive analysis processing and judgment on catching site and the state of the catching robot and used for providing remote intervention and management for catching management personnel in man-machine coordination catching operation, a mother ship used for carrying the management personnel and collecting and transporting catching objects, and a GPS (Global Positioning System) used for positioning the spatial location of the mother ship; information interaction is carried out between Agent in the catching robot and the mother ship on the water surface, and the actions of benthic walking, identification and space orientation of the catching objects, control catching and the like are autonomously finished. The autonomous navigation and man-machine coordination catching operating system of the benthic organism catching robot is simple in mechanism, low in control complexity, limited in intelligentization, high in catching efficiency, good in environmental suitability and low in manufacturing and maintenance costs, and can pointedly realize catching.
Owner:ZHEJIANG UNIV OF TECH
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